CN106366552B - 一种解决塑料制件光腐蚀的abs合金材料及其制备方法 - Google Patents
一种解决塑料制件光腐蚀的abs合金材料及其制备方法 Download PDFInfo
- Publication number
- CN106366552B CN106366552B CN201610767694.0A CN201610767694A CN106366552B CN 106366552 B CN106366552 B CN 106366552B CN 201610767694 A CN201610767694 A CN 201610767694A CN 106366552 B CN106366552 B CN 106366552B
- Authority
- CN
- China
- Prior art keywords
- photoetch
- plastic part
- alloy material
- abs alloy
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920003023 plastic Polymers 0.000 title claims abstract description 36
- 239000004033 plastic Substances 0.000 title claims abstract description 36
- 239000000956 alloy Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 35
- 230000004888 barrier function Effects 0.000 claims abstract description 22
- 239000000843 powder Substances 0.000 claims abstract description 18
- 239000004065 semiconductor Substances 0.000 claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 12
- 238000005453 pelletization Methods 0.000 claims abstract description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 20
- 230000003078 antioxidant effect Effects 0.000 claims description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- 239000004611 light stabiliser Substances 0.000 claims description 17
- 229910052757 nitrogen Inorganic materials 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 10
- 239000000314 lubricant Substances 0.000 claims description 10
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 9
- 239000011787 zinc oxide Substances 0.000 claims description 9
- 239000006229 carbon black Substances 0.000 claims description 7
- 239000007822 coupling agent Substances 0.000 claims description 7
- 150000001412 amines Chemical class 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- 238000005253 cladding Methods 0.000 claims description 6
- TXQVDVNAKHFQPP-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] octadecanoate Chemical group CCCCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO TXQVDVNAKHFQPP-UHFFFAOYSA-N 0.000 claims description 5
- 239000012964 benzotriazole Substances 0.000 claims description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 150000002989 phenols Chemical class 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 2
- SHLNMHIRQGRGOL-UHFFFAOYSA-N barium zinc Chemical compound [Zn].[Ba] SHLNMHIRQGRGOL-UHFFFAOYSA-N 0.000 claims description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 2
- 239000003077 lignite Substances 0.000 claims description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 2
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims 1
- 229960002380 dibutyl phthalate Drugs 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 239000010445 mica Substances 0.000 claims 1
- 229910052618 mica group Inorganic materials 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 239000000454 talc Substances 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 8
- 230000007774 longterm Effects 0.000 abstract description 3
- 238000013461 design Methods 0.000 abstract description 2
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 description 14
- 239000000047 product Substances 0.000 description 13
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 9
- -1 silicon Alkane Chemical class 0.000 description 7
- 238000004381 surface treatment Methods 0.000 description 7
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexamethylene diamine Natural products NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 4
- 238000010792 warming Methods 0.000 description 4
- 238000004378 air conditioning Methods 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 description 2
- 229920007019 PC/ABS Polymers 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000000088 plastic resin Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- CHIHQLCVLOXUJW-UHFFFAOYSA-N benzoic anhydride Chemical compound C=1C=CC=CC=1C(=O)OC(=O)C1=CC=CC=C1 CHIHQLCVLOXUJW-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007688 edging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002305 electric material Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000005494 tarnishing Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3009—Sulfides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明公开了一种解决塑料制件光腐蚀的ABS合金材料及其制备方法，其是将微纳半导体粉体与ABS树脂进行混合，再将除光阻隔剂外的其他物料混合均匀后，加入到挤出机中，再将光阻隔剂以侧喂料的方式加入，熔融后进行挤出、冷却、风干、切粒得到解决塑料制件光腐蚀的ABS合金材料。本发明方法制备方法简单，制得的ABS合金材料可以实现超高的清晰度和透度，颠覆了塑料隐藏显示制件透度提高的路径，成功解决塑料隐藏显示件透度与清晰度相互矛盾的囧途，同时从根本上解决塑料制件的光腐蚀现象，保证长期光照表面无任何印迹。本产品优异的抗光腐蚀性，解决了困扰家电行业十几年的光腐蚀现象，使得家电行业的隐藏显示设计不再受到局限。
Description
技术领域
本发明涉及一种解决塑料制件光腐蚀的ABS合金材料及其制备方法，属于高分子材料技术领域。
背景技术
目前，世界各国家电行业的发展越来越从人性出发，智慧家居正在慢慢走近我们的生活的方方面面，人类对于家电的需求不在满足于只是简简单单的电器功能使用，更希望家电成为生活装饰、健康等提高舒适感的一部分。“晨之美、食有度、居无忧、呼倍畅、享私厨、沐唤新、枕安眠”这种智慧的生活场景成为家电发展的必然趋势。
隐藏显示就是这场家电革命中闪现出的重要的一员大将，隐藏显示即可以保持家电面板的一体化，大大提高了外观的美感，同时防止了水和外界液体的浸入，提高了安全性。
然而LED灯长时间的光辐照，塑料树脂中的微量物质会发生一定变化，光路会被击穿，使得塑料树脂变白变紫，在制件表面显现出一个数字的印子，难以消退。这个瓶颈严重制约了家电的发展。
目前改善家电材料光腐蚀现象的文献只有锦湖日立有报道，但是以ABS为基材采用光致发光技术，同时采用光阻隔剂解决这一问题的文献的国内未见报道。专利号CN201410770776.1、名称为一种可改善空调面板光腐蚀现象的PC/ABS组合物及其制备方法，该专利中以PC/ABS为基材，未使用光阻隔剂，TIO2未经接枝和表面包覆处理，未使用光屏蔽剂，其只能改善空调面板的光腐蚀现象不能从根本上解决上述问题。
发明内容
为了解决现有技术的不足和缺陷，本发明提供了一种解决塑料制件光腐蚀的ABS合金材料，该材料具有较好的清晰度和透度，且从根本上解决了塑料制件的光腐蚀现象，保证长期光照表面无任何印迹，同时其外观具有同金属喷涂同样的美学效果，且其制备程序简单、无污染。
为了实现上述目的本发明采用如下技术方案：
本发明的一种解决塑料制件光腐蚀的ABS合金材料，由以下重量份的原料组分制成：
上述所述的一种解决塑料制件光腐蚀的ABS合金材料中，所述微纳半导体粉体为纳米ZnO和/或纳米ZnS。
上述所述的一种解决塑料制件光腐蚀的ABS合金材料中，所述光阻隔剂为使用硅烷偶联剂进行表面改性处理过的矿物，所述的矿物为超细滑石粉、纳米碳酸钙、硫酸钡、云母粉、硅灰石、聚酰胺纤维中的至少一种。
上述所述的一种解决塑料制件光腐蚀的ABS合金材料中，所选改性TiO2为经接枝和包覆处理的金红石型纳米级TIO2，粒径为10～100nm。所述接枝是指纳米级TIO2接枝丙烯晴单体得接枝产物，所述包覆是指接枝产物与偶联剂形成包覆产物。
接枝的方法可以为：在1000ML圆底烧瓶中加入纳米级TIO2、接枝单体丙烯晴单体、二甲苯(作为溶剂)和氧化苯甲酰或者过氧化环己酮引发剂，置于油浴恒温槽中，边搅拌边通入氮气，升温至110-130℃，进行接枝反应50-70min，得接枝产物；其中，TIO2、丙烯晴单体、二甲苯三者重量比2-3:1:5-10，引发剂用量可为上述三者总重量的0.1-0.5％。
包覆方法可以为：将上述接枝产物在高速搅拌下，升温至90～100℃时加入偶联剂(也可以是偶联剂的稀释溶液如重量浓度10-20t％偶联剂的丙酮溶液或二甲苯溶液等)，碱调pH值为10-11，温度达到100-110℃，反应700-750h即得改性TiO2。
上述所述的一种解决塑料制件光腐蚀的ABS合金材料中，所用抗氧剂为受阻酚类抗氧剂、亚磷酸类抗氧剂或者复合型抗氧剂或者绿色抗氧剂。
所述的受阻酚类抗氧剂选自2,2-亚甲基-双(4-甲基-6-叔丁基酚)、N,N-[3-(3,5-二叔丁基-4-羟基苯基)丙酰]六甲撑二胺、4,4'-硫代双(6-叔丁基-3-甲基苯酚)或者3,9-双[1,1-二甲基-2-[(3-叔丁基-4-羟基-5-甲基苯基)丙酰氧基]乙基]-2,4,8,10-四氧杂螺[5.5]十；复合型抗氧剂为N，N’-双[3-(3’,5’-二叔丁基-4’-羟基苯基)丙酰己二胺；绿色抗氧剂为a-维生素E或者对甲苯酚与双环戊二烯丁基化合反应生成物。
上述所述的一种解决塑料制件光腐蚀的ABS合金材料中，所述润滑剂选自季戊四醇硬脂酸酯、N,N-已撑双硬脂酰胺、褐煤蜡、甘油单酯酸值、酰胺蜡、邻苯二甲酸二辛脂、丁基硬脂酸酯中的至少一种。
上述所述的一种解决塑料制件光腐蚀的ABS合金材料中，所述光稳定剂为受阻胺类、亚磷酸酯类光稳定剂和苯并三唑类光稳定剂中的至少一种。
上述所述的一种解决塑料制件光腐蚀的ABS合金材料中，所述光屏蔽剂为OnCapLight Shield、炭黑、二氧化钛、氧化锌、锌钡中的一种或者几种。炭黑是吸附剂，而氧化锌和二氧化钛稳定剂为白色颜料，可使光反射而呈现白色。
本发明还提供了上一种解决塑料制件光腐蚀的ABS合金材料的制备方法，其包括步骤：首先将微纳半导体粉体与ABS树脂在混料机中进行混合，再将除光阻隔剂外的其他物料加入混合均匀后，加到双螺杆挤出机的料斗中，同时将光阻隔剂以侧喂料的方式加入，经熔融共混挤出、冷却、风干、切粒成解决塑料制件光腐蚀的ABS合金材料。
本发明中所述微纳半导体粉体光致发光可吸收对材料危害最大的紫外波段，同时转化为可见光源，大大提高了材料本身的抗变色能力，使隐藏显示塑料件抗光腐蚀性大大提高，宏观表现为材料颜色不变。
本发明采用微纳半导体粉体，采用了二次光致发光技术，可在一定范围内将源头紫外光进行转变，降低了有害光的强度，同时加入自制的光阻隔剂和光屏蔽剂，阻止了有害紫外光的投射，大大降低了光在塑料制件中蚀刻强度，从而达到消除光的蚀刻材料现象。
本产品超高的清晰度和透度(透光度9-11％；雾度小于80)，颠覆了塑料隐藏显示制件透度提高的路径，成功解决塑料隐藏显示件透度与清晰度相互矛盾的囧途，同时从根本上解决塑料制件的光腐蚀现象，保证长期光照表面无任何印迹，推动了家电行业尤其是空调业品质的变革。本产品优异的抗光腐蚀性，解决了困扰家电行业十几年的光腐蚀现象，使得家电行业的隐藏显示设计不再受到局限。
具体实施方式
下述实施例是对于本发明内容的进一步说明以作为对本发明技术内容的阐释，但本发明的实质内容并不仅限于下述实施例所述，本领域的普通技术人员可以且应当知晓任何基于本发明实质精神的简单变化或替换均应属于本发明所要求的保护范围。
所选改性TiO2为经接枝和包覆处理的金红石型纳米级TIO2，粒径为10～100nm。所述接枝是指纳米级TIO2接枝丙烯晴单体得接枝产物，所述包覆是指接枝产物与偶联剂形成包覆产物。具体为：在1000ML圆底烧瓶中加入纳米级TIO2、接枝单体丙烯晴单体、二甲苯、引发剂过氧化环己酮，置于油浴恒温槽中，边搅拌边通入氮气，升温至120℃，进行接枝反应60min，得接枝产物；其中，TIO2、丙烯晴单体、二甲苯三者重量比3:1:6，引发剂用量为上述三者总重量的0.2％；将上述接枝产物在高速搅拌下，升温至95℃时加入10wt％硅烷偶联剂的丙酮溶液，碱调pH值为11，温度达到105℃，反应720h即得改性TiO2。
实施例1：
上述光阻隔剂为硅烷偶联剂表面处理的超细滑石粉，抗氧剂为N，N’-双[3-(3’,5’-二叔丁基-4’-羟基苯基)丙酰己二胺，润滑剂为季戊四醇硬脂酸酯，光稳定剂为受阻胺类HS-944，光屏蔽剂为炭黑，微纳半导体粉体为纳米ZnO与纳米ZnS的混合。
制备方法如下：
首先将微纳半导体粉体与ABS树脂在混料机中进行混合，再将除光阻隔剂外的其他物料加入混合均匀后，加到双螺杆挤出机的料斗中，同时将光阻隔剂以侧喂料的方式加入，经熔融共混挤出、冷却、风干、切粒成解决塑料制件光腐蚀的ABS合金材料。
比较例1：(不添加微纳半导体粉体)
上述光阻隔剂为硅烷偶联剂表面处理的纳米碳酸钙，抗氧剂为2,2-亚甲基-双(4-甲基-6-叔丁基酚)，润滑剂为N,N-已撑双硬脂酰胺，光稳定剂为苯并三唑类光稳定剂UV-5411，光屏蔽剂为OnCap Light Shield。
制备方法如下：
称取以上重量百分含量的各组分，并加入高混料机中混合，将混合好的物料加到双螺杆挤出机的料斗中，解决塑料制件光腐蚀的ABS合金材料.
比较例2：(不添加光阻隔剂)
上述光阻隔剂为硅烷偶联剂表面处理的纳米碳酸钙，抗氧剂为2,2-亚甲基-双(4-甲基-6-叔丁基酚)，润滑剂为N,N-已撑双硬脂酰胺，光稳定剂为苯并三唑类光稳定剂UV-5411，光屏蔽剂为OnCap Light Shield。
制备方法如下：
首先将微纳半导体粉体与ABS树脂在混料机中进行混合，再将其他物料加入混合均匀后，加到双螺杆挤出机的料斗中，经熔融共混挤出、冷却、风干、切粒成解决塑料制件光腐蚀的ABS合金材料。
比较例3：(不添加光屏蔽剂)
上述光阻隔剂为硅烷偶联剂表面处理的纳米碳酸钙，抗氧剂为2,2-亚甲基-双(4-甲基-6-叔丁基酚)，润滑剂为N,N-已撑双硬脂酰胺，光稳定剂为苯并三唑类光稳定剂UV-5411。
制备方法如下：
称取以上重量百分含量的各组分，并加入高混料机中混合，将混合好的物料加到双螺杆挤出机的料斗中，解决塑料制件光腐蚀的ABS合金材料.
表1合金材料主要物性指标：
实施例2
上述光阻隔剂为硅烷偶联剂表面处理的硫酸钡，抗氧剂为N，N’-双[3-(3’,5’-二叔丁基-4’-羟基苯基)丙酰己二胺，润滑剂为季戊四醇硬脂酸酯，光稳定剂为受阻胺类HS-944，光屏蔽剂为炭黑，微纳半导体粉体为纳米ZnO与纳米ZnS的混合。
制备方法同实施例1。
比较例4：
采用未改性的Tio2替换实施例2中的改性Tio2，其他同实施例2。
实施例3
上述光阻隔剂为硅烷偶联剂表面处理的超细滑石粉，抗氧剂为N，N’-双[3-(3’,5’-二叔丁基-4’-羟基苯基)丙酰己二胺，润滑剂为季戊四醇硬脂酸酯，光稳定剂为受阻胺类HS-944，光屏蔽剂为炭黑，微纳半导体粉体为纳米ZnO与纳米ZnS的混合。
制备方法同实施例1。
实施例4
上述光阻隔剂为硅烷偶联剂表面处理的超细滑石粉，抗氧剂为N，N’-双[3-(3’,5’-二叔丁基-4’-羟基苯基)丙酰己二胺，润滑剂为季戊四醇硬脂酸酯，光稳定剂为受阻胺类HS-944，光屏蔽剂为炭黑，微纳半导体粉体为纳米ZnO与纳米ZnS的混合。
制备方法同实施例1。
表2合金材料主要物性指标：
从以上表格中可以看出，实验可以显著解决困扰家电行业的光腐蚀现象。以上所述尽是本发明的优选方案，应当指出，对于本技术领域的普通技术人员，再不脱离本发明的前提下，还可以做出若干改进和补充，这些改进和补充也应视为本发明的保护范围。
Claims (7)
1.一种解决塑料制件光腐蚀的ABS合金材料，其特征在于，由以下重量份的原料组分制成：
ABS树脂 20-90份
光阻隔剂 2~10份
改性TiO2 0.1~0.8份
抗氧剂 0.1-0.8份
润滑剂 0.1-2份
光稳定剂 0.2-0.5份
光屏蔽剂 0.2-3份
微纳半导体粉体 2-5份；
所述微纳半导体粉体为纳米ZnO和/或纳米ZnS；
所述光阻隔剂为使用硅烷偶联剂进行表面改性处理过的矿物，所述的矿物为超细滑石粉、纳米碳酸钙、硫酸钡、云母粉、硅灰石、聚酰胺纤维中的至少一种；
所选改性TiO2为经接枝和包覆处理的金红石型纳米级TiO2，粒径为10~100nm。
2.根据权利要求1所述的一种解决塑料制件光腐蚀的ABS合金材料，其特征在于， 所述接枝是指纳米级TiO2接枝丙烯晴单体得接枝产物，所述包覆是指接枝产物与偶联剂形成包覆产物。
3.根据权利要求1所述的一种解决塑料制件光腐蚀的ABS合金材料，其特征在于，所用抗氧剂为受阻酚类抗氧剂、亚磷酸类抗氧剂或者复合型抗氧剂或者绿色抗氧剂。
4.根据权利要求1所述的一种解决塑料制件光腐蚀的ABS合金材料，其特征在于，所述润滑剂选自季戊四醇硬脂酸酯、N,N-已撑双硬脂酰胺、褐煤蜡、甘油单脂酸酯、酰胺蜡、邻苯二甲酸二辛脂、丁基硬脂酸酯中的至少一种。
5.根据权利要求1所述的一种解决塑料制件光腐蚀的ABS合金材料，其特征在于，所述光稳定剂为受阻胺类、亚磷酸酯类光稳定剂和苯并三唑类光稳定剂中的至少一种。
6.根据权利要求1所述的一种解决塑料制件光腐蚀的ABS合金材料，其特征在于，所述光屏蔽剂为OnCap Light Shield、 炭黑、二氧化钛、氧化锌、锌钡中的一种或者几种。
7.权利要求1-6任一项所述ABS合金材料的制备方法，其特征在于，包括下述步骤：首先将微纳半导体粉体与ABS树脂在混料机中进行混合，再将除光阻隔剂外的其他物料加入混合均匀后，加到双螺杆挤出机的料斗中，同时将光阻隔剂以侧喂料的方式加入，经熔融共混挤出、冷却、风干、切粒成解决塑料制件光腐蚀的ABS合金材料。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610767694.0A CN106366552B (zh) | 2016-08-29 | 2016-08-29 | 一种解决塑料制件光腐蚀的abs合金材料及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610767694.0A CN106366552B (zh) | 2016-08-29 | 2016-08-29 | 一种解决塑料制件光腐蚀的abs合金材料及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106366552A CN106366552A (zh) | 2017-02-01 |
| CN106366552B true CN106366552B (zh) | 2019-01-04 |
Family
ID=57902536
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610767694.0A Active CN106366552B (zh) | 2016-08-29 | 2016-08-29 | 一种解决塑料制件光腐蚀的abs合金材料及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106366552B (zh) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115536977B (zh) * | 2022-10-21 | 2025-09-23 | 上海金山锦湖日丽塑料有限公司 | 一种适合户外使用的abs材料及其制备方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL121883C (zh) * | 1962-10-31 | |||
| JPH06271758A (ja) * | 1993-03-17 | 1994-09-27 | Mitsubishi Gas Chem Co Inc | 耐光性樹脂組成物 |
| JP4587651B2 (ja) * | 2003-07-29 | 2010-11-24 | 旭化成ケミカルズ株式会社 | スチレン系樹脂組成物 |
| CN101885895B (zh) * | 2010-07-28 | 2012-07-04 | 太仓市华鼎塑料有限公司 | 一种abs树脂的改性方法及改性abs树脂 |
| CN103183891B (zh) * | 2013-04-02 | 2014-12-03 | 扬州大学 | 基于ZnO量子点的紫外吸收可见透明的有机玻璃及制备 |
| CN103146133A (zh) * | 2013-04-10 | 2013-06-12 | 苏州旭光聚合物有限公司 | 一种具有抗光老化的纳米TiO2/ABS复合材料及其制备方法 |
| CN103819867B (zh) * | 2014-02-19 | 2017-10-03 | 广东美的制冷设备有限公司 | 抗光腐蚀型abs组合物、透光板和空调器 |
| CN105237941A (zh) * | 2015-11-18 | 2016-01-13 | 上海瀚氏模具成型有限公司 | 一种耐光照老化abs塑料及其制备方法 |
-
2016
- 2016-08-29 CN CN201610767694.0A patent/CN106366552B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN106366552A (zh) | 2017-02-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101440189B (zh) | 冰箱板材专用色母粒及其制备方法 | |
| CN107987503A (zh) | 一种具有金属光泽免喷涂的高冲击pc合金材料及其制备方法 | |
| CN103408800A (zh) | 一种色母料用高分散性改性碳酸钙及其制备方法 | |
| TW200837017A (en) | Transparent zinc sulphide having a high specific surface area | |
| CN102888071A (zh) | 改善白度和闪烁效果的美学树脂及其制备方法 | |
| WO2017121223A1 (zh) | 一种pbat树脂组合物 | |
| CN106810842A (zh) | 一种耐候阻燃可用于室外灯罩的光扩散pc及其制备方法 | |
| CN103602194A (zh) | 一种丙烯酸酯防水涂料 | |
| CN109265902B (zh) | 一种阻燃abs材料及其制备方法和应用 | |
| CN106366552B (zh) | 一种解决塑料制件光腐蚀的abs合金材料及其制备方法 | |
| CN105348816A (zh) | 一种高强度高抗撕硅橡胶及其制备方法和使用方法 | |
| CN113429676B (zh) | 一种具有抗菌功能的耐磨聚丙烯靴套及其制备方法 | |
| CN108299690A (zh) | 聚氨酯鞋底及其制备方法 | |
| FI125473B (en) | Titanium dioxide pigment | |
| CN110452558B (zh) | 一种制备硬质pvc用纳米碳酸钙的方法 | |
| CN106916429A (zh) | 白色高韧性高灼热丝起燃温度聚碳酸酯组合物及其制备方法 | |
| CN106221014A (zh) | 一种纳米铜抗菌塑料母粒 | |
| WO2007046661A1 (en) | Ethylene vinyl acetate based polymer foams with low density and injection preparation method thereof, and materials for medical and healthcare use | |
| CN108912910A (zh) | 一种防霉涂料 | |
| CN104559390A (zh) | 乳胶漆合成粉 | |
| CN106243704A (zh) | 一种led用散热呼吸器尼龙材料及其制备方法 | |
| CN108047771A (zh) | 一种复合钛白粉的制备方法 | |
| CN104962014B (zh) | 一种碳酸钙树脂材料及其制作方法 | |
| JP2006291156A (ja) | 光輝性の高い真珠光沢顔料の製造方法及びその製造方法により製造された真珠光沢顔料 | |
| CN110423438A (zh) | 一种高光泽高韧性pbt改性材料及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: High tech Zone Hefei city Anhui province 230088 City Road No. 2 Applicant after: New material Limited by Share Ltd Address before: High tech Zone Hefei city Anhui province 230088 City Road No. 2 Applicant before: Hefei Orinko Plastics Group Co., Ltd. |
|
| CB02 | Change of applicant information | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |