CN106337278A - 一种阻燃硬挺整理剂及其制备方法 - Google Patents

一种阻燃硬挺整理剂及其制备方法 Download PDF

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CN106337278A
CN106337278A CN201610726088.4A CN201610726088A CN106337278A CN 106337278 A CN106337278 A CN 106337278A CN 201610726088 A CN201610726088 A CN 201610726088A CN 106337278 A CN106337278 A CN 106337278A
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Abstract

本发明提供了一种阻燃硬挺整理剂及其制备方法。制备方法如下：（1）将氢氧化铝、失水山梨醇单油酸酯、聚乙二醇硬脂酸酯加入去离子水中搅拌10‑30分钟；（2）加入（5，5’‑二溴甲基‑1，3‑二氧2‑氧代2‑磷杂环己烷2‑氧乙基）胺、二（5，5‑二溴甲基‑1，3，2‑二氧六环磷酰）双酚、聚乙烯亚胺、月桂基乙二醇醚加入搅拌20‑40分钟；（3）将改性淀粉、瓜尔胶羟丙基三甲基氯化铵、月桂基硫酸镁、防腐剂DL605，在温度20‑40℃下超声波振荡30‑40分钟；（4）将上组分混合，高速剪切40‑60分钟。本发明的阻燃硬挺整理剂具有好的阻燃和硬挺效果，阻燃整理和硬挺整理一步即可完成。

Description

一种阻燃硬挺整理剂及其制备方法
技术领域
本发明涉及纺织材料后整理领域，具体涉及一种阻燃硬挺整理剂及其制备方法。
背景技术
各种家庭装饰布制用品，如窗帘、地毯，应当优选具有阻燃性能并且具有一定硬挺度的织物。硬挺整理是织物后整理的一种，它通过浸轧硬挺剂，使织物纱线中的纤维之间在一定条件下产粘结作用，硬挺剂在纤维内部、纤维之间或纤维的表面形成薄膜或产生交联，从而使织物产生硬挺，厚实，丰满的手感。阻燃整理也是通过后整理，使得织物获得阻燃的效果。目前，实用最多的助燃剂是无机阻燃剂，如氢氧化铝、氢氧化镁等，虽然它们具有较好的阻燃效果，但其添加量大，一般需要60wt%，达不到高效阻燃的效果。因此需要选用用量少，并且阻燃效果好的其他阻燃剂。同样，要使得织物同时获得多种功能，需要分多步进行，因此需要提供一种整理剂，实现整理的一步化。所以克服现有技术的不足是目前纺织助剂技术领域亟需解决的问题。
发明内容
要解决的技术问题：本发明的目的是提供一种阻燃硬挺整理剂，实现阻燃、硬挺整理一步化，并具有较好的阻燃效果和硬挺效果。
技术方案：一种阻燃硬挺整理剂，由以下成分按重量份制备而成：氢氧化铝10-20份、失水山梨醇单油酸酯8-15份、聚乙二醇硬脂酸酯5-10份、（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺3-9份、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚2-8份、聚乙烯亚胺1.5-4.5份、月桂基乙二醇醚0.3-1.8份、改性淀粉5-12份、瓜尔胶羟丙基三甲基氯化铵3-6份、月桂基硫酸镁2.5-4.5份、防腐剂DL605 0.5-1.5份、去离子水80-120份。
进一步优选的，所述的一种阻燃硬挺整理剂，由以下成分按重量份制备而成：氢氧化铝10-15份、失水山梨醇单油酸酯10-13份、聚乙二醇硬脂酸酯6-9份、（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺5-7份、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚3-5份、聚乙烯亚胺2.5-4.0份、月桂基乙二醇醚0.8-1.5份、改性淀粉7-12份、瓜尔胶羟丙基三甲基氯化铵4-6份、月桂基硫酸镁2.5-3.5份、防腐剂DL605 0.7-1.2份、去离子水90-115份。
上述阻燃硬挺整理剂的制备方法包括以下步骤：
（1）将氢氧化铝、失水山梨醇单油酸酯、聚乙二醇硬脂酸酯加入去离子水中搅拌10-30分钟；
（2）加入（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚、聚乙烯亚胺、月桂基乙二醇醚加入搅拌20-40分钟；
（3）将改性淀粉、瓜尔胶羟丙基三甲基氯化铵、月桂基硫酸镁、防腐剂DL605，在温度20-40℃下超声波振荡30-40分钟；
（4）将上组分混合，高速剪切40-60分钟。
进一步的，所述的一种阻燃硬挺整理剂的制备方法，所述步骤（1）中搅拌时间为15-25分钟。
进一步的，所述的一种阻燃硬挺整理剂的制备方法，所述步骤（2）中搅拌时间为25-35分钟。
进一步的，所述的一种阻燃硬挺整理剂的制备方法，所述步骤（3）中温度为25-35℃，超声波振荡时间为35分钟。
进一步的，所述的一种阻燃硬挺整理剂的制备方法，所述步骤（4）中高速剪切的时间为40-50分钟。
有益效果：本发明的阻燃硬挺整理剂，在无机阻燃剂添加较少的情况下，即可获得较好的阻燃效果，水洗前阻燃测试损毁长度为2.6cm，5次水洗以后损毁长度为2.9cm，同时，经过整理的织物硬挺性较好，水洗前的硬挺度为10.5cm，5次水洗后仍可达到9.5cm，下降率为9.5%。这种处理方法简单，获得的织物的整理效果较好。
具体实施方式
实施例1
一种阻燃硬挺整理剂，由以下按重量份制备而成：氢氧化铝10份、失水山梨醇单油酸酯15份、聚乙二醇硬脂酸酯5份、（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺3份、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚8份、聚乙烯亚胺1.5份、月桂基乙二醇醚1.8份、改性淀粉12份、瓜尔胶羟丙基三甲基氯化铵6份、月桂基硫酸镁2.5份、防腐剂DL605为0.5份、去离子水120份。
上述阻燃硬挺剂制备方法为：（1）将氢氧化铝、失水山梨醇单油酸酯、聚乙二醇硬脂酸酯加入去离子水中搅拌10分钟；（2）加入（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚、聚乙烯亚胺、月桂基乙二醇醚加入搅拌40分钟；（3）将改性淀粉、瓜尔胶羟丙基三甲基氯化铵、月桂基硫酸镁、防腐剂DL605，在温度20℃下超声波振荡30分钟；（4）将上组分混合，高速剪切40分钟。
实施例2
一种阻燃硬挺整理剂，由以下按重量份制备而成：氢氧化铝20份、失水山梨醇单油酸酯8份、聚乙二醇硬脂酸酯10份、（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺9份、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚2份、聚乙烯亚胺4.5份、月桂基乙二醇醚0.3份、改性淀粉5份、瓜尔胶羟丙基三甲基氯化铵3份、月桂基硫酸镁4.5份、防腐剂DL605为1.5份、去离子水80份。
上述阻燃硬挺剂制备方法为：（1）将氢氧化铝、失水山梨醇单油酸酯、聚乙二醇硬脂酸酯加入去离子水中搅拌30分钟；（2）加入（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚、聚乙烯亚胺、月桂基乙二醇醚加入搅拌20分钟；（3）将改性淀粉、瓜尔胶羟丙基三甲基氯化铵、月桂基硫酸镁、防腐剂DL605，在温度40℃下超声波振荡40分钟；（4）将上组分混合，高速剪切60分钟。
实施例3
一种阻燃硬挺整理剂，由以下按重量份制备而成：氢氧化铝10份、失水山梨醇单油酸酯13份、聚乙二醇硬脂酸酯9份、（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺5份、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚3份、聚乙烯亚胺2.5份、月桂基乙二醇醚0.8份、改性淀粉7份、瓜尔胶羟丙基三甲基氯化铵4份、月桂基硫酸镁2.5份、防腐剂DL605为0.7份、去离子水90份。
上述阻燃硬挺剂制备方法为：（1）将氢氧化铝、失水山梨醇单油酸酯、聚乙二醇硬脂酸酯加入去离子水中搅拌25分钟；（2）加入（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚、聚乙烯亚胺、月桂基乙二醇醚加入搅拌35分钟；（3）将改性淀粉、瓜尔胶羟丙基三甲基氯化铵、月桂基硫酸镁、防腐剂DL605，在温度25℃下超声波振荡40分钟；（4）将上组分混合，高速剪切50分钟。
实施例4
一种阻燃硬挺整理剂，由以下按重量份制备而成：氢氧化铝15份、失水山梨醇单油酸酯10份、聚乙二醇硬脂酸酯6份、（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺7份、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚5份、聚乙烯亚胺4.0份、月桂基乙二醇醚1.5份、改性淀粉12份、瓜尔胶羟丙基三甲基氯化铵6份、月桂基硫酸镁3.5份、防腐剂DL605为1.2份、去离子水115份。
上述阻燃硬挺剂制备方法为：（1）将氢氧化铝、失水山梨醇单油酸酯、聚乙二醇硬脂酸酯加入去离子水中搅拌15分钟；（2）加入（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚、聚乙烯亚胺、月桂基乙二醇醚加入搅拌25分钟；（3）将改性淀粉、瓜尔胶羟丙基三甲基氯化铵、月桂基硫酸镁、防腐剂DL605，在温度35℃下超声波振荡35分钟；（4）将上组分混合，高速剪切40分钟。
实施例5
一种阻燃硬挺整理剂，由以下按重量份制备而成：氢氧化铝12份、失水山梨醇单油酸酯12份、聚乙二醇硬脂酸酯7份、（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺6份、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚4份、聚乙烯亚胺3份、月桂基乙二醇醚1份、改性淀粉9份、瓜尔胶羟丙基三甲基氯化铵5份、月桂基硫酸镁3份、防腐剂DL605为0.9份、去离子水100份。
上述阻燃硬挺剂制备方法为：（1）将氢氧化铝、失水山梨醇单油酸酯、聚乙二醇硬脂酸酯加入去离子水中搅拌20分钟；（2）加入（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚、聚乙烯亚胺、月桂基乙二醇醚加入搅拌30分钟；（3）将改性淀粉、瓜尔胶羟丙基三甲基氯化铵、月桂基硫酸镁、防腐剂DL605，在温度30℃下超声波振荡35分钟；（4）将上组分混合，高速剪切45分钟。
对比例1
一种阻燃硬挺整理剂，由以下按重量份制备而成：氢氧化铝10份、失水山梨醇单油酸酯15份、聚乙二醇硬脂酸酯5份、聚乙烯亚胺1.5份、月桂基乙二醇醚1.8份、改性淀粉12份、瓜尔胶羟丙基三甲基氯化铵6份、月桂基硫酸镁2.5份、防腐剂DL605为0.5份、去离子水120份。
上述阻燃硬挺剂制备方法为：（1）将氢氧化铝、失水山梨醇单油酸酯、聚乙二醇硬脂酸酯加入去离子水中搅拌10分钟；（2）加入聚乙烯亚胺、月桂基乙二醇醚加入搅拌40分钟；（3）将改性淀粉、瓜尔胶羟丙基三甲基氯化铵、月桂基硫酸镁、防腐剂DL605，在温度20℃下超声波振荡30分钟；（4）将上组分混合，高速剪切40分钟。
对比例2
一种阻燃硬挺整理剂，由以下按重量份制备而成：氢氧化铝20份、失水山梨醇单油酸酯8份、聚乙二醇硬脂酸酯10份、（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺9份、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚2份、聚乙烯亚胺4.5份、月桂基乙二醇醚0.3份、改性淀粉5份、防腐剂DL605为1.5份、去离子水80份。
上述阻燃硬挺剂制备方法为：（1）将氢氧化铝、失水山梨醇单油酸酯、聚乙二醇硬脂酸酯加入去离子水中搅拌30分钟；（2）加入（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚、聚乙烯亚胺、月桂基乙二醇醚加入搅拌20分钟；（3）将改性淀粉、防腐剂DL605，在温度40℃下超声波振荡40分钟；（4）将上组分混合，高速剪切60分钟。
本发明的阻燃硬挺整理剂，在无机阻燃剂添加较少的情况下，即可获得较好的阻燃效果，水洗前阻燃测试损毁长度为2.6cm，5次水洗以后损毁长度为2.9cm，同时，经过整理的织物硬挺性较好，水洗前的硬挺度为10.5cm，5次水洗后仍可达到9.5cm，下降率为9.5%。
表1 阻燃硬挺整理剂处理织物后的各项性能指标
注：该织物为涤纶织物（经纬密度 340×170）。

Claims (7)

1.一种阻燃硬挺整理剂，其特征在于，由以下成分按重量份制备而成：氢氧化铝10-20份、失水山梨醇单油酸酯8-15份、聚乙二醇硬脂酸酯5-10份、（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺3-9份、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚2-8份、聚乙烯亚胺1.5-4.5份、月桂基乙二醇醚0.3-1.8份、改性淀粉5-12份、瓜尔胶羟丙基三甲基氯化铵3-6份、月桂基硫酸镁2.5-4.5份、防腐剂DL605为0.5-1.5份、去离子水80-120份。
2.一种阻燃硬挺整理剂，其特征在于，由以下成分按重量份制备而成：氢氧化铝10-15份、失水山梨醇单油酸酯10-13份、聚乙二醇硬脂酸酯6-9份、（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺5-7份、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚3-5份、聚乙烯亚胺2.5-4.0份、月桂基乙二醇醚0.8-1.5份、改性淀粉7-12份、瓜尔胶羟丙基三甲基氯化铵4-6份、月桂基硫酸镁2.5-3.5份、防腐剂DL605为0.7-1.2份、去离子水90-115份。
3.一种阻燃硬挺整理剂的制备方法，其特征在于，包括以下步骤：
（1）将氢氧化铝、失水山梨醇单油酸酯、聚乙二醇硬脂酸酯加入去离子水中搅拌10-30分钟；
（2）加入（5，5’-二溴甲基-1，3-二氧2-氧代2-磷杂环己烷2-氧乙基）胺、二（5，5-二溴甲基-1，3，2-二氧六环磷酰）双酚、聚乙烯亚胺、月桂基乙二醇醚加入搅拌20-40分钟；
（3）将改性淀粉、瓜尔胶羟丙基三甲基氯化铵、月桂基硫酸镁、防腐剂DL605，在温度20-40℃下超声波振荡30-40分钟；
（4）将上组分混合，高速剪切40-60分钟。
4.根据权利要求3所述的一种阻燃硬挺整理剂的制备方法，其特征在于：所述步骤（1）中搅拌时间为15-25分钟。
5.根据权利要求3所述的一种阻燃硬挺整理剂的制备方法，其特征在于：所述步骤（2）中搅拌时间为25-35分钟。
6.根据权利要求3所述的一种阻燃硬挺整理剂的制备方法，其特征在于：所述步骤（3）中温度为25-35℃，超声波振荡时间为35分钟。
7.根据权利要求3所述的一种阻燃硬挺整理剂的制备方法，其特征在于：所述步骤（4）中高速剪切的时间为40-50分钟。
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