CN106336730A - Environment-friendly aqueous black ink - Google Patents

Environment-friendly aqueous black ink Download PDF

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Publication number
CN106336730A
CN106336730A CN201610723028.7A CN201610723028A CN106336730A CN 106336730 A CN106336730 A CN 106336730A CN 201610723028 A CN201610723028 A CN 201610723028A CN 106336730 A CN106336730 A CN 106336730A
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weight portion
weight
oil
essential oil
traditional chinese
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魏本武
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/16—Writing inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/16—Writing inks
    • C09D11/17—Writing inks characterised by colouring agents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicines Containing Plant Substances (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses an environmental-friendly aqueous black ink, which has effects of long-term air negative ion releasing, air purification, human health benefiting, and a certain inhibition and killing effect on Staphylococcus, Escherichia coli, gram-positive bacteria and a variety of pathogenic bacteria and fungi, has characteristics of fragrant odor, refreshing and pressure relieving, can leave long-lasting aroma after the use, further has health effects of refreshing and fatigue eliminating, is suitable for all ages of people, and has the wide application prospect.

Description

A kind of environment-friendly water-based black ink
Technical field
The present invention relates to a kind of ink, particularly to a kind of environment-friendly water-based black ink.
Background technology
Ink is a kind of conventional consumptive material, can be used for routine office work or textile printing field, but traditional general ink is only Have writing function, do not have and refresh oneself and produce the health-care effects such as anion, user when long using with produce taediumvitae, due to The single function of traditional ink, can not meet the multi-demandses of people.
Content of the invention
In view of the shortcomings of the prior art, the present invention provides a kind of smell pure and fresh for the user of ink, has and refreshes oneself Effect and the ink of negative ion health effect, it not only can discharge negative aeroion, purify air for a long time, is good for beneficial to human body Health；Also to staphylococcus, Escherichia coli, gram-positive bacteria etc., multiple germs and fungi have certain suppression, killing action；With When fragrant odour, pure and fresh soothe the spirit, pressure of releiving, also can expelling mosquito, will not to human body produce harmful effect, have widely Application prospect.
The purpose of the present invention is achieved by the following technical solution:
A kind of environment-friendly water-based black ink it is characterised in that: by following component by weight: dispersible pigment color paste 23 weight Part, bis-phenol a19 weight portion, glycerine 4.5 weight portion, anhydrous sodium sulfate 2.3 weight portion, triethanolamine 2.7 weight portion, triethylamine 3.3 weight portions, acetone 3.6 weight portion, double thiocarbamate 0.25 weight portions, active mineral matter powder 1.7 weight portion, surface Activating agent compound 1.2 weight portion, sustained release agent 0.55 weight portion, essential oil of traditional Chinese medicine 3.85 weight portion, deionized water 62 weight portion, institute The pigment stating mill base is high-carbon black pigment, and the average grain diameter of described dispersible pigment color paste is 75nm, and described active mineral matter powder is germanium Stone, fluorite, tourmaline, gahnite are dravite and lithium electricity by weight the mixture of 2.5:3:3.7:2, wherein tourmaline By weight the mixture of 5:3, particle diameter≤13 μm of described active mineral matter powder, wherein said essential oil of traditional Chinese medicine passes through such as gas stone Lower step is prepared from,
S1, take vernonia anthelmintica 40 weight portion to clean, naturally dry, be subsequently placed in 90 DEG C of frying pans and fry to savory effusion, so Air washer 17 weight portion afterwards, is placed in constant temperature oven less than 60 DEG C and dries, water content≤6.5%；
S2, eupatorium 17.5 weight portion is cleaned, puts in salt solution and soak 3.5 hours, the salt water yield by immersion spice quality 3.7 Times, put into and steam in pot thoroughly, take out, dry, the concentration of salt solution is 27%；
S3, by calamus 13 weight portion, frutus cnidii 15 weight portion, elm bark 6 weight portion, agalloch eaglewood 6.5 weight portion, camphorwood 4 weight Part, peppermint 1.5 weight portion decontamination, put into together with step s1 and the made bulk drug of s2 and in micronizer, be crushed to 60 mesh, Prepared bulk drug powder, standby；
S4, by step s3 be obtained bulk drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, adjust extraction Pressure power 27.65mpa, 45.10 DEG C of extraction temperature, carbon dioxide flow is 0.6m3/ h, dynamic extraction 2.5h, are directly separating Kettle outlet triangular flask collects volatile oil a, standby；
S5, by raspberry 3.5 weight portion, anemone vitifolia 3.5 weight portion, Moschus 3.5 weight portion, Lysimachia foenum-graecum 1.5 weight portion, sweet Marjoram 1.75 weight portion is cleaned and is dried, and puts in micronizer together and is crushed to 70 mesh, then plus deionized water soak 6 little When, amount of water by 6.5 times of immersion bulk drug quality, dispersed with stirring is mixed well, prepared Traditional Chinese drug mixture, standby；
S6, the Traditional Chinese drug mixture that step s5 is obtained decoct 2 hours in 80 DEG C, collect distillate, and add ether to extract, distillation Then plus anhydrous sodium sulfate drying the volume ratio of liquid and ether is 2:1, takes upper oil phase, that is, volatile oil b is obtained, standby；
S7, step s4 and s6 made volatile oil a and volatile oil b mixing are mixed well prepared miscella, then sequentially add while stirring P-Cymene, lemon, grapefruit essential oil, Geranium Essential and RADIX PAEONIAE ALBA essential oil, are sufficiently stirred for 35 minutes, stand 30 points Clock, is sufficiently stirred for mixing well, filtering and impurity removing, obtains final product essential oil of traditional Chinese medicine, wherein, described miscella and P-Cymene, lemon, grape The mass ratio of shaddock oil, Geranium Essential and RADIX PAEONIAE ALBA essential oil is 1.3:0.4:0.75:0.6:0.5:0.3.
In a preferred embodiment, also include origanum oil 1.3 weight portion in the bulk drug powder of step s3 and spend in vain Dalmatian chrysanthemum 1.5 weight portion.
In a preferred embodiment, the Traditional Chinese drug mixture of step s5 also includes borneol 0.6 weight portion and lotus leaf 0.4 Weight portion.
In a preferred embodiment, the essential oil of traditional Chinese medicine of step s7 also includes eucalyptus oil 0.3 weight portion.
Equipment involved in the present invention, raw material and method, are the usual equipment using of the industry, raw material and method, This repeats no more.
Wherein each essential oil component must be sufficiently mixed with surfactant, sustained release agent, to reach slow release effect, each essential oil and The addition of anion natural mineral powder must be appropriate, and not only antibiotic and sterilizing is moreover it is possible to stable mood, so to the not normal heart Reason state has the effect in front, can purify, pacify soul, can mitigate angry and beaten sensation, and making one can be with the flat gas of the heart With ground to life, because its energy centre of equilibrium nerve, helpful to alarmed and dejected state, also have significantly flat Quiet with releive function, insomniac is had goodish relax to put console with spirit, for pacify hot-tempered enter or moody temper have Goodish effect, can improve operating efficiency.
The present invention with reference to modern Chinese medicine pharmacological research, verifies from the drug screening of existing Chinese medicine and repeatedly, gives full play to respectively Group weight portion synergy, wherein each traditional Chinese medicinal components are described as follows.
Vernonia anthelmintica: " Xinhua's book on Chinese herbal medicine outline ": fruit；Bitter, cool in nature.There is heat clearing and inflammation relieving, promoting blood circulation and removing blood stasis, the work(of desinsection Energy.For treating skin wrinkle, expelling parasite.
Eupatorium: corynebacterium diphtheriae, staphylococcus aureus, sarcine, proteus, typhoid bacillus etc. are had suppression make With.Its volatile oil infected by influenza has inhibitory action.
Calamus: its flower, stem aromatic flavour, have functions that to have one's ideas straightened out, eliminating the phlegm, dissipate wind, epidemic disease of can dispelling intelligence development, physical fitness, can Make spices or mosquito dispersing.
Frutus cnidii: nature and flavor: warm in nature, taste is pungent, hardship.Indication: warming kidney and enhancing body, eliminating dampness, wind-dispelling, desinsection.For impotence, Gong Leng, cold-dampness under band, arthritis with fixed pain caused by dampness pain in the back；Control outward eczema of vulva, married woman's pruritus vulvae, trichomonas vaginitis.
Raspberry: also known as red raspberry, tree Wo Pao, raspberry, Mai Pao (during harvesting wheat season, result, therefore named) etc., it is a kind of rose The xylophyta of common vetch section rubus, bacteriostasis 100% decoction flat board burrows method, has inhibitory action to staphylococcus, to suddenly Random vibrios also has inhibitory action.
Anemone vitifolia: 1. " Shaanxi Chinese herbal medicine ": " bitter, cool, slightly poisonous." 2. " Chinese herbal medicine is commonly used in Sichuan ": " and toil, temperature, Slightly poisonous." removing toxic substances, apocenosis myogenic, scattered stasis detumescence, have and kill maggot, wriggler, change long-pending, detumescence, the scattered stasis of blood, control stubborn dermatitis, the favus of the scalp, malaria Disease, infantile malnutrition, dysentery, carbuncle furuncle sore swells, scrofula, traumatic injury.
Elm bark: the dry bark for Ulmaceae or root skin, sweet, flat, nontoxic；Li Shui, treating stranguria, detumescence, for urine Obstructed, stranguria with turbid discharge, oedema, ulcer carbuncle on the back, erysipelas, mange.
Agalloch eaglewood: " Compendium of Materia Medica " record wood has strong antibacterial efficacy, fragrance enters spleen, god's qi-regulating, tonifying five zang organs, cough-relieving clearly Resolving sputum, warm stomach temperature spleen, ventilation analgesic therapy, can be used as medicine, be first-class medicinal material superfine product.
Camphorwood: aiphyllium, bark yellowish-brown, there is irregular longitudinal crack, on the south main product the Changjiang river and southwestern various places.Winter Cut down trees and split broken or be sawn into bulk, dry or air-dry.Timber bulk is not of uniform size, surface rufous to burgundy, and cross section is visible Annual ring.Matter is again hard.There is strong camphor fragrance, taste is refrigerant, have pungent sense, warm in nature, taste is pungent；Sensible can ward off dirty, middle benefit gas to stop Bitterly, dampness removing desinsection.
Moschus: have and have one's ideas straightened out, ward off dirty, dredging collateral, effect of the scattered stasis of blood；Control apoplexy, coma due to blocking of the respiratory system, frightened epilepsy, middle evil unhappiness, Xin Fubao Bitterly, the lump in the abdomen hypochondriac lump, traumatic injury, swollen ulcer drug." this warp ": master wards off bad odor, a kind of malaria, epilepsy convulsion, goes three worms.
Peppermint: for the dry aerial parts of labiate peppermint, dispelling wind and heat from the body, the sharp clearly head, profit pharynx promoting eruption, soothing the liver row Gas.
Lysimachia foenum-graecum: containing similar cumarin aromatic oil, essence can be refined, as spices such as tobacco and face creams；In dry product cartonning Can Anti-moth-eating clothing；Hyoscine again, has dispersing wind and cold, wards off dirty effect, evil cold headache, upper qi-stagnant lumbago, abdominal distension uncomfortable in chest, something lost when controlling Essence, ascarifuge etc., are famous and precious fragrant plants.
Marjoram: can improve that mood is depressed and addictive disease, especially to liberal-mindedness and vigorous endurance stress symptom effectively, can expansion of blood vessels, Hypotensive, mitigate and burden, help eliminate palpitaition, have excellent nerve to pacify and calm function.
P-Cymene: to bacillus anthracis, Alpha-hemolytic streptococcus, b- Streptococcus hemolyticus, corynebacterium diphtheriae, bacillus pseudodiphthericus, lung 10 kinds of Gram-positives such as diplococcoid, staphylococcus aureus, Staphylococcus citreus, white Portugal Portugal coccus, hay bacillus Aerophil all has antibacterial action, also has bacteriostasis for multiple pathomycetes.
Lemon: there are biocidal efficacies, be effective cardiotonic, be generally used for reducing blood pressure.The characteristic energy of its antibacterial Mitigate and have a sore throat, cough, catching a cold and influenza, headache, antimigraine, gout and arthritis can be mitigated.Feel hot agitation When, pure and fresh impression can be brought, help clarify the state of mind, effectively improve operating efficiency.
Geranium Essential: there is hemostasis, vasoconstriction, asthma, liver and expelling toxin, gall stone, kidney toxin expelling, kidney stone, diuresis, flesh Carnic acid pain, Oily, aging skin activates, bleb, ochrodermia, fat-reducing, promotes to scab, eczema, sunburn of burning, tinea, the moon Through having some setbacks, engorgement of breasts inflammation, mitigate melancholy uneasy, there is deodorant, antibacterial, the effect of sterilization.
RADIX PAEONIAE ALBA essential oil: there is the effects such as blood-supplementing blood-nourishing, astringing YIN to stop sweating, wherein Paeoniflorin has antibacterial, antipyretic, anti-inflammatory, changes Kind myocardial nutritional flow, expansion of blood vessels, antagonism acute myocardial ischemia, suppression platelet aggregation, calmness, analgesia, spasmolysis, anti-burst Ulcer, the effect of regulation blood sugar.Decoction can suppress shigella dysenteriae, streptococcus pneumonia, Escherichia coli, typhoid bacillus, hemolytic hammer Bacterium, Pseudomonas aeruginosa etc..
Origanum oil: the herb of Labiatae origanum wild marjoram origznum vul-garel., also known as only careless, the wild chaste tree of dysentery The ground such as mustard accord with name, have heat-clearing, dampness elimination, driving away summer heat, induce sweat, sterilization that qi-regulating is extremely strong, bacteriostasis, the volatilization extracted from wild marjoram Oil, cause enteritis bacterium common to 31 kinds and shigella flexneri, are the pure Chinese medicine additives of most broad-spectrum antiseptic.
Chrysanthemum cinesariaefolium: the general designation of chrysanthemum artemisia (tanacetum) several plants, removing dampness and destroying parasites, kill crab louse, head louse, body Lice, flea, the effect except mosquito desinsection.
Borneol: pungent, bitter, cool.There is inducing resuscitation of having one's ideas straightened out, heat-clearing dissipates poison, removing nebula.Cure mainly high fever apoplexy coma due to blocking of the respiratory system shies epilepsy, middle wind phlegm Faint frightened epilepsy, summer-heat and damp blinds clear key, larynx numbness is deaf, aphtha tooth swells, sore carbuncle infantile malnutrition due to digestive disturbances or intestinalparasites hemorrhoid, red eye, swell pain, pterygium.
Lotus leaf: for the leaf of nymphaeaceae plant lotus, play the role of clearing heat and detoxicating, cool blood, hemostasis.Have clearing summer-heat and damp, rise send out clear The effects such as sun, cooling blood and hemostasis.
Eucalyptus oil: one of most common and widest essential oil of purposes, there is good health-care effect, help focal attention Power.Sinus infection, influenza, bronchitis, cold nasal obstruction and other respiratory diseases can effectively be alleviated.There is good resisting Bacterium and sterilization idiocratic, in some certain food, eucalyptus oil is also as fragrance component.Carry this essential oil in travelling, permissible Effectively resist mosquito bite and insect bite, treat skin measles.It is good culicifuge.Mixing with water can become a kind of and simple and effective disappear Toxic agent.
Beneficial effects of the present invention:
The present invention provides a kind of smell pure and fresh for user, has stimulating effect and the ink of negative ion health effect, it is not only Negative aeroion can be discharged for a long time, purify air, beneficial to health；Also thin to staphylococcus, Escherichia coli, Grain-positive Multiple germ such as bacterium and fungi have certain suppression, killing action；Fragrant odour simultaneously, pure and fresh soothe the spirit, pressure of releiving, also can drive Catch up with mosquito, harmful effect will not be produced it is adaptable to each age groups to human body, its appropriate add other function ingredients after still Original effect and quality can be kept.
1st, tourmaline is a kind of silicate mineral, and its chemical formula is na (mg, fe, mn, li, al) 3al6 (si6o18) (bo3) 3 (oh, f) 4, it contacts under electrostatic field with hydrone, just hydrone can be ionized into hydrogen ion (h+) and hydrogen-oxygen Radical ion (oh-), hydroxide ion and water molecules form basic hydroxide group anion (h2o oh-), as " air bear from Son ", current scientific research proves: anion can not only facilitate human body synthesis and vitamin storage, the life of strengthening and human activin Reason activity, has highly important impact to the vital movement of human body and other biological, is referred to as " air vitamin ".Anion Effectively adsorb indoor harmful substance, the such as construction and decoration harmful substance such as formaldehyde, toluene, not only itself do not increase pollution, Er Qieqing Purifying room air, is inherently eliminated construction and decoration syndrome, ensures that health is unaffected.
2nd, the traditional Chinese medicine ingredients containing in the present invention, not only thin to staphylococcus, tubercle bacillus, Pseudomonas aeruginosa, Grain-negative Multiple germ such as bacterium and gram-positive bacteria and fungi have certain suppression, killing action；Fragrant odour simultaneously, property is gentle, Pure and fresh soothe the spirit, help hormone secretion, the effect of anxiety of releiving, also there is certain mosquito-repelling effect simultaneously, more it is essential that The Long-Time Service present invention will not produce harmful effect it is adaptable to each age groups to human body, before having application widely Scape.
Specific embodiment
Embodiment.
A kind of environment-friendly water-based black ink it is characterised in that: by following component by weight: dispersible pigment color paste 23 Weight portion, bis-phenol a19 weight portion, glycerine 4.5 weight portion, anhydrous sodium sulfate 2.3 weight portion, triethanolamine 2.7 weight portion, three second Amine 3.3 weight portion, acetone 3.6 weight portion, double thiocarbamate 0.25 weight portions, active mineral matter powder 1.7 weight portion, table Face activating agent compound 1.2 weight portion, sustained release agent 0.55 weight portion, essential oil of traditional Chinese medicine 3.85 weight portion, deionized water 62 weight portion, The pigment of described mill base is high-carbon black pigment, and the average grain diameter of described dispersible pigment color paste is 75nm, and described active mineral matter powder is Germanite, fluorite, tourmaline, gahnite are dravite and lithium by weight the mixture of 2.5:3:3.7:2, wherein tourmaline By weight the mixture of 5:3, particle diameter≤13 μm of described active mineral matter powder, wherein said essential oil of traditional Chinese medicine passes through tourmaline Following steps are prepared from,
S1, take vernonia anthelmintica 40 weight portion to clean, naturally dry, be subsequently placed in 90 DEG C of frying pans and fry to savory effusion, so Air washer 17 weight portion afterwards, is placed in constant temperature oven less than 60 DEG C and dries, water content≤6.5%；
S2, eupatorium 17.5 weight portion is cleaned, puts in salt solution and soak 3.5 hours, the salt water yield by immersion spice quality 3.7 Times, put into and steam in pot thoroughly, take out, dry, the concentration of salt solution is 27%；
S3, by calamus 13 weight portion, frutus cnidii 15 weight portion, elm bark 6 weight portion, agalloch eaglewood 6.5 weight portion, camphorwood 4 weight Part, peppermint 1.5 weight portion decontamination, put into together with step s1 and the made bulk drug of s2 and in micronizer, be crushed to 60 mesh, Prepared bulk drug powder, standby；
S4, by step s3 be obtained bulk drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, adjust extraction Pressure power 27.65mpa, 45.10 DEG C of extraction temperature, carbon dioxide flow is 0.6m3/ h, dynamic extraction 2.5h, are directly separating Kettle outlet triangular flask collects volatile oil a, standby；
S5, by raspberry 3.5 weight portion, anemone vitifolia 3.5 weight portion, Moschus 3.5 weight portion, Lysimachia foenum-graecum 1.5 weight portion, sweet Marjoram 1.75 weight portion is cleaned and is dried, and puts in micronizer together and is crushed to 70 mesh, then plus deionized water soak 6 little When, amount of water by 6.5 times of immersion bulk drug quality, dispersed with stirring is mixed well, prepared Traditional Chinese drug mixture, standby；
S6, the Traditional Chinese drug mixture that step s5 is obtained decoct 2 hours in 80 DEG C, collect distillate, and add ether to extract, distillation Then plus anhydrous sodium sulfate drying the volume ratio of liquid and ether is 2:1, takes upper oil phase, that is, volatile oil b is obtained, standby；
S7, step s4 and s6 made volatile oil a and volatile oil b mixing are mixed well prepared miscella, then sequentially add while stirring P-Cymene, lemon, grapefruit essential oil, Geranium Essential and RADIX PAEONIAE ALBA essential oil, are sufficiently stirred for 35 minutes, stand 30 points Clock, is sufficiently stirred for mixing well, filtering and impurity removing, obtains final product essential oil of traditional Chinese medicine, wherein, described miscella and P-Cymene, lemon, grape The mass ratio of shaddock oil, Geranium Essential and RADIX PAEONIAE ALBA essential oil is 1.3:0.4:0.75:0.6:0.5:0.3.
In a preferred embodiment, also include origanum oil 1.3 weight portion in the bulk drug powder of step s3 and spend in vain Dalmatian chrysanthemum 1.5 weight portion.
In a preferred embodiment, the Traditional Chinese drug mixture of step s5 also includes borneol 0.6 weight portion and lotus leaf 0.4 Weight portion.
In a preferred embodiment, the essential oil of traditional Chinese medicine of step s7 also includes eucalyptus oil 0.3 weight portion.
Test the ink in this above-described embodiment using air ion static method of testing, anion burst size is in 430-650 Individual/m3, and sustained release negative aeroion, it is more beneficial for long-term purify air, reach the basic demand of health of people.
Reference examples.
Colour carbon black 20g, phenol 11g, glycerine 4g, BTA 3g, triethanolamine 1g, triethylamine 3g, sodium acid carbonate 5g, polyoxyethylene groups ethers nonionic fluorocarbon surfactant 1.5g, sustained release agent 0.4g, marjoram essential oil 0.6g, wheat Bud essential oil 0.5g, Lavender 0.5g, RADIX PAEONIAE ALBA essential oil 0.4g, cypress essential oil 0. 4g, eucalyptus quintessence oil 0.4g, tarragon essence Oily 0. 4g, Peppermint essential oil 0.4g, deionized water 75g.
Test the ink in this above-mentioned reference examples using air ion static method of testing, anion burst size is in 0/m3, There is no the function of release negative aeroion.
(1) acute toxicity test is carried out to obtained essential oil of traditional Chinese medicine, result is as follows:
1. Mouse oral acute toxicity test: the ld50 of Mouse oral essential oil of traditional Chinese medicine is 383.55g/kg, 95% credible is limited to 294.68g/kg～499.31g/kg.And the toxicity criterion of air freshener is: Mouse oral anxious poison ld50 >=5g/ Kg, is judged to nontoxic.The ld50 of this essential oil of traditional Chinese medicine is higher than 76 times of nontoxic standard, therefore, it is determined that being nontoxic.
2. chmice acute toxicity on inhalation test: the lc50 that chmice acute sucks essential oil of traditional Chinese medicine is 24863.99g/m3,95% Credible be limited to 16837.34g/m3～33387.46g/m3.And the toxicity criterion of air freshener is: chmice acute Suck (2h) lc50 ＞ 10000mg/m3, the nontoxic level in true border.The lc50 of this essential oil of traditional Chinese medicine is higher than the 2486 of nontoxic standard Times, therefore, it is determined that being nontoxic.
Through inspection, its fragrance, color and luster, refraction index, relative density, arsenic content, heavy metal contain obtained essential oil of traditional Chinese medicine Amount, ph value all meet the requirement of national standard.
(2) check above-mentioned ink anion burst size result such as table 1.
(3) to the test improving the state of mind.
Main method is that ink uses volunteer to test, and recruits 60 people, respectively using the ink in above-mentioned 2 kinds of embodiments, By scl-90 questionnaire (i.e. " Self-reporting inventory-scl90 ", be in the world one of foremost Mental health test scale), By continuous 1 week using following the tracks of, to judge that the present invention acts in the actual efficacy of aspect of refreshing oneself, wherein 3 people are noninductive to be subject to；8 people Impression is general；3 people think that this product is invalid for stimulating effect；There are 46 people to feed back this product and there is effect of preferably refreshing oneself, can make People's notice is concentrated, and efficient is 76.67%.
(4) repelling effect test.
Repelling effect according to common ink of the prior art and ink in above-described embodiment carries out contrast test, test Data is shown in Table 2.
Conclusion: the ink in the embodiment of the present invention has certain repelling effect.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, common for art For technical staff, can also make other changes in different forms on the basis of the above description, here need not All of embodiment cannot be exhaustive, all any modifications within the spirit and principles in the present invention, made, equivalent replace Change, improve, be still included within protection scope of the present invention.

Claims (1)

1. a kind of environment-friendly water-based black ink it is characterised in that: by following component by weight: dispersible pigment color paste 23 weight Amount part, bis-phenol a19 weight portion, glycerine 4.5 weight portion, anhydrous sodium sulfate 2.3 weight portion, triethanolamine 2.7 weight portion, triethylamine 3.3 weight portions, acetone 3.6 weight portion, double thiocarbamate 0.25 weight portions, active mineral matter powder 1.7 weight portion, surface Activating agent compound 1.2 weight portion, sustained release agent 0.55 weight portion, essential oil of traditional Chinese medicine 3.85 weight portion, deionized water 62 weight portion, institute The pigment stating mill base is high-carbon black pigment, and the average grain diameter of described dispersible pigment color paste is 75nm, and described active mineral matter powder is germanium Stone, fluorite, tourmaline, gahnite are dravite and lithium electricity by weight the mixture of 2.5:3:3.7:2, wherein tourmaline By weight the mixture of 5:3, particle diameter≤13 μm of described active mineral matter powder, wherein said essential oil of traditional Chinese medicine passes through such as gas stone Lower step is prepared from,
S1, take vernonia anthelmintica 40 weight portion to clean, naturally dry, be subsequently placed in 90 DEG C of frying pans and fry to savory effusion, so Air washer 17 weight portion afterwards, is placed in constant temperature oven less than 60 DEG C and dries, water content≤6.5%；
S2, eupatorium 17.5 weight portion is cleaned, puts in salt solution and soak 3.5 hours, the salt water yield by immersion spice quality 3.7 Times, put into and steam in pot thoroughly, take out, dry, the concentration of salt solution is 27%；
S3, by calamus 13 weight portion, frutus cnidii 15 weight portion, elm bark 6 weight portion, agalloch eaglewood 6.5 weight portion, camphorwood 4 weight Part, peppermint 1.5 weight portion decontamination, put into together with step s1 and the made bulk drug of s2 and in micronizer, be crushed to 60 mesh, Prepared bulk drug powder, standby；
S4, by step s3 be obtained bulk drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, adjust extraction Pressure power 27.65mpa, 45.10 DEG C of extraction temperature, carbon dioxide flow is 0.6m3/ h, dynamic extraction 2.5h, are directly separating Kettle outlet triangular flask collects volatile oil a, standby；
S5, by raspberry 3.5 weight portion, anemone vitifolia 3.5 weight portion, Moschus 3.5 weight portion, Lysimachia foenum-graecum 1.5 weight portion, sweet Marjoram 1.75 weight portion is cleaned and is dried, and puts in micronizer together and is crushed to 70 mesh, then plus deionized water soak 6 little When, amount of water by 6.5 times of immersion bulk drug quality, dispersed with stirring is mixed well, prepared Traditional Chinese drug mixture, standby；
S6, the Traditional Chinese drug mixture that step s5 is obtained decoct 2 hours in 80 DEG C, collect distillate, and add ether to extract, distillation Then plus anhydrous sodium sulfate drying the volume ratio of liquid and ether is 2:1, takes upper oil phase, that is, volatile oil b is obtained, standby；
S7, step s4 and s6 made volatile oil a and volatile oil b mixing are mixed well prepared miscella, then sequentially add while stirring P-Cymene, lemon, grapefruit essential oil, Geranium Essential and RADIX PAEONIAE ALBA essential oil, are sufficiently stirred for 35 minutes, stand 30 points Clock, is sufficiently stirred for mixing well, filtering and impurity removing, obtains final product essential oil of traditional Chinese medicine, wherein, described miscella and P-Cymene, lemon, grape The mass ratio of shaddock oil, Geranium Essential and RADIX PAEONIAE ALBA essential oil is 1.3:0.4:0.75:0.6:0.5:0.3.
CN201610723028.7A 2016-02-19 2016-08-25 Environment-friendly aqueous black ink Withdrawn CN106336730A (en)

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CN106810977A (en) * 2017-02-14 2017-06-09 合肥智慧龙图腾知识产权股份有限公司 A kind of functional paint for being exclusively used in landscape stone material and preparation method thereof
CN108059870A (en) * 2017-12-26 2018-05-22 吕绍淼 A kind of antibiotic property offset ink and preparation method thereof
CN113249000A (en) * 2021-05-25 2021-08-13 中山市富日印刷材料有限公司 High-gloss wear-resistant environment-friendly low-odor water-based gloss oil and preparation method thereof

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CN104212236A (en) * 2014-08-20 2014-12-17 中山艺展装饰工程有限公司 Fragrant ink with refreshing effect
CN104212240A (en) * 2014-08-20 2014-12-17 中山艺展装饰工程有限公司 Ink prepared from compound plant extracts for ink-jet printer
CN104530826A (en) * 2014-12-18 2015-04-22 无锡伊诺永利文化创意有限公司 Ball pen ink with health function

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CN104212236A (en) * 2014-08-20 2014-12-17 中山艺展装饰工程有限公司 Fragrant ink with refreshing effect
CN104212240A (en) * 2014-08-20 2014-12-17 中山艺展装饰工程有限公司 Ink prepared from compound plant extracts for ink-jet printer
CN104530826A (en) * 2014-12-18 2015-04-22 无锡伊诺永利文化创意有限公司 Ball pen ink with health function

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