CN106283717A - 聚对苯二甲酸1,3‑丙二醇酯面料免蒸洗印花工艺 - Google Patents

聚对苯二甲酸1,3‑丙二醇酯面料免蒸洗印花工艺 Download PDF

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CN106283717A
CN106283717A CN201610751577.5A CN201610751577A CN106283717A CN 106283717 A CN106283717 A CN 106283717A CN 201610751577 A CN201610751577 A CN 201610751577A CN 106283717 A CN106283717 A CN 106283717A
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disperse
terephthalic acid
steam cleaning
poly terephthalic
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唐俊松
张建芳
陆叶洪
孙磊
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Shenghong Group Co Ltd
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Abstract

聚对苯二甲酸1，3‑丙二醇酯面料免蒸洗印花工艺，包括白坯打卷、预定型、印花、烘干、定型后整理和成品打卷步骤，所述分散染料组合物包括20~30%的耐高温分散染料、5~10%生物马来酸酐‑牛磺酸‑丙烯酰胺‑烯丙基磺酸钠共聚物、5~15%的羧甲基化木质素磺酸钠、5~15%的十二烷基苯磺酸钠、5~15%的聚丙烯酸钠以及余量的水。所述印花使用的糊料包括1.5~3%的乳化剂OP、25~35%的航空级火油、3~4%的粘合剂、1~3%的增稠剂，以及余量的水。本发明的糊料可以促进耐高温分散染料的上染率。本发明的节水率为73.68%，节能率为75.12%，印花水洗污水减排量为100%。

Description

聚对苯二甲酸1,3-丙二醇酯面料免蒸洗印花工艺
技术领域
本发明涉及一种聚对苯二甲酸1，3-丙二醇酯面料免蒸洗印花工艺，属于纺织品印染技术领域。
背景技术
随着科技的进步和社会经济的快速发展，对生态环境的保护日益重视。在纺织领域，生物工程技术、数码技术、自动控制技术、无水染色技术被用于开发高性能、高附加值纺织产品，一方面实现从原料到加工过程的绿色、低碳和可持续发展，另一方面实现纺织产品的生态化。开发以生物质为原料的纤维，特别是生物质合成纤维成为近年来的热点，从资源和环境两方面都符合社会发展的趋势，一方面实现对石化原料资源替代，减少对石油资源的过度依赖，另一方面实现对化工加工工艺路线替代，减少生产过程和最终废弃物对环境的影响。
聚对苯二甲酸1,3-丙二醇酯(polytrimethylene terephthalate，PTT)是继50年代聚对苯二甲酸乙二醇酯(PET)工业化，和70年代聚对苯二甲酸丁二酯(PBT)产业化以后实现工业规模开发的可成纤的聚酯材料。它克服了PET纤维的刚性和PBT纤维的柔性，兼具聚酯和聚酰胺纤维的优点，具有优良的弹性回复性、蓬松性、易染性、内在的抗污性、抗静电性和良好的色牢度等特点。以生物基PTT复合纤维为原料，设计开发具有不同风格特征和功能性生物基PTT复合纤维服用和家用系列纺织品，通过环保的染整技术进行深加工，开发高附加值面料极具市场开发潜力，本文通过近年来新开发的“免蒸洗无水印花技术”应用在生物基聚对苯二甲酸1，3-丙二醇酯面料的开发上，对相关工艺要点进行技术探讨，为生物基聚对苯二甲酸1，3-丙二醇酯面料的环保染整加工技术提供参考。
发明内容
本发明目的是提供一种聚对苯二甲酸1，3-丙二醇酯面料免蒸洗印花工艺。
为达到上述目的，本发明采用的技术方案是：一种聚对苯二甲酸1，3-丙二醇酯面料免蒸洗印花工艺，包括白坯打卷、预定型、印花、烘干、定型后整理和成品打卷步骤，所述印花使用的分散染料组合物包括下列质量百分比的材料：
所述印花使用的糊料包括下列质量百分比的材料：
优选的技术方案为：所述耐高温分散染料选自分散黄30#、分散红167#、分散蓝291:1、分散紫93#、分散橙288#、分散蓝79#。
优选的技术方案为：所述糊料包括下列质量百分比的材料：
由于上述技术方案运用，本发明与现有技术相比具有下列优点和效果：
1、本发明可以使分散染料充分发色，达到色牢度生产要求；
2、本发明有助于减低印染加工对其记忆能力的影响，由于工序少，减少了传统加工经常出现的褶皱印、擦伤、记忆效果降低等印染难题。
3、本发明的节水率为73.68％,节能率为75.12％，印花水洗污水减排量为100％。
具体实施方式
下面结合实施例对本发明作进一步描述：
实施例一：聚对苯二甲酸1，3-丙二醇酯面料免蒸洗印花工艺
一种聚对苯二甲酸1，3-丙二醇酯面料免蒸洗印花工艺，包括白坯打卷、预定型、印花、烘干、定型后整理和成品打卷步骤，所述印花使用的分散染 料组合物包括下列质量百分比的材料：
所述耐高温分散染料为分散橙288#。
马来酸酐-牛磺酸-丙烯酰胺-烯丙基磺酸钠共聚物的制备方法可以是：在带搅拌器、滴液漏斗、温度计和回流冷凝管的1000ml四颈瓶中先加入120ml环己烷/乳化剂Span 80和Tween 80各50ml,然后加入一定比例的马来酸酐和牛磺酸、升温至80℃，搅拌使之溶解、充分反应50min后，用两个滴液漏斗分别滴入一定比例的丙烯酰胺，烯丙基磺酸钠和水的混和液以及少量过硫酸钾溶于水的溶液，控制反应温度85℃，1h后滴完，再反应2h然后将冷凝管换成蒸馏装置，蒸出环己烷-水共沸物，回收。冷却出料，然后用惰性溶剂将乳化剂洗掉，得到共聚物。
所述印花使用的糊料，所述糊料包括下列质量百分比的材料：
增稠剂为CMC-Na。
材料及设备：
材料：PTT记忆面料；药品：实施例一制备的糊料、实施例制得的分散染料组合物、普通分散染料、海藻酸钠糊料、保险粉、净洗剂209。
设备：力根拉幅定型机，德国玛诺整纬机，奥地利齐玛圆网磁棒印花机，圆筒蒸箱，绳状水洗机、圆筒蒸箱、UltraScan XE型测色仪、LFY－1A织物折痕恢复性测定仪。
色浆配置。
印花工艺及生产流程。
利用印花机将配置好的色浆印制到PTT记忆面料上，传统工艺采用圆筒蒸化，经皂洗、还原清洗、烘干工序，得到成品；而免蒸洗工艺采用烘定一体，直接发色到成品。
PTT记忆性能测试。
折皱回复角：按DB/T 3819－1997标准，在LFY－1A织物折痕恢复性测定仪上测试经向和纬向的急弹和缓弹回复角三次，用经纬向回复角之和的平均值表示。
蒸化条件对回复角的影响。
表1蒸化工艺对折皱回复角的影响。
种类 坯布 免蒸洗工艺 圆筒蒸化样
急弹 104.2 110.5 146.8
缓弹 115.8 125.6 154.3
表1可知，PTT织物根据印花工艺不同，织物的弹力回复角相差很大，而弹力回复角大意味着织物纤维的刚性大，即织物记忆能力的下降，记忆效果的丧失。
Dandurand等人通过用X-射线衍射方法对PTT晶体中大分子链构象研究表明，PTT大分子链中-O-CH2-CH2-CH2-O-单元具有1种能量最低的反式-旁式-旁式-反式构象，即呈现出明显的“Z”字形结构，使得PTT大分子链具有如同线圈弹簧一样的变形弹性。在外力作用下，“旁式”单元发生链旋转而转变为“反式”构象，而且由于这种构象转变仅仅包含C-C和C-O键旋转，分子链的伸长很容 易发生，旋转过程中的构象转变过程是完全可逆的，外力除去后又恢复原状，由此赋予了PTT纤维良好的内在回复性。另有资料分别对高温染色和低温染色的PTT纤维进行了X-射线衍射分析发现，高温染色的PTT纤维结晶度明显增加。这就破坏了PTT原有的弹簧模型，从而影响了PTT纤维的记忆效果。
记忆效果是衡量聚对苯二甲酸1，3-丙二醇酯面料的重要指标，印染加工工序越少，其记忆性能的影响就越低，采用免蒸洗技术加工记忆面料能够有效的保护PTT纤维的记忆效果，同时免蒸洗技术，缩短了加工工序，减少了生产疵品的概率，另外其节能降耗显著。分子链在高温条件下运动加剧，破坏了原有微观分子结构，如结晶度和取向度，从而导致记忆效果的丧失；圆筒蒸化温度低，对分子链段的影响较小，所以记忆效果保持较好。
色牢度测试：
由上表表明，免蒸洗印花工艺色牢度优异，基本接近传统印花工艺。
两印花工艺能源消耗对比：
表2两印花工艺水消耗对比表。
项目 传统印花工艺 免蒸洗印花工艺
前处理用水(t) 0.35 0.35
印花用水(t) 0.30 0.30
印花水洗用水(t) 0.84 0
其他用水(t) 0.27 0.27
合计用水量(t) 1.76 0.92
表3两印花工艺煤消耗对比表
项目 传统印花工艺 免蒸洗印花工艺
前处理用煤(kg标煤) 14.652 14.652
定型用煤(kg标煤) 5.132 5.132
汽蒸热熔用煤(kg标煤) 8.243 0
印花水洗用煤(kg标煤) 7.253 0
其他用煤(kg标煤) 9.451 9.451
合计用煤(kg标煤) 44.731 29.235
上述数据参照行业标准FZ/T01002-2010规定：用水用煤量按处理每100m织物计算，织物密度100～140g/m2，门幅1.6m以下；工艺中所耗用的蒸汽、电均折算为标煤。通过以上两表可知：该工艺的节水率为73.68％,节能率为75.12％，印花水洗污水减排量为100％。
实施例二：聚对苯二甲酸1，3-丙二醇酯面料免蒸洗印花工艺。
一种聚对苯二甲酸1，3-丙二醇酯面料免蒸洗印花工艺，包括白坯打卷、预定型、印花、烘干、定型后整理和成品打卷步骤，所述印花使用的分散染料组合物包括下列质量百分比的材料：
所述耐高温分散染料为分散黑为分散蓝291:1、分散紫93#和分散橙288#的混合制品。
所述印花使用的糊料包括下列质量百分比的材料：
增稠剂为改性淀粉。
上述实施例只为说明本发明的技术构思及特点，其目的在于让熟悉此项 技术的人士能够了解本发明的内容并据以实施，并不能以此限制本发明的保护范围。凡根据本发明精神实质所作的等效变化或修饰，都应涵盖在本发明的保护范围之内。

Claims (3)

1.一种聚对苯二甲酸1，3-丙二醇酯面料免蒸洗印花工艺，其特征在于：包括白坯打卷、预定型、印花、烘干、定型后整理和成品打卷步骤，所述印花使用的分散染料组合物包括下列质量百分比的材料：
耐高温分散染料 20~30%；
马来酸酐-牛磺酸-丙烯酰胺-烯丙基磺酸钠共聚物 5~10%；
羧甲基化木质素磺酸钠 5~15%；
十二烷基苯磺酸钠 5~15%；
聚丙烯酸钠 5~15%；
水 余量；
所述印花使用的糊料包括下列质量百分比的材料：
乳化剂OP 1.5~3%；
航空级火油 25~35%；
粘合剂 3~4%；
增稠剂 1~3%；
水 余量。
2.根据权利要求1所述的聚对苯二甲酸1，3-丙二醇酯面料免蒸洗印花工艺，其特征在于：所述耐高温分散染料选自分散黄30#、分散红167#、分散蓝291:1、分散紫93#、分散橙288#、分散蓝79#。
3.根据权利要求1所述的聚对苯二甲酸1，3-丙二醇酯面料免蒸洗印花工艺，其特征在于：所述糊料包括下列质量百分比的材料：
乳化剂OP 2.1%；
航空级火油 30%；
粘合剂 3.5%；
增稠剂 1.5%；
水 余量。
CN201610751577.5A 2016-08-29 2016-08-29 聚对苯二甲酸1,3‑丙二醇酯面料免蒸洗印花工艺 Pending CN106283717A (zh)

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