CN106273897A - 一种各向异性聚丙烯板‑金属复合材料及其制备方法 - Google Patents

一种各向异性聚丙烯板‑金属复合材料及其制备方法 Download PDF

Info

Publication number
CN106273897A
CN106273897A CN201610645730.6A CN201610645730A CN106273897A CN 106273897 A CN106273897 A CN 106273897A CN 201610645730 A CN201610645730 A CN 201610645730A CN 106273897 A CN106273897 A CN 106273897A
Authority
CN
China
Prior art keywords
polypropylene
anisotropy
composite
composite fibre
metal layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610645730.6A
Other languages
English (en)
Other versions
CN106273897B (zh
Inventor
王利平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhuhai Xinyidai Composite Material Co Ltd
Original Assignee
Zhuhai Xinyidai Composite Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhuhai Xinyidai Composite Material Co Ltd filed Critical Zhuhai Xinyidai Composite Material Co Ltd
Priority to CN201610645730.6A priority Critical patent/CN106273897B/zh
Publication of CN106273897A publication Critical patent/CN106273897A/zh
Application granted granted Critical
Publication of CN106273897B publication Critical patent/CN106273897B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/18—Handling of layers or the laminate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/08—Interconnection of layers by mechanical means
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09J123/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/10—Homopolymers or copolymers of propene
    • C09J123/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/06—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0253—Polyolefin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54—Yield strength; Tensile strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

本发明提供一种各向异性聚丙烯板‑金属复合材料的制备方法，其包括以下步骤：配置聚丙烯专用粘合剂；制备复合纤维：将上述粘合剂涂布在聚丙烯薄膜上，并将涂布后的聚丙烯薄膜切成一定宽度的纤维，加热牵拉，得到复合纤维；将所述复合纤维按一定方式编制或将所述复合纤维切成一定长度的短切纤维后分撒在硬质基板上辊压得到各项力学性能异性的各向异性聚丙烯膜片；提供上金属层和下金属层，将至少一层所述各向异性聚丙烯片夹设于所述上金属层和下金属层之间，热压成型。本发明用各向异性聚丙烯板代替PVC塑料与铝板、箔或其他金属板、箔复合得到的复合板材具有比重小(聚丙烯的比重为0.92)，使用温度高，无毒无味，抗张强度、抗冲击强度高。

Description

一种各向异性聚丙烯板-金属复合材料及其制备方法
技术领域
本发明涉及复合材料技术领域，尤其涉及一种各向异性聚丙烯板-金属复合材料。
背景技术
目前塑料与铝板的复合材料主要用PVC(聚氯乙烯)塑料，聚氯乙烯比重大(达到1.38)，使用温度低，燃烧时会放出有毒气体，抗冲击强度低，再成型性差。
各向异性聚丙烯-金属复合材料具有良好的耐冲击性，高的抗弯曲性能，比同厚度的铝镁合金总量轻30％以上。可广泛用于家电生产，高端装修，高端箱包，豪华车内饰等。采用各向异性聚丙烯板代替PVC塑料与铝板、箔或其他金属板、箔复合得到的复合板材具有比重小(聚丙烯的比重为0.92)，使用温度高，无毒无味，抗张强度、抗冲击强度高。
发明内容
有鉴于背景技术所述，本发明有必要提供一种各向异性聚丙烯板-金属复合材料。
本发明的目的是通过以下技术方案实现的：
一种各向异性聚丙烯板-金属复合材料的制备方法，其包括以下步骤：
S1、配置聚丙烯专用粘合剂；
S2、制备复合纤维：将上述粘合剂涂布在聚丙烯薄膜上，并将涂布后的聚丙烯薄膜切成一定宽度的纤维，加热牵拉，得到复合纤维；
S3、将所述复合纤维按一定方式编制或将所述复合纤维切成一定长度的短切纤维后分撒在硬质基板上经过辊压得到各项力学性能异性的各向异性聚丙烯膜片；
S4、提供上金属层和下金属层，将至少一层所述各向异性聚丙烯膜片夹设于所述上金属层和下金属层之间，热压成型。
在S1中，所述聚丙烯专用粘合剂的制备方法为：
按照以下质量百分比提供配方原料：高密度聚乙烯50-20份、聚丙烯树脂20-50份、EVA树脂50-80份、石蜡1-5份、顺丁烯二酸酐1-5份、丙烯酸酯1-5份、二甲苯50-100份、过氧化物0.1-1份；
按上述各种物料混合，在密封容器中加热到65-70度保温60分钟；
再加热到90度反应180分钟得到所述粘合剂。
在S2中，所述加热牵拉时的温度为100-150度。
在S3中，所述辊压的温度为120-160度。
在S4中，所述上金属层和/下金属层为金属板或金属箔。
优选的，所用的金属板或金属箔可以是铜、铁、马口铁、镀铬铁、镀锌铁、铝、不锈钢等材料。
上述方法中，采用的各向异性聚丙烯片的层数根据需要的产品厚度来决定。
本发明还提供一种各向异性聚丙烯板-金属复合材料，其由作为外表面的第一金属层和第二金属层，以及夹设于所述第一金属层和第二金属层之间的压合的至少一层各向异性聚丙烯膜片构成。
优选的，所述上金属层和下金属层为金属板或金属箔。
更优选的，所用的金属板或金属箔可以是铜、铁、马口铁、镀铬铁、镀锌铁、铝、不锈钢等材料。
所述各向异性聚丙烯膜片是由按一定方式编制的复合纤维或将所述复合纤维切成一定长度的短切纤维后分撒在硬质基板上经过辊压得到的；所述复合纤维是由涂布有所述聚丙烯专用粘合剂的聚丙烯薄膜切成一定宽度的纤维，加热牵拉，得到的复合纤维。
与现有技术相比，本发明具有以下优点：
本发明用各向异性聚丙烯板代替PVC塑料与铝板、箔或其他金属板、箔复合得到的复合板材具有比重小(聚丙烯的比重为0.92)，使用温度高，无毒无味，抗张强度、抗冲击强度高。
附图说明
图1为本发明实施例的各向异性聚丙烯板-金属复合材料成品的剖视图；
图2为本发明实施例的各向异性聚丙烯板-金属复合材料的分解结构示意图。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白，以下结合附图及实施例，对本发明进行进一步详细说明。应当理解，此处所描述的具体实施例仅仅用以解释本发明，并不用于限定本发明。
本实施例提供一种各向异性聚丙烯板-金属复合材料成品，如图1所示，其由作为外表面的上下铝板1，以及夹设于所述上下铝板1之间的相互压合的至少一层各向异性聚丙烯膜片2。
本实施例提供各向异性聚丙烯板-金属复合材料的制备方法，其包括以下步骤：
1、将0.2mm的铝板进行除油清洗，干燥处理，按需要的规格切成片；
2、取标重为180克/平方米的各向异性聚丙烯膜片8张；
3、将所述铝板和所述各向异性聚丙烯膜片按图2的方式排列；
4、将按上述排好的料置于层压机上。
5、升温到130℃，压制5-10分钟后通入冷却水冷却到50度以下。
6、打开层压机取出物料，得到各项异性聚丙烯-金属复合板材料。
所述各向异性聚丙烯膜片2的制备方法为：
S1、配置聚丙烯专用粘合剂：
按照以下质量百分比提供配方原料：高密度聚乙烯50-20份、聚丙烯树脂20-50份、EVA树脂50-80份、石蜡1-5份、顺丁烯二酸酐1-5份、丙烯酸酯1-5份、二甲苯50-100份、过氧化物0.1-1份；
按上述各种物料混合，在密封容器中加热到65-70度保温60分钟；
再加热到90度反应180分钟得到粘合剂。
S2、制备复合纤维：将上述粘合剂涂布在聚丙烯薄膜上，并将涂布后的聚丙烯薄膜切成一定宽度的纤维，加热牵拉，得到复合纤维；
S3、将所述复合纤维按一定方式编制或将所述复合纤维切成一定长度的短切纤维后分撒在硬质基板上经过辊压得到各项力学性能异性的各向异性聚丙烯膜片：所述硬质基板优选不锈钢板，也可以采用其他的金属或者非金属材质的硬质基板，所述硬质基板的功能和作用为制备各向异性聚丙烯膜片的治具，辊压完成后，需将制得的各向异性聚丙烯膜片从所述硬质基板表面剥离。

Claims (10)

1.一种各向异性聚丙烯板-金属复合材料的制备方法，其包括以下步骤：
S1、配置聚丙烯专用粘合剂；
S2、制备复合纤维：将上述粘合剂涂布在聚丙烯薄膜上，并将涂布后的聚丙烯薄膜切成一定宽度的纤维，加热牵拉，得到复合纤维；
S3、将所述复合纤维按一定方式编制或将所述复合纤维切成一定长度的短切纤维后分撒在硬质基板上辊压得到各项力学性能异性的各向异性聚丙烯膜片；
S4、提供上金属层和下金属层，将至少一层所述各向异性聚丙烯片夹设于所述上金属层和下金属层之间，热压成型。
2.根据权利要求1所述的方法，其特征在于：
在所述S1中，所述聚丙烯专用粘合剂的制备方法为：
按照以下质量百分比提供配方原料：高密度聚乙烯50-20份、聚丙烯树脂20-50份、EVA树脂50-80份、石蜡1-5份、顺丁烯二酸酐1-5份、丙烯酸酯1-5份、二甲苯50-100份、过氧化物0.1-1份；
将上述各种物料混合，在密封容器中加热到65-70度保温60分钟；
再加热到90度反应180分钟得到粘合剂。
3.根据权利要求1所述的方法，其特征在于：
在所述S2中，所述加热牵拉时的温度为100-150度。
4.根据权利要求1所述的方法，其特征在于：
在所述S3中，所述辊压的温度为120-160度。
5.根据权利要求1所述的方法，其特征在于：
在所述S4中，所述上金属层和/或下金属层为金属板或金属箔。
6.根据权利要求5所述的方法，其特征在于：
所用的金属板或金属箔是铜、铁、马口铁、镀铬铁、镀锌铁、铝或不锈钢。
7.一种各向异性聚丙烯板-金属复合材料，其特征在于：其由作为外表面的第一金属层和第二金属层，以及夹设于所述第一金属层和第二金属层之间的压合的至少一层各向异性聚丙烯膜片构成。
8.根据权利要求7所述的复合材料，其特征在于：
所述上金属层和下金属层为金属板或金属箔。
9.根据权利要求7所述的复合材料，其特征在于：
所用的金属板或金属箔是铜、铁、马口铁、镀铬铁、镀锌铁、铝或不锈钢。
10.根据权利要求7所述的复合材料，其特征在于：所述各向异性聚丙烯膜片是由按一定方式编制的复合纤维或将所述复合纤维切成一定长度的短切纤维后分撒在硬质基板上经过辊压得到的；所述复合纤维是由涂布有聚丙烯专用粘合剂的聚丙烯薄膜切成一定宽度的纤维，加热牵拉，得到的复合纤维。
CN201610645730.6A 2016-08-08 2016-08-08 一种各向异性聚丙烯板-金属复合材料及其制备方法 Active CN106273897B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610645730.6A CN106273897B (zh) 2016-08-08 2016-08-08 一种各向异性聚丙烯板-金属复合材料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610645730.6A CN106273897B (zh) 2016-08-08 2016-08-08 一种各向异性聚丙烯板-金属复合材料及其制备方法

Publications (2)

Publication Number Publication Date
CN106273897A true CN106273897A (zh) 2017-01-04
CN106273897B CN106273897B (zh) 2019-03-29

Family

ID=57666812

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610645730.6A Active CN106273897B (zh) 2016-08-08 2016-08-08 一种各向异性聚丙烯板-金属复合材料及其制备方法

Country Status (1)

Country Link
CN (1) CN106273897B (zh)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000013892A1 (en) * 1998-09-03 2000-03-16 Linlan Induction Ab Sandwich construction
CN2373258Y (zh) * 1999-06-15 2000-04-12 徐跃 金属薄板与聚丙烯复合板材
CN2472920Y (zh) * 2001-04-03 2002-01-23 陈猛 金属复合装饰板材
CN102070833A (zh) * 2010-12-27 2011-05-25 金发科技股份有限公司 一种提高聚丙烯极性用填充母粒及其制备方法
CN103507330A (zh) * 2012-06-18 2014-01-15 上海杰事杰新材料(集团)股份有限公司 一种复合芯铝塑板及其制备方法
CN105172277A (zh) * 2015-10-30 2015-12-23 成都同明新材料技术有限公司 一种自增强聚丙烯复合材料板材

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000013892A1 (en) * 1998-09-03 2000-03-16 Linlan Induction Ab Sandwich construction
CN2373258Y (zh) * 1999-06-15 2000-04-12 徐跃 金属薄板与聚丙烯复合板材
CN2472920Y (zh) * 2001-04-03 2002-01-23 陈猛 金属复合装饰板材
CN102070833A (zh) * 2010-12-27 2011-05-25 金发科技股份有限公司 一种提高聚丙烯极性用填充母粒及其制备方法
CN103507330A (zh) * 2012-06-18 2014-01-15 上海杰事杰新材料(集团)股份有限公司 一种复合芯铝塑板及其制备方法
CN105172277A (zh) * 2015-10-30 2015-12-23 成都同明新材料技术有限公司 一种自增强聚丙烯复合材料板材

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
何红媛主编: "《材料成形技术基础》", 31 August 2000, 东南大学出版社 *
言灏景: "《纤维材料导论》", 31 December 1990, 纺织工业出版社 *

Also Published As

Publication number Publication date
CN106273897B (zh) 2019-03-29

Similar Documents

Publication Publication Date Title
JP5890851B2 (ja) 特性の異なる領域を含む複合材料および方法
JP5915780B2 (ja) 繊維強化熱可塑性プラスチックを用いた積層基材
US10322568B2 (en) Shaped product of fiber-reinforced composite material and method of manufacturing the same
TW200902604A (en) Prepreg base material, layered base material, fiber reinforced plastics, manufacturing method of prepreg base material and manufacturing method of fiber reinforced plastics
CN107428117B (zh) 层叠体
KR101969489B1 (ko) 해양오염을 방지하는 친환경 부표
CN104335603B (zh) 电声换能器用的不对称多层隔膜
JP2014508055A5 (ja) 曲げ剛性を備えた積層板、同積層板からの成形品、及びその製造方法
CN201970502U (zh) 一种汽车顶篷用碳纤维聚氨酯复合板结构
CN101224651A (zh) 金属薄板与非金属纤维胶片复合材料
JP2015517935A (ja) 環境にやさしい高強度樹脂複合材
CN106273897A (zh) 一种各向异性聚丙烯板‑金属复合材料及其制备方法
JP6179632B2 (ja) 不燃性化粧パネル
JPWO2019189582A1 (ja) 成形品の製造方法
CN110104006A (zh) 一种轻量环保型高速列车中顶板及其制备方法
JP5990966B2 (ja) 不燃性化粧パネル
JP2012206348A (ja) 繊維強化ａｂｓ系樹脂材料及び成形体
JP5625884B2 (ja) 不燃性化粧パネル
CN208714590U (zh) 一种汽车内饰件及模具
JP2015063019A (ja) 熱可塑性積層シート及びその製造方法
JP2012025149A (ja) 自動車部材用の繊維強化複合材、及びその製造方法
CN107428116A (zh) 夹芯板及其制造方法
JP2017001371A (ja) 繊維強化プラスチック成形板の製造方法
CN107531020A (zh) 夹芯板、其制造方法及夹芯板结构体
JP5082272B2 (ja) 容器用樹脂被覆鋼板およびその製造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant