CN106243470A - 一种耐磨鞋制品材料及制备方法 - Google Patents

一种耐磨鞋制品材料及制备方法 Download PDF

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CN106243470A
CN106243470A CN201610612374.8A CN201610612374A CN106243470A CN 106243470 A CN106243470 A CN 106243470A CN 201610612374 A CN201610612374 A CN 201610612374A CN 106243470 A CN106243470 A CN 106243470A
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Abstract

本发明公开了一种耐磨鞋制品材料及制备方法,其中耐磨鞋制品材料原料由以下重量份比例组成:EVA:45‑58份、POE:8‑15份、聚氨酯橡胶:8‑15份、碳酸钙:5‑8份、DCP:0.5‑1份、二氮烯二羧酸酰胺:1‑2份、发泡促进剂:0.5‑0.8份、硬脂酸:0.8‑1.3份、色母料:2‑3份、纳米二氧化硅:5‑10份、达玛树脂:5‑10份,氢氧化镁阻燃剂:3‑8份,本发明的鞋制品材料在保证原有材料低密度的基础上,对其弹性、抗撕裂性和抗剥离性进行提升,特别是耐磨性能提升效果明显,本发明还提供了一种耐磨鞋制品材料的制备方法。

Description

一种耐磨鞋制品材料及制备方法
技术领域
本发明涉及复合材料技术领域,具体涉及一种耐磨鞋制品材料及制备方法。
背景技术
EVA是由乙烯-醋酸乙烯共聚物(也称为乙烯-乙酸乙烯共聚物)是由乙烯(E)和乙酸乙烯(VA)共聚而制得,英文名称为:Ethylene Vinyl Acetate,简称为EVA,E/VAC。聚合方法用高压本体聚合(塑料用)、溶液聚合(PVC加工助剂)、乳液聚合(粘合剂)、悬浮聚合。乙酸乙烯(VA)含量高于30%的采用乳液聚合,乙酸乙烯含量低的就用高压本体聚合,Eva化学名是乙烯-醋酸乙烯酯共聚物,是一种普通的材料,是日常生活中比较常见的一类中底材料,用它制成的成品具有柔软性好、防震、防滑、抗压力性强,如我们常见的拖鞋、棉鞋、手机保护套等。
EVA交联发泡材料具有密度低、物理性能好、无毒等特点,通过近年来的发展,广泛用于床垫、儿童地板、鞋类等制品,但EVA交联发泡材料的抗剥离性能、抗撕裂性能以及弹性等性能一般,由于其本身性质的局限性,很难达到集耐磨、高回弹、力学性能好以及拉伸强度高、耐水性能好等特点于一身,同时由于不同工艺对产品的质量及性能存在较大的影响。
发明内容
为了解决上述存在的问题,弥补现有技术的不足,本发明通过采用优化设计EVA、POE、AC、DCP等比例,添加聚氨酯橡胶、纳米二氧化硅和氢氧化镁阻燃剂,采用阶梯式密炼工艺,并经多次打薄处理,对产品进行改性,辅以特定橡胶材料,使其耐磨性能、弹性、抗撕裂性有较大提升。
一种耐磨鞋制品材料及制备方法,其中耐磨鞋制品材料原料由以下重量份比例组成:EVA:45-58份、POE:8-15份、聚氨酯橡胶:8-15份、碳酸钙:5-8份、发泡促进剂:0.5-0.8份、硬脂酸:0.8-1.3份、色母料:2-3份、纳米二氧化硅:5-10份、达玛树脂:5-10份,氢氧化镁阻燃剂:3-8份、DCP:0.5-1份、二氮烯二羧酸酰胺:1-2份。
一种耐磨鞋制品材料及制备方法,其主要制备步骤如下:
(1)首先按照工艺配方将所述组分秤取EVA:45-58份、POE:8-15份、聚氨酯橡胶:8-15份、碳酸钙:5-8份、发泡促进剂:0.5-0.8份、硬脂酸:0.8-1.3份、色母料:2-3份、纳米二氧化硅:5-10份、达玛树脂:5-10份,将其充分混合后待用,按照工艺配方秤取适量的氢氧化镁阻燃剂、发泡剂二氮烯二羧酸酰胺和交联剂DCP,比例为氢氧化镁阻燃剂:3-8份、DCP:0.5-1份、二氮烯二羧酸酰胺:1-2份;
(2)将上述混合组分加入密炼机进行阶梯式密炼,密炼温度控制在82~86摄氏度,时间控制在10~15分钟,然后将密炼的温度控制在88~92摄氏度,时间控制在10~15分钟,加入交联剂和发泡剂,再将密炼温度控制在95~99摄氏度,时间控制在8~10分钟,然后进行翻料步骤,时间控制在2~3分钟;
(3)将上述步骤经过密炼的混合料进行开炼,将开炼机辊轮温度控制在90~95摄氏度,将其打匀,进行2~4次打薄操作,设置辊轮间距为0.8~2毫米;
(4)将开炼完成的料置入造粒机进行造粒;
(5)将所需的粒状料放入模具中,通过热压发泡操作,其中热压发泡时间控制在10~15分钟,发泡温度控制在165~175摄氏度,加硫时间控制在3~8分钟;
(6)将热压发泡后的产品冷却后定型即可。
具体实施方式
实施例1
一种耐磨鞋制品材料及制备方法,其中耐磨鞋制品材料原料由以下重量份比例组成:EVA:45份、POE:8份、聚氨酯橡胶:8份、碳酸钙:5份、发泡促进剂:0.5份、硬脂酸:0.8份、色母料:2份、纳米二氧化硅:5份、达玛树脂:5份,氢氧化镁阻燃剂:3份、DCP:0.5份、二氮烯二羧酸酰胺:1份。
一种耐磨鞋制品材料及制备方法,其主要制备步骤如下:
(1)首先按照工艺配方将所述组分秤取EVA:45份、POE:8份、聚氨酯橡胶:8份、碳酸钙:5份、发泡促进剂:0.5份、硬脂酸:0.8份、色母料:2份、纳米二氧化硅:5份、达玛树脂:5份,将其充分混合后待用,按照工艺配方秤取适量的氢氧化镁阻燃剂、发泡剂二氮烯二羧酸酰胺和交联剂DCP,比例为氢氧化镁阻燃剂:3份、DCP:0.5份、二氮烯二羧酸酰胺:1份;
(2)将上述混合组分加入密炼机进行阶梯式密炼,密炼温度控制在82摄氏度,时间控制在10分钟,然后将密炼的温度控制在88摄氏度,时间控制在10分钟,加入交联剂和发泡剂,再将密炼温度控制在95摄氏度,时间控制在8分钟,然后进行翻料步骤,时间控制在2分钟;
(3)将上述步骤经过密炼的混合料进行开炼,将开炼机辊轮温度控制在90摄氏度,将其打匀,进行2次打薄操作,设置辊轮间距为0.8毫米;
(4)将开炼完成的料置入造粒机进行造粒;
(5)将所需的粒状料放入模具中,通过热压发泡操作,其中热压发泡时间控制在10分钟,发泡温度控制在165摄氏度,加硫时间控制在3分钟;
(6)将热压发泡后的产品冷却后定型即可。
实施例2
一种耐磨鞋制品材料及制备方法,其中耐磨鞋制品材料原料由以下重量份比例组成:EVA:58份、POE:15份、聚氨酯橡胶:15份、碳酸钙:8份、发泡促进剂:0.8份、硬脂酸:1.3份、色母料:3份、纳米二氧化硅:10份、达玛树脂:10份,氢氧化镁阻燃剂:8份、DCP:1份、二氮烯二羧酸酰胺:2份。
一种耐磨鞋制品材料及制备方法,其主要制备步骤如下:
(1)首先按照工艺配方将所述组分秤取EVA:58份、POE:15份、聚氨酯橡胶:15份、碳酸钙:8份、发泡促进剂:0.8份、硬脂酸:1.3份、色母料:3份、纳米二氧化硅:10份、达玛树脂:10份,将其充分混合后待用,按照工艺配方秤取适量的氢氧化镁阻燃剂、发泡剂二氮烯二羧酸酰胺和交联剂DCP,比例为氢氧化镁阻燃剂:8份、DCP:1份、二氮烯二羧酸酰胺:2份;
(2)将上述混合组分加入密炼机进行阶梯式密炼,密炼温度控制在86摄氏度,时间控制在15分钟,然后将密炼的温度控制在92摄氏度,时间控制在15分钟,加入交联剂和发泡剂,再将密炼温度控制在99摄氏度,时间控制在10分钟,然后进行翻料步骤,时间控制在3分钟;
(3)将上述步骤经过密炼的混合料进行开炼,将开炼机辊轮温度控制在95摄氏度,将其打匀,进行4次打薄操作,设置辊轮间距为2毫米;
(4)将开炼完成的料置入造粒机进行造粒;
(5)将所需的粒状料放入模具中,通过热压发泡操作,其中热压发泡时间控制在15分钟,发泡温度控制在175摄氏度,加硫时间控制在8分钟;
(6)将热压发泡后的产品冷却后定型即可。
实施例3
一种耐磨鞋制品材料及制备方法,其中耐磨鞋制品材料原料由以下重量份比例组成:EVA:48份、POE:10份、聚氨酯橡胶:10份、碳酸钙:6份、发泡促进剂:0.7份、硬脂酸:0.9份、色母料:2份、纳米二氧化硅:8份、达玛树脂:7份,氢氧化镁阻燃剂:5份、DCP:1份、二氮烯二羧酸酰胺:1份。
一种耐磨鞋制品材料及制备方法,其主要制备步骤如下:
(1)首先按照工艺配方将所述组分秤取EVA:48份、POE:10份、聚氨酯橡胶:10份、碳酸钙:6份、发泡促进剂:0.7份、硬脂酸:0.9份、色母料:2份、纳米二氧化硅:8份、达玛树脂:7份,将其充分混合后待用,按照工艺配方秤取适量的氢氧化镁阻燃剂、发泡剂二氮烯二羧酸酰胺和交联剂DCP,比例为氢氧化镁阻燃剂:5份、DCP:1份、二氮烯二羧酸酰胺:1份;
(2)将上述混合组分加入密炼机进行阶梯式密炼,密炼温度控制在84摄氏度,时间控制在11分钟,然后将密炼的温度控制在88摄氏度,时间控制在12分钟,加入交联剂和发泡剂,再将密炼温度控制在95摄氏度,时间控制在10分钟,然后进行翻料步骤,时间控制在2分钟;
(3)将上述步骤经过密炼的混合料进行开炼,将开炼机辊轮温度控制在95摄氏度,将其打匀,进行4次打薄操作,设置辊轮间距为2毫米;
(4)将开炼完成的料置入造粒机进行造粒;
(5)将所需的粒状料放入模具中,通过热压发泡操作,其中热压发泡时间控制在15分钟,发泡温度控制在175摄氏度,加硫时间控制在3分钟;
(6)将热压发泡后的产品冷却后定型即可。

Claims (2)

1.一种耐磨鞋制品材料及制备方法,其特征在于,耐磨鞋制品材料原料由以下重量份比例组成:EVA:45-58份、POE:8-15份、聚氨酯橡胶:8-15份、碳酸钙:5-8份、发泡促进剂:0.5-0.8份、硬脂酸:0.8-1.3份、色母料:2-3份、纳米二氧化硅:5-10份、达玛树脂:5-10份,氢氧化镁阻燃剂:3-8份、DCP:0.5-1份、二氮烯二羧酸酰胺:1-2份。
2.根据权利要求1所述的一种耐磨鞋制品材料及制备方法,其特征在于,主要制备步骤如下:
(1)首先按照工艺配方将所述组分秤取EVA:45-58份、POE:8-15份、聚氨酯橡胶:8-15份、碳酸钙:5-8份、发泡促进剂:0.5-0.8份、硬脂酸:0.8-1.3份、色母料:2-3份、纳米二氧化硅:5-10份、达玛树脂:5-10份,将其充分混合后待用,按照工艺配方秤取适量的氢氧化镁阻燃剂、发泡剂二氮烯二羧酸酰胺和交联剂DCP,比例为氢氧化镁阻燃剂:3-8份、DCP:0.5-1份、二氮烯二羧酸酰胺:1-2份;
(2)将上述混合组分加入密炼机进行阶梯式密炼,密炼温度控制在82~86摄氏度,时间控制在10~15分钟,然后将密炼的温度控制在88~92摄氏度,时间控制在10~15分钟,加入交联剂和发泡剂,再将密炼温度控制在95~99摄氏度,时间控制在8~10分钟,然后进行翻料步骤,时间控制在2~3分钟;
(3)将上述步骤经过密炼的混合料进行开炼,将开炼机辊轮温度控制在90~95摄氏度,将其打匀,进行2~4次打薄操作,设置辊轮间距为0.8~2毫米;
(4)将开炼完成的料置入造粒机进行造粒;
(5)将所需的粒状料放入模具中,通过热压发泡操作,其中热压发泡时间控制在10~15分钟,发泡温度控制在165~175摄氏度,加硫时间控制在3~8分钟;
(6)将热压发泡后的产品冷却后定型即可。
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