CN1062289C - Anti-wash type glazing agent - Google Patents
Anti-wash type glazing agent Download PDFInfo
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- CN1062289C CN1062289C CN96119859A CN96119859A CN1062289C CN 1062289 C CN1062289 C CN 1062289C CN 96119859 A CN96119859 A CN 96119859A CN 96119859 A CN96119859 A CN 96119859A CN 1062289 C CN1062289 C CN 1062289C
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- component
- flushing
- wash
- quaternary ammonium
- silicon oil
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Abstract
The present invention relates to an anti-wash type glazing agent, which belongs to the field of paints. The present invention provides three anti-wash cationic emulsion components, preparation methods for the anti-wash cationic emulsion components, a formula of a glazing agent using the anti-wash components, and a preparation method for a glazing agent. The glazing agent has the functions of resisting water, dust, oxidation, acid rain, static electricity, ultraviolet rays and the washing of a washing agent and improving the surface brightness, has the decontamination effect and is suitable for the protection of the surfaces (with or without a paint film or electroplated layer), of metal, such as automobiles, motorcycles, machines, meters and outer shells of household appliances.
Description
The present invention relates to have multi-functional anti-wash type glazing agent, it belongs to paint field, be mainly used in the metallic surface waterproof and dustproof of (having or not paint film or electrolytic coating), anti-oxidation, anti-acid rain, anti-electrostatic and antiultraviolet, has the increase surface brightness simultaneously, the function of anti-clean-out system flushing is applicable to the protection of automobile, motorcycle, machinery, instrument, household electrical appliances and other metallic surfaces.The present invention does not contain harmful solvent, and is to human body safety, harmless to the metallic surface.
At present, the domestic automobile lustering agent adopts methyl-silicone oil or wax to form bright protective membrane mostly.The not anti-clean-out system flushing of this film, light is not lasting, must be diligent in using, thereby take material, effort and time-consuming.And the lustering agent that has uses hazardous solvent, fluorine Lyons or liquefaction gas, and they are inflammable, explosive, and are dangerous to human body and environment.The external lustering agent product that has occurred adopting amino-functional emulsion or cation amino official energy emulsion, they have anti-flushing characteristic, and for example some United States Patent (USP)s (patent No. 4246029,4509981,4600436 and 4997478) come to this.
One, the invention provides the three kinds of different cationic galactomannans of anti-flushing fluid components:
1. anti-flushing component A: polydimethylsiloxane/amine salt type or quaternary ammonium salt cation surfactant emulsion;
2. anti-flushing B component: amido silicon oil/amine salt type or quaternary ammonium salt cation surfactant emulsion;
3. anti-flushing component C: hydroxy silicon oil/amine salt type or quaternary ammonium salt cation surfactant supernatant liquid.
The structural formula of polydimethylsiloxane is
It is the polymerization degree; Molecular weight 3～60,000;
The manufacture method of each anti-flushing component is according to weight percent, each emulsified thing (is respectively a polydimethylsiloxane, amido silicon oil and hydroxy silicon oil) be 30-60%, cats product is 1-10%, water is 30-69%, above-mentioned three kinds of compositions is put into same container successively stir, make its full and uniform emulsification after, promptly get corresponding anti-flushing component A, B component and component C.
Practical experience shows, the lustering agent that contains above-mentioned three kinds of cationic galactomannan fluid components is coated in and all helps on the metallic surface to form from the teeth outwards to be evenly distributed, has high-gloss finish, adhere firmly is lasting, organosilicon protective layer as thin as a wafer, thus play the good result of waterproof and dustproof, anti-oxidation, anti-acid rain, anti-electrostatic, blast degree and anti-flushing.Two, the prescription of anti-wash type glazing agent is formed (following each component is all counted by weight percentage)
Carnauba wax or montanin wax or ceresine 2～8% preferably get 3～5%; Whiteruss 1～20% preferably gets 2～10%; Oleic acid 0.4～2% preferably gets 0.6～1%; Anti-flushing component 3～6% preferably gets 4～5%; Nonionogenic tenside 3～6% preferably gets 4～5%, and abrasive 0～25% preferably gets 3～20%; Urea 2～4% preferably gets 2～3%, and Xylo-Mucine 0-0.4% preferably gets 0.1～0.3%; Oxidation inhibitor 0.1～0.2%, ultraviolet screener 0.1～0.2%; Spices a little; Add water to 100% at last.
Carnauba wax or montanin wax or ceresine, whiteruss helps film forming, and emulsifying effect is arranged; Oleic acid helps film forming, and regulating effect is arranged; Anti-flushing component is used for film forming and increases luminance brightness; Nonionogenic tenside adopts alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, sorbitan stearate Soxylat A 25-7, dehydration acid pears alcohol oleic acid ester Soxylat A 25-7, sorbitan tristearate and sorbitan monooleate; Abrasive plays the cleaning soil-removing action; Urea plays sterilization, stabilization; Xylo-Mucine has thickening power; Oxidation inhibitor can slow down the oxidation of wax; Ultraviolet screener has the uvioresistant effect.This prescription can make aqua or paste.Three, the manufacture method of anti-wash type glazing agent:
Component carnauba wax in the anti-wash type glazing agent prescription in the specification sheets two or montanin wax or ceresine, whiteruss and oleic acid are put into number one container internal heating successively be fused into liquid; Pour in the number one container after component water being heated to the temperature of wax mixed solution in the number one container with No. second container, put into other composition of prescription simultaneously, kept the constant temperature stir about 15 minutes, after full and uniform emulsification, progressively cooling was also constantly stirred 15 minutes, after near room temperature, stop to stir, can bottle.
The embodiment of the invention 1:
With 50 gram polydimethylsiloxanes, 5 gram octadecyl trimethyl ammonium chlorides and 45 gram water are put into same container for stirring successively, make its full and uniform emulsification after, promptly get 100 and restrain anti-flushing component A;
With 50 gram amido silicon oils, 5 gram octadecyl trimethyl ammonium chlorides and 45 gram water are put into same container for stirring successively, make the full and uniform emulsification of tool after, promptly get 100 and restrain anti-flushing B component:
With 50 gram hydroxy silicon oils; 5 gram dodecyl dimethyl benzyl ammonium chlorides and 45 gram water are put into same container for stirring successively, make its full and uniform emulsification after, promptly get 100 and restrain anti-flushing component C.The embodiment of the invention 2:
The anti-wash type glazing agent weight percentages of components
Anti-flushing component A 4%
Anti-flushing B component 4%
Ceresine 4.2%
Whiteruss 2.52%
Oleic acid 0.7%
Fatty alcohol-polyoxyethylene ether 3%
Sorbitan tristearate 1.45%
Xylo-Mucine 0.3%
β-(4-hydroxyl-3,5-di-tert-butyl-phenyl)
The positive octadecanol ester 0.1% of propionic acid
2-hydroxyl-4-methoxy benzophenone 0.2%
Spices a little
Water 79.35%
To be coated in metallic surface sample (10CM according to the lustering agent that embodiment 2 makes with paint film
*Produce very bright gloss 10CM), touching with hand has smooth and thick and heavy sense.In acid corrosion-resistant test, be that 2.5% dilute sulphuric acid and dilute hydrochloric acid drip respectively and is sprinkling upon on the sample surfaces that applies lustering agent with concentration, at room temperature, and through 24 hours, after acid solution cleaned up, sample for reference surface, the discovery vestige that is corroded.In wash off resistance test, take the cleaning wet sponge to dip in goldfish board dish detergent stoste that daily use chemicals two factories in Beijing produce after ceaselessly firmly the wipe samples surface reaches 40 minutes with hand, the luminance brightness of sample surfaces is constant substantially, be sprayed on the sample surfaces with clear water, water still is globule shape, illustrates that the protective film that lustering agent forms still exists.The embodiment of the invention 3:
4% anti-flushing B component in embodiment 2 prescription is changed into 2% anti-flushing B component and 2% anti-flushing component C, and all the other components are constant.Specimen test result is identical with the test-results of example 2.
Claims (1)
1. anti-wash type glazing agent, this lustering agent comprises carnauba wax or montanin wax or ceresine 3～5%; Whiteruss 2～10%; Oleic acid 0.6～1%; Anti-flushing component 4～5%; Nonionogenic tenside 4～5%; Abrasive 3～20%; Urea 2～3%; Xylo-Mucine 0.1～0.3%; β-(4-hydroxyl-3,5-di-tert-butyl-phenyl) 0.1～0.2%; 2-hydroxyl-4-methoxy benzophenone 0.1～0.2%; Spices a little; Add water to 100% at last; Nonionogenic tenside adopts alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, sorbitan stearate Soxylat A 25-7, the sorbitan monooleate Soxylat A 25-7, sorbitan tristearate and sorbitan monooleate, anti-flushing component is selected from anti-flushing component A, B or C
(1) anti-flushing component A: polydimethylsiloxane/amine salt type or quaternary ammonium salt cation surfactant supernatant liquid;
(2) anti-flushing B component: amido silicon oil/amine salt type or quaternary ammonium salt cation surfactant supernatant liquid;
(3) anti-flushing component C: hydroxy silicon oil/amine salt type or quaternary ammonium salt cation surfactant supernatant liquid;
The manufacture method of each anti-flushing component is according to weight percent, three kinds of emulsified things, wherein component A is a polydimethylsiloxane, B component is an amido silicon oil, component C is a hydroxy silicon oil, respectively get 30～60%, amine salt type or quaternary ammonium salt cation surfactant 1-10%, water 30-69%, more than three kinds of compositions put into same container successively and stir, after making its full and uniform emulsification, promptly get corresponding anti-flushing component A, B and C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96119859A CN1062289C (en) | 1996-10-04 | 1996-10-04 | Anti-wash type glazing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96119859A CN1062289C (en) | 1996-10-04 | 1996-10-04 | Anti-wash type glazing agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1150966A CN1150966A (en) | 1997-06-04 |
| CN1062289C true CN1062289C (en) | 2001-02-21 |
Family
ID=5126003
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96119859A Expired - Fee Related CN1062289C (en) | 1996-10-04 | 1996-10-04 | Anti-wash type glazing agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1062289C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106085247A (en) * | 2016-06-12 | 2016-11-09 | 东莞理工学院 | A kind of antistatic automobile buffing wax cleaned with glazing one and preparation method thereof |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103013348B (en) * | 2012-12-14 | 2014-03-26 | 吴江市利达上光制品有限公司 | Antistatic leather glazing agent |
| CN102993984A (en) * | 2012-12-14 | 2013-03-27 | 吴江市利达上光制品有限公司 | Anti-ultraviolet leather polish |
| CN105462505A (en) * | 2015-08-07 | 2016-04-06 | 无锡桥阳机械制造有限公司 | Machine manufacturing post-treatment intensifying and protecting agent |
| CN107663424A (en) * | 2016-07-28 | 2018-02-06 | 金猴集团威海鞋业有限公司 | A kind of New-type leather glazing moistening cleaning tissue |
| CN106398548A (en) * | 2016-08-27 | 2017-02-15 | 安徽天瞳智能科技有限公司 | Acid and alkali resistant low-yellowing composite material |
| CN106398545A (en) * | 2016-08-27 | 2017-02-15 | 安徽天瞳智能科技有限公司 | Composite material with superhydrophobic performance |
| CN107313050A (en) * | 2017-07-18 | 2017-11-03 | 苏州文仓乐器有限公司 | A kind of metal handicrafts glazing agent |
| CN110628331A (en) * | 2019-10-18 | 2019-12-31 | 廖华平 | Furniture high-gloss agent and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1089979A (en) * | 1993-01-16 | 1994-07-27 | 沈阳德丽日化制造公司 | A kind of jacket oil and manufacture method thereof |
-
1996
- 1996-10-04 CN CN96119859A patent/CN1062289C/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1089979A (en) * | 1993-01-16 | 1994-07-27 | 沈阳德丽日化制造公司 | A kind of jacket oil and manufacture method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106085247A (en) * | 2016-06-12 | 2016-11-09 | 东莞理工学院 | A kind of antistatic automobile buffing wax cleaned with glazing one and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1150966A (en) | 1997-06-04 |
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