CN107523448A - A kind of cleaning agent of cleaning fan of sucking oil fume heavy oil stain and preparation method thereof - Google Patents

A kind of cleaning agent of cleaning fan of sucking oil fume heavy oil stain and preparation method thereof Download PDF

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Publication number
CN107523448A
CN107523448A CN201710704860.7A CN201710704860A CN107523448A CN 107523448 A CN107523448 A CN 107523448A CN 201710704860 A CN201710704860 A CN 201710704860A CN 107523448 A CN107523448 A CN 107523448A
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China
Prior art keywords
parts
cleaning
cleaning agent
oil stain
heavy oil
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Application number
CN201710704860.7A
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Chinese (zh)
Inventor
陈庆
曾军堂
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Chengdu New Keli Chemical Science Co Ltd
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Chengdu New Keli Chemical Science Co Ltd
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Priority to CN201710704860.7A priority Critical patent/CN107523448A/en
Publication of CN107523448A publication Critical patent/CN107523448A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/94Mixtures with anionic, cationic or non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • C11D3/128Aluminium silicates, e.g. zeolites
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2093Esters; Carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/36Organic compounds containing phosphorus
    • C11D3/361Phosphonates, phosphinates or phosphonites
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/90Betaines

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention provides a kind of cleaning agent of cleaning fan of sucking oil fume heavy oil stain, is related to cleaning agent technical field, is made up of the raw material of following parts by weight:37 parts of nano zeolite powder, 25 parts of nano inorganic fiber, 5 10 parts of chelating agent, 7 15 parts of glyceride, 7 15 parts of ethoxylated dodecyl alcohol, 7 15 parts of cocamidopropyl betaine, 40 50 parts of water;Its preparation method is that nano zeolite powder, nano inorganic fiber are added to the water, scattered at a high speed, adds chelating agent, glyceride, stirs, add ethoxylated dodecyl alcohol, cocamidopropyl betaine, stir, produce.Cleaning agent long-time stability prepared by the present invention are good, do not stimulate skin, only need to be a little toward spraying on oil stain during use, are gently smeared with cloth, can quickly remove the oil stain on smoke exhaust ventilator and other kitchen tools, and do not damage utensil and its lacquer painting on surface.

Description

A kind of cleaning agent of cleaning fan of sucking oil fume heavy oil stain and preparation method thereof
Technical field
The present invention relates to cleaning agent technical field, and in particular to a kind of cleaning agent and its system of cleaning fan of sucking oil fume heavy oil stain Preparation Method.
Background technology
With our people's living standard step up and enhancing to health consciousness, China's house detergent disappear The amount of expense is increasing, shows very big development prospect.Predicted according to research, the coming years, Chinese daily-use chemical industry articles for use will be held Continuous steady-state growth, compound growth rate are maintained at 13.4% or so, and overall market can reach more than 2,000 hundred million yuan.Obtain employment large enterprise 300 More families.
As the development of society and the raising of the level of consumption, people are also increasing to the demand of detergent.Domestic consumer one The straight solid detergent accustomed to using based on washing powder and laundry soap, and in recent years, liquid detergent increases speed with what is be exceedingly fast Degree is changing the Distribution Pattern of detergent market.Liquid detergent compared with solid detergent, it is easy to use, dissolving is rapid, Cold washing effect is good, system it is alkaline it is low, more gentle to fabric and skin, be adapted to mechanization washing process, while also have Formula is flexible.The developing direction of detergent is at present:To green safe, multifunctional direction development;Research and design novel surface is lived The effective catalyst of property agent molecule structure;Improve the use of natural reproducible raw material;Greenization preparation and clean manufacturing;Develop low Stimulation, hard water resistance, low-temperature resistance and the high value added product with the multiple functions such as submissive, nursing, antibacterial, color protection, pure and fresh.
Discharge household electrical appliances of the smoke exhaust ventilator as kitchen fume, during much time using generally air inlet, passage, Shell surface forms thick oil stain.Conventional cleaning agent is difficult that infiltration emulsifies thick oil stain, so as to be made for cleaning fan of sucking oil fume Into very big puzzlement.In order to effectively remove oil stain, people are mostly firmly using acid(Such as acetic acid), highly basic auxiliary agent and hyperconcetration clean Agent is used cooperatively, and cleaning effect is more obvious.This method is used not only for cleaning fan of sucking oil fume by people, and for cleaning cupboard The serious kitchen object of the oil stains such as cabinet, table top.But after being cleaned multiple times, we can have found that smoke exhaust ventilator, the lacquer painting of cabinet are dimmed very Come off to corrugation.Its main cause is caused by acid, alkali corrode while oil stain permeate to the lacquer painting of smoke exhaust ventilator, cabinet.
The content of the invention
It is difficult to infiltration cleaning for existing kitchen heavy oil stain, and soda acid cleaning is easily caused cooking-fume exhauster cabinet lacquer painting The defects of damage, the present invention propose a kind of cleaning agent of cleaning fan of sucking oil fume heavy oil stain and preparation method thereof, the cleaning agent of preparation Long-time stability are good, can quickly remove the oil stain on smoke exhaust ventilator and other kitchen tools, and do not damage utensil and utensil table The lacquer painting in face.
To solve the above problems, the present invention uses following technical scheme:
A kind of cleaning agent of cleaning fan of sucking oil fume heavy oil stain, is made up of the raw material of following parts by weight:Nano zeolite powder 3-7 parts, receive Rice inorfil 2-5 parts, chelating agent 5-10 parts, glyceride 7-15 parts, ethoxylated dodecyl alcohol 7-15 parts, cocamidopropyl third Base glycine betaine 7-15 parts, water 40-50 parts.
Preferably, it is made up of the raw material of following parts by weight:5 parts of nano zeolite powder, 4 parts of nano inorganic fiber, chelating agent 7 Part, 10 parts of glyceride, 12 parts of ethoxylated dodecyl alcohol, 9 parts of cocamidopropyl betaine, 45 parts of water.
Preferably, the nano inorganic fiber is in glass fibre, alumina silicate fibre, alumina fibre, quartz fibre It is one or two or more kinds of.
Preferably, the chelating agent is hydroxy ethylene diphosphonic acid, disodium ethylene diamine tetraacetate, ethylenediamine tetrem One or two or more kinds in sour four sodium.
Preferably, the glyceride is tristerin.
A kind of preparation method of the cleaning agent of cleaning fan of sucking oil fume heavy oil stain, step are as follows:By nano zeolite powder, nanometer nothing Machine fiber is added to the water, scattered at a high speed, adds chelating agent, glyceride, stirs, and adds ethoxylated dodecyl alcohol, coconut palm Oleamidopropyl betaine, stir, produce.
Preferably, the scattered rotating speed of the high speed is 1600-2000r/min.
The present invention compared with prior art, has the advantages that:The nano zeolite powder of the present invention is by aluminosilicate The three-D space structure that skeleton is formed, there are hole of all sizes and passage in its skeleton, there is certain adsorptivity, can To adsorb some electrically charged dirts in greasy dirt, it is adsorbed onto in hole or passage and is eliminated;Nano inorganic fiber has very Good mechanical strength, towing oil stain composition can be wound;Nano zeolite powder, nano inorganic fiber, chelating agent in formula and sweet Grease forms micro- brush auxiliary agent, has good permeability and fissility, rubbing action can be produced with heavy oil stain, as countless micro- Seeing brush promotes glyceride to dissolve heavy oil stain, and under the synergic emulsifying effect of surfactant, can reach quick removing The effect of heavy oil stain;Further, since micro- brush auxiliary agent particle diameter is Nano grade, the lacquer painting on the surfaces such as lampblack absorber, cabinet will not be damaged; Cleaning agent long-time stability prepared by the present invention are good, do not stimulate skin, only need during use to spray on oil stain a little, gently smeared i.e. with cloth Can, the oil stain on smoke exhaust ventilator and other kitchen tools can be quickly removed, and do not damage utensil and its lacquer painting on surface.
Embodiment
Below by way of embodiment, the present invention is described in further detail, but this should not be interpreted as to the present invention Scope be only limitted to following example.In the case where not departing from above method thought of the present invention, according to ordinary skill The various replacements or change that knowledge and customary means are made, should be included in the scope of the present invention.
Embodiment 1
A kind of cleaning agent of cleaning fan of sucking oil fume heavy oil stain, is made up of the raw material of following parts by weight:Nano zeolite powder 5 part, nanometer 4 parts of alumina fibre, 7 parts of hydroxy ethylene diphosphonic acid, 10 parts of tristerin, 12 parts of ethoxylated dodecyl alcohol, cocounut oil 9 parts of amido propyl betaine, 45 parts of water.
Preparation method, step are as follows:Nano zeolite powder, nano-alumina fiber are added to the water, 1800r/min's Carry out disperseing at a high speed under rotating speed, add hydroxy ethylene diphosphonic acid, tristerin, stir 7min, add laruyl alcohol polyoxy Vinethene, cocamidopropyl betaine, 8min is stirred, is produced.
Embodiment 2
A kind of cleaning agent of cleaning fan of sucking oil fume heavy oil stain, is made up of the raw material of following parts by weight:Nano zeolite powder 6 part, nanometer 4 parts of alumina silicate fibre, 8 parts of disodium ethylene diamine tetraacetate, 12 parts of tristerin, 10 parts of ethoxylated dodecyl alcohol, cocounut oil 12 parts of amido propyl betaine, 46 parts of water.
Preparation method, step are as follows:Nano zeolite powder, nanometer aluminium silicate fiber are added to the water, 1600r/min's Carry out disperseing at a high speed under rotating speed, add disodium ethylene diamine tetraacetate, tristerin, stir 5min, add laruyl alcohol polyoxy Vinethene, cocamidopropyl betaine, 10min is stirred, is produced.
Embodiment 3
A kind of cleaning agent of cleaning fan of sucking oil fume heavy oil stain, is made up of the raw material of following parts by weight:Nano zeolite powder 3 part, nanometer 5 parts of alumina silicate fibre, 5 parts of hydroxy ethylene diphosphonic acid, 15 parts of tristerin, 7 parts of ethoxylated dodecyl alcohol, cocounut oil acyl 15 parts of aminocarbonyl propyl glycine betaine, 40 parts of water.
Preparation method, step are as follows:Nano zeolite powder, nanometer aluminium silicate fiber are added to the water, 2000r/min's Carry out disperseing at a high speed under rotating speed, add hydroxy ethylene diphosphonic acid, tristerin, stir 5min, add laruyl alcohol polyoxy Vinethene, cocamidopropyl betaine, 5min is stirred, is produced.
Embodiment 4
A kind of cleaning agent of cleaning fan of sucking oil fume heavy oil stain, is made up of the raw material of following parts by weight:Nano zeolite powder 6 part, nanometer 3 parts of alumina fibre, 8 parts of tetrasodium ethylenediamine tetraacetate, 9 parts of tristerin, 9 parts of ethoxylated dodecyl alcohol, cocounut oil acyl 9 parts of aminocarbonyl propyl glycine betaine, 44 parts of water.
Preparation method, step are as follows:Nano zeolite powder, nano-alumina fiber are added to the water, 2000r/min's Carry out disperseing at a high speed under rotating speed, add tetrasodium ethylenediamine tetraacetate, tristerin, stir 10min, add laruyl alcohol polyoxy Vinethene, cocamidopropyl betaine, 10min is stirred, is produced.
Embodiment 5
A kind of cleaning agent of cleaning fan of sucking oil fume heavy oil stain, is made up of the raw material of following parts by weight:Nano zeolite powder 7 part, nanometer 2 parts of quartz fibre, 10 parts of disodium ethylene diamine tetraacetate, 7 parts of tristerin, 15 parts of ethoxylated dodecyl alcohol, cocounut oil acyl 7 parts of aminocarbonyl propyl glycine betaine, 50 parts of water.
Preparation method, step are as follows:Nano zeolite powder, nanometer quartz fibre are added to the water, in turning for 1600r/min Speed is lower disperse at a high speed, is added disodium ethylene diamine tetraacetate, tristerin, is stirred 10min, adds laruyl alcohol polyoxy second Alkene ether, cocamidopropyl betaine, 5min is stirred, is produced.
Embodiment 6
A kind of cleaning agent of cleaning fan of sucking oil fume heavy oil stain, is made up of the raw material of following parts by weight:Nano zeolite powder 5 part, nanometer 5 parts of glass fibre, 7 parts of hydroxy ethylene diphosphonic acid, 12 parts of tristerin, 12 parts of ethoxylated dodecyl alcohol, cocounut oil acyl 10 parts of aminocarbonyl propyl glycine betaine, 46 parts of water.
Preparation method, step are as follows:Nano zeolite powder, nanometer glass fiber are added to the water, in turning for 1700r/min Speed is lower disperse at a high speed, is added hydroxy ethylene diphosphonic acid, tristerin, is stirred 8min, adds laruyl alcohol polyoxy second Alkene ether, cocamidopropyl betaine, 8min is stirred, is produced.
The cleaning agent of 1-6 of the embodiment of the present invention cleaning fan of sucking oil fume heavy oil stains prepared is subjected to oil stain cleaning experiment and production Product corrosion test, result of the test are shown in Table 1.
Test method:
1st, cleaning performance is tested:Thickness is selected to be cut into 20cmx20cm stainless steel substrates for the stainless steel plate of 1mm 304 materials, 15g edible oils are uniformly spread on every, are put into baking oven in 200 °C of h of constant temperature 12, stainless steel substrates surface is formed close attachment Clc layer;The cleaning agent that 10mL is prepared is poured into small hand-held plastic mist spray bottle, is equably sprayed on dirty plate, 3min Afterwards, greasy dirt is firmly wiped with equally uniform with clean sponge block, record removes time and oily waste degradation rate.
2nd, corrosion test:Clean stainless steel substrates, aluminium flake are taken, surface spraying has the stainless steel substrates and surface spraying of PU lacquer paintings There is the aluminium flake of PE lacquer paintings, the correct amount on electronic balance, be then placed in tank (somewhat side is hanging), pour into the cleaning of preparation Agent, until stainless steel substrates and aluminium flake flood completely;After soaking 24 h, taking-up is dried after being rinsed well with water, on electronic balance Correct amount, rate of corrosion is calculated with difference weight method.
Table 1:The oil stain elimination effect and rate of corrosion of cleaning agent
From table 1 it follows that cleaning agent prepared by the present invention removes effect height for heavy oil stain, when reaching more than 95%, and removing Between it is short, very low to stainless steel, aluminium material, and the rate of corrosion of PU, PE lacquer painting, 24 h rate of corrosion is less than 0.004, does not damage device Tool and its lacquer painting on surface.

Claims (7)

1. a kind of cleaning agent of cleaning fan of sucking oil fume heavy oil stain, it is characterised in that be made up of the raw material of following parts by weight:Nanometer boiling Stone flour 3-7 parts, nano inorganic fiber 2-5 parts, chelating agent 5-10 parts, glyceride 7-15 parts, ethoxylated dodecyl alcohol 7-15 parts, Cocamidopropyl betaine 7-15 parts, water 40-50 parts.
2. the cleaning agent of cleaning fan of sucking oil fume heavy oil stain according to claim 1, it is characterised in that by following parts by weight Raw material is made:5 parts of nano zeolite powder, 4 parts of nano inorganic fiber, 7 parts of chelating agent, 10 parts of glyceride, ethoxylated dodecyl alcohol 12 parts, 9 parts of cocamidopropyl betaine, 45 parts of water.
3. the cleaning agent of cleaning fan of sucking oil fume heavy oil stain according to claim 1 or 2, it is characterised in that the nanometer nothing Machine fiber is the one or two or more kinds in glass fibre, alumina silicate fibre, alumina fibre, quartz fibre.
4. the cleaning agent of cleaning fan of sucking oil fume heavy oil stain according to claim 1 or 2, it is characterised in that the chela Mixture is the one or two or more kinds in hydroxy ethylene diphosphonic acid, disodium ethylene diamine tetraacetate, tetrasodium ethylenediamine tetraacetate.
5. the cleaning agent of cleaning fan of sucking oil fume heavy oil stain according to claim 1 or 2, it is characterised in that the glyceride For tristerin.
6. a kind of preparation method of cleaning agent according to any described cleaning fan of sucking oil fume heavy oil stains of claim 1-5, it is special Sign is that step is as follows:Nano zeolite powder, nano inorganic fiber are added to the water, it is scattered at a high speed, add chelating agent, glycerine Ester, stir, add ethoxylated dodecyl alcohol, cocamidopropyl betaine, stir, produce.
7. the preparation method of the cleaning agent of cleaning fan of sucking oil fume heavy oil stain according to claim 6, it is characterised in that described Scattered rotating speed is 1600-2000r/min at a high speed.
CN201710704860.7A 2017-08-17 2017-08-17 A kind of cleaning agent of cleaning fan of sucking oil fume heavy oil stain and preparation method thereof Withdrawn CN107523448A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109181900A (en) * 2018-10-30 2019-01-11 四川夏商生物科技有限公司 A kind of kitchen ventilator biological cleaner and preparation method thereof
CN116814344A (en) * 2023-06-28 2023-09-29 潍坊凯利来生物科技有限公司 Heavy oil cleaning agent for kitchen and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102399653A (en) * 2010-09-08 2012-04-04 武生智 Washing powder formula
KR20120075334A (en) * 2010-12-28 2012-07-06 김양섭 [kitchen hood filter cleaner gaseuraenji] naoh (sodium hydroxide), a mild dishwashing detergent (gogeupalkolgye, alkilbenjengye, surfactants), incense (ohrenjihyang, lemon zest, rabendeohyang, soliphyang, padobaramhyang) of water containing a cleaning agent added proportions
CN103666842A (en) * 2013-12-02 2014-03-26 青岛海芬海洋生物科技有限公司 Special concentrated tableware detergent for catering industry
CN104593171A (en) * 2015-02-01 2015-05-06 晋江市科创源专利服务有限公司 Sanitary ware cleaner

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102399653A (en) * 2010-09-08 2012-04-04 武生智 Washing powder formula
KR20120075334A (en) * 2010-12-28 2012-07-06 김양섭 [kitchen hood filter cleaner gaseuraenji] naoh (sodium hydroxide), a mild dishwashing detergent (gogeupalkolgye, alkilbenjengye, surfactants), incense (ohrenjihyang, lemon zest, rabendeohyang, soliphyang, padobaramhyang) of water containing a cleaning agent added proportions
CN103666842A (en) * 2013-12-02 2014-03-26 青岛海芬海洋生物科技有限公司 Special concentrated tableware detergent for catering industry
CN104593171A (en) * 2015-02-01 2015-05-06 晋江市科创源专利服务有限公司 Sanitary ware cleaner

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109181900A (en) * 2018-10-30 2019-01-11 四川夏商生物科技有限公司 A kind of kitchen ventilator biological cleaner and preparation method thereof
CN116814344A (en) * 2023-06-28 2023-09-29 潍坊凯利来生物科技有限公司 Heavy oil cleaning agent for kitchen and preparation method thereof

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