CN1150966A

CN1150966A - Anti-wash type glazing agent

Info

Publication number: CN1150966A
Application number: CN 96119859
Authority: CN
Inventors: 余士本; 余湛
Original assignee: Individual
Current assignee: Individual
Priority date: 1996-10-04
Filing date: 1996-10-04
Publication date: 1997-06-04
Anticipated expiration: 2016-10-04
Also published as: CN1062289C

Abstract

An anti-flushing polishing paint suitable for metal surface of car, motocycle, machinery, instrument, furniture etc. contains either of three anti-flushing cationic emulsions and has the functions of water proof, dust prevention, anti-oxidation, protect against acidic rain, static electricity and ultraviolet ray. It can increase the surface brightness.

Description

Anti-wash type glazing agent

The present invention relates to have multi-functional anti-wash type glazing agent, it belongs to paint field, is mainly used in the metallic surface waterproof of (having or not paint film or electrolytic coating), dustproof, anti-oxidation, anti-acid rain, anti-electrostatic, and antiultraviolet have the increase surface brightness simultaneously, the function of anti-clean-out system flushing, and clean effect is arranged, be applicable to automobile, motorcycle, machinery, instrument, the protection of household electrical appliances and other metallic surfaces.The present invention does not contain harmful solvent, and is to human body safety, harmless to the metallic surface.

At present, the domestic automobile lustering agent adopts methyl-silicone oil or wax to form bright protective membrane mostly.The not anti-clean-out system flushing of this film, light is not lasting, must be diligent in using, thereby take material, effort and time-consuming.And the lustering agent that has uses hazardous solvent, fluorine Lyons or liquefaction gas, and they are inflammable, and are explosive, dangerous to human body and environment.The external lustering agent product that has occurred adopting amino-functional emulsion or cation amino official energy emulsion, they have anti-flushing characteristic, and for example some United States Patent (USP)s (patent No. 4246029,4509981,4600436 and 4997478) come to this.

One. the invention provides the three kinds of different cationic galactomannans of anti-flushing fluid components:

1. anti-flushing component A:107 silicon rubber/amine salt type or quaternary ammonium salt cation surfactant emulsion;

2. anti-flushing B component: amido silicon oil/amine salt type or quaternary ammonium salt cation surfactant emulsion;

3. anti-flushing component C: hydroxy silicon oil/amine salt type or quaternary ammonium salt cation surfactant emulsion.

The manufacture method of each anti-flushing component is according to weight percent, and each emulsified thing (being respectively 107 silicon rubber, amido silicon oil and hydroxy silicon oil) is 30-60%, and amine salt type or quaternary ammonium salt cation surfactant are 1-10%, and water is 30-69%.Above-mentioned three kinds of compositions are put into same container successively stir, make its full and uniform emulsification after, promptly get corresponding anti-flushing component A, B component and component C.

Practical experience shows, the lustering agent that contains above-mentioned three kinds of cationic galactomannan fluid components is coated in and all helps on the metallic surface to form from the teeth outwards to be evenly distributed, have high-gloss finish, adhere firmly is lasting, organosilicon protective layer as thin as a wafer, thereby play waterproof, dustproof, anti-oxidation, anti-acid rain, anti-electrostatic, the good result of increase surface brightness and anti-flushing.Two. the prescription of anti-wash type glazing agent is formed (following each component is all counted by weight percentage)

Natural wax (carnauba wax, montanin wax, ceresine, paraffin and beeswax) 2-8% preferably gets 3-5%; Whiteruss 1-20% preferably gets 2-10%; Oleic acid 0.4-2% preferably gets 0.6-1%; Anti-flushing component 3-6% preferably gets 4-5%; Nonionogenic tenside 3-6% preferably gets 4-5%; Abrasive 0-25% preferably gets 3-20%; Urea 2-4% preferably gets 2-3%; CMC-NA 0-0.4% preferably gets 0.1-0.3%; Oxidation inhibitor 0.1-0.2%; Ultraviolet screener 0.1-0.2%; Spices a little; Add water to 100% at last.

Natural wax, whiteruss helps film forming, and emulsifying effect is arranged; Oleic acid helps film forming, and regulating effect is arranged; Anti-flushing component is used for film forming and increases luminance brightness; Nonionogenic tenside adopts alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, sorbitan stearate Soxylat A 25-7, dehydration acid pears alcohol oleic acid ester Soxylat A 25-7, sorbitan tristearate and sorbitan monooleate; Abrasive plays the cleaning soil-removing action; Urea plays sterilization, stabilization; CMC-Na has thickening power; Oxidation inhibitor can slow down the oxidation of wax; Ultraviolet screener has the uvioresistant effect.This prescription can make aqua or paste.Three, the manufacture method of anti-wash type glazing agent:

Component natural wax, whiteruss and oleic acid in the anti-wash type glazing agent prescription in the specification sheets two are put into number one container internal heating successively be fused into liquid, pour in the number one container after component water being heated to the temperature of wax mixed solution in the number one container with No. second container, put into other component of prescription simultaneously, kept the constant temperature stir about 15 minutes, after full and uniform emulsification, progressively cooling was also constantly stirred 15 minutes, stopped to stir after near room temperature, can bottle.

The embodiment of the invention 1:

With 50 grams, 107 silicon rubber, 5 gram 1831 cats products and 45 gram water are put into same container for stirring successively, make its full and uniform emulsification after, promptly get 100 and restrain anti-flushing component A;

With 50 gram amido silicon oils, 5 gram 1831 cats products and 45 gram water are put into same container successively and are stirred, make its full and uniform emulsification after, promptly get 100 and restrain anti-flushing B component;

With 50 gram hydroxy silicon oils, 5 gram 1227 cats products and 45 gram water are put into same container for stirring successively, make its full and uniform emulsification after, promptly get 100 and restrain anti-flushing component C.The embodiment of the invention 2:

The anti-wash type glazing agent weight percentages of components

Anti-flushing component A 4%

Anti-flushing B component 4%

Ceresine 4.2%

Whiteruss 2.52%

Oleic acid 0.7%

Fatty alcohol-polyoxyethylene ether 3%

Sorbitan tristearate 1.45%

CMC-Na 0.3％

Antioxidant 1076 0.1%

UV light absorber UV-9 0.2%

Spices a little

Water 79.53%

To be coated in metallic surface sample (10CM according to the lustering agent that embodiment 2 makes with paint film ^*Produce very bright gloss 10CM), touching with hand has smooth and thick and heavy sense.In the acid corrosion-resistant test, with concentration is that 2.5% dilute sulphuric acid and dilute hydrochloric acid drip respectively and is sprinkling upon on the sample surfaces that applies lustering agent, at room temperature, through 24 hours, after acid solution cleaned up, the sample for reference surface, do not find to be corroded vestige, in wash off resistance test, take the cleaning wet sponge to dip in goldfish board dish detergent stoste that daily use chemicals two factories in Beijing produce after ceaselessly firmly the wipe samples surface reaches 40 minutes with hand, the luminance brightness of sample surfaces is constant substantially, is sprayed on the sample surfaces with clear water, water still is globule shape, illustrates that the protective film that lustering agent forms still exists.The embodiment of the invention 3:

4% anti-flushing B component in embodiment 2 prescription is changed into the anti-flushing component C of 2% anti-flushing B component and 2%, and all the other components are constant.Specimen test result is identical with the test-results of example 2.

Claims

1, the three kinds of different cationic galactomannans of anti-flushing fluid components:

1). anti-flushing component A:107 silicon rubber/amine salt type or quaternary ammonium salt cation surfactant emulsion;

2). anti-flushing B component: amido silicon oil/amine salt type or quaternary ammonium salt cation surfactant emulsion;

3). anti-flushing component C: hydroxy silicon oil/amine salt type or quaternary ammonium salt cation surfactant emulsion.

The manufacture method of each anti-flushing component is according to weight percent, (component A is 107 silicon rubber to each emulsified thing, B component is an amido silicon oil, component C is a hydroxy silicon oil) 30-60%, amine salt type or quaternary ammonium salt cation surfactant 1-10%, water 30-69%, more than three kinds of compositions put into same container successively and stir, after making its full and uniform emulsification, promptly get corresponding anti-flushing component A, B component and component C.

2, the prescription of anti-wash type glazing agent is formed (following each component is all counted by weight percentage):

Natural wax (carnauba wax, montanin wax, ceresine, paraffin, beeswax) 2-8%, preferably 3-5%; Whiteruss 1-20%, preferably 2-10%; Oleic acid 0.4-2%, preferably 0.6-1.5%; Anti-flushing component 3-6% in the claim one, preferably 4-5%; Nonionogenic tenside 3-6%, preferably 4-5%; Abrasive 0-25%, preferably 3-20%; Urea 2-4%, preferably 2-3%; CMC-Na0-0.4%, preferably 0.1-0.3%; Antioxidant 1076 0.1-0.2%; Ultraviolet screener Uv-9 0.1-0.2%; Spices is a small amount of, adds water to 100% at last.

Nonionogenic tenside adopts alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, sorbitan stearate Soxylat A 25-7, sorbitan monooleate Soxylat A 25-7, sorbitan tristearate and sorbitan monooleate.

3, the manufacture method of anti-wash type glazing agent:

Natural wax, whiteruss and oleic acid in the claim two are put into number one container internal heating successively be fused into liquid, pour in the number one container heat water to the temperature of wax mixed solution in the number one container with No. second container after, add other component in the prescription simultaneously, kept the constant temperature stir about 15 minutes, after full and uniform emulsification, progressively cooling and continuous the stirring 15 minutes stop to stir after near room temperature, can bottle.