CN106085247A - A kind of antistatic automobile buffing wax cleaned with glazing one and preparation method thereof - Google Patents

A kind of antistatic automobile buffing wax cleaned with glazing one and preparation method thereof Download PDF

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Publication number
CN106085247A
CN106085247A CN201610408295.5A CN201610408295A CN106085247A CN 106085247 A CN106085247 A CN 106085247A CN 201610408295 A CN201610408295 A CN 201610408295A CN 106085247 A CN106085247 A CN 106085247A
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wax
antistatic
emulsion
glazing
automobile
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CN106085247B (en
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徐勇军
蔡其文
蔡卓弟
尹辉斌
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Dongguan University of Technology
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Dongguan University of Technology
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09GPOLISHING COMPOSITIONS; SKI WAXES
    • C09G1/00Polishing compositions
    • C09G1/06Other polishing compositions
    • C09G1/08Other polishing compositions based on wax
    • C09G1/10Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin
    • C09G1/12Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin mixtures of wax and silicon-containing polycondensates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/835Mixtures of non-ionic with cationic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/08Silicates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/18Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/28Heterocyclic compounds containing nitrogen in the ring
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/378(Co)polymerised monomers containing sulfur, e.g. sulfonate
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/667Neutral esters, e.g. sorbitan esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols

Abstract

The present invention relates to buffing wax field, it is specifically related to a kind of antistatic automobile buffing wax cleaned with glazing one and preparation method thereof, a kind of cleaning of the present invention and the antistatic automobile buffing wax of glazing one, in parts by weight, component is the preservative of the ultraviolet absorber of the brightener of the compositional liquor of the emulsion of antistatic additive, 5%~10%, 25%~35%, 1%~2%, 0.1%~0.3%, 0.1%~0.2% and the deionized water of 55%~65% of 1%~4%;Described antistatic additive is sulfonated phenylethylene and maleic acid polymers or sulfonated polystyrene polymers;The solute of described emulsion is the mixture of Brazil wax, paraffin, Fischer-Tropsch wax and emulsifying agent, and solvent is emulsifying agent, and the mass fraction of solute is 15%~20%, and in solute, Brazil wax, paraffin, the mass ratio of Fischer-Tropsch wax are 2:4:1~2:8:1.The automobile polishing wax of the present invention integrates the functions such as cleaning dedusting, polishing, anti-ultraviolet, antistatic, sterilization, easy to use.

Description

A kind of antistatic automobile buffing wax cleaned with glazing one and preparation method thereof
Technical field
The present invention relates to buffing wax field, particularly relate to a kind of clean and glazing one antistatic automobile buffing wax and Its preparation method.
Background technology
Along with the progress of society, the development of science and technology, the metallic article application in industrial or agricultural and people's lives field is increasingly Extensively, the use of metallic article is required more and more higher by people, and the polishing effect of metallic article increasingly causes the attention of people.
Hyundai Motor uses metallic paint more and more widely, and the finishing system of metallic paint is that colored paint (lacquer) adds clear recoat, With the passage of time, the color of lacquer can produce and take off change, and then affects automobile appearance.For protection metallic paint, keep vehicle body beautiful neatly, Car owner usually i.e. can be formed coating of wax film at bodywork surface outermost layer protect vehicle body for liking car waxing.
The use of major part car wax needs three steps to complete, and the first step cleans car surface, and second step is that surface is beaten Wax and etc. cere mummification, the 3rd step is removed unnecessary wax, is i.e. polished, in general polishing with strength to ensure surface-brightening Change.
There are problems in traditional automobile waxing process, on the one hand, during carwash, cleaning agent majority used is detergent, fertilizer Soap and dish detergent etc. be universal rather than the product of tailored version, and pH value is typically 10.3~10.9, and automotive paints acid and alkali-resistance Holding capacity is pH value less than 8.0, the cleaning agent more than 8.0 of the life-time service pH value, though car surface dust can be removed, to paint Face causes infringement, and the lighter tarnishes, severe one heavy corrosion.Second aspect, wax used during waxing is generally hard waxes, car Body waxing within more than 20 hour, just can be polished after (some product time can be shorter, the most several hours), period, cere by Can adsorb substantial amounts of dust and the grains of sand in electrostatic interaction, during polishing, they can scratch lacquer painting, produces a large amount of cut, has a strong impact on light Pool degree.The third aspect, automobile polishing process needs through three process, and operation is complicated, in-convenience in use.Fourth aspect, existing The automobile polishing wax of technology only has the function promoting surface brightness, and function is more single, and using effect is bad.
Summary of the invention
For solving the problems referred to above, the present invention provides merits such as having collection cleaning dedusting, polishing, anti-ultraviolet, antistatic, sterilization Can be in one, a kind of cleaning easy to use and the antistatic automobile buffing wax of glazing one and preparation method thereof.
The technical solution adopted in the present invention is: a kind of cleaning and the antistatic automobile buffing wax of glazing one, by quality Mark meter, component is the compositional liquor of the emulsion of antistatic additive, 5%~10%, 25%~35%, 1%~2% of 1%~4% The preservative of the ultraviolet absorber of brightener, 0.1%~0.3%, 0.1%~0.2% and the deionized water of 55%~65%; Described antistatic additive is sulfonated phenylethylene and maleic acid polymers or sulfonated polystyrene polymers;The solute of described emulsion is The mixture of Brazil wax, paraffin, Fischer-Tropsch wax and emulsifying agent, solvent is emulsifying agent, the mass fraction of solute be 15%~ 20%, in solute, Brazil wax, paraffin, the mass ratio of Fischer-Tropsch wax are 2:4:1~2:8:1.
Being improved to further technique scheme, described compositional liquor is cation and the surface activity of nonionic composition Agent, the component of compositional liquor be mass fraction be the fatty alcohol of Dodecyl trimethyl ammonium chloride, 25%~35% of 8%~12% The deionization of the sodium silicate of iminodisuccinic acid tetrasodium salt, 2%~4%, 50%~60% of polyoxyethylene ether, 1%~3% Water.
Being improved to further technique scheme, described ultraviolet absorber is benzotriazole.
Being improved to further technique scheme, described preservative is sorbic acid salt.
Being improved to further technique scheme, the emulsifying agent in described emulsion is Span80 and Tween80.
Being improved to further technique scheme, described brightener is polydimethylsiloxane.
The manufacture method of a kind of antistatic automobile buffing wax cleaned with glazing one, comprises the following steps,
1. emulsion and compositional liquor are prepared;
2. take reaction vessel, in reaction vessel, add 55 parts~65 parts of deionized waters, add 0.1 part~0.2 part and prevent Rotten agent, stirs to mix homogeneously under room temperature;
3. to step 2. in add step 1. in compositional liquor 25 parts~35 parts, stirring to mix homogeneously;
4. to step 3. in add step 1. in emulsion 5 parts~10 parts, add 1 part~4 parts of antistatic additive, stirring extremely It is uniformly dispersed;
5. to step 4. 1 part~2 parts of brighteners, 0.1 part~0.3 part of ultraviolet absorber of middle addition, stirring is continued to microemulsion Liquid is completely dispersed uniformly, obtains oil-in-water type automobile polishing wax.
Being improved to further technique scheme, the preparation method of step 1. middle emulsion is to weigh a certain amount of Mass ratio be the Brazil wax of 2:4:1~2:8:1, paraffin, Fischer-Tropsch wax in a container, add emulsifying agent Span80 and Tween80, obtains the emulsion that mass fraction is 15%~20% of Brazil wax, paraffin, Fischer-Tropsch wax mixture solute, Heating in 90 ± 5 DEG C of thermostat water baths and dissolve, stirring, to making emulsion dispersed, is then incubated under 30 ± 5 DEG C of environment, To uniform and stable emulsion.
Being improved to further technique scheme, the preparation method of step 1. middle compositional liquor is that taking mass fraction is The imino group of the fatty alcohol-polyoxyethylene ether of Dodecyl trimethyl ammonium chloride, 25%~35%, 1%~3% of 8%~12% The deionized water of the sodium silicate of disuccinic acid tetrasodium salt, 2%~4%, 50%~60%, stirring, mix homogeneously, prepare compounding Liquid.
The invention have the benefit that
1, on the one hand, the automobile polishing wax of the present invention contains emulsion and the compositional liquor with cleaning function, has increase The brightener of car surface brightness function, has the ultraviolet absorber absorbing ultraviolet function, has the anti-of anti-static function Electrostatic agent, has the preservative of sterilizing function so that the present invention collects cleaning dedusting, polishing, anti-ultraviolet, antistatic, sterilization etc. Function is in one, functional diversities;Second aspect, in the present invention, the solute of emulsion is Brazil wax, paraffin, Fischer-Tropsch wax With the mixture of emulsifying agent, solvent is emulsifying agent, and the mass fraction of solute is 15%~20%, Brazil wax, stone in solute Wax, the mass ratio of Fischer-Tropsch wax are 2:4:1~2:8:1 so that the automobile polishing wax that the present invention prepares is oil-in-water shape, can directly spray It is applied to car surface, produces medium foam, polish gently with non-woven cotton again with after towel, one layer can be formed and have anti-quiet Electricity and the bright film of anti-ultraviolet function, easy to use, clean dust collection capacity strong;The third aspect, antistatic additive is sulfonation benzene second Alkene and maleic acid polymers or sulfonated polystyrene polymers, sheet resistance value can reach 107~1010Ohm, antistatic effect Significantly;Fourth aspect, the PH of the automobile polishing wax of the present invention is 6~8, to automobile metal and lacquer painting non-corrosiveness, to human body skin Skin nonirritant;5th aspect, in emulsion, paraffin content is higher, carries out compounding use by compositional liquor, can be formed stable The automobile polishing wax of emulsified state, the cere formed during use is stable, and owing to paraffin price is low, advantageously reduces the present invention's Production cost.
2, compositional liquor be cation and nonionic composition surfactant, the component of compositional liquor be mass fraction be 8% ~the imino-diacetic of the fatty alcohol-polyoxyethylene ether of the Dodecyl trimethyl ammonium chloride of 12%, 25%~35%, 1%~3% The deionized water of the sodium silicate of succinic acid tetrasodium salt, 2%~4%, 50%~60%.Composition in compositional liquor be cation and Nonionic, without anion, will not be combined formation precipitation, improve the use of the present invention further with the metallic paint of car surface Effect, and compositional liquor is owing to containing Dodecyl trimethyl ammonium chloride and fatty alcohol-polyoxyethylene ether, having cleaning and emulsifying Function so that the oil-in-water state of final products is more stable, and sodium silicate plays cementation so that the cere molecular density of formation Height, closely stable, iminodisuccinic acid tetrasodium salt plays the effect of chelating agent so that combine tight between each formula of the present invention Close, stable in properties, compositional liquor be mainly composed of deionized water, price is low, reduces the production cost of the present invention.
3, ultraviolet absorber is benzotriazole, and the strong absorbing wavelength of energy is the ultraviolet of 270~380nm, chemically stable Property good, volatility is minimum, be conducive to promote the present invention anti-ultraviolet property.
4, preservative is sorbic acid salt, good anti-bacterial effect, and better heat stability, when automobile is exposed to the sun in the sun not Easily decompose, improve the antibacterial effect of the present invention further.
5, brightener is polydimethylsiloxane, and energy is heat-resisting, cold-resistant, waterproof, viscosity varies with temperature little and surface tension Little, when automobile is in high temperature or low temperature or rainwater environment, brightener is formed stable so that automobile polishing is effective, cere Stable in properties.
6, the emulsifying agent in emulsion is Span80 and Tween80, and Brazil wax, paraffin, Fischer-Tropsch wax can be the most molten Solution, in Span80 and Tween80, forms in stable condition emulsion.
7, the manufacture method of the antistatic automobile buffing wax of a kind of cleaning and glazing one, preparation technology is simple, reacts ring Border is easily reached.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1:
A kind of cleaning and the antistatic automobile buffing wax of glazing one, in terms of mass fraction, its component is, antistatic additive 1%, emulsion 7%, compositional liquor 25%, polydimethylsiloxane 1.5%, ultraviolet absorber 0.3%, preservative 0.2% and going Ionized water 65%.
Wherein, antistatic additive is sulfonated phenylethylene and maleic acid polymers, i.e.TL-3 (U.S. Aksu promise shellfish That company).
Wherein, the solute of emulsion is Brazil wax (Suzhou Louis Bernot rubber-plastics material company limited), paraffin (Maoming stone Change Southern Sea Brand), Fischer-Tropsch wax (Malaysia shell) and the mixture of emulsifying agent (Zibo Correspondent oils and fats Fine Chemical Co., Ltd), Solvent is emulsifying agent, and the mass fraction of solute is 15%, and in solute, Brazil wax, paraffin, the mass ratio of Fischer-Tropsch wax are 2:4: 1。
Wherein, compositional liquor is cation and the surfactant of nonionic composition, and the component of compositional liquor is that mass fraction is The Dodecyl trimethyl ammonium chloride (Shanghai Ying Gongmei link detection reagent company limited) of 10%, the aliphatic alcohol polyethenoxy of 30% Ether (Jiangsu Hai'an Petrochemical Plant), the iminodisuccinic acid tetrasodium salt (Shandong Yuan Lian Chemical Co., Ltd.) of 2%, 3% Sodium silicate (Hua Chuan Chemical Co., Ltd. of Wuhan City), the deionized water of 55%, form in this ratio is compounding.
Ultraviolet absorber is benzotriazole, and the strong absorbing wavelength of energy is the ultraviolet of 270~380nm, chemical stability Good, volatility is minimum, is conducive to promoting the anti-ultraviolet property of the present invention.
Preservative is sorbic acid potassium salt (eastman chemical product company), and good anti-bacterial effect, and better heat stability work as automobile It is not easily decomposed when being exposed to the sun in the sun, improves the antibacterial effect of the present invention further.
Brightener is polydimethylsiloxane (Si Luoke), and energy is heat-resisting, cold-resistant, waterproof, viscosity varies with temperature little and table Surface tension is little, and when automobile is in high temperature or low temperature or rainwater environment, brightener is formed stable so that automobile polishing effect Good, cere stable in properties.
Emulsifying agent in emulsion is Span80 (Zibo Correspondent oils and fats Fine Chemical Co., Ltd) and Tween80 (Zibo Correspondent oils and fats Fine Chemical Co., Ltd), Brazil wax, paraffin, Fischer-Tropsch wax can well be dissolved in Span80 and Tween80 In, form in stable condition emulsion.
A kind of preparation method of the antistatic automobile buffing wax cleaned with glazing one:
1. emulsion and compositional liquor are prepared;
2. take reaction vessel, in reaction vessel, add deionized water 65kg, add preservative 0.2kg, under room temperature Stirring is to mix homogeneously;
3. to step 2. in add step 1. in compositional liquor 25kg, stirring to mix homogeneously;
4. to step 3. in add step 1. in emulsion 7kg, add antistatic additive 1kg, stirring to being uniformly dispersed;
5. to step 4. middle brightener 1.5kg, the ultraviolet absorber 0.3kg of adding, continuation stirring is completely dispersed to microemulsion Uniformly, oil-in-water type automobile polishing wax is obtained.
Wherein, the compound method of emulsion is: weigh a certain amount of mass ratio be the Brazil wax of 2:4:1, paraffin and Fischer-Tropsch wax (Fischer-Tropsch wax softening point 90 DEG C), in a container, adds emulsifying agent Span80 and Tween80, and the solvent of blended wax accounts for breast The mass fraction changing liquid is 15%~20%, heats and dissolves, be stirred vigorously 30min and make emulsifying in 90 ± 5 DEG C of thermostat water baths Liquid is dispersed, is then incubated 15min at 30 DEG C, finally gives uniform and stable Brazil wax/paraffin/Fischer-Tropsch wax emulsifying Liquid.
Embodiment 2:
A kind of cleaning and the antistatic automobile buffing wax of glazing one, in terms of mass fraction, its component is, antistatic additive 3%, emulsion 5%, compositional liquor 35%, polydimethylsiloxane 1.5%, ultraviolet absorber 0.3%, preservative 0.2% and going Ionized water 55%.
Wherein, antistatic additive is sulfonated polystyrene polymers, i.e.(U.S. Akzo Nobel is public for TL-130 Department).
Wherein, the solute of emulsion is Brazil wax (Suzhou Louis Bernot rubber-plastics material company limited), paraffin (Maoming stone Change Southern Sea Brand), Fischer-Tropsch wax (Malaysia shell) and the mixture of emulsifying agent (Zibo Correspondent oils and fats Fine Chemical Co., Ltd), Solvent is emulsifying agent, and the mass fraction of solute is 15%, and in solute, Brazil wax, paraffin, the mass ratio of Fischer-Tropsch wax are 2:8: 1。
Wherein, compositional liquor is cation and the surfactant of nonionic composition, and the component of compositional liquor is that mass fraction is The Dodecyl trimethyl ammonium chloride (Shanghai Ying Gongmei link detection reagent company limited) of 10%, the aliphatic alcohol polyethenoxy of 30% Ether (Jiangsu Hai'an Petrochemical Plant), (Shandong far joins the limited public affairs of chemical industry to the chelating agent iminodisuccinic acid tetrasodium salt of 2% Department), the sodium silicate (Hua Chuan Chemical Co., Ltd. of Wuhan City) of 3%, the deionized water of 55%, form in this ratio is compounding.
Ultraviolet absorber is benzotriazole, and the strong absorbing wavelength of energy is the ultraviolet of 270~380nm, chemical stability Good, volatility is minimum, is conducive to promoting the anti-ultraviolet property of the present invention.
Preservative is sorbic acid potassium salt (eastman chemical product company), and good anti-bacterial effect, and better heat stability work as automobile It is not easily decomposed when being exposed to the sun in the sun, improves the antibacterial effect of the present invention further.
Brightener is polydimethylsiloxane (Si Luoke), and energy is heat-resisting, cold-resistant, waterproof, viscosity varies with temperature little and table Surface tension is little, and when automobile is in high temperature or low temperature or rainwater environment, brightener is formed stable so that automobile polishing effect Good, cere stable in properties.
Emulsifying agent in emulsion is Span80 (Zibo Correspondent oils and fats Fine Chemical Co., Ltd) and Tween80 (Zibo Correspondent oils and fats Fine Chemical Co., Ltd), Brazil wax, paraffin, Fischer-Tropsch wax can well be dissolved in Span80 and Tween80 In, form in stable condition emulsion.
A kind of preparation method of the antistatic automobile buffing wax cleaned with glazing one:
1. emulsion and compositional liquor are prepared;
2. take reaction vessel, in reaction vessel, add deionized water 55kg, add preservative 0.2kg, under room temperature Stirring is to mix homogeneously;
3. to step 2. in add step 1. in compositional liquor 35kg, stirring to mix homogeneously;
4. to step 3. in add step 1. in emulsion 5kg, add antistatic additive 3kg, stirring to being uniformly dispersed;
5. to step 4. middle brightener 1.5kg, the ultraviolet absorber 0.3kg of adding, continuation stirring is completely dispersed to microemulsion Uniformly, oil-in-water type automobile polishing wax is obtained.
Wherein, the compound method of emulsion is: weigh a certain amount of mass ratio be the Brazil wax of 2:8:1, paraffin and Fischer-Tropsch wax (Fischer-Tropsch wax softening point 90 DEG C), in a container, adds emulsifying agent Span80 and Tween80, and the solvent of blended wax accounts for breast The mass fraction changing liquid is 15%~20%, heats and dissolves, be stirred vigorously 30min and make emulsifying in 90 ± 5 DEG C of thermostat water baths Liquid is dispersed, is then incubated 15min at 30 DEG C, finally gives uniform and stable Brazil wax/paraffin/Fischer-Tropsch wax emulsifying Liquid.
Matched group:
Buy the higher buffing wax in market share three kinds from the market, be matched group 1 respectively: protect and grant profit (BOTNY) throwing Light wax, matched group 2:SOFT99 radiance water wax liquid wax and matched group 3: Wei Sili (Veslee) cleaning and polishing liquid wax.
Test experiments:
Respectively the automobile polishing wax of embodiment 1, embodiment 2 and matched group is used in same model and surface cleanness phase On same automobile, observe Product Status, glossiness, cleaning capacity, antistatic effect and anti-uv-ray, test result such as table Shown in 1:
Table 1: test result statistical table
Interpretation of result:
It can be seen that it is solid, shaped that the guarantor of matched group 1 grants profit (BOTNY) buffing wax from the experimental result statistical table of table 1, In-convenience in use, and not there is when being used alone cleaning capacity, it is necessary to matching purge agent uses, matched group 2 and the throwing of matched group 3 Light wax is all in O/w emulsion shape, easy to use, has decontamination and the effect of light, but surface resistivity is too high, and antistatic is imitated The most bad.
Relative to matched group 1, matched group 2 and matched group 3, the automobile polishing wax of the present invention, in O/w emulsion shape, can be straight Connect and be sprayed at car surface, easy to use;Glossiness is high, and polishing effect is good;Soil removal efficiency is high, and cleaning capacity is strong;Sheet resistance is high, And not higher than 1010, antistatic effect is good;Ultraviolet ray transmissivity is low, and preventing ultraviolet effect is good.Therefore, the present invention has good Combination property, provides the product of a excellent performance for car detailing, and the market space is wide.
Embodiment described above only have expressed the several embodiments of the present invention, and it describes more concrete and detailed, but also Therefore the restriction to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that, for those of ordinary skill in the art For, without departing from the inventive concept of the premise, it is also possible to make some deformation and improvement, these broadly fall into the guarantor of the present invention Protect scope.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.

Claims (9)

1. one kind is cleaned and the antistatic automobile buffing wax of glazing one, it is characterised in that: in parts by weight, component is 1% ~the brightener of the compositional liquor of the emulsion of the antistatic additive of 4%, 5%~10%, 25%~35%, 1%~2%, 0.1%~ The preservative of ultraviolet absorber, 0.1%~0.2% of 0.3% and the deionized water of 55%~65%;Described antistatic additive is sulphur Change styrene and maleic acid polymers or sulfonated polystyrene polymers;The solute of described emulsion be Brazil wax, paraffin, Fischer-Tropsch wax and the mixture of emulsifying agent, solvent is emulsifying agent, and the mass fraction of solute is 15%~20%, babassu in solute Wax, paraffin, the mass ratio of Fischer-Tropsch wax are 2:4:1~2:8:1.
A kind of cleaning the most according to claim 1 and the antistatic automobile buffing wax of glazing one, it is characterised in that: described Compositional liquor be cation and nonionic composition surfactant, the component of compositional liquor be mass fraction be the ten of 8%~12% Iminodisuccinic acid four sodium of the fatty alcohol-polyoxyethylene ether of dialkyl group trimethyl ammonium chloride, 25%~35%, 1%~3% The deionized water of the sodium silicate of salt, 2%~4%, 50%~60%.
A kind of cleaning the most according to claim 1 and the antistatic automobile buffing wax of glazing one, it is characterised in that: described Ultraviolet absorber is benzotriazole.
A kind of cleaning the most according to claim 1 and the antistatic automobile buffing wax of glazing one, it is characterised in that: described Preservative is sorbic acid salt.
A kind of cleaning the most according to claim 1 and the antistatic automobile buffing wax of glazing one, it is characterised in that: described Emulsifying agent in emulsion is Span80 and Tween80.
A kind of cleaning the most according to claim 1 and the antistatic automobile buffing wax of glazing one, it is characterised in that: described Brightener is polydimethylsiloxane.
7. one kind is cleaned and the manufacture method of glazing antistatic automobile buffing wax integrally, it is characterised in that: comprise the following steps,
1. emulsion and compositional liquor are prepared;
2. take reaction vessel, in reaction vessel, add 55 parts~65 parts of deionized waters, add 0.1 part~0.2 portion of preservative, Stir to mix homogeneously under room temperature;
3. to step 2. in add step 1. in compositional liquor 25 parts~35 parts, stirring to mix homogeneously;
4. to step 3. in add step 1. in emulsion 5 parts~10 parts, add 1 part~4 parts of antistatic additive, stirring to dispersion Uniformly;
5. to step 4. 1 part~2 parts of brighteners, 0.1 part~0.3 part of ultraviolet absorber of middle addition, stirring is continued complete to microemulsion Entirely it is uniformly dispersed, obtains oil-in-water type automobile polishing wax.
The manufacture method of a kind of antistatic automobile buffing wax cleaned with glazing one the most according to claim 7, it is special Levy and be: the preparation method of step 1. middle emulsion is to weigh the babassu that a certain amount of mass ratio is 2:4:1~2:8:1 Wax, paraffin, Fischer-Tropsch wax, in a container, add emulsifying agent Span80 and Tween80, obtain Brazil wax, paraffin, Fischer-Tropsch wax The mass fraction of mixture solute is the emulsion of 15%~20%, heats and dissolve in 90 ± 5 DEG C of thermostat water baths, and stirring is extremely Make emulsion dispersed, be then incubated under 30 ± 5 DEG C of environment, obtain uniform and stable emulsion.
The manufacture method of a kind of antistatic automobile buffing wax cleaned with glazing one the most according to claim 7, it is special Levy and be: the preparation method of step 1. middle compositional liquor is to take the trimethyl chlorination that mass fraction is 8%~12% The silicic acid of iminodisuccinic acid tetrasodium salt, 2%~4% of the fatty alcohol-polyoxyethylene ether of ammonium, 25%~35%, 1%~3% Receive, 50%~the deionized water of 60%, stirring, mix homogeneously, prepare compositional liquor.
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CN109852258A (en) * 2017-11-30 2019-06-07 菏泽海诺知识产权服务有限公司 A kind of decontamination wax and preparation method thereof
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CN109852258A (en) * 2017-11-30 2019-06-07 菏泽海诺知识产权服务有限公司 A kind of decontamination wax and preparation method thereof
CN113088197A (en) * 2021-05-20 2021-07-09 谢文锁 Polishing wax and preparation method thereof

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