CN106957747A - A kind of microcapsules non-water type vehicle cleaning detergent and preparation method thereof - Google Patents

A kind of microcapsules non-water type vehicle cleaning detergent and preparation method thereof Download PDF

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Publication number
CN106957747A
CN106957747A CN201710206224.1A CN201710206224A CN106957747A CN 106957747 A CN106957747 A CN 106957747A CN 201710206224 A CN201710206224 A CN 201710206224A CN 106957747 A CN106957747 A CN 106957747A
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China
Prior art keywords
parts
microcapsules
type vehicle
water
vehicle cleaning
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Pending
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CN201710206224.1A
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Chinese (zh)
Inventor
吴长应
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Wuhu Yangzhan New Material Technology Service Co Ltd
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Wuhu Yangzhan New Material Technology Service Co Ltd
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Priority to CN201710206224.1A priority Critical patent/CN106957747A/en
Publication of CN106957747A publication Critical patent/CN106957747A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/835Mixtures of non-ionic with cationic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2093Esters; Carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3715Polyesters or polycarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/74Carboxylates or sulfonates esters of polyoxyalkylene glycols

Abstract

A kind of microcapsules non-water type vehicle cleaning detergent and preparation method thereof, belongs to material clean field, and non-water type vehicle cleaning detergent of the invention includes the raw material of following parts by weight:30 35 parts of dodecyl benzyl dimethyl ammonium chloride, 35 40 parts of sorbitol polyoxyethylene ether laurate, 7 10 parts of CARNAUBA WAX microcapsules, 35 parts of cetyl trimethylammonium bromide, 56 parts of suspending agent, 23 parts of aqueous wax, 35 parts of the tertiary butyl ether of ethylene glycol, 40 50 parts of ionized water, 23 parts of essence.The anhydrous detergent solution of the present invention need not use water, you can cleaning, glazing, waxing, the purpose of maintenance four steps unification be realized, with excellent washing, nursing and glazing persistence.

Description

A kind of microcapsules non-water type vehicle cleaning detergent and preparation method thereof
Technical field
The invention belongs to material clean field, more particularly to a kind of microcapsules non-water type vehicle cleaning detergent and preparation method thereof.
Background technology
With the development of Domestic Automotive Industry, automobile enters common people family.Automobile decoration, motor vehicle repair, Motor Maintenance etc. Industry also enters the development passage rapidly grown up.Vehicle was in using, easily full of dust, therefore, and carwash is into have An essential homework in car family.Current carwash market, either HAND CAR ASH or automatic car washing machine carwash, are all needed Substantial amounts of running water is wanted, the special special industry water for being directed to The Wash, water price remains high.According to relevant report " Beijing The notice of the issue adjustment Committee of Development and Reform today non-resident use water price lattice in Beijing, from 1 day May in 2014, car wash trade, bathing industry, Pure water industry, golf course, skifield water user these special industries user, water price are 160 yuan every cubic metre ", it is assumed that it is every Car car washing water is 100 liters, is 16 yuan only with water cost price, therefore artificial and venue cost is considered in carwash shop, is washed every time Fare will collect 40 yuan substantially.This is also one not small spending to car owner.
Simultaneously, it is contemplated that China's vehicle fleet size cumulative year after year, car washing water total amount is also continuously increased.And China is individual lack Man of land that abounds in rivers and lakes, especially in northern area, water resource is especially precious, and substantial amounts of water resource is used for into automobile, it is clear that be a kind of resource wave Take.And on automobile it is complete it is cured after easily washed away by rainwater, persistence is poor.
The content of the invention
In view of the above problems, it is an object of the invention to provide a kind of microcapsules waterless carwash liquid, it is intended to which solution has washing Car high cost, the technical problem of waste water resource, and there is the anhydrous detergent of the present invention excellent washing, nursing and glazing to hold Long property.
The present invention uses following technical scheme:
A kind of microcapsules non-water type vehicle cleaning detergent, includes the raw material of following parts by weight:Dodecyl benzyl dimethyl ammonium chloride 30-35 parts, 35-40 parts of sorbitol polyoxyethylene ether laurate, 7-10 parts of CARNAUBA WAX microcapsules, cetyl trimethyl 3-5 parts of ammonium bromide, 5-6 parts of suspending agent, aqueous wax 2-3 parts, tertiary butyl ether 3-5 parts of ethylene glycol, 40-50 parts of ionized water, essence 2-3 Part.
It is preferred that, described CARNAUBA WAX microcapsules are that the CARNAUBA WAX of 3-4 mass parts is dissolved in into 70-80 mass parts Water in, and add the hydrophilic emulsifier of 2-3 mass parts, emulsion reaction carried out in the presence of 40-50 DEG C of magnetic stirring apparatus It is made, the stir speed (S.S.) of described magnetic stirring apparatus is 1000-3000rpm, and emulsification times are 30-40min.
It is preferred that, described suspending agent is macromolecule polyacrylic acid.
It is preferred that, described aqueous wax is aqueous montanin wax.
It is preferred that, described essence is lemon extract.
A kind of preparation method of microcapsules non-water type vehicle cleaning detergent, ionized water is added in agitator tank, is heated to add at 50 DEG C Enter dodecyl benzyl dimethyl ammonium chloride, sorbitol polyoxyethylene ether laurate, CARNAUBA WAX microcapsules, cetyl Trimethylammonium bromide, suspending agent, aqueous wax, the tertiary butyl ether of ethylene glycol and being stirred continuously then are sequentially added under the conditions of 40 DEG C to be made It all dissolves, and is cooled to after normal temperature, and addition essence, which stirs, both obtains non-water type vehicle cleaning detergent.
The beneficial effects of the present invention are:
1) present invention is used cooperatively using cationic surfactant with nonionic surfactant, and detergency ability is more preferable, Be sprayed at car body shell, you can play its excellent wetting, infiltration, foaming loosen, dissolving, suspension effect and dirt is had Effect is removed, and cleaning, glazing, waxing, the purpose of maintenance four steps unification can be achieved.
2) CARNAUBA WAX microcapsules are added, it is ensured that persistence of the cured matter in car surface.
3) present invention is added with care agent, and the nursing of current waxing can be substituted completely, has polishing effect, is not only applicable In carbody shell, the decontamination on the hard objects such as leather, plastics, metal, plank, floor tile surface is equally applicable to.
4) present invention contains sludge anti redeposition agent, the dirt after washing is easy to removing, is difficult redeposited in object Surface.
Embodiment
Embodiment 1
A kind of microcapsules non-water type vehicle cleaning detergent, includes the raw material of following parts by weight:Dodecyl benzyl dimethyl ammonium chloride 30 parts, 35 parts of sorbitol polyoxyethylene ether laurate, 7 parts of CARNAUBA WAX microcapsules, cetyl trimethylammonium bromide 3 Part, 5 parts of suspending agent, 2 parts of aqueous wax, 3 parts of the tertiary butyl ether of ethylene glycol, 40 parts of ionized water, 2 parts of essence.
Described CARNAUBA WAX microcapsules are dissolved in the CARNAUBA WAX of 3 mass parts in the water of 70 mass parts, and are added Enter the hydrophilic emulsifier of 2 mass parts, emulsion reaction is carried out in the presence of 40-50 DEG C of magnetic stirring apparatus and is made, described magnetic The stir speed (S.S.) of power agitator is 1000-3000rpm, and emulsification times are 30-40min.
A kind of preparation method of microcapsules non-water type vehicle cleaning detergent, ionized water is added in agitator tank, is heated to add at 50 DEG C Enter dodecyl benzyl dimethyl ammonium chloride, sorbitol polyoxyethylene ether laurate, CARNAUBA WAX microcapsules, cetyl Trimethylammonium bromide, suspending agent, aqueous wax, the tertiary butyl ether of ethylene glycol and being stirred continuously then are sequentially added under the conditions of 40 DEG C to be made It all dissolves, and is cooled to after normal temperature, and addition essence, which stirs, both obtains non-water type vehicle cleaning detergent.
Embodiment 2
A kind of microcapsules non-water type vehicle cleaning detergent, includes the raw material of following parts by weight:Dodecyl benzyl dimethyl ammonium chloride 35 parts, 40 parts of sorbitol polyoxyethylene ether laurate, 10 parts of CARNAUBA WAX microcapsules, cetyl trimethylammonium bromide 5 Part, 6 parts of suspending agent, 3 parts of aqueous wax, 5 parts of the tertiary butyl ether of ethylene glycol, 50 parts of ionized water, 3 parts of essence.
Described CARNAUBA WAX microcapsules are dissolved in the CARNAUBA WAX of 4 mass parts in the water of 80 mass parts, and are added Enter the hydrophilic emulsifier of 3 mass parts, emulsion reaction is carried out in the presence of 40-50 DEG C of magnetic stirring apparatus and is made, described magnetic The stir speed (S.S.) of power agitator is 1000-3000rpm, and emulsification times are 30-40min.
A kind of preparation method of microcapsules non-water type vehicle cleaning detergent, ionized water is added in agitator tank, is heated to add at 50 DEG C Enter dodecyl benzyl dimethyl ammonium chloride, sorbitol polyoxyethylene ether laurate, CARNAUBA WAX microcapsules, cetyl Trimethylammonium bromide, suspending agent, aqueous wax, the tertiary butyl ether of ethylene glycol and being stirred continuously then are sequentially added under the conditions of 40 DEG C to be made It all dissolves, and is cooled to after normal temperature, and addition essence, which stirs, both obtains non-water type vehicle cleaning detergent.
Embodiment 3
A kind of microcapsules non-water type vehicle cleaning detergent, includes the raw material of following parts by weight:Dodecyl benzyl dimethyl ammonium chloride 32 parts, 38 parts of sorbitol polyoxyethylene ether laurate, 9 parts of CARNAUBA WAX microcapsules, cetyl trimethylammonium bromide 4 Part, 6 parts of suspending agent, 3 parts of aqueous wax, 4 parts of the tertiary butyl ether of ethylene glycol, 45 parts of ionized water, 3 parts of essence.
Described CARNAUBA WAX microcapsules are dissolved in the CARNAUBA WAX of 4 mass parts in the water of 80 mass parts, and are added Enter the hydrophilic emulsifier of 3 mass parts, emulsion reaction is carried out in the presence of 40-50 DEG C of magnetic stirring apparatus and is made, described magnetic The stir speed (S.S.) of power agitator is 1000-3000rpm, and emulsification times are 30-40min.
A kind of preparation method of microcapsules non-water type vehicle cleaning detergent, ionized water is added in agitator tank, is heated to add at 50 DEG C Enter dodecyl benzyl dimethyl ammonium chloride, sorbitol polyoxyethylene ether laurate, CARNAUBA WAX microcapsules, cetyl Trimethylammonium bromide, suspending agent, aqueous wax, the tertiary butyl ether of ethylene glycol and being stirred continuously then are sequentially added under the conditions of 40 DEG C to be made It all dissolves, and is cooled to after normal temperature, and addition essence, which stirs, both obtains non-water type vehicle cleaning detergent.
Just the use process of the present invention is further described below:Without using high pressure water washing during carwash, only need by In this product injection watering can, car surface is then uniformly sprayed onto, is then directly wiped clean with rag, if necessary, you can It is spray several times more, until wiping clean completely;Carwash only needs 100-200ml waterless carwash liquid substantially, and cost only needs several yuan, Not only reduce car-cleaning cost, it also avoid water resource waste, and car owner oneself also can carwash in person, sewage will not be produced, Save car-cleaning time.In addition, user can also use this product clean other materials, such as glass, marble, metope etc., Equally there is good cleaning performance.
The performance comparison of non-water type vehicle cleaning detergent and foam shampoo made from the embodiment of the present invention 1 see the table below 1.
Table 1

Claims (9)

1. a kind of microcapsules non-water type vehicle cleaning detergent, it is characterised in that include the raw material of following parts by weight:Dodecyl dimethyl benzyl 30-35 parts of ammonium chloride, 35-40 parts of sorbitol polyoxyethylene ether laurate, 7-10 parts of CARNAUBA WAX microcapsules, hexadecane 3-5 parts of base trimethylammonium bromide, 5-6 parts of suspending agent, aqueous wax 2-3 parts, tertiary butyl ether 3-5 parts of ethylene glycol, ionized water 40-50 Part, 2-3 parts of essence.
2. a kind of microcapsules non-water type vehicle cleaning detergent according to claim 1, it is characterised in that:Include the original of following parts by weight Material:30 parts of dodecyl benzyl dimethyl ammonium chloride, 35 parts of sorbitol polyoxyethylene ether laurate, CARNAUBA WAX microcapsules 7 parts, 3 parts of cetyl trimethylammonium bromide, 5 parts of suspending agent, 2 parts of aqueous wax, 3 parts of the tertiary butyl ether of ethylene glycol, 40 parts of ionized water, 2 parts of essence.
3. a kind of microcapsules non-water type vehicle cleaning detergent according to claim 1, it is characterised in that include the original of following parts by weight Material:35 parts of dodecyl benzyl dimethyl ammonium chloride, 40 parts of sorbitol polyoxyethylene ether laurate, CARNAUBA WAX microcapsules 10 parts, 5 parts of cetyl trimethylammonium bromide, 6 parts of suspending agent, 3 parts of aqueous wax, 5 parts of the tertiary butyl ether of ethylene glycol, ionized water 50 Part, 3 parts of essence.
4. a kind of microcapsules non-water type vehicle cleaning detergent according to claim 1, it is characterised in that include the original of following parts by weight Material:32 parts of dodecyl benzyl dimethyl ammonium chloride, 38 parts of sorbitol polyoxyethylene ether laurate, CARNAUBA WAX microcapsules 9 parts, 4 parts of cetyl trimethylammonium bromide, 6 parts of suspending agent, 3 parts of aqueous wax, 4 parts of the tertiary butyl ether of ethylene glycol, 45 parts of ionized water, 3 parts of essence.
5. a kind of microcapsules non-water type vehicle cleaning detergent according to claim any one of 1-4, it is characterised in that:Described cohune The cured microcapsules of palmitic acid are dissolved in the CARNAUBA WAX of 3-4 mass parts in the water of 70-80 mass parts, and add the parent of 2-3 mass parts Water emulsifier, in the presence of 40-50 DEG C of magnetic stirring apparatus carrying out emulsion reaction is made, the stirring of described magnetic stirring apparatus Speed is 1000-3000rpm, and emulsification times are 30-40min.
6. a kind of microcapsules non-water type vehicle cleaning detergent according to claim any one of 1-4, it is characterised in that:Described suspending agent For macromolecule polyacrylic acid.
7. a kind of microcapsules non-water type vehicle cleaning detergent according to claim any one of 1-4, it is characterised in that:Described water-borne wax Matter is aqueous montanin wax.
8. a kind of microcapsules non-water type vehicle cleaning detergent according to claim any one of 1-4, it is characterised in that:Described essence is Lemon extract.
9. a kind of preparation method of the microcapsules non-water type vehicle cleaning detergent described in any one of claim 1-4, it is characterised in that:By ion Water is added in agitator tank, is heated to add dodecyl benzyl dimethyl ammonium chloride, sorbitol polyoxyethylene ether month at 50 DEG C Cinnamic acid ester, CARNAUBA WAX microcapsules, cetyl trimethylammonium bromide, then sequentially added under the conditions of 40 DEG C suspending agent, The tertiary butyl ether of aqueous wax, ethylene glycol and being stirred continuously makes its all dissolve, be cooled to after normal temperature, adds essence and stirs both Non-water type vehicle cleaning detergent.
CN201710206224.1A 2017-03-31 2017-03-31 A kind of microcapsules non-water type vehicle cleaning detergent and preparation method thereof Pending CN106957747A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108034525A (en) * 2017-12-26 2018-05-15 王恩佳 A kind of environmentally friendly vehicle clean-care agent and preparation method thereof
FR3095657A1 (en) * 2019-04-30 2020-11-06 Valeo Systemes D'essuyage Use of a composition of microcapsules for cleaning a vehicle

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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FR3095657A1 (en) * 2019-04-30 2020-11-06 Valeo Systemes D'essuyage Use of a composition of microcapsules for cleaning a vehicle

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