CN106212456B - A kind of composition improving crop root ability and yield - Google Patents
A kind of composition improving crop root ability and yield Download PDFInfo
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- CN106212456B CN106212456B CN201610665407.5A CN201610665407A CN106212456B CN 106212456 B CN106212456 B CN 106212456B CN 201610665407 A CN201610665407 A CN 201610665407A CN 106212456 B CN106212456 B CN 106212456B
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group, wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of compositions for improving crop root ability and yield, it includes 2- (acetoxyl group) benzoic acid of 60 parts by weight, the diethyl aminoethyl hexanoate of 3.6-12 parts by weight, the wetting agent of 0.5-2 parts by weight and the dispersing agent of 0.5-3 parts by weight.2- (acetoxyl group) benzoic acid and diethyl aminoethyl hexanoate are used in compounding by the present invention, except that can expand adjustable range, improve drug effect and selectivity is outer, the dosage of plant growth regulator, relative reduction drug cost can also be reduced, and shortens the residual period of medicament, phytotoxicity is avoided, crop safety is made.Composition provided by the invention has and improves crop root ability and yield and drought-resistant ability, increases the effect of crop yield, solves single plant growth regulator using the problems such as narrow, crop-selective is strong, dangerous there are phytotoxicity.
Description
Technical field
The present invention relates to a kind of compositions for improving crop root ability and yield, belong to plant growth regulator technical field.
Background technique
Plant growth regulator is a kind of pesticide for coordinate plant growth development, including artificial synthesized compound
With the natural phytohormone extracted from biology.With the fast development of agricultural, requirement of the people to agricultural product is also higher and higher,
The use of plant growth regulation also becomes more extensively.By the use of plant growth regulator, can reduce because
The underproduction caused by natural calamity achievees the effect that improve agricultural output, improving quality.
Due to the increasingly exacerbation of environmental pollution, the planting environment of crop is more and more severe, improves the root system ability of crop, reaches
It is a current imperative job to volume increase, improvement crop quality and drought-resistant ability, but existing plant growth regulator
Effect it is relatively simple, application is relatively narrow, and crop-selective is stronger, and effect is not satisfactory, while also to certain crops, there is latent
Phytotoxicity it is dangerous.
Summary of the invention
In view of this, the present invention provides a kind of plant growth regulator composition, has and improve crop root ability and production
Amount and drought-resistant ability, increase the effect of crop yield, solve single plant growth regulator it is strong using narrow, crop-selective,
The problems such as dangerous there are phytotoxicity.
In order to solve the above technical problems, technical solution of the present invention provides a kind of raising crop root ability and yield
Composition, it includes the raw material of following weight parts composition:
It is the raw material for including following weight parts composition that the composition of the raising crop root ability and yield, which more preferably matches:
Further, the wetting agent is selected from dodecyl sodium naphthalene sulfonate, dodecyl naphthalene sulfonic acid potassium, butyl naphthalene sulfonic acids
At least one of sodium, lauryl sodium sulfate, alkyl naphthalene sodium sulphate and diisooctyl succinate sodium sulfonate, more preferably select fourth
Diacid di-isooctyl sodium sulfonate.
Further, the dispersing agent is in lignosulfonates, alkylnaphthalene sulfonate and poly- polymeric carboxylic salt
At least one more preferably selects alkylnaphthalene sulfonate.
Further, the composition of the raising crop root ability and yield further includes that the nutrition of 8-10 parts by weight is auxiliary
Material, the nutrition accessory are selected from at least one of trace element fertilizer, nitrogenous fertilizer, phosphate fertilizer and potash fertilizer, make the present composition while having
The double action of standby plant growth regulating and fertilizer.
Further, the dosage form of the composition for improving crop root ability and yield is solvable pulvis, water-dispersible grain
Agent, soluble granule, pulvis and tablet.
When combination dosage form is solvable pulvis and pulvis, the composition of the raising crop root ability and yield is also wrapped
The anti-caking agent of 2-10 parts by weight is included, the anti-caking agent is selected from anhydrous magnesium sulfate and white carbon black;Since anhydrous magnesium sulfate is water-soluble
Property it is good and containing mineral element magnesium needed for plant, so the preferred anhydrous magnesium sulfate of anti-caking agent.
When combination dosage form is water dispersible granules, the composition of the raising crop root ability and yield further includes
The disintegrating agent of 1-5 parts by weight.
When combination dosage form is tablet, the combination of compositions object for improving crop root ability further includes 0.1-5 weight
Measure the release agent of part and the binder of 1-10 parts by weight.
2- (acetoxyl group) benzoic acid (ASA) belongs to acetyl salicylic acids, belongs to widely used medicine, trade name Ah Si
Woods, is agriculturally being mainly used in promotion plant growth, can induce Systemic Acquired Resistance In Plants, drought resisting, cold-resistant, it is waterlogging-resistant,
Salt resistance alkali, volume increase growth promotion and the outstanding behaviours for improving crop quality, are that existing plant growth regulator is incomparable, are living
The most powerful plant growth regulator of property highest, function.It is thick that seedling stage promoting root growth, trophophase growth promoting, productive phase, promote stalk when reality, harvesting
Strong, non-lodging promotes the balance and Physiological effect of crop hormone, promotes the synthesis of chlorophyll, enhances anti-adversity ability, improves crop
Anti pathologic immunity power;Make the nutrients such as crop uniform pickup N, P, K.Plant leaf blade stomatal movement is adjusted, to reach preferable
Drought resisting purpose, it is obvious to the anti-transpiration of crops, it can effectively mitigate crops drought, arid crop root system pair can be improved
The utilization rate of deep subsoil water storage enhances the drought-resistant ability of crop and improves efficiency of water application.Meeting water resolves into salicylic acid simultaneously
And acetic acid, salicylic acid have, and have the function of to adjust plant immune system, improve the disease resistance of plant, acetic acid can inhibit ethyl alcohol
The bioactivity of acid oxidase can be improved the photosynthesis of crop, increase photosynthate, to improve yield, be used in crop
Survival rate not only can be improved in cultivation, also promote robust growth, improve resistance etc..Its structure and property are as follows: white crystals
Property powder, odorless, micro-strip tart flavour are slightly soluble in water, are dissolved in ethyl alcohol, ether, chloroform, also is soluble in stronger alkaline solution, decomposes simultaneously.
Diethyl aminoethyl hexanoate is the high energy plant growth regulator with wide spectrum and breakthrough effect, and it is green to improve leaf in plant body
Element, protein, the content and photosynthetic rate of nucleic acid improve the activity of peroxidase and nitrate reductase, promote the carbon of plant,
Nitrogen metabolism enhances the absorption of plant pair liquid manure and the accumulation of dry matter, promotes the division and elongation of plant cell, promote root system
Development, adjusts the balance of internal nutrient;Enhance crop, disease-resistant, the drought resisting of fruit tree, cold tolerance;Delay plant senesecence, promotes to make
The quality that object is precocious, increases production, improves crop;To reach volume increase, increase matter.
2- (acetoxyl group) benzoic acid and diethyl aminoethyl hexanoate are all preferably plant growth regulator, but when being single use, are deposited
Narrow in application, crop-selective is strong, and the two is used in compounding by the undesirable disadvantage of effect, the present invention, and adjusting can be expanded by removing
Range, improves drug effect and selectivity is outer, can also reduce the dosage of plant growth regulator, relative reduction drug cost, and
In the residual period for shortening medicament, phytotoxicity is avoided, crop safety is made.But the compound proportion of the two be not arbitrary proportion can,
Its compound proportion needs in the framework of the present definition, and the two use simultaneously could improve root length and the grain side of volume increase again
Face has synergistic function, specifically described in specific embodiment as described below.
Compared with prior art, composition provided by the invention, which has, improves crop root ability and yield and drought resisting energy
Power increases the effect of crop yield, and procedure of processing is simple, high production efficiency, and does not contain any organic solvent, acid and alkali
Property substance, storage is easy there is no any agglomeration, flatulence phenomenon, packaging, and Transport Safety is high.
Specific embodiment
In order to make those skilled in the art more fully understand technical solution of the present invention, With reference to embodiment
The present invention is described in further detail.
One, the compound proportion of 2- (acetoxyl group) benzoic acid and diethyl aminoethyl hexanoate is determined
The mixture that is uniformly mixed to get 2- (acetoxyl group) benzoic acid (A) and diethyl aminoethyl hexanoate (B) by mass ratio in table and
Single dose handles crop respectively, by the setting percentage of measuring and calculating crop later period and blank district, average spike length, mass of 1000 kernel, rate of growth,
The economical character index of root condition etc. come measure mixture reasonability.
Effect evaluation method:
Calculation formula is as follows:
Growth rate: E=(test data-clear water control)/clear water control * 100%
Inhibiting rate: E=(clear water control-test data)/clear water control * 100%
Theoretical value E0:E0=X+Y-X*Y/100 (Gowing formula)
Wherein: the growth rate or inhibiting rate for A single dose that X is dosage when being P;The growth rate or suppression for B single dose that Y is dosage when being Q
Rate processed;E0 is dosage when being P+Q A+B theory growth rate or inhibiting rate;E is the real growth rate or inhibiting rate of each processing;
As E-E0 > 10%, illustrate that composition generates synergistic effect.
As E-E0 < -10%, illustrate that composition generates antagonism.
When E-E0 is between ± 10%, illustrate that composition generates addition.
1.1 regulating compositions test indoor pot rice seedling plant impact effect
Test crop: rice;
Test method: referring to " farm-chemical indoor determination test rule NY/T2061.2-2011 " plant growth regulator
Part 2: promote plant strain growth test cauline leaf spraying;
Test result: referring to Tables 1 and 2.
1 regulating composition of table influences indoor pot rice seedling plant
Processing | Average root long (cm) | Root growth rate (%) | E-E0/% |
A:B=1:0.06 | 18.41 | 8.68 | 3.54 |
A:B=1:0.07 | 18.61 | 9.86 | 3.33 |
A:B=1:0.08 | 19.25 | 13.64 | 6.42 |
A:B=1:0.1 | 20.30 | 19.83 | 12.09 |
A:B=1:0.12 | 19.24 | 13.58 | 7.81 |
A:B=1:0.14 | 18.41 | 8.68 | 3.54 |
A:B=1:0.2 | 18.32 | 8.15 | 4.52 |
A single dose control group | 17.25 | 1.83 | — |
B single dose control group 1 | 17.51 | 3.36 | — |
B single dose control group 2 | 17.75 | 4.78 | — |
B single dose control group 3 | 17.87 | 5.49 | — |
B single dose control group 4 | 17.96 | 6.02 | — |
B single dose control group 5 | 17.62 | 4.01 | — |
B single dose control group 6 | 17.51 | 3.36 | — |
B single dose control group 7 | 17.25 | 1.83 | — |
Clear water | 16.94 | — | — |
It is tested and is found by indoor pot rice seedling physical signs, after 2- (acetoxyl group) benzoic acid, diethyl aminoethyl hexanoate
The effect of being obviously promoted is all had to root elongation growth, by data in table visible 2- (acetoxyl group) benzoic acid, diethyl aminoethyl hexanoate by real
Testing design proportion has addition to the growth of the root of rice, especially in 2- (acetoxyl group) benzoic acid: diethyl aminoethyl hexanoate 1:
When 0.1, have obvious synergistic function.
2 regulating composition of table influences indoor pot rice yield
It is tested and is found by indoor pot rice yield physical signs, after 2- (acetoxyl group) benzoic acid, diethyl aminoethyl hexanoate
The effect of being obviously promoted is all had to effective fringe of rice, grain number per spike, setting percentage, mass of 1000 kernel, by visible 2- (the acetyl oxygen of data in table
Base) benzoic acid, diethyl aminoethyl hexanoate in mass of 1000 kernel of the experimental design ratio to rice have addition, especially in 2- (acetoxyl group) benzene
Formic acid: it when diethyl aminoethyl hexanoate is 1:0.1, has obvious synergistic function.
1.2 regulating compositions test field rice yield effect
Experimental subjects: rice;
Experiment purpose: coordinate plant growth promotes volume increase;
Test site is Jianyang City's Pingquan town;
Method of administration, application period and dosage: corresponding sample is prepared according to the composition ratio of table 3, is then carried out complete
Strain even spraying;According to the growth characteristics of rice, based on spraying equal medicine amount liquids, if 16 processing, 4 repetitions, totally 64
Cell.Each plot area is at least more than 16 square meters.It is arranged using random district's groups, keeps the initial condition of each cell as far as possible
Unanimously.It is sprayed respectively in heading stage, blooming stage, pustulation period, it is total to spray medical fluid 3 times.
Testing index: rice yield calculates gained rate of growth.
It surveys and produces formula
1. cell production, which is surveyed, produces formula
Cell production (kilogram)=spike number/square metre × grain number/fringe × mass of 1000 kernel (gram) × setting percentage % × plot area
(square metre) ÷ 1000 (grain) ÷ 1000 (gram)
2. hectare yield, which is surveyed, produces formula
Hectare yield (kilogram)=spike number/square metre × grain number/fringe × mass of 1000 kernel (gram) × setting percentage % × 10000 are (flat
Square rice) ÷ 1000 (grain) ÷ 1000 (gram)
3. being produced than control increase and decrease and comparing calculation formula
Than control volume increase %=(test variety cell or hectare yield-check variety cell or hectare yield) ÷ control
Kind cell or hectare yield × 100%
Experimental result is in strict accordance with specified in National Standard of the People's Republic of China " pesticide efficacy field trial criterion "
Calculation method is calculated, and the composition composition the results are shown in Table 3 to increasing production of rice.
3 regulating composition of table is to rice yield impact effect
It is tested and is found by field efficacy, using having after 2- (acetoxyl group) benzoic acid, diethyl aminoethyl hexanoate to the yield of rice
It is obviously promoted effect, by data in table visible 2- (acetoxyl group) benzoic acid, diethyl aminoethyl hexanoate in experimental design ratio to rice
Yield has addition, especially in 2- (acetoxyl group) benzoic acid: diethyl aminoethyl hexanoate is 1:(0.08-0.12) when, have obvious
Synergistic function, in 2- (acetoxyl group) benzoic acid: synergistic most obvious when diethyl aminoethyl hexanoate is 1:0.1.
1.3 regulating compositions test field corn yield effect
Experimental subjects: corn;
Experiment purpose: coordinate plant growth promotes volume increase;
Test site: Jianyang City Pingquan town;
Method of administration, application period and dosage: corresponding sample is prepared according to the composition ratio of table 4, is then carried out complete
Strain even spraying;According to the growth characteristics of corn, based on spraying equal medicine amount liquids, if 16 processing, 4 repetitions, totally 64
Cell.Each plot area is at least more than 32 square meters.It is arranged using random district's groups, keeps the initial condition of each cell as far as possible
Unanimously.It is sprayed respectively in tri-leaf period, ear period, flower period, it is total to spray medical fluid 3 times.
Testing index: corn yield calculates gained rate of growth.
Experimental result is in strict accordance with specified in National Standard of the People's Republic of China " pesticide efficacy field trial criterion "
Calculation method is calculated, and the composition composition the results are shown in Table 4 to increasing production of rice.
4 regulating composition of table is to Yield of Corn effect
It is tested and is found by field efficacy, using having after 2- (acetoxyl group) benzoic acid, diethyl aminoethyl hexanoate to the yield of corn
It is obviously promoted effect, by data in table visible 2- (acetoxyl group) benzoic acid, diethyl aminoethyl hexanoate in experimental design ratio to corn
Yield has addition, especially in 2- (acetoxyl group) benzoic acid: diethyl aminoethyl hexanoate is 1:(0.08-0.12) when, have obvious
Synergistic function.In 2- (acetoxyl group) benzoic acid: synergistic most obvious when diethyl aminoethyl hexanoate is 1:0.1.
To sum up, obtaining 2- (acetoxyl group) benzoic acid with the mass ratio that compounds of diethyl aminoethyl hexanoate is 1:(0.06~0.2), it is optimal multiple
It is 1:0.1 with mass ratio.
Two, specific embodiment
Embodiment 1: present composition soluble powder is prepared according to following weight parts composition:
Preparation method: taking above-mentioned each component example to be in mass ratio pre-mixed, and high speed disintegrator crushes, and remixes up to product.
Embodiment 2: present composition water dispersible granules are prepared according to following weight parts composition
Preparation method: taking above-mentioned each component example to be in mass ratio pre-mixed, and high speed disintegrator crushes, and remixes, and mediates, makes
Grain, is drying to obtain product.
Embodiment 3: present composition pulvis is prepared according to following weight parts composition
Preparation method: it takes above-mentioned each component example to be in mass ratio pre-mixed, crushes, remix up to product.
Embodiment 4: present composition tablet is prepared according to following weight parts composition
Preparation method: it takes above-mentioned each component example to be in mass ratio pre-mixed, crushes, remix, tabletting is up to product.
Embodiment 5: present composition soluble granule is prepared according to following weight parts composition
Preparation method: it takes above-mentioned each component example to be in mass ratio pre-mixed, crushes, remix, mediate, be granulated, be drying to obtain
Product.
The above is only the preferred embodiment of the present invention, it is noted that above-mentioned preferred embodiment is not construed as pair
Limitation of the invention, protection scope of the present invention should be defined by the scope defined by the claims..For the art
For those of ordinary skill, without departing from the spirit and scope of the present invention, several improvements and modifications can also be made, these change
It also should be regarded as protection scope of the present invention into retouching.
Claims (9)
1. a kind of composition for improving crop root ability and yield, it is characterised in that: it includes the original of following weight parts composition
Material:
2. a kind of composition for improving crop root ability and yield according to claim 1, it is characterised in that: the profit
Humectant is selected from dodecyl sodium naphthalene sulfonate, dodecyl naphthalene sulfonic acid potassium, sodium butylnaphthalenesulfonate, lauryl sodium sulfate, alkylnaphthalene
Base sodium sulphate and diisooctyl succinate sodium sulfonate.
3. a kind of composition for improving crop root ability and yield according to claim 1, it is characterised in that: described point
Powder is selected from lignosulfonates, alkylnaphthalene sulfonate and poly- polymeric carboxylic salt.
4. a kind of composition for improving crop root ability and yield according to claim 1, it is characterised in that: described to mention
The composition of high crop root system ability and yield further includes the nutrition accessory of 8-10 parts by weight, and the nutrition accessory is selected from micro member
Plain fertilizer, nitrogenous fertilizer, phosphate fertilizer and potash fertilizer.
5. a kind of composition for improving crop root ability and yield according to claim 1, it is characterised in that: described to mention
The dosage form of the composition of high crop root system ability and yield is solvable pulvis, water dispersible granules, soluble granule, pulvis, tablet.
6. a kind of composition for improving crop root ability and yield according to claim 5, it is characterised in that: when described
When the dosage form for improving the composition of crop root ability and yield is solvable pulvis and pulvis, the raisings crop root ability with
The composition of yield further includes the anti-caking agent of 2-10 parts by weight.
7. a kind of composition for improving crop root ability and yield according to claim 6, it is characterised in that: described anti-
Agglomeration agent is selected from anhydrous magnesium sulfate and white carbon black.
8. a kind of composition for improving crop root ability and yield according to claim 5, it is characterised in that: when described
When the dosage form for improving the composition of crop root ability and yield is water dispersible granules, the raising crop root ability and yield
Composition further include 1-5 parts by weight disintegrating agent.
9. a kind of composition for improving crop root ability and yield according to claim 5, it is characterised in that: work as institute
It states and improves the dosage form of the composition of crop root ability and yield when being tablet, crop root ability and the yield of improving
Composition further includes the release agent of 0.1-5 parts by weight and the binder of 1-10 parts by weight.
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1097092A (en) * | 1993-07-06 | 1995-01-11 | 时宏业 | Bingchongbi plant-growth regulator |
DE102004034272A1 (en) * | 2004-07-15 | 2006-02-09 | Bayer Cropscience Ag | Composition useful for controlling animal pests, especially insects, comprises a synergistic mixture of acetylsalicylic acid and a neonicotinoid compound |
CN104855384A (en) * | 2015-04-16 | 2015-08-26 | 广东中迅农科股份有限公司 | Pesticide composition containing 2-(acetoxyl)benzoic acid and indolebutyric acid |
-
2016
- 2016-08-15 CN CN201610665407.5A patent/CN106212456B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1097092A (en) * | 1993-07-06 | 1995-01-11 | 时宏业 | Bingchongbi plant-growth regulator |
DE102004034272A1 (en) * | 2004-07-15 | 2006-02-09 | Bayer Cropscience Ag | Composition useful for controlling animal pests, especially insects, comprises a synergistic mixture of acetylsalicylic acid and a neonicotinoid compound |
CN104855384A (en) * | 2015-04-16 | 2015-08-26 | 广东中迅农科股份有限公司 | Pesticide composition containing 2-(acetoxyl)benzoic acid and indolebutyric acid |
Non-Patent Citations (2)
Title |
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1.6%胺鲜酯对水稻生长影响及增产作用研究;徐伟松 等;《安徽农业科学》;20140201;第42卷(第4期);第994-995页 |
烯效唑与胺鲜酯复配浸种对水稻秧苗生长的影响;梁喜龙 等;《湖北农业科学》;20110430;第50卷(第7期);第1325-1329页 |
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Effective date of registration: 20230315 Address after: No. 18, Industrial Park, Jiangxian Development Zone, Yuncheng City, Shanxi Province 043600 Patentee after: SHANXI HAOZHIDA BIOLOGICAL SCIENCE & TECHNOLOGY Co.,Ltd. Address before: No. 80, Qipan Road, Jianyang City, Chengdu City, Sichuan Province Patentee before: SICHUAN GUOGUANG AGROCHEMICAL Co.,Ltd. |