CN106120444A - 一种静电印刷专用铜版卡涂料及其应用 - Google Patents

一种静电印刷专用铜版卡涂料及其应用 Download PDF

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CN106120444A
CN106120444A CN201610486761.1A CN201610486761A CN106120444A CN 106120444 A CN106120444 A CN 106120444A CN 201610486761 A CN201610486761 A CN 201610486761A CN 106120444 A CN106120444 A CN 106120444A
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徐琦
陈汉彬
李娟�
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Gold HuaSheng Paper (SuZhou Industrial Park) Co Ltd
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Abstract

本发明公开了一种静电印刷专用铜版卡涂料，其由如下质量份的成分组成：颜料100份；胶乳10‑15份；消泡剂0.01‑2份；流变剂0.01‑2份；分散剂0.01‑2份；纸面电阻调节剂1‑5份；增白剂0.5‑3份；杀菌剂0.01‑2份；pH调节剂0.01‑3份。本发明通过涂料中纸面电阻调节剂作用，在铜版卡表面形成高电阻的涂层，在保证了铜版卡原有印刷物性外，提升了纸张涂料的电阻性能，使纸张在静电印刷过程中，印刷效果好，色彩饱和度佳，网点清晰，对铜卡纸作为印刷封面有更好的质量。

Description

一种静电印刷专用铜版卡涂料及其应用
技术领域
本发明属于造纸领域，具体涉及一种静电印刷专用铜版卡涂料及其应用。
背景技术
铜版卡(Art Board)是以原纸涂布白色涂料制成的高级印刷卡纸，主要用于印刷高级书刊的封面、彩色画片、各种精美的商品广告、样本、商品包装、商标等。
铜版卡的主要原料是铜版原纸和涂料。对铜版原纸的要求是厚薄均匀，伸缩性小，强度较高，抗水性好。纸面不得有斑点、皱纹、孔眼等纸病，用来涂布的涂料是由优质的白色颜料、胶粘剂及辅助添加剂等组成的。目前抄造铜版卡的生产流程一般为散浆，磨浆，添加湿部化学品，上浆，脱水，前干燥，表面施胶，后干燥，卷曲成纸制成原纸，再通过底涂、面涂双层涂布，干燥、压光之后卷曲制成。
铜版卡属于高档印刷用纸主要用于高档印品。在进行静电印刷的过程中，对纸张除了一些基本物性方面的要求外，对静电复印纸的表面电阻率有很高的要求。现有的铜版卡纸在静电印刷过程中，电阻性能不高，印刷网点模糊，印刷效果差。
发明内容
为满足市场对静电印刷专用铜版卡的需求，本发明公开了一种静电印刷专用的铜版卡涂料，能够在铜版卡表面形成高电阻的涂层，提升纸张涂料的电阻性能，从而使铜版卡的印刷效果更好。
为实现上述技术目的，本发明的技术方案为：
一种静电印刷专用的铜版卡涂料，由如下质量份的成分组成：
填料100份；胶乳10-15份；消泡剂0.01-2份；流变剂0.01-2份；分散剂0.01-2份；纸面电阻调节剂1-5份；增白剂0.5-3份；杀菌剂0.01-2份；pH调节剂0.01-3份。
其中，所述胶乳选自醋酸乙烯胶乳、苯乙烯-丁二烯胶乳、羟基丁苯胶乳、醋酸乙烯-丙烯酸酯胶乳、丙烯酸酯胶乳中的一种或几种。
其中，所述填料选自研磨碳酸钙、沉淀碳酸钙、滑石粉、白土、瓷土、二氧化钛、云母粉、石英粉中的一种或几种。
其中，所述消泡剂选自聚乙二醇、脂肪酸防沫剂、二氧化硅类消泡剂、矿物油、聚乙烯蜡、高碳脂肪醇、磷酸三丁酯、乳化甲基硅油中的一种或几种。
其中，所述流变剂选自羧甲基纤维素钠、聚酰胺、变性酰胺共聚物、聚乙烯醇、改性丙烯酸共聚物中的一种或几种。
其中，所述分散剂选自多磷酸盐、聚丙烯酸钠、羧酸盐中的一种或几种。
其中，多磷酸盐为六偏磷酸钠、焦磷酸钠。
其中，所述杀菌剂选自异噻唑啉酮及其衍生物、三丹油、或氮、硫环状有机化合物中的一种或几种。
其中，所述pH调节剂选自氢氧化钠、碳酸氢三钠、磷酸氢二钠中的一种或几种。
其中，所述纸面电阻调节剂选自对苯二甲酸丁二醇酯、异苯二甲酸中的一种或几种。
其中，所述增白剂选自二苯乙烯、萘二甲酰亚胺、苯基吡唑啉中的一种或几种。
本发明还提供了一种静电印刷专用铜版卡涂料的应用，所述应用步骤如下：1)静电印刷专用铜版卡涂料的制备
将下列原料按照质量份数配比依次添加，混合高速分散均匀后，待用；
具体原料配比：填料100份；胶乳10-15份；消泡剂0.01-2份；流变剂0.01-2份；分散剂0.01-2份；纸面电阻调节剂1-5份；增白剂0.5-3份；杀菌剂0.01-2份；pH调节剂0.01-3份；
2)原纸涂布
在原纸两面进行涂布，涂布量为单面5-20g/m2；
3)将涂布后的纸板干燥、压光，得到静电印刷专用铜版卡。
本发明通过涂料中的纸面电阻调节剂作用，在铜版卡表面形成高电阻的涂层，提升了纸张涂料的电阻性能，使纸张在静电印刷过程中，印刷效果好，色彩饱和度佳，网点清晰，对铜版卡纸作为印刷封面有更好的质量。
附图说明
图1是本发明实施例1涂布铜版卡的印刷网点图。
图2是本发明实施例2涂布铜版卡的印刷网点图。
图3是本发明实施例3涂布铜版卡的印刷网点图。
图4是对比例涂布铜版卡的印刷网点图。
具体实施方式
以下实施例用于说明本发明，但不应用来限制本发明的范围。
实施例1：
一种静电印刷专用铜版卡涂料，按照质量份数的原料如下：研磨碳酸钙70份，瓷土30份，苯乙烯-丁二烯胶乳12份，聚乙二醇0.01份，羧甲基纤维素钠0.02份，六偏磷酸钠0.02份；异噻唑啉酮0.02份，氢氧化钠0.15份，二苯乙烯1.5份，对苯二甲酸丁二醇酯1份。
按照上述比例，顺序添加各物料，经过高速分散，得分散均匀的涂料。在178g/m2铜版原纸的两面进行涂布，单面涂布量为15g/m2。控制两面涂布基本一致，误差范围控制在0-10％以内。
涂布后干燥，使用超级压光机压光，以保证松厚度和平滑度、光泽度的特质。进行关键物性测试，见表1。
实施例2：
一种静电印刷专用铜版卡涂料，按照质量份数的原料如下：研磨碳酸钙70份，瓷土30份，苯乙烯-丁二烯胶乳12份，聚乙二醇0.01份，羧甲基纤维素钠0.02份，六偏磷酸钠0.02份；异噻唑啉酮0.02份，氢氧化钠0.15份，二苯乙烯2份，对苯二甲酸丁二醇酯2.5份。
按照上述比例，顺序添加各物料，经过高速分散，得分散均匀的涂料。在178g/m2铜版原纸的两面进行涂布，单面涂布量为15g/m2。控制两面涂布基本一致，误差范围控制在0-10％以内。
涂布后干燥，使用超级压光机压光，以保证松厚度和平滑度、光泽度的特质。并进行关键物性测试，见表1。
实施例3：
一种静电印刷专用铜版卡涂料，按照质量份数的原料如下：研磨碳酸钙50份，瓷土50份，苯乙烯-丁二烯胶乳12份，聚乙二醇0.01份，羧甲基纤维素钠0.02份，六偏磷酸钠0.02份；异噻唑啉酮0.02份，氢氧化钠0.15份，二苯乙烯2.5份，异苯二甲酸5份。
按照上述比例，顺序添加各物料，经过高速分散，得分散均匀的涂料。在178g/m2铜版原纸的两面进行涂布，单面涂布量为15g/m2。控制两面涂布基本一致，误差范围控制在0-10％以内。
涂布后干燥，使用超级压光机压光，以保证松厚度和平滑度、光泽度的特质。进行关键物性测试，见表1。
对比例：
普通铜版卡涂料配方：研磨碳酸钙100份，异氰酸酯2份，苯乙烯-丁二烯胶乳12份，聚乙二醇0.01份，羧甲基纤维素钠0.02份，六偏磷酸钠0.02份；异噻唑啉酮0.02份，氢氧化钠0.15份，二苯乙烯1份。
按照上述比例，顺序添加各物料，经过高速分散，得分散均匀的涂料。在178g/m2铜版原纸的两面进行涂布，单面涂布量为15g/m2。控制两面涂布基本一致，误差范围控制在0-10％以内。
涂布后干燥，使用超级压光机压光，以保证松厚度和平滑度、光泽度的特质。进行关键物性测试，见表1。
表1基本物性对比表
由表1可知，本发明实施例1-3中铜版卡的平滑度及粗糙度均达到所需要求，IGT强度也与对比例相当，但实施例1-3的纸面电阻均大于对比例；另外从图1-图4可以看出，在印刷网点清晰性方面，实施例1-3(图1、图2、图3)比对比例(图4)有明显的优势。
本发明通过涂料中的纸面电阻调节剂作用，在铜版卡表面形成高电阻的涂层，提升了纸张涂料的电阻性能，使纸张在静电印刷过程中，印刷效果好，色彩饱和度佳，网点清晰，对铜版卡纸作为印刷封面有更好的质量。
以上为对本发明实施例的描述，通过对所公开的实施例的上述说明，使本领域专业技术人员能够实现或使用本发明。对这些实施例的多种修改对本领域的专业技术人员来说将是显而易见的，本文中所定义的一般原理可以在不脱离本发明的精神或范围的情况下，在其它实施例中实现。因此，本发明将不会被限制于本文所示的这些实施例，而是要符合与本文所公开的原理和新颖特点相一致的最宽的范围。

Claims (10)

1.一种静电印刷专用铜版卡涂料，其特征在于，所述静电印刷专用铜版卡涂料由如下质量份的成分组成：
填料100份；胶乳10-15份；消泡剂0.01-2份；流变剂0.01-2份；分散剂0.01-2份；纸面电阻调节剂1-5份；增白剂0.5-3份；杀菌剂0.01-2份；pH调节剂0.01-3份。
2.如权利要求1所述的静电印刷专用铜版卡涂料，其特征在于，所述胶乳选自醋酸乙烯胶乳、苯乙烯-丁二烯胶乳、羟基丁苯胶乳、醋酸乙烯-丙烯酸酯胶乳、丙烯酸酯胶乳中的一种或几种。
3.如权利要求1所述的静电印刷专用铜版卡涂料，其特征在于，所述填料选自研磨碳酸钙、沉淀碳酸钙、滑石粉、白土、瓷土、二氧化钛、云母粉、石英粉中的一种或几种。
4.如权利要求1所述的静电印刷专用铜版卡涂料，其特征在于，所述消泡剂选自聚乙二醇、脂肪酸防沫剂、二氧化硅类、矿物油、聚乙烯蜡、高碳脂肪醇、磷酸三丁酯、乳化甲基硅油中的一种或几种。
5.如权利要求1所述的静电印刷专用铜版卡涂料，其特征在于，所述流变剂选自羧甲基纤维素钠、聚酰胺、变性酰胺共聚物、聚乙烯醇、改性丙烯酸共聚物中的一种或几种。
6.如权利要求1所述的静电印刷专用铜版卡涂料，其特征在于，所述杀菌剂选自异噻唑啉酮及其衍生物、三丹油、氮、硫环状有机化合物中的一种或几种。
7.如权利要求1所述的静电印刷专用铜版卡涂料，其特征在于，所述pH调节剂选自氢氧化钠、碳酸氢三钠、磷酸氢二钠中的一种或几种。
8.如权利要求1所述的静电印刷专用铜版卡涂料，其特征在于，所述纸面电阻调节剂选自对苯二甲酸丁二醇酯，异苯二甲酸中的一种或几种。
9.如权利要求1所述的静电印刷专用铜版卡涂料，其特征在于，所述增白剂选自二苯乙烯、萘二甲酰亚胺、苯基吡唑啉中的一种或几种。
10.一种静电印刷专用铜版卡涂料的应用，其特征在于，所述应用的具体步骤如下：
1)静电印刷专用铜版卡涂料的制备
将下列原料按照质量份数配比依次添加，混合高速分散均匀后，待用；
具体原料配比：颜料100份；胶乳10-15份；消泡剂0.01-2份；流变剂0.01-2份；分散剂0.01-2份；纸面电阻调节剂1-5份；增白剂0.5-3份；杀菌剂0.01-2份；pH调节剂0.01-3份；
2)原纸涂布
在原纸两面进行涂布，涂布量为单面5-20g/m2；
3)将涂布后的纸板干燥、压光，得到静电印刷专用铜版卡。
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