CN106116982A - A kind of fertilizer additive improving soil water-reataining fertilizer-keeping and preparation method thereof - Google Patents
A kind of fertilizer additive improving soil water-reataining fertilizer-keeping and preparation method thereof Download PDFInfo
- Publication number
- CN106116982A CN106116982A CN201610479529.5A CN201610479529A CN106116982A CN 106116982 A CN106116982 A CN 106116982A CN 201610479529 A CN201610479529 A CN 201610479529A CN 106116982 A CN106116982 A CN 106116982A
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- Prior art keywords
- fertilizer
- water
- keeping
- starch
- raw material
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/70—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting wettability, e.g. drying agents
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Soil Sciences (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of fertilizer additive improving soil water-reataining fertilizer-keeping and preparation method thereof, it is made up of the raw material of following weight portion: acrylic acid, starch, N, N'-methylene-bisacrylamide, polyglutamic acid, activated sludge, biogas waste residue, ammonium molybdate, Kaolin, sodium carboxymethyl cellulose, agricultural crop straw, cellulose microbial inoculum, plant source raw material and appropriate water;The invention belongs to the fertilizer additive of a kind of resin water conservation fertilizer conservation, starch is utilized to be grafted, can be indirect by the microorganism in soil, will not be negatively affected to soil, material based on acrylic acid, there is good water absorbing capacity, the most reserved moisture, promote that the water supply of crops, invention utilize vapor extraction method, extract corresponding active component from the plant with pest-resistant volatile material, in the additive adding fertilizer, along with resin is degraded, the volatile flavor distributed, can play the effect walking quickly and keeping away insect.
Description
Technical field
The invention belongs to the Technology field of fertilizer, be specifically related to a kind of fertilizer improving soil water-reataining fertilizer-keeping and add
Agent and preparation method thereof.
Background technology
In nature, by known to the low-molecular-weight secondary metabolites of phytosynthesis and release just more than 100,000 kinds, its
In volatile material just account for significant proportion, and there is certain " abnormal smells from the patient " mostly.This kind of material is as a kind of behavior hint
Chemical signal play very important effect between plant and between plant and insecticide, anti-by chemical pesticide is cured the disease
Insect pest not only breaks up environment, wastes resource, the main Drug resistance that also can improve crop pest and serious Pesticide Residue,
The improvement affecting health insect simultaneously becomes more and more difficult.
The volatile material of plant belongs to the secondary metabolite of plant, typically distributes from leaf surface, plays and walks quickly and keeps away
The effect of insect, is mainly derived from the fatty acid of plant, aminoacid and the metabolism of class phenylpropyl alcohol alkane, a series of by chloroplast
Enzymatic reaction completes, and discharges, can be divided into 4 classes: isoprene, monoterpene, other active and secondary active substance in air, including
Alkanes, alcohols, esters, phosphinylidyne class and acids, they form fatty acid derivant, aromatic compound, monoterpene and sesquialter
Terpene compound, has the most antibacterial and anti-insect activity, may be directly applied to the Biological control of pest and disease damage.
The advantage that biological preparation prevents is: general disease pest is played avoidance effect, does not strangles, and does not destroy original
Biological chain, so disease pest class will not produce resistance, is also a kind of protection to beneficial organism, a lot of the most this biological plant sources
Active substance of plant belongs to the active substance of natural extract plant, does not have toxicity, is free from side effects human body, in soil
Slowly volatilization, plays the effect of prevention, will be wholly absent after a period of time, make the agricultural product of plantation, quality more preferably, more strong
Health.Easy to use, as long as adding soil with fertilizer or together with the adding ingredient of fertilizer, the larva of insect is typically all
Being originated in soil, directly effect soil is best protection.
Summary of the invention
The present invention is in order to play certain prevention and control of plant diseases, pest control effect while improving crop nutrition content, and invention one has
Keep away insect pest effect fertilizer additive, realize particular by the following manner:
A kind of fertilizer additive improving soil water-reataining fertilizer-keeping, it is characterised in that be made up of the raw material of following weight portion: acrylic acid
20 ~ 30, starch 5 ~ 8, N, N'-methylene-bisacrylamide 0.1 ~ 0.3, polyglutamic acid 1 ~ 4, activated sludge 10 ~ 15, biogas are useless
Slag 20 ~ 25, ammonium molybdate 3 ~ 6, Kaolin 1 ~ 3, sodium carboxymethyl cellulose 0.5 ~ 1.0, agricultural crop straw 40 ~ 50, cellulose microbial inoculum 2
~ 3, plant source raw material 30 ~ 40 and appropriate water;
Described plant source raw material be with weight (part) be the unit fresh tomato leaf 3 ~ 6 of mixing, Folium seu Cortex Nerii 6 ~ 10, Folium Cinnamomi porrecti 8 ~
12, Fructus Gleditsia 4 ~ 6, acer monoes 2 ~ 5, Pinus tabuliformis 10 ~ 15, ailanthus altissima (mill.) swingle 10 ~ 14 and Folium Ginkgo 7 ~ 12, after preliminary pulverizing, 0 ~ 5 DEG C of cold preservation is standby.
The preparation method of a kind of fertilizer additive improving soil water-reataining fertilizer-keeping, it is characterised in that include following step
Rapid:
(1) by plant source raw mill 40 ~ 60min uniformly slurry, ultrasonication prepares serosity, adds by material-water ratio 1:2 ~ 3
Entering distilled water diluting, employing steam reflux, extract, 2 ~ 3h must be rich in the aqueous solution of extracting solution;
(2) agricultural crop straw is tentatively pulverized, mixing biogas waste residue and activated sludge, for covering at aforementioned straw, inoculation
Cellulose microbial inoculum, retting 15 ~ 20 days after mixing, after completing, sterilizing ball milling become homogenate, and the water adding its total weight parts 2 ~ 3 times is dilute
Release, filter out filtrate, add after concentration to the aqueous solution described in (1);
(3) Kaolin was pulverized 140 ~ 180 mesh sieves, and mixed other following residual components being not directed to and join described in (2)
In mixed solution, stirring and evenly mixing;
(4) being added to the mixed liquor described in (3) by starch, 75 ~ 85 DEG C of stirrings that heat up under water bath condition are to starch gelatinization, cooling
Being sequentially added into acrylic acid and N, N'-methylene-bisacrylamide to room temperature, stirring 5 ~ 10min reacts in 60 ~ 70 DEG C of water-baths
1.5 ~ 2h, is dried at 70 ~ 80 DEG C after completing, finally grinds to form powder.
The material that invention is chosen has Folium seu Cortex Nerii, and its leaf contains the Cardiac glycosides materials such as folinerinum C, and toxicity is big, can kill
Worm;Folium Cinnamomi porrecti, plant contains Camphora, monoterpene and sesquialter Monoterpenes, has anthelmintic paralysis effect;Semen Ginkgo, plant contains Folium illicii Lanceolati
Acid, ginkegetin, sterols material, toxic, there is anthelmintic insecticidal action;Fructus Lycopersici esculenti, containing multiple Flavonoid substances and life
The licopersicin etc. of alkaloids class, can cause insecticide deterrent, refusing to eat and intoxicating phenomenon;Other tree class blade has going back of this effect same
There are Fructus Gleditsia, acer monoes, Pinus tabuliformis, ailanthus altissima (mill.) swingle;
Invent Fructus Lycopersici esculenti liquid as raw material, use distilled water lifting manipulation to obtain the water solublity crude extract in tomato leaf, mix chlorine cyanogen
Chrysanthemum ester acts on Muskmelon Plants, and research extract, for the resistance effect of aphid, utilizes taking food of EPG instrument test aphid,
Aphid and the plant that takes food thereof are accessed same circuit, and the lancet of aphid, as electrode, forms loop during very moment needle-penetration plant,
Just have corresponding display, understand the situation that takes food of aphid with this, between test data sheet 1 ~ 10h aphid take food situation, send out
Passage the most in time, aphid seldom or causes damage almost without to the blade of Fructus Melo at the beginning, and passage in time is sweet
The blade of melon is compromised gradually, shows: the crude extract of Fructus Lycopersici esculenti can prevent the harm of aphid, crude extract anthelminthic effect to show
Antifeedant upper, this active substance belongs to a kind of volatile material.
Invention is in order to be applied to reality the action time and action effect improving plant extract, it is necessary to ensure that store this
Volatile active material belongs to the material of a kind of slow degraded, simultaneously because planting site is dried, rapid dehydration is likely to lead
Cause volatile material lost efficacy or distributed too fast, do not have the effect of long-time protection, in the face of problem above is invented volatility
Extracting solution is combined with resin-phase, uses acrylic resin, and it is the resin of a kind of high-hydroscopicity, and it connects with C-C simultaneously
High molecular polymer, can be utilized by microbial degradations such as the staphylococcus in soil, streptococcus, can slowly discharge volatility and resist
Worm material, is greatly prolonged protected effect.
Beneficial effects of the present invention: the invention belongs to the fertilizer additive of a kind of resin water conservation fertilizer conservation, utilize starch to carry out
Grafting, can be indirect by the microorganism in soil, will not be negatively affected to soil, the material based on acrylic acid, have
Well water absorbing capacity, effectively reserves moisture, promotes that the water supply of crops, invention utilize vapor extraction method, from having
The plant of pest-resistant volatile material is extracted corresponding active component, in the additive adding fertilizer, along with resin is degraded,
The volatile flavor distributed, can play the effect walking quickly and keeping away insect.
Detailed description of the invention
Embodiment 1:
A kind of fertilizer additive improving soil water-reataining fertilizer-keeping, it is characterised in that be made up of the raw material of following weight portion (Kg): third
Olefin(e) acid 26, starch 7, N, N'-methylene-bisacrylamide 0.2, polyglutamic acid 3, activated sludge 14, biogas waste residue 22, ammonium molybdate
5, Kaolin 2, sodium carboxymethyl cellulose 0.8, agricultural crop straw 45, cellulose microbial inoculum 2, plant source raw material 35 and appropriate water;
Described plant source raw material is to be the unit fresh tomato leaf 5 of mixing, Folium seu Cortex Nerii 8, Folium Cinnamomi porrecti 9, Fructus Gleditsia with weight (Kg)
5, acer monoes 4, Pinus tabuliformis 12, ailanthus altissima (mill.) swingle 13 and Folium Ginkgo 10, after preliminary pulverizing, 0 ~ 5 DEG C of cold preservation is standby.
The preparation method of a kind of fertilizer additive improving soil water-reataining fertilizer-keeping, it is characterised in that include following step
Rapid:
(1) by plant source raw mill 40 ~ 60min uniformly slurry, ultrasonication prepares serosity, adds by material-water ratio 1:2 ~ 3
Entering distilled water diluting, employing steam reflux, extract, 2 ~ 3h must be rich in the aqueous solution of extracting solution;
(2) agricultural crop straw is tentatively pulverized, mixing biogas waste residue and activated sludge, for covering at aforementioned straw, inoculation
Cellulose microbial inoculum, retting 15 ~ 20 days after mixing, after completing, sterilizing ball milling become homogenate, and the water adding its total weight parts 2 ~ 3 times is dilute
Release, filter out filtrate, add after concentration to the aqueous solution described in (1);
(3) Kaolin was pulverized 140 ~ 180 mesh sieves, and mixed other following residual components being not directed to and join described in (2)
In mixed solution, stirring and evenly mixing;
(4) being added to the mixed liquor described in (3) by starch, 75 ~ 85 DEG C of stirrings that heat up under water bath condition are to starch gelatinization, cooling
Being sequentially added into acrylic acid and N, N'-methylene-bisacrylamide to room temperature, stirring 5 ~ 10min reacts in 60 ~ 70 DEG C of water-baths
1.5 ~ 2h, is dried at 70 ~ 80 DEG C after completing, finally grinds to form powder.
Select 5 mu of fresh kidney beans growing areas as test, by the fertilizer additive of the present invention with common applying fertilizer when
Using after the ratio mixing of fertilizer 1:10,5 mu of rice terrace fertilizer of matched group show without any composition, result: test group
Fresh kidney beans can be greatly saved common fertilizer consumption, fertilizer efficiency is preferable, and soil water-retaining performance is excellent, also has good anthelmintic effect
Really, the spending in terms of fertilizer is saved.
Claims (2)
1. the fertilizer additive improving soil water-reataining fertilizer-keeping, it is characterised in that be made up of the raw material of following weight portion: propylene
Acid 20 ~ 30, starch 5 ~ 8, N, N'-methylene-bisacrylamide 0.1 ~ 0.3, polyglutamic acid 1 ~ 4, activated sludge 10 ~ 15, biogas
Waste residue 20 ~ 25, ammonium molybdate 3 ~ 6, Kaolin 1 ~ 3, sodium carboxymethyl cellulose 0.5 ~ 1.0, agricultural crop straw 40 ~ 50, CELLULOLYTIC BACTERIUM
Agent 2 ~ 3, plant source raw material 30 ~ 40 and appropriate water;
Described plant source raw material be with weight (part) be the unit fresh tomato leaf 3 ~ 6 of mixing, Folium seu Cortex Nerii 6 ~ 10, Folium Cinnamomi porrecti 8 ~
12, Fructus Gleditsia 4 ~ 6, acer monoes 2 ~ 5, Pinus tabuliformis 10 ~ 15, ailanthus altissima (mill.) swingle 10 ~ 14 and Folium Ginkgo 7 ~ 12, after preliminary pulverizing, 0 ~ 5 DEG C of cold preservation is standby.
A kind of preparation method of the fertilizer additive improving soil water-reataining fertilizer-keeping, it is characterised in that
Including following step:
(1) by plant source raw mill 40 ~ 60min uniformly slurry, ultrasonication prepares serosity, adds by material-water ratio 1:2 ~ 3
Entering distilled water diluting, employing steam reflux, extract, 2 ~ 3h must be rich in the aqueous solution of extracting solution;
(2) agricultural crop straw is tentatively pulverized, mixing biogas waste residue and activated sludge, for covering at aforementioned straw, inoculation
Cellulose microbial inoculum, retting 15 ~ 20 days after mixing, after completing, sterilizing ball milling become homogenate, and the water adding its total weight parts 2 ~ 3 times is dilute
Release, filter out filtrate, add after concentration to the aqueous solution described in (1);
(3) Kaolin was pulverized 140 ~ 180 mesh sieves, and mixed other following residual components being not directed to and join described in (2)
In mixed solution, stirring and evenly mixing;
(4) being added to the mixed liquor described in (3) by starch, 75 ~ 85 DEG C of stirrings that heat up under water bath condition are to starch gelatinization, cooling
Being sequentially added into acrylic acid and N, N'-methylene-bisacrylamide to room temperature, stirring 5 ~ 10min reacts in 60 ~ 70 DEG C of water-baths
1.5 ~ 2h, is dried at 70 ~ 80 DEG C after completing, finally grinds to form powder.
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CN201610479529.5A CN106116982A (en) | 2016-06-24 | 2016-06-24 | A kind of fertilizer additive improving soil water-reataining fertilizer-keeping and preparation method thereof |
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CN201610479529.5A CN106116982A (en) | 2016-06-24 | 2016-06-24 | A kind of fertilizer additive improving soil water-reataining fertilizer-keeping and preparation method thereof |
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Cited By (5)
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CN106699990A (en) * | 2016-11-30 | 2017-05-24 | 西安建筑科技大学 | Synthetic water absorption and water retention material with high volume of non-dehydrated state sludge and preparing method |
CN108586111A (en) * | 2018-08-02 | 2018-09-28 | 句容市丰源生态农业有限公司 | A kind of prevention pear tree root system aging, rotten solid fertilizer and preparation method thereof |
CN110055078A (en) * | 2019-04-16 | 2019-07-26 | 安徽泓森高科林业股份有限公司 | A kind of plant water keeping agent and preparation method thereof |
CN110511092A (en) * | 2019-09-29 | 2019-11-29 | 河北天郎生物科技有限公司 | A kind of fertilizer synergistic auxiliary agent and preparation method thereof containing chlorogenic acid |
CN114591113A (en) * | 2022-04-14 | 2022-06-07 | 青岛合子肥生物科技有限公司 | Special fertilizer for tomatoes and preparation method thereof |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106699990A (en) * | 2016-11-30 | 2017-05-24 | 西安建筑科技大学 | Synthetic water absorption and water retention material with high volume of non-dehydrated state sludge and preparing method |
CN106699990B (en) * | 2016-11-30 | 2019-06-04 | 西安建筑科技大学 | The non-dehydration state sludge high additive synthesis water-absorbing-retaining material of one kind and preparation method |
CN108586111A (en) * | 2018-08-02 | 2018-09-28 | 句容市丰源生态农业有限公司 | A kind of prevention pear tree root system aging, rotten solid fertilizer and preparation method thereof |
CN110055078A (en) * | 2019-04-16 | 2019-07-26 | 安徽泓森高科林业股份有限公司 | A kind of plant water keeping agent and preparation method thereof |
CN110511092A (en) * | 2019-09-29 | 2019-11-29 | 河北天郎生物科技有限公司 | A kind of fertilizer synergistic auxiliary agent and preparation method thereof containing chlorogenic acid |
CN114591113A (en) * | 2022-04-14 | 2022-06-07 | 青岛合子肥生物科技有限公司 | Special fertilizer for tomatoes and preparation method thereof |
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Application publication date: 20161116 |