CN101589720A - A kind of insecticides that contains indenes worm prestige - Google Patents
A kind of insecticides that contains indenes worm prestige Download PDFInfo
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- CN101589720A CN101589720A CNA2009101593376A CN200910159337A CN101589720A CN 101589720 A CN101589720 A CN 101589720A CN A2009101593376 A CNA2009101593376 A CN A2009101593376A CN 200910159337 A CN200910159337 A CN 200910159337A CN 101589720 A CN101589720 A CN 101589720A
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- pleocidin
- indenes worm
- worm prestige
- insecticides
- composition
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Abstract
The invention discloses a kind of insecticides.Said composition is made up of indenes worm prestige and two kinds of active ingredients of pleocidin and auxiliary agent, solvent or carrier, and wherein the part by weight of indenes worm prestige and pleocidin is between 50: 1～1: 30, and the active ingredient total content is 1%-80%.Said composition has higher cooperative synergism, has enlarged the control spectrum, helps to overcome and delay pest resistance to insecticide, and is better with the compatibility of environment.But the lepidoptera pest that said composition high-efficiency prevention and control paddy and wheat, cotton, fruit tree and vegetables etc. are upward taken place, thrips etc. especially can be used for preventing and treating high resistance beet armyworm and diamondback moth larvae, and its effect is used separately apparently higher than its single agent.
Description
Technical field
The present invention relates to composition pesticide, especially a kind of complex pesticide composition that contains indenes worm prestige.
Background technology
In the control of diseases and pests of agronomic crop, chemical control still in the highest flight.But long-term a large amount of chemical pesticide that uses makes the pesticide resistance of germ, insect constantly increase, and the kind of drug-fast sick Chinese caterpillar fungus is also more and more.Will kill the sick worm of these pesticide resistance today, dosage must be increased several times, so both increase production cost, the natural enemy that can kill off the insect pests again causes crop pests to cause disaster again and again.Particularly serious is, uses chemical pesticide in a large number, also can aggravate environmental pollution, infringement human body health.Therefore, in the current extermination of disease and insect pest, be badly in need of the agricultural chemicals of efficient, low toxicity, low-residual.
Indenes worm prestige (indoxacarb) is the new and effective low toxic pesticide of being succeeded in developing by du pont company of oxadiazines class, is a kind of broad spectrum activity efficient pesticides, and does not have cross resistance with other insecticide, is to substitute one of desirable kind of organic phosphorous insecticide.Its mechanism of action is different from present various insecticides fully, is the sodium channel inhibitor, causes target pest coordination, paralysis, final dead.Be mainly used in the control multiple lepidoptera pest of vegetables, fruit tree and cotton such as diamond-back moth, beet armyworm, cabbage caterpillar, prodenia litura, cotton bollworm etc.But its interior absorption in making object is very poor, essentially no conductivity.
Pleocidin (spinosad) has another name called multiple killing teichomycin, is the novel biopesticide of The Dow Agrosciences, LLC.'s exploitation.The existing insecticidal properties efficiently of pleocidin has again the characteristic of beneficial insect and mammalian safe is arranged, and is fit to pollution-free vegetable, fruit production application, is the insecticide of a kind of low toxicity, efficient, wide spectrum.Insect had tag fast and stomach poison function, blade is had stronger osmosis, can kill subepidermal insect, the longevity of residure is longer, can the effectively preventing Lepidoptera, diptera and thrips insect.
The mode of action novelty of pleocidin can sustained activation target insect acetylcholine nicotine receptor, also can influence the GABA acceptor, does not have cross resistance with present common insecticide.But report is arranged, and pleocidin has found to produce the field population of resistance in the control of beet armyworm and diamond-back moth.Arizona State in US West, the leaf vegetables of the pleocidin of commodity in useization control first insect is in 1997, find that in 1999 measure beet armyworm field population has produced 3.9-14 resistance doubly to this medicament, and pleocidin is not carried out the Thailand beet armyworm population that resistance is managed, its resistance is up to 85 times.
Good mixed pesticide can produce synergistic effect, can delay the pesticide resistance of germ, insect after the use, improves the control efficiency of medicament to sick worm, has both had an economic benefit, and good ecology and social benefit are also arranged.Utilize the agriculture chemical compounding technology to become one of main path of exploitation agricultural chemicals new product.
Summary of the invention
The purpose of this invention is to provide a kind of good disinsection effect, safe, Synergistic insecticidal compositions that control spectrum is wide.Another purpose provides a kind of compounded pesticides that contains indenes worm prestige and pleocidin, is used for the control of crop pests.By rationally being mixed between indenes worm prestige and the pleocidin, can enlarge insecticidal spectrum, improve drug effect, reduce dosage, effectively solve the pest resistance problem, and safety is higher, can be used as the insecticide of high-quality vegetables, fruit.Technical scheme of the present invention is as follows:
A kind of insecticides is characterized in that active ingredient is indenes worm prestige and pleocidin, and the part by weight of indenes worm prestige and pleocidin is between 50: 1～1: 30.Composition can adopt known method to be processed into missible oil, aqueous emulsion, microemulsion, suspending agent, wetting powder and water dispersible granules, and the total content of active ingredient is 1%--80% in the preparation.
As a kind of improvement of the present invention, active ingredient indenes worm prestige and pleocidin part by weight are 5: 1～1: 5 preferably in the composition.
Insecticides of the present invention, all effective to nearly all lepidoptera pest, but high-efficiency prevention and control beet armyworm, prodenia litura, diamond-back moth, cotton bollworm etc., sucking pest there is good preventive effect, can also the effectively preventing diptera, thrips, coleoptera and part orthoptera pest etc.
The present invention is that indenes worm prestige and pleocidin carry out composite mix preparation and application thereof, and its advantage and good effect are as follows:
1. behind indenes worm prestige and the pleocidin compound, have obvious synergistic effect, reduce single agent consumption separately, can effectively prevent and treat the insect that existing medicament has been produced resistance.
2. indenes worm prestige and pleocidin compound, not only nearly all lepidoptera pest is had fine preventive effect, leafhopper, fleahopper, thrips are also had good control efficiency, insect is planted by the Zhiduo County of can a dispenser holding concurrently, prevent and treat cost thereby reduce the peasant, receive remarkable economic efficiency and social benefit.
3. indenes worm prestige is different with the pleocidin mechanism of action, is mixed to use to overcome and to delay pest resistance to insecticide, prolongs the service life of medicament.
Embodiment
The present invention will be further described below in conjunction with embodiment.
The embodiment of the invention further specifies the application and the beneficial effect of composition with following biologicall test and test of pesticide effectiveness example, but does not constitute any limitation of the invention.Used preparation among the embodiment, the former medicine of 94% indenes worm prestige is du pont company production, the former medicine of 90% pleocidin is that The Dow Agrosciences, LLC. produces, and is mixed with the preparation that needs by my research institute of company.
Biologic test example 1: indenes worm prestige, pleocidin and different proportioning are to the toxicity test of beet armyworm
Employing is soaked leaf and connect the worm method: reagent agent is made into certain density mother liquor, and it is stand-by to be diluted to 5 gradient concentrations with clear water again, establishes clear water and is contrast.Get fresh and tender cabbage leaves and be cut into the fragment of the long big or small basically identical of about 50mm, with the blade that shears prepare for reagent liquid in dipping 10 seconds, take out allow it dry naturally after, put into the culture dish (φ 120mm) that is lined with filter paper in advance.In ware, insert beet armyworm 3 instar larvaes then, 10 in every ware, every concentration repeats for 3 times.Dispose, cover the ware lid, place in the greenhouse and cultivate, routine observation, inspection record death condition after 72 hours is calculated lethality, and obtains virulence regression equation formula, correlation coefficient and the lethal concentration of 50 (LC according to the probit value analytical method
50).The synergy mode adopts abundant co-toxicity coefficient (CTC) method that waits the nineteen sixty proposition of Sun Yun.The computing formula of co-toxicity coefficient is as follows:
Actual measurement toxicity index (ATI)=(standard medicament LC
50/ reagent agent LC
50) * 100
The percentage composition of B in percentage composition+B medicament ATI * mixture of A in theoretical toxicity index (TTI)=A medicament ATI * mixture
Co-toxicity coefficient (CTC)=(mixture ATI/ mixture TTI) * 100
When CTC≤80, then the composition performance is for antagonism, and when 80＜CTC＜120, then the composition performance is for summation action, and when CTC 〉=120, then the composition performance is synergistic effect.The results are shown in Table 1.
Table 1 indenes worm prestige, pleocidin and different proportioning are to the toxicity test (72h) of beet armyworm
| Reagent agent | LC 50 (mg/L) | Correlation coefficient (r) | Actual measurement toxicity index (ATI) | Theoretical toxicity index (TTI) | Co-toxicity coefficient (CTC) |
| Indenes worm prestige (I) | 0.53 | 0.9812 | 100 | - | - |
| Pleocidin (S) | 1.72 | 0.9867 | 30.81 | - | - |
| I∶S(50∶1) | 0.41 | 0.9824 | 129.27 | 98.78 | 130.87 |
| I∶S(10∶1) | 0.36 | 0.9921 | 147.22 | 94.36 | 156.02 |
| I∶S(5∶1) | 0.24 | 0.9865 | 220.83 | 88.52 | 249.53 |
| I∶S(1∶1) | 0.29 | 0.9909 | 182.76 | 65.41 | 279.45 |
| I∶S(1∶5) | 0.31 | 0.9813 | 170.97 | 42.33 | 404.25 |
| I∶S(1∶10) | 1.09 | 0.9803 | 48.63 | 37.09 | 131.11 |
| I∶S(1∶30) | 1.33 | 0.9783 | 39.85 | 33.03 | 120.64 |
The results are shown in Table 1.By table 1 as seen, indenes worm prestige and pleocidin are mixed in the ratio of 50: 1,10: 1,5: 1,1: 1,1: 5,1: 10 and 1: 30, its co-toxicity coefficient to beet armyworm is respectively 130.87,156.02,249.53,279.45,404.25,131.11,120.64, all shows as synergistic effect.Wherein, when indenes worm prestige and pleocidin are mixed in 5: 1,1: 1,1: 5 ratio, beet armyworm is shown as significant more synergistic effect.
Biologic test example 2: indenes worm prestige, pleocidin and different proportioning are to the toxicity test of diamond-back moth
Method connects the worm method with the leaf that soaks shown in the biologic test example 1.
The results are shown in Table 2.
Table 2 indenes worm prestige, pleocidin and different proportioning are to the toxicity test (72h) of diamond-back moth
| Reagent agent | LC 50 (mg/L) | Correlation coefficient (r) | Actual measurement toxicity index (ATI) | Theoretical toxicity index (TTI) | Co-toxicity coefficient (CTC) |
| Indenes worm prestige (I) | 1.17 | 0.9903 | 100 | - | - |
| Pleocidin (S) | 1.39 | 0.9832 | 84.17 | - | - |
| I∶S(50∶1) | 0.81 | 0.9946 | 144.44 | 99.69 | 144.89 |
| I∶S(10∶1) | 0.76 | 0.9811 | 153.95 | 98.55 | 156.22 |
| I∶S(5∶1) | 0.54 | 0.9854 | 216.67 | 97.33 | 222.61 |
| I∶S(1∶1) | 0.61 | 0.9859 | 191.80 | 92.08 | 208.30 |
| I∶S(1∶5) | 0.67 | 0.9863 | 174.63 | 86.83 | 201.12 |
| I∶S(1∶10) | 0.92 | 0.9903 | 127.17 | 85.64 | 148.49 |
| I∶S(1∶30) | 1.13 | 0.9833 | 103.54 | 84.68 | 122.27 |
By table 2 as seen, indenes worm prestige and pleocidin are mixed in the ratio of 50: 1,10: 1,5: 1,1: 1,1: 5,1: 10 and 1: 30, it is respectively 144.89,156.22,222.61,208.30,201.12,148.49,122.27 to the diamond-back moth co-toxicity coefficient, all shows as synergistic effect.Wherein, when indenes worm prestige and pleocidin are mixed in 5: 1,1: 1,1: 5 ratio, to the significant more synergistic effect of showing as of diamond-back moth.
Example of formulations:
The preparation processing method that adopts in the following example of formulations is well known by persons skilled in the art, can according to circumstances change to some extent.
Example of formulations 1:18% indenes worm prestige. pleocidin missible oil
Indenes worm prestige 15% (weight ratio)
Pleocidin 3% (weight ratio)
Farming newborn 600# (emulsifier) 7% (weight ratio)
Farming newborn 2201# (emulsifier) 5% (weight ratio)
Dimethylbenzene (solvent) surplus
Take by weighing various compositions such as indenes worm prestige, pleocidin by weight, indenes worm prestige, pleocidin, most of dimethylbenzene are dropped into modulation kettle, starting agitator mixes, former medicine is dissolved in the solvent, for the dissolution velocity of accelerating former medicine can suitably heat, but heating-up temperature should not be higher than the boiling point of solvent.Treat that former medicine all dissolves back (if temperature needs cooling when higher), adding agricultural newborn 600#, agricultural newborn 2201# and remaining solvent again continues to mix, mixing is reduced to room temperature with temperature in the kettle later, promptly makes the insecticides missible oil that contains indenes worm prestige and pleocidin of the present invention.
The part by weight of indenes worm prestige and pleocidin can change between 50: 1～1: 30 (example 50: 1,10: 1,1: 1,1: 10,1: 30) in the present embodiment, and both total weight contents still are 18%, form new embodiment.
This embodiment preparation is used to prevent and treat wild cabbage vegetable garden beet armyworm.18% indenes worm prestige. pleocidin missible oil 20g.a.i./ha converts water spray, and the control efficiency of dispenser after 1 day, 3 days, 7 days reaches 91.53%, 94.21%, 97.68% respectively.15% indenes worm prestige missible oil 30g.a.i./ha converts water spray, and the control efficiency after 1 day, 3 days, 7 days reaches 79.32%, 82.64%, 85.41% respectively.5% pleocidin missible oil 30g.a.i./ha converts water spray, and the control efficiency after 1 day, 3 days, 7 days reaches 73.84%, 80.36%, 82.21% respectively.Behind indenes worm prestige and the pleocidin compound, the independent use of the more single agent of the control efficiency of beet armyworm is significantly improved, and the dosage minimizing, drug cost reduced.
Example of formulations 2:20% indenes worm prestige. the pleocidin aqueous emulsion
Indenes worm prestige 5% (weight ratio)
Pleocidin 15% (weight ratio)
Farming newborn 600# (emulsifier) 8% (weight ratio)
Toluene (cosolvent) 10% (weight ratio)
Ethylene glycol (antifreezing agent) 1% (weight ratio)
The deionized water surplus
By the prescription requirement, mixing stirring and dissolving such as indenes worm prestige, pleocidin, cosolvent, emulsifier are made oil phase, under the 60-90r/min stirring action, directly add deionized water in the oil phase, stir about 30min, get shallow emulsion liquid, promptly get Pesticidal combination aqueous emulsion product of the present invention after sample analysis is qualified.
The part by weight of indenes worm prestige and pleocidin can change between 50: 1～1: 30 (example 50: 1,10: 1,1: 1,1: 10,1: 30) in the present embodiment, and both total weight contents still are 40%, form new embodiment.
This embodiment preparation is used to prevent and treat vegetable garden a variety of Chinese cabbage diamond-back moth.20% indenes worm prestige. pleocidin aqueous emulsion 20g.a.i./ha converts water spray, and the control efficiency of dispenser after 1 day, 3 days, 7 days reaches 86.23%, 89.61%, 93.54% respectively.15% indoxacarb aqueous emulsion 30g.a.i./ha converts water spray, and the control efficiency after 1 day, 3 days, 7 days reaches 75.63%, 78.45%, 84.76% respectively.5% pleocidin aqueous emulsion 30g.a.i./ha converts water spray, and the control efficiency after 1 day, 3 days, 7 days reaches 70.86%, 74.90%, 81.21% respectively.Behind indenes worm prestige and the pleocidin compound, the independent use of the more single agent of the control efficiency of diamond-back moth is significantly improved, and the dosage minimizing, drug cost reduced.
Example of formulations 3:18% indenes worm prestige. the pleocidin microemulsion
Indenes worm prestige 3% (weight ratio)
Pleocidin 15% (weight ratio)
Farming breast 1601 (emulsifier) 20% (weight ratio)
Acetone (cosolvent) 5% (weight ratio)
Deionized water (solvent) surplus (weight ratio)
By the prescription requirement, indenes worm prestige, pleocidin, cosolvent, emulsifier stirring and dissolving are made oil phase, under the 60-90r/min stirring action, deionized water is directly added in the oil phase, stir 15-30min, get transparency liquid.Each index promptly gets Pesticidal combination microemulsion of the present invention after qualified by analysis.
The part by weight of indenes worm prestige and pleocidin can change between 50: 1～1: 30 (example 50: 1,10: 1,1: 1,1: 10,1: 30) in the present embodiment, and both total weight contents still are 40%, form new embodiment.
This embodiment preparation is used to prevent and treat cotton bollworm.18% indenes worm prestige. pleocidin microemulsion 20g.a.i./ha converts water spray, and the control efficiency of dispenser after 1 day, 3 days, 7 days reaches 89.42%, 92.74%, 96.16% respectively.15% indenes worm prestige microemulsion 30g.a.i./ha converts water spray, and the control efficiency after 1 day, 3 days, 7 days reaches 80.31%, 82.72%, 87.11% respectively.5% pleocidin microemulsion 30g.a.i./ha converts water spray, and the control efficiency after 1 day, 3 days, 7 days reaches 76.13%, 81.36%, 84.21% respectively.Behind indenes worm prestige and the pleocidin compound, the independent use of the more single agent of the control efficiency of cotton bollworm is significantly improved, and the dosage minimizing, drug cost reduced.
Example of formulations 4:40% indenes worm prestige. pleocidin suspension
Indenes worm prestige 15% (weight ratio)
Pleocidin 25% (weight ratio)
Neopelex (wetting agent) 1% (weight ratio)
Calcium lignosulfonate (dispersant) 2% (weight ratio)
Methylcellulose (tackifier) 2% (weight ratio)
Bentonite (stabilizing agent) 3% (weight ratio)
Ethylene glycol (antifreezing agent) 2% (weight ratio)
Deionized water (solvent) She amount
According to prescription, in having the dispersion tank of high speed agitator, former medicine and calcium lignosulfonate are scattered in the water the former medicine of coarse crushing; This mixture through coarse crushing is sent in the attrition mill continuously with constant displacement pump, carried out fine pulverizing; The material that separates, discharges with medium is sent into last blending tank, and the methocel solution that modulates is in addition added blending tank, mixes equably with the material of having pulverized, obtains final suspending agent.
The part by weight of indenes worm prestige and pleocidin can change between 50: 1～1: 30 (example 50: 1,10: 1,1: 1,1: 10,1: 30) in the present embodiment, and both total weight contents still are 40%, form new embodiment.
This embodiment preparation is used to prevent and treat colorado potato beetle.40% indenes worm prestige. pleocidin suspension 20g.a.i./ha converts water spray, and the control efficiency of dispenser after 1 day, 3 days, 7 days reaches 90.53%, 93.23%, 94.81% respectively.30% indenes worm prestige suspending agent 30g.a.i./ha converts water spray, and the control efficiency after 1 day, 3 days, 7 days reaches 75.32%, 78.74%, 80.41% respectively.50% pleocidin suspension 30g.a.i./ha converts water spray, and the control efficiency after 1 day, 3 days, 7 days reaches 72.44%, 78.36%, 80.41% respectively.Behind indenes worm prestige and the pleocidin compound, the independent use of the more single agent of the control efficiency of colorado potato beetle is significantly improved, and the dosage minimizing, drug cost reduced.
Example of formulations 5:50% indenes worm prestige. the pleocidin wetting powder
Indenes worm prestige 30% (weight ratio)
Pleocidin 20% (weight ratio)
Calcium lignosulfonate (dispersant) 10% (weight ratio)
Lauryl sodium sulfate (wetting agent) 3% (weight ratio)
Potter's clay (carrier) surplus
Take by weighing various compositions such as indenes worm one-tenth, pleocidin by weight, through drying, the cooling of filler; Being mixed of filler, former medicine, auxiliary agent, levigate, mix; The operations such as packing of wetting powder product promptly make the insecticides wetting powder that contains indenes worm prestige and pleocidin of the present invention.
The part by weight of indenes worm prestige and pleocidin can change between 50: 1～1: 30 (example 50: 1,10: 1,1: 1,1: 10,1: 30) in the present embodiment, and both total weight item content still are 50%, form new embodiment.
This embodiment preparation is used to prevent and treat the leek thrips.50% indenes worm prestige. pleocidin wetting powder 20g.a.i./ha converts water spray, and the control efficiency of dispenser after 1 day, 3 days, 7 days reaches 86.34%, 89.22%, 93.68% respectively.40% indenes worm prestige wetting powder 30g.a.i./ha converts water spray, and the control efficiency after 1 day, 3 days, 7 days reaches 72.32%, 75.64%, 67.14% respectively.50% pleocidin wetting powder 30g.a.i./ha converts water spray, and the control efficiency after 1 day, 3 days, 7 days reaches 73.84%, 80.36%, 76.21% respectively.Behind indenes worm prestige and the pleocidin compound, the independent use of the more single agent of the control efficiency of leek thrips is significantly improved, and the dosage minimizing, drug cost reduced.
Example of formulations 6:50% indenes worm prestige. the pleocidin water dispersible granules
Indenes worm prestige 30% (weight ratio)
Pleocidin 20% (weight ratio)
Calcium lignosulfonate (dispersant) 10% (weight ratio)
Lauryl sodium sulfate (wetting agent) 3% (weight ratio)
Potter's clay (carrier) surplus
Take by weighing various compositions such as indenes worm prestige, pleocidin by weight, adopt the extruder grain method to make the insecticides water dispersible granules that contains indenes worm prestige and pleocidin of the present invention.
The part by weight of indenes worm prestige and pleocidin can change between 50: 1～1: 30 (example 50: 1,10: 1,1: 1,1: 10,1: 30) in the present embodiment, and both total weight item content still are 50%, form new embodiment.
This embodiment preparation is used to prevent and treat cotton leaf bug and resembles.50% indenes worm prestige. pleocidin water dispersible granules 20g.a.i./ha converts water spray, and the control efficiency of dispenser after 1 day, 3 days, 7 days reaches 83.26%, 88.11%, 93.27% respectively.60% indenes worm prestige water dispersible granules 30g.a.i./ha converts water spray, and the control efficiency after 1 day, 3 days, 7 days reaches 71.41%, 78.47%, 84.31% respectively.50% pleocidin water dispersible granules 30g.a.i./ha converts water spray, and the control efficiency after 1 day, 3 days, 7 days reaches 73.41%, 79.60%, 83.05% respectively.Behind indenes worm prestige and the pleocidin compound, the independent use of the more single agent of the control efficiency of cotton leaf bug elephant is significantly improved, and the dosage minimizing, drug cost reduced.
Claims (5)
1. an insecticides is characterized in that active ingredient is indenes worm prestige and pleocidin, and wherein the part by weight of indenes worm prestige and pleocidin is between 50: 1～1: 30.
2. insecticides according to claim 1 is characterized in that active ingredient indenes worm becomes and the part by weight of pleocidin is 5: 1～1: 5.
3. according to claim 1 or 2, the formulation that it is characterized in that composition is missible oil, aqueous emulsion, microemulsion, suspending agent, wetting powder and water dispersible granules.
4. according to claim 3, it is characterized in that the active ingredient total content is 1%--80% in the composition.
5. claim 1 or 2 described insecticides are used to prevent and treat Lepidoptera, thrips, the Semiptera insect of taking place on paddy and wheat, cotton, fruit tree and the vegetables.
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| CN2009101593376A CN101589720B (en) | 2009-07-08 | 2009-07-08 | Pesticide composition containing indoxacarb |
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| CN2009101593376A CN101589720B (en) | 2009-07-08 | 2009-07-08 | Pesticide composition containing indoxacarb |
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| CN101589720B CN101589720B (en) | 2012-07-25 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102860316A (en) * | 2012-09-28 | 2013-01-09 | 南京农业大学 | Insecticidal composite containing spinetoram |
| CN102986707A (en) * | 2012-12-18 | 2013-03-27 | 北京燕化永乐农药有限公司 | Complex insecticide |
| CN104472524A (en) * | 2014-11-21 | 2015-04-01 | 张英芹 | Red imported fire ant aerosol |
| CN105851039A (en) * | 2016-04-29 | 2016-08-17 | 山东胜伟园林科技有限公司 | Botanical insecticide containing garlic extracts and preparation method of botanical insecticide |
| US9955694B2 (en) | 2014-08-05 | 2018-05-01 | Dow Global Technologies Llc | Emulsifiable concentrates of indoxacarb |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1663381A (en) * | 2005-03-16 | 2005-09-07 | 广东省农业科学院植物保护研究所 | Vegetable pesticide |
| CN100559948C (en) * | 2008-03-28 | 2009-11-18 | 中国农业大学 | The composition pesticide that contains pleocidin and carbamate insecticide |
-
2009
- 2009-07-08 CN CN2009101593376A patent/CN101589720B/en active Active
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102860316A (en) * | 2012-09-28 | 2013-01-09 | 南京农业大学 | Insecticidal composite containing spinetoram |
| CN102986707A (en) * | 2012-12-18 | 2013-03-27 | 北京燕化永乐农药有限公司 | Complex insecticide |
| US9955694B2 (en) | 2014-08-05 | 2018-05-01 | Dow Global Technologies Llc | Emulsifiable concentrates of indoxacarb |
| CN104472524A (en) * | 2014-11-21 | 2015-04-01 | 张英芹 | Red imported fire ant aerosol |
| CN105851039A (en) * | 2016-04-29 | 2016-08-17 | 山东胜伟园林科技有限公司 | Botanical insecticide containing garlic extracts and preparation method of botanical insecticide |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101589720B (en) | 2012-07-25 |
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