CN102578098B - Insecticidal composition containing spinosad and thiocyclam - Google Patents
Insecticidal composition containing spinosad and thiocyclam Download PDFInfo
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- CN102578098B CN102578098B CN201210010843.0A CN201210010843A CN102578098B CN 102578098 B CN102578098 B CN 102578098B CN 201210010843 A CN201210010843 A CN 201210010843A CN 102578098 B CN102578098 B CN 102578098B
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- thiocyclam
- multiple killing
- killing teichomycin
- rice
- thrips
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- 229940014213 spinosad Drugs 0.000 title abstract description 5
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- 229940005550 Sodium alginate Drugs 0.000 description 1
- 241000985245 Spodoptera litura Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 231100000765 Toxin Toxicity 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N Tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- HVLLSGMXQDNUAL-UHFFFAOYSA-N Triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 230000000996 additive Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive Effects 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 235000005824 corn Nutrition 0.000 description 1
- 230000004059 degradation Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 229940079593 drugs Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N ethanolamine Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N ethylene glycol monomethyl ether Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000003958 fumigation Methods 0.000 description 1
- 238000010413 gardening Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000002045 lasting Effects 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 231100000194 ovacidal Toxicity 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920001888 polyacrylic acid Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 235000021003 saturated fats Nutrition 0.000 description 1
- 210000004894 snout Anatomy 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- MSXHSNHNTORCAW-UHFFFAOYSA-M sodium 3,4,5,6-tetrahydroxyoxane-2-carboxylate Chemical compound [Na+].OC1OC(C([O-])=O)C(O)C(O)C1O MSXHSNHNTORCAW-UHFFFAOYSA-M 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 239000001187 sodium carbonate Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000002588 toxic Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Abstract
The invention discloses an insecticidal composition containing spinosad and thiocyclam, the composition contains the spinosad and the thiocyclam, and the weight ratio of the spinosad to the thiocyclam is (50:1)-(1:80). The composition disclosed by the invention can be used for controlling a variety of insect pests, has obvious synergy, can expand the insecticidal spectrum and has higher activity against asparagus caterpillar, diamond back moth, thrips, paddy borer, rice leaf roller, striped rice borer, paddy thrips, leafhopper, rice gall midge, plant hopper, peach aphid, apple aphid, European red mite, pear leaf worm and citrus leaf-miner; and furthermore, the composition can reduce the dosage of pesticide, reduce the residual quantity of the pesticide on crops and reduce environmental pollution, and is safe to people and animals, good in environmental compatibility and less prone to causing drug resistance of the pests.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of Pesticidal combination containing multiple killing teichomycin and thiocyclam.
Background technology
Multiple killing teichomycin (spinosad), have insect and tag fast and stomach poison function, have stronger osmosis to blade, can kill subepidermal insect, the longevity of residure is longer, has certain ovicidal action to some insects.Without systemic action.Can effectively preventing Lepidoptera, diptera and Thysanoptera, also well can prevent and treat in coleoptera and orthoptera that some takes food the pest species of blade in a large number, poor to the control efficiency of sucking pest and mite class.Safer to predatory natural enemy insect, because insecticidal action mechanism is unique, not yet find to there is mutual drug-fast report with other insecticides at present.To plant safety without poisoning.Be suitable for vegetables, fruit tree, gardening, crops use.Insecticidal effect affects less by raining.
Thiocyclam (thiocyclam-hydrogenoxalate), molecular formula: C
7h
13nO
4s
3, structural formula: N, N-dimethyl 1,2,3-trithian-5-amido oxalate, is sandworm toxin insecticide, has and tag and stomach poison function also have certain interior suction and fumigation action, and can ovicidal.Slower to the toxic effect of insect, poisoning the lighter can be brought back to life sometimes.It disappears comparatively fast in plant corpus, and the longevity of residure is shorter, and residual quantity during results in crop is little.Thiocyclam is effective to Lepidoptera, coleoptera, homoptera pest, can be used for preventing and treating the various pests on paddy rice, corn, beet, fruit tree, vegetables, but large to the toxicity of silkworm.
But in the real process of agricultural production, the problem that pest control the most easily produces is the generation of pest resistance to insecticide.
Different cultivars composition carries out composite, is to prevent and treat the very common method of resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals is all additive effect, really has the seldom composite of synergistic effect, especially synergistic effect clearly, very high composite just less of co-toxicity coefficient.Through inventor's research, find by multiple killing teichomycin and thiocyclam composite after can produce good synergistic effect, and about multiple killing teichomycin and the composite relevant report of thiocyclam and apply not yet open.
Summary of the invention
Resistance that multiple killing teichomycin single dose Long-Time Service may bring occurs, degradation problem under drug effect, and the Pesticidal combination that the present invention proposes contains A, B two kinds of active components, and appropriate surfactant and carrier.
Contain a Pesticidal combination for multiple killing teichomycin and thiocyclam, comprise effective active component multiple killing teichomycin and thiocyclam, auxiliary agent, it is characterized in that: multiple killing teichomycin and thiocyclam weight ratio are 50: 1 ~ 1: 80.
Described Pesticidal combination, is characterized in that: the weight ratio of multiple killing teichomycin and thiocyclam is 30: 1 ~ 1: 60, is preferably 20: 1 ~ 1: 50.
Described Pesticidal combination, is characterized in that: the weight ratio of multiple killing teichomycin and thiocyclam is 10: 1 ~ 1: 40, is preferably 5: 1 ~ 1: 20.
Surfactant selected by Pesticidal combination of the present invention is known in those skilled in the art: can be selected from one or more in dispersant, wetting agent, binding agent or defoamer.According to different dosage form, in preparation, disintegrant known in those skilled in the art, antifreeze etc. can also be contained.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, one or more during ester polyoxyethylene is phonetic.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, tea are withered, one or more in silkworm excrement, soapberry powder.
Described disintegrant is selected from: one or more in sodium bicarbonate, sodium carbonate, bentonite, urea, ammonium sulfate, aluminium chloride.
Described binding agent is selected from: one or more in gelatin, melon glue, gum Arabic, xanthans, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, crospolyvinylpyrrolidone, polyethylene glycol, polyvinyl alcohol.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, polyethylene glycol.
Described defoamer is selected from: silicone, C
8 ~ 10aliphatic alcohols, C
10 ~ 20one or more in saturated fat acids (as capric acid) and acid amides, silicone oil, silicone compound.
Described emulsifier is selected from: agriculture breast 500# (alkyl benzene calcium sulfonate), OP series phosphate (thermally coupled distillation columns), 600# phosphate (phenyl phenol polyoxyethanyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, agriculture breast 400# (benzyl dimethyl phenol polyoxyethyl ether), agriculture breast 600# (phenyl phenol polyoxyethyl ether), Nongru-700 # (alkylphenol-formaldehyde resin polyoxyethyl ether), agriculture breast 36# (phenethyl fluosite polyoxyethyl ether), agriculture breast 1600# (phenethyl phenol polyoxyethanyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), agriculture breast 33# (alkylaryl polyoxyethylene polyoxypropylene ether), agriculture breast 34# (alkylaryl polyoxyethylene poly-oxygen propylene aether), Span series (sorbitan monostearate), TWEEN Series (sorbitan fatty acid ester APEO), one or more in AEO series (fat alcohol alcohol APEO).
Described stabilizing agent is selected from: one or more in BHT, triphenyl phosphite, epoxychloropropane, tributyl phosphate, triethanolamine, diethanol amine, monoethanolamine.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Composition of the present invention can by user before use through diluting or directly using.Its preparation can be prepared by common processing method, after mixing, then adds surfactant as one or more in dispersant, stabilizing agent, wetting agent, adhesive, defoamer etc. by active substance with liquid flux or solid carrier.
Pesticidal combination of the present invention, can be processed into acceptable formulation on any agricultural chemicals on demand.Wherein preferred dosage form is wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
Composition comprises following constituent content when making wetting powder: multiple killing teichomycin 1 ~ 50%, thiocyclam 1 ~ 80%, dispersant 5 ~ 10%, wetting agent 2 ~ 10%, filler surplus.
By active component multiple killing teichomycin, thiocyclam, dispersant, wetting agent, filler mixing, mix in mixed cylinder, mix again after airslide disintegrating mill is pulverized, namely can be made into the wetting powder product of the present composition.
Composition comprises following constituent content when making water dispersible granules: multiple killing teichomycin 1 ~ 50%, thiocyclam 1 ~ 80%, dispersant 3 ~ 12%, wetting agent 1 ~ 8%, disintegrant 1 ~ 10%, binding agent 1 ~ 8%, filler surplus.
Active component multiple killing teichomycin, thiocyclam, dispersant, wetting agent, disintegrant, filler etc. are obtained together the particle diameter needed through air-flow crushing, then add other auxiliary agents such as binding agent, obtain granulation materials.Item is quantitatively sent in fluidized bed granulating dryer through granulating and after drying, obtaining the water dispersible granules product of the present composition.
Composition comprises following constituent content when making suspending agent: multiple killing teichomycin 0.1 ~ 30%, thiocyclam 0.1 ~ 50%, dispersant 2 ~ 10%, wetting agent 2 ~ 10%, defoamer 0.1 ~ 1%, binding agent 0.1 ~ 2%, antifreeze 0.1 ~ 8%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze in above-mentioned formulation material are mixed through high speed shear, add active component multiple killing teichomycin, thiocyclam, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μm, the suspending agent product of the obtained present composition.
Composition comprises following constituent content when making suspension emulsion: multiple killing teichomycin 0.1 ~ 30%, thiocyclam 0.1 ~ 50%, emulsifier 2 ~ 12%, and dispersant 2 ~ 10%, defoamer 0.1 ~ 2%, thickener 0.1 ~ 2%, antifreeze 0.1 ~ 8%, stabilizing agent 0.05 ~ 3%, water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in above-mentioned formulation material are mixed through high speed shear, add the former medicine of thiocyclam, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μm, obtained thiocyclam suspending agent, then by former for multiple killing teichomycin medicine, emulsifier and the direct emulsification of various auxiliary agent high speed agitators in suspending agent, the suspension emulsion product of the obtained present composition.
Composition comprises following constituent content when making aqueous emulsion: multiple killing teichomycin 0.1% ~ 30%, thiocyclam 0.1% ~ 50%, solvent 2% ~ 10%, emulsifier 2% ~ 12%, dispersant 2% ~ 10%, co-emulsifier 0.2% ~ 5%, antifreeze 0.1% ~ 8%, defoamer 0.1% ~ 2%, thickener 0.1% ~ 2%, deionized water adds to 100%.
By having former medicine, solvent, emulsifier, co-emulsifier to be added together in above-mentioned formula, make to be dissolved into homogeneous oil phase.Deionized water, dispersant, antifreeze, defoamer, thickener are mixed, becomes homogeneous aqueous phase, under high velocity agitation, aqueous phase is slowly instilled oil phase, make the finely disseminated aqueous emulsion product of the present composition.
Composition comprises following constituent content when making microemulsion: multiple killing teichomycin 0.1% ~ 30%, thiocyclam 0.1% ~ 50%, emulsifier 5% ~ 15%, solvent 2% ~ 10%, antifreeze 5% ~ 10%, stabilizing agent 0.5% ~ 3%, deionized water adds to 100%.
Above-mentioned formula Central Plains medicine, solvent, emulsifier are added in mother liquor modulation kettle, obtained homogeneous oil phase, deionized water, antifreeze etc. are mixed and injects product modulation kettle, through high-speed stirred, mix and make the transparent or semitransparent microemulsion product of the present composition.
The invention has the advantages that: (1) multiple killing teichomycin and thiocyclam composite after, there is notable synergistic and lasting effect; (2) expand insecticidal spectrum, have greater activity to beet armyworm, diamond-back moth, thrips, paddy stem borer, rice leaf roller, striped rice borer, paddy rice thrips, leafhopper, rice gall midge, plant hopper, black peach aphid, apple aphid, European red mite, pear leaf worm, citrus leaf-miner; (3) decrease the dosage of agricultural chemicals, reduce the residual quantity of agricultural chemicals on crop, alleviate environmental pollution; (4), insect good to person poultry safety, Environmental compatibility not easily develops immunity to drugs.
Embodiment
Below in conjunction with embodiment to further instruction of the present invention, the percentage in embodiment is all weight percentage, but the present invention is not limited thereto.
Application Example one
Example 1 30% multiple killing teichomycin thiocyclam wetting powder
Multiple killing teichomycin 5%, thiocyclam 25%, polycarboxylate 10%, neopelex 6%, diatomite to 100%, mixture carries out air-flow crushing, obtained 30% multiple killing teichomycin thiocyclam wetting powder.
Example 2 42% multiple killing teichomycin thiocyclam wetting powder
Multiple killing teichomycin 2%, thiocyclam 40%, aliphatic amine polyoxyethylene are phonetic 8%, Nekal BX 7%, attapulgite add to 100%, and mixture carries out air-flow crushing, obtained 42% multiple killing teichomycin thiocyclam wetting powder.
Example 3 81% multiple killing teichomycin thiocyclam wetting powder
Multiple killing teichomycin 1%, thiocyclam 80%, lignosulfonates 6%, soapberry powder 4%, diatomite to 100%, mixture carries out air-flow crushing, obtained 81% multiple killing teichomycin thiocyclam wetting powder.
Example 4 20% multiple killing teichomycin thiocyclam water dispersible granules
Multiple killing teichomycin 10%, thiocyclam 10%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, silkworm excrement 5%, sodium bicarbonate 3%, kaolin add to 100%, the obtained 20% multiple killing teichomycin thiocyclam water dispersible granules of mixing.
Example 5 55% multiple killing teichomycin thiocyclam water dispersible granules
Multiple killing teichomycin 5%, thiocyclam 50%, polycarboxylate 8%, spaonin powder 4%, aluminium chloride 2.5%, bentonite add to 100%, the obtained 55% multiple killing teichomycin thiocyclam water dispersible granules of mixing.
Example 6 80% multiple killing teichomycin thiocyclam water dispersible granules
Multiple killing teichomycin 5%, thiocyclam 75%, ester polyoxyethylene are phonetic 6%, lauryl sodium sulfate 4%, ammonium sulfate 2%, attapulgite add to 100%, the obtained 80% multiple killing teichomycin thiocyclam water dispersible granules of mixing.
Example 7 10% multiple killing teichomycin thiocyclam suspending agent
Multiple killing teichomycin 2%, thiocyclam 8%, naphthalene sulfonic acid-formaldehyde condensation product 8%, silicone compound 0.1%, methylcellulose 0.9%, propane diols 3%, deionized water add to 100%, the obtained 10% multiple killing teichomycin thiocyclam suspending agent of mixing.
Example 8 40% multiple killing teichomycin thiocyclam suspending agent
Multiple killing teichomycin 5%, thiocyclam 35%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 6%, silicone oil 0.3%, xanthans 0.7%, polyethylene glycol 2.8%, deionized water add to 100%, the obtained 40% multiple killing teichomycin thiocyclam suspending agent of mixing.
Example 9 50% multiple killing teichomycin thiocyclam suspending agent
Multiple killing teichomycin 5%, thiocyclam 45%, alkyl benzene sulfonate calcium salt 5%, silicone 0.2%, hydroxyethylcellulose 1%, ethylene glycol 2.5%, deionized water add to 100%, the obtained 50% multiple killing teichomycin thiocyclam suspending agent of mixing.
Example 10 11% multiple killing teichomycin thiocyclam suspension emulsion
Multiple killing teichomycin 10%, thiocyclam 1%, polyoxyethylene carboxylate 9%, wetting and penetrating agent F 2%, Magnesiumaluminumsilicate 1.1%, sorbitan monostearate 7%, glycerine 2.9%, C
8 ~ 10aliphatic alcohols 0.4%, water add to 100%, through mixing obtained 11% multiple killing teichomycin thiocyclam suspension emulsion.
Example 11 30.5% multiple killing teichomycin thiocyclam suspension emulsion
Multiple killing teichomycin 0.5%, thiocyclam 30%, lignosulfonates 8%, spaonin powder 3%, xanthans 0.7%, alkyl benzene calcium sulfonate 8%, diethylene glycol (DEG) 2%, silicone oil 0.2%, water add to 100%, through mixing obtained 30.5% multiple killing teichomycin thiocyclam suspension emulsion.
Example 12 40% multiple killing teichomycin thiocyclam suspension emulsion
Multiple killing teichomycin 3%, thiocyclam 37%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, tea are withered 4%, CMC 1%, fatty alcohol-polyoxyethylene ether 7%, propane diols 2.2%, silicone compound 0.3%, water add to 100%, through mixing obtained 40% multiple killing teichomycin thiocyclam suspension emulsion.
Example 13 12% multiple killing teichomycin thiocyclam aqueous emulsion
Multiple killing teichomycin 10%, thiocyclam 2%, N-pyrrolidones 6%, methyl alcohol 4%, benzene castor oil polyoxyethylene ether 5%, triethylene glycol 3%, silicone 0.2%, deionized water adds to 100%, the obtained 12% multiple killing teichomycin thiocyclam aqueous emulsion of mixing.
Example 14 25% multiple killing teichomycin thiocyclam aqueous emulsion
Multiple killing teichomycin 2%, thiocyclam 23%, DMF 5%, cyclohexanone 6%, phenyl phenol polyoxyethanyl ether phosphate 7%, ethylene glycol 2.5%, C
8 ~ 10aliphatic alcohols 0.5%, deionized water adds to 100%, through mixing obtained 25% multiple killing teichomycin thiocyclam aqueous emulsion.
Example 15 30% multiple killing teichomycin thiocyclam aqueous emulsion
Multiple killing teichomycin 3%, thiocyclam 27%, 3-methyl cyclohexanol ketenes 7%, vegetable oil 5%, benzyl dimethyl phenol polyoxyethyl ether 8%, propane diols 2.8%, silicone 0.3%, deionized water adds to 100%, through mixing obtained 30% multiple killing teichomycin thiocyclam aqueous emulsion.
Example 16 22% multiple killing teichomycin thiocyclam microemulsion
Multiple killing teichomycin 2%, thiocyclam 20%, NOP 8%, ethylene glycol monomethyl ether 3%, ethylene oxide-propylene oxide block copolymer 8%, triethylene glycol 2%, C
10 ~ 20saturated fat acids 0.2%, deionized water adds to 100%, the obtained 22% multiple killing teichomycin thiocyclam microemulsion of mixing.
Example 17 31% multiple killing teichomycin thiocyclam microemulsion
Multiple killing teichomycin 1%, thiocyclam 30%, toluene 6%, ethyl acetate 5%, sorbitan fatty acid ester APEO 8%, ethylene glycol 3%, silicone compound 0.1%, deionized water adds to 100%, through mixing obtained 31% multiple killing teichomycin thiocyclam microemulsion.
Example 18 50% multiple killing teichomycin thiocyclam microemulsion
Multiple killing teichomycin 4%, thiocyclam 46%, toluene 5%, acetone 6%, alkylphenol-formaldehyde resin polyoxyethyl ether 6%, glycerine 2.5%, silicone oil 0.4%, deionized water adds to 100%, the obtained 50% multiple killing teichomycin thiocyclam microemulsion of mixing.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
The embodiment of the present invention is the method adopting Toxicity Determination and field trial to combine.First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80≤CTC≤120 are summation action, CTC > 120 is synergistic effect, on this basis, then carry out field trial.
Test method: respectively the mother liquor of each for multiple killing teichomycin thiocyclam mixed agent is diluted to five series concentration during test, is placed in beaker respectively for subsequent use.Adopt the method connecing worm after first soaking leaf, take out after the blade of the same size not contacting any medicament is soaked 5s in the liquid configured, naturally dry, put into insect box, then connect for examination 3 instar larvae, raise under 25 DEG C of conditions, often process and repeat for 3 times, often repeating examination borer population used is 20, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50value.If contrast lethality is greater than 10%, be then considered as invalid test.Computing formula is as follows:
Insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value (x) to, draws virulence regression equation, and calculate the value of often kind of medicament thus with method of least squares.Co-toxicity coefficient CTC is calculated according to the abundant equation of Sun Yun.Computing formula following (take multiple killing teichomycin as standard agent, its toxicity index is 100):
TI × the P of theoretical toxicity index (the TTI)=multiple killing teichomycin of M
multiple killing teichomycintI × the P of+thiocyclam
thiocyclam
In formula: M is the mixture of different ratio
P
thiocyclamfor the ratio that thiocyclam is shared in the composition
P
multiple killing teichomycinfor the ratio that multiple killing teichomycin is shared in the composition
A is selected from multiple killing teichomycin;
B is selected from thiocyclam.
Application Example two:
For examination insect: wild cabbage diamond-back moth.
Test medicine provides by Shaanxi Meibang Pesticide Co., Ltd..
Experimental scheme: through effective lethal concentration scope of preliminary experiment determination multiple killing teichomycin, thiocyclam and the two different ratio mixture.
Toxicity test result one
Table 1 multiple killing teichomycin and thiocyclam different ratio are to the toxicity test of wild cabbage diamond-back moth
As shown in Table 1, multiple killing teichomycin and thiocyclam composite control wild cabbage diamond-back moth proportioning 50: 1 to 1: 80 time, co-toxicity coefficient is all greater than 120, illustrate that multiple killing teichomycin and thiocyclam mixture in 50: 1 to 1: 80 scopes all shows synergistic effect, especially when the proportioning of multiple killing teichomycin and thiocyclam is 1: 1 to 1: 20 time, synergistic effect is more obviously given prominence to, wherein when multiple killing teichomycin and thiocyclam weight ratio are 1: 10, co-toxicity coefficient is maximum, synergistic effect is the most obvious, inventor finds when the weight ratio of multiple killing teichomycin and thiocyclam is 50: 1 ~ 1: 80, to beet armyworm by test, thrips, paddy stem borer, rice leaf roller, striped rice borer, paddy rice thrips, leafhopper, rice gall midge, plant hopper, black peach aphid, apple aphid, European red mite, pear leaf worm, citrus leaf-miner also has good synergistic effect, and co-toxicity coefficient is all greater than 120, and when the weight ratio of multiple killing teichomycin and thiocyclam is 5: 1, 4: 1, 3: 1, 2: 1, 1: 1, 1: 2, 1: 3, 1: 4, 1: 5, 1: 6, 1: 7, 1: 8, 1: 9, 1: 10, 1: 11, 1: 12, 1: 13, 1: 14, 1: 15, 1: 16, 1: 17, 1: 18, 1: 19, 1: 20, 1: 21, 1: 22, 1: 23, 1: 24, 1: 25, 1: 26, 1: 27, 1: 28, 1: 29, when 1: 30, synergistic effect is more obvious.
Application Example three multiple killing teichomycin and thiocyclam and the composite control rice leaf roller test of pesticide effectiveness thereof
This experimental establishment is in Fengtai County, Huainan City of Anhui Province, and test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided, contrast medicament 25 grams per liter multiple killing teichomycin suspending agent (commercial), the solvable pulvis of 50% thiocyclam (autogamy).
Investigation rice leaf roller insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 1 day, 4 days, 7 days investigation insect pest indexes after dispenser also calculate preventive effect.Experimental result is as follows:
Table 2 multiple killing teichomycin, thiocyclam and the composite control rice leaf roller test of pesticide effectiveness thereof
As can be seen from Table 2, multiple killing teichomycin and thiocyclam composite after effectively can prevent and treat rice leaf roller, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects, when multiple killing teichomycin and thiocyclam composite after beet armyworm, diamond-back moth, thrips, paddy stem borer, striped rice borer, paddy rice thrips, leafhopper, rice gall midge, plant hopper, black peach aphid, apple aphid, European red mite, pear leaf worm, citrus leaf-miner control efficiency more than 95%, control efficiency is better than the preventive effect of single dose, has good synergistic effect.
Application Example four multiple killing teichomycin and thiocyclam and the composite water prevention chilo suppressalis test of pesticide effectiveness thereof
This experimental establishment is in Ankang City Ziyang County, Shaanxi Province, and test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided, contrast medicament 25 grams per liter multiple killing teichomycin suspending agent (commercial), the solvable pulvis of 50% thiocyclam (autogamy).
Investigation rice-stem borer insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 1 day, 4 days, 7 days investigation insect pest indexes after dispenser also calculate preventive effect.Experimental result is as follows:
Table 3 multiple killing teichomycin, thiocyclam and the composite water prevention chilo suppressalis test of pesticide effectiveness thereof
As can be seen from Table 3, multiple killing teichomycin and thiocyclam composite after can effective water prevention chilo suppressalis, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects, when multiple killing teichomycin and thiocyclam composite after beet armyworm, diamond-back moth, thrips, paddy stem borer, rice leaf roller, paddy rice thrips, leafhopper, rice gall midge, plant hopper, black peach aphid, apple aphid, European red mite, pear leaf worm, citrus leaf-miner control efficiency more than 95%, control efficiency is better than the preventive effect of single dose, has good synergistic effect.
Application Example five multiple killing teichomycin and thiocyclam and the composite control Chinese cabbage beet armyworm test of pesticide effectiveness thereof
This experimental establishment is in Weinan city Linwei district, Shaanxi Province, and test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided, contrast medicament 25 grams per liter multiple killing teichomycin suspending agent (commercial), the solvable pulvis of 50% thiocyclam (autogamy).
Investigation Chinese cabbage beet armyworm insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 1 day, 4 days, 7 days investigation insect pest indexes after dispenser also calculate preventive effect.Experimental result is as follows:
Table 4 multiple killing teichomycin, thiocyclam and the composite control Chinese cabbage beet armyworm test of pesticide effectiveness thereof
As can be seen from Table 4, multiple killing teichomycin and thiocyclam composite after can effectively prevent and treat Chinese cabbage beet armyworm, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects, when multiple killing teichomycin and thiocyclam composite after diamond-back moth, thrips, paddy stem borer, rice leaf roller, striped rice borer, paddy rice thrips, leafhopper, rice gall midge, plant hopper, black peach aphid, apple aphid, European red mite, pear leaf worm, citrus leaf-miner control efficiency more than 95%, control efficiency is better than the preventive effect of single dose, has good synergistic effect.
Application Example six multiple killing teichomycin and thiocyclam and the composite control Yellow Rice Borer test of pesticide effectiveness thereof
This experimental establishment is in Fengtai County, Huainan City of Anhui Province, and test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided, contrast medicament 25 grams per liter multiple killing teichomycin suspending agent (commercial), the solvable pulvis of 50% thiocyclam (autogamy).
Investigation Yellow Rice Borer insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 1 day, 4 days, 7 days investigation insect pest indexes after dispenser also calculate preventive effect.Experimental result is as follows:
Table 5 multiple killing teichomycin, thiocyclam and the composite control Yellow Rice Borer test of pesticide effectiveness thereof
As can be seen from Table 5, multiple killing teichomycin and thiocyclam composite after effectively can prevent and treat Yellow Rice Borer, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects, when multiple killing teichomycin and thiocyclam composite after rice indulge leaf snout moth's larva, beet armyworm, diamond-back moth, cotton bollworm, pink bollworm, cabbage caterpillar, tomato moth, Hellula undalis, colorado potato beetles, corn borer, black cutworm, rice-stem borer, prodenia litura, flea beetle, Americal rice leaf miner, lima bean pod borer, cucumber melon aphid, Bemisia tabaci, liriomyza bryoniae, thrips, aphid control efficiency more than 95%, control efficiency is better than the preventive effect of single dose, has good synergistic effect.
Application Example seven multiple killing teichomycin and thiocyclam and the composite control eggplant thrips test of pesticide effectiveness thereof
This experimental establishment is in Weinan City Pucheng County, Shaanxi Province, and test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided, contrast medicament 25 grams per liter multiple killing teichomycin suspending agent (commercial), the solvable pulvis of 50% thiocyclam (autogamy).
Investigation eggplant thrips insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 1 day, 4 days, 7 days investigation insect pest indexes after dispenser also calculate preventive effect.Experimental result is as follows:
Table 6 multiple killing teichomycin, thiocyclam and the composite control eggplant thrips test of pesticide effectiveness thereof
As can be seen from Table 6, multiple killing teichomycin and thiocyclam composite after can effectively prevent and treat eggplant thrips, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects, when multiple killing teichomycin and thiocyclam composite after beet armyworm, diamond-back moth, paddy stem borer, rice leaf roller, striped rice borer, paddy rice thrips, leafhopper, rice gall midge, plant hopper, black peach aphid, apple aphid, European red mite, pear leaf worm, citrus leaf-miner control efficiency more than 95%, control efficiency is better than the preventive effect of single dose, has good synergistic effect.
Application Example eight multiple killing teichomycin and thiocyclam and the composite control rice gall midge test of pesticide effectiveness thereof
This experimental establishment is in Gongan County, Jingzhou City of Hubei Province, and test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided, contrast medicament 25 grams per liter multiple killing teichomycin suspending agent (commercial), the solvable pulvis of 50% thiocyclam (autogamy).
Investigation rice gall midge insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 1 day, 4 days, 7 days investigation insect pest indexes after dispenser also calculate preventive effect.Experimental result is as follows:
Table 7 multiple killing teichomycin, thiocyclam and the composite control rice gall midge test of pesticide effectiveness thereof
As can be seen from Table 7, multiple killing teichomycin and thiocyclam composite after can preventing and killing rice gall insect, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects, when multiple killing teichomycin and thiocyclam composite after beet armyworm, diamond-back moth, thrips, paddy stem borer, rice leaf roller, striped rice borer, paddy rice thrips, leafhopper, plant hopper, black peach aphid, apple aphid, European red mite, pear leaf worm, citrus leaf-miner control efficiency more than 95%, control efficiency is better than the preventive effect of single dose, has good synergistic effect.
Claims (6)
1. contain a Pesticidal combination for multiple killing teichomycin and thiocyclam, comprise effective active component multiple killing teichomycin and thiocyclam, auxiliary agent, it is characterized in that: multiple killing teichomycin and thiocyclam weight ratio are 50:1 ~ 1:80.
2. Pesticidal combination according to claim 1, is characterized in that: the weight ratio of multiple killing teichomycin and thiocyclam is 30:1 ~ 1:60.
3. Pesticidal combination according to claim 2, is characterized in that: the weight ratio of multiple killing teichomycin and thiocyclam is 10:1 ~ 1:40.
4. Pesticidal combination according to claim 1, is characterized in that: composition makes wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
5. Pesticidal combination according to claim 1 is for preventing and treating the purposes of insect pest on Cereal, vegetables, fruit tree.
6. purposes according to claim 5, is characterized in that: described insect pest is beet armyworm, diamond-back moth, thrips, paddy stem borer, rice leaf roller, striped rice borer, paddy rice thrips, leafhopper, rice gall midge, plant hopper, black peach aphid, apple aphid, European red mite, pear leaf worm, citrus leaf-miner.
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| CN105685044B (en) * | 2016-02-27 | 2019-01-01 | 江苏天容集团股份有限公司 | Pesticidal combination containing ethyl pleocidin and thiocyclam |
| CN107821400A (en) * | 2017-11-15 | 2018-03-23 | 惠州市永耐宝新材料有限公司 | A kind of composition pesticide |
| CN113115780B (en) * | 2021-04-27 | 2022-06-07 | 中土化工（安徽）有限公司 | Insecticidal composition containing spinosad and thiocyclam |
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