CN106106444A - A kind of agricultural insecticidal microemulsion of anti-light solution and preparation method thereof - Google Patents
A kind of agricultural insecticidal microemulsion of anti-light solution and preparation method thereof Download PDFInfo
- Publication number
- CN106106444A CN106106444A CN201610630772.2A CN201610630772A CN106106444A CN 106106444 A CN106106444 A CN 106106444A CN 201610630772 A CN201610630772 A CN 201610630772A CN 106106444 A CN106106444 A CN 106106444A
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- CN
- China
- Prior art keywords
- light solution
- microemulsion
- agricultural insecticidal
- agent
- benzoate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to the agricultural insecticidal microemulsion of a kind of anti-light solution, including the component of following weight ratio: emamectin-benzoate 1% 20%, capillary 1% 20%, anti-light solution agent 0.1% 2%, solvent 5% 40%, emulsifying agent 3% 20%, water supplies 100%.The invention also discloses the agricultural insecticidal microemulsion preparation method of anti-light solution, the microemulsion of the present invention uses rational processing technique, and steady quality, good drug efficacy, the lasting period is long, shelf-stable.
Description
Technical field
The present invention relates to agricultural insecticidal microemulsion of a kind of anti-light solution and preparation method thereof, belong to agrochemical field.
Background technology
Emamectin-benzoate, is through a kind of Effective Anti being chemically modified to obtain with avilamycin for raw material
The insecticidal/acaricidal agent of raw element, has the advantages such as efficient, wide spectrum, lasting period length, and the mechanism of action is to hinder pest movements nerve information
Transmitting and make health paralysis death, model of action is based on stomach toxicity, to crop without interior absorption energy, but can penetrate into crop epidermis group
In knitting, there is the longer lasting period, a lot of insects are had the activity that other pesticide are incomparable, especially to Lepidoptera, dipteron
Mesh, thrips class ultra high efficiency.
Capillary is new pyrrole compounds, acts on the mitochondrion of insect bodies inner cell, by insect bodies
Mixed-functional oxidase works, and mainly suppresses the adenosine diphosphate (ADP) (ADP) conversion to adenosine triphosphate (ATP).And Adenosine triphosphate
Glycosides stored cells maintains energy necessary to its vital functions.This medical instrument has stomach toxicity and action of contace poison.Strong at blade face permeability, have
Certain systemic action, and have that insecticidal spectrum is wide, preventive effect is high, holding effect length, the feature of safety.Resistant insect can be controlled.
Emamectin-benzoate and capillary are all high-efficient broad-spectrum insecticides, and insecticidal mechanism is different,
No interactions resistance, the insect that the antagonism property of medicine is serious is effective equally, the emamectin-benzoate of the present invention and capillary
Compounding microemulsion uses rational processing technique just can obtain steady quality, good drug efficacy, and the lasting period is long, the methylamino of shelf-stable
The microemulsion product that abamectin benzoate is compounding with capillary.
Summary of the invention
It is an object of the invention to provide agricultural insecticidal microemulsion of a kind of anti-light solution and preparation method thereof.
Technical scheme: the agricultural insecticidal microemulsion of a kind of anti-light solution, including the component of following weight ratio: methylamino Avermectin
Element its benzoate 1%-20%, capillary 1%-20%, anti-light solution agent 0.1%-2%, solvent 5%-40%, emulsifying agent 3%-
20%, water supplies 100%.
Described anti-light solution agent is UV-327, one or more mixed in D-902, BHT, BHA, Weir 3000,318
Close.
Described solvent is Ketohexamethylene, methanol, ethanol, dissolved oil, mineral oil, turpentine-based vegetable oil, Oleum Terebinthinae, oleic acid first
The mixing of one or more in ester, sec-butyl acetate.
Described emulsifying agent is alkylphenol polyoxyethylene, styryl phenol polyethenoxy ether, alkaryl phenol polyethenoxy
Ether phosphate, castor oil polyoxyethylene ether, alkylbenzenesulfonate, disecoctylmaleate sodium sulfonate, polyol fatty acid
Ester and ethylene oxide adduct, Oleum Ricini, sorbitan fatty vinegar polyoxyethylene ether, sodium lauryl sulphate, chlorination
The mixing of one or more in potassium, sodium sulfate.
Described water is deionized water.
The preparation method of the agricultural insecticidal microemulsion of a kind of anti-light solution of the present invention: with solvent by Affirm (Merck Co.) benzene
After the former medicine of formates, the former medicine of capillary and anti-light solution agent are all dissolved, add certain proportion emulsifying agent mix homogeneously, add go from
Sub-water, after stirring, i.e. obtains the microemulsion of the present invention.
The rational processing technique of employing of the present invention obtains steady quality, good drug efficacy, and the lasting period is long, the methylamino of shelf-stable
The microemulsion product that abamectin benzoate is compounding with capillary.
The agricultural insecticidal microemulsion of a kind of anti-light solution of the present invention, compared with traditional microemulsion, adds environmentally friendly
Anti-light solution agent, use rational processing technique, steady quality, good drug efficacy, lasting period length, shelf-stable.
Detailed description of the invention
In order to be better understood from the essence of the present invention, the technology contents of the present invention is described with example below, but the present invention
Content be not limited thereto.
Embodiment one: 6% emamectin-benzoate chlorfenapyr microemulsion.
Precise 73% emamectin-benzoate 1.36g, 95% capillary former medicine 5.36g and D-902
0.1g, complete by 2g Ketohexamethylene, 5g methanol and 20g solvent naphtha stirring and dissolving, add styryl phenol polyethenoxy ether 10g and suitable
After butene dioic acid di-sec-octyl sodium sulfonate 3g stirs, add deionized water, i.e. obtain 6% Affirm (Merck Co.) benzoic acid
Salt chlorfenapyr microemulsion；After testing, emamectin-benzoate content 1%, capillary content 5%.
Embodiment two: 6.5% emamectin-benzoate chlorfenapyr microemulsion.
Precise 73% emamectin-benzoate 2.1g, 95% capillary former medicine 5.36g and D-902
0.1g, uses 2g Ketohexamethylene, 5g methanol and 17g solvent naphtha stirring and dissolving complete, adds styryl phenol polyethenoxy ether 10g and suitable
After butene dioic acid di-sec-octyl sodium sulfonate 4g stirs, add deionized water, i.e. obtain 6.5% Affirm (Merck Co.) benzene first
Hydrochlorate chlorfenapyr microemulsion；After testing, emamectin-benzoate content 1.5%, capillary content 5%.
Embodiment three: 11% emamectin-benzoate chlorfenapyr microemulsion.
Precise 73% emamectin-benzoate 1.36g, 95% capillary former medicine 10.53g and D-902
0.1g, complete by 2g Ketohexamethylene, 10g methanol and 30g solvent naphtha stirring and dissolving, add styryl phenol polyethenoxy ether 11g and
After disecoctylmaleate sodium sulfonate 9g stirs, add deionized water, i.e. obtain 11% Affirm (Merck Co.) benzene
Formates chlorfenapyr microemulsion；After testing, emamectin-benzoate content 1%, capillary content 10%.
Embodiment four: photodissociation testing experiment.
In order to more effectively understand the performance of the anti-light solution microemulsion of the present invention, 6% obtained by the embodiment of the present invention one
Emamectin-benzoate chlorfenapyr microemulsion is done photodissociation together with blank (i.e. without anti-light solution agent) and is tested:
MS-PRE multifunctional light chemical reaction assay device is carried out: using artificial light source xenon lamp, reaction temperature is 25 DEG C, by this
The 6% emamectin-benzoate chlorfenapyr microemulsion that the bright embodiment of the present invention one obtains is dilute together with blank
After releasing 10 times, putting in 10ml quartz glass photolytic cell, be respectively placed on illumination rotating disk, illuminance is 2370lux, and ultraviolet radiates
Illumination 13.5W CM2Regular water sampling in experiment, after 16 hours, the changes of contents of test emamectin-benzoate.
Keep photochemical reaction isolation other light sources in experimental period, reduce the impact on result of the test.
Test result such as table 1 below, as can be seen from the test results, the emamectin-benzoate worm of the present invention
The stability of demodicid mite nitrile microemulsion is more preferable.
Table 1, photodissociation result of the test
Claims (6)
1. the agricultural insecticidal microemulsion of an anti-light solution, it is characterised in that include the component of following weight ratio: methylamino Avermectin
Element its benzoate 1%-20%, capillary 1%-20%, anti-light solution agent 0.1%-2%, solvent 5%-40%, emulsifying agent 3%-
20%, water supplies 100%.
The agricultural insecticidal microemulsion of a kind of anti-light solution the most according to claim 1, it is characterised in that: described anti-light solution agent
For the mixing of one or more in UV-327, D-902, BHT, BHA, Weir 3000,318.
The agricultural insecticidal microemulsion of a kind of anti-light solution the most according to claim 1, it is characterised in that: described solvent is hexamethylene
One in ketone, methanol, ethanol, dissolved oil, mineral oil, turpentine-based vegetable oil, Oleum Terebinthinae, methyl oleate, sec-butyl acetate or
Several mixing.
The agricultural insecticidal microemulsion of a kind of anti-light solution the most according to claim 1, it is characterised in that: described emulsifying agent is
Alkylphenol polyoxyethylene, styryl phenol polyethenoxy ether, alkaryl phenol polyethenoxy ether phosphate, castor oil polyoxyethylene
Ether, alkylbenzenesulfonate, disecoctylmaleate sodium sulfonate, polyol fatty acid ester and ethylene oxide adduct thereof, castor
One or more in Oleum Sesami, sorbitan fatty vinegar polyoxyethylene ether, sodium lauryl sulphate, potassium chloride, sodium sulfate
Mixing.
The agricultural insecticidal microemulsion of a kind of anti-light solution the most according to claim 1, it is characterised in that: described water be from
Sub-water.
6. the preparation method of the agricultural insecticidal microemulsion of a kind of anti-light solution described in a claim 1, it is characterised in that: with molten
After Methylaminoemamectin benzoate, the former medicine of capillary and anti-light solution agent are all dissolved by agent, add certain proportion breast
Agent mix homogeneously, adds deionized water, after stirring, i.e. obtains the microemulsion of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610630772.2A CN106106444A (en) | 2016-08-03 | 2016-08-03 | A kind of agricultural insecticidal microemulsion of anti-light solution and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610630772.2A CN106106444A (en) | 2016-08-03 | 2016-08-03 | A kind of agricultural insecticidal microemulsion of anti-light solution and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106106444A true CN106106444A (en) | 2016-11-16 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610630772.2A Pending CN106106444A (en) | 2016-08-03 | 2016-08-03 | A kind of agricultural insecticidal microemulsion of anti-light solution and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106508926A (en) * | 2016-12-12 | 2017-03-22 | 山东润博生物科技有限公司 | Suspension concentrate of emamectin benzoate and chlorfenapyr, and preparation method and application thereof |
| CN109197882A (en) * | 2018-09-14 | 2019-01-15 | 河北威远生物化工有限公司 | A kind of emamectin benzoate B2a/B2b benzoate emulsion and preparation method thereof |
| CN110178850A (en) * | 2019-06-04 | 2019-08-30 | 广西汇丰生物科技有限公司 | One kind containing emamectin benzoate and capillary composition pesticide |
| CN110663687A (en) * | 2019-10-23 | 2020-01-10 | 河北天发生物科技有限公司 | Emulsifier and application of auxiliary agent containing emulsifier in pesticide preparation processing |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106508926A (en) * | 2016-12-12 | 2017-03-22 | 山东润博生物科技有限公司 | Suspension concentrate of emamectin benzoate and chlorfenapyr, and preparation method and application thereof |
| CN109197882A (en) * | 2018-09-14 | 2019-01-15 | 河北威远生物化工有限公司 | A kind of emamectin benzoate B2a/B2b benzoate emulsion and preparation method thereof |
| CN109197882B (en) * | 2018-09-14 | 2021-07-30 | 河北威远生物化工有限公司 | Emamectin benzoate emulsion B2a/B2B and preparation method thereof |
| CN110178850A (en) * | 2019-06-04 | 2019-08-30 | 广西汇丰生物科技有限公司 | One kind containing emamectin benzoate and capillary composition pesticide |
| CN110663687A (en) * | 2019-10-23 | 2020-01-10 | 河北天发生物科技有限公司 | Emulsifier and application of auxiliary agent containing emulsifier in pesticide preparation processing |
| CN110663687B (en) * | 2019-10-23 | 2021-06-29 | 河北天发生物科技有限公司 | Emulsifier and application of auxiliary agent containing emulsifier in pesticide preparation processing |
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Application publication date: 20161116 |