CN106035364A - Insecticide composition containing tefluthrin and cyromazine - Google Patents

Insecticide composition containing tefluthrin and cyromazine Download PDF

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Publication number
CN106035364A
CN106035364A CN201610569809.5A CN201610569809A CN106035364A CN 106035364 A CN106035364 A CN 106035364A CN 201610569809 A CN201610569809 A CN 201610569809A CN 106035364 A CN106035364 A CN 106035364A
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cyromazine
tefluthrin
pesticidal combination
weight
agent
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CN201610569809.5A
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CN106035364B (en
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吴泽伟
陈佛祥
王礼文
朱刚
张志伟
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Guangdong Zhongxun Agri Science Corp
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Guangdong Zhongxun Agri Science Corp
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses an insecticide composition containing tefluthrin and cyromazine. The insecticide composition comprises effective components tefluthrin and cyromazine, wherein the weight ratio of tefluthrin to cyromazine is (1:15)-(15:1); the total weight of tefluthrin and cyromazine accounts for 2-80% of the insecticide composition in percentage by weight. The insecticide composition containing tefluthrin and cyromazine can be prepared as a suspending agent, a micro-capsule suspending agent, emulsion in water, microemulsion, an ultra-low volume liquid, wettable powder, an aqueous dispersion granular agent and granules according to practical application demands, and can be applied to prevention and treatment on chive maggots in Chinese chive fields.

Description

A kind of containing Tefluthrin with the Pesticidal combination of cyromazine
Technical field
The present invention relates to a kind of containing Tefluthrin with the Pesticidal combination of cyromazine, be to be with Tefluthrin and cyromazine Effective ingredient, is applied to Chinese chive field preventing and treating fragrant-flowered garlic maggot.
Background technology
The resistance problem of agricultural disease pest and weed is a global problem, the weight that always agricultural science and technology worker pays close attention to Point problem；Along with agricultural disease pest and weed chemical prevention continuity, the increase of Pesticide use amount and non-science year in year out makes With pesticide, pest resistance is day by day serious, and the pest species producing resistance is on the increase；Meanwhile, the use pesticide of high intensity, cause Practice for Pesticide Residue in Agricultural Products exceeds standard, environmental pollution and peasant's drug cost increase etc., is unfavorable for agricultural sustainable development；Therefore, grind Study carefully exploitation efficiently, low toxicity, the pesticide of environmental protection agricultural sustainable development is had positive effect.
Tefluthrin (tefluthrin), chemical name: 2,3,5,6-tetra-fluoro-4-methyl-benzyls (Z)-(1RS, 3RS)-3- (2-chloro-2,3,3-trifluoro propyl)-2,2-dimethyl cyclopropane carboxylic acid's ester；Tefluthrin is pyrethroid insecticides, energy Preventing and treating coleoptera and the Lepidoptera perched in soil and some Diptera pest well.
Cyromazine (cyromazine), chemical name: N-cyclopropyl-1,3,5-triazines-2,4,6-triamines.Cyromazine is elder brother Worm growth regulator, has strong Uptake and translocation effect, can lure that Diptera larvae and pupa are morphologically distorted into, and adult eclosion is not Complete or suppressed.
The mixture of different pesticide species, is the common methods of preventing and treating agricultural disease pest and weed；Screened by formulation of pesticide, sieve Select rational formula, actual prevention effect can be effectively improved, reduce dosage, reduce cost, delay disease pest and weed Drug resistance Generation, be agricultural synthesis administer important means；The recipe determination of Tefluthrin and cyromazine has been carried out deeply by the present inventor Enter research, find that Tefluthrin and cyromazine carry out mixture and have obvious potentiation to make fragrant-flowered garlic maggot in certain mixed ratio scope With, after further study, complete the present invention.
The compositions application of Tefluthrin and cyromazine there is no report at present.
Summary of the invention
Present invention solves the technical problem that be to provide a kind of efficiently, low toxicity and the lasting period long, can effectively prevent and treat agricultural pests A kind of containing Tefluthrin with the compositions of cyromazine.
For solving the problems referred to above, the technical solution adopted in the present invention is: one is containing Tefluthrin and cyromazine combination The ratio of weight and number of thing, Tefluthrin and cyromazine is 1:15～15:1, and Tefluthrin and cyromazine weight summation are in pesticide group Percentage by weight in compound is 2～80%.
Described a kind of Pesticidal combination containing Tefluthrin and cyromazine can be according to well known to a person skilled in the art Method, is configured to suspending agent, micro-capsule suspension, aqueous emulsion, microemulsion, ultra low volume liquids, wettable powder, water-dispersible grain One in agent or granule, is applied to Chinese chive field preventing and treating fragrant-flowered garlic maggot.
Described a kind of Pesticidal combination containing Tefluthrin and cyromazine is possibly together with helping needed for preparation pesticidal preparations Agent, auxiliary agent is solvent, emulsifying agent, wetting agent, stabilizer, dispersant, thickening agent, pH adjusting agent, defoamer, antifreezing agent, filler The mixing of one or more in agent etc., is known substance, is various auxiliary agents conventional in pesticidal preparations, according to different situations Can be varied from, be not particularly limited.
Described a kind of containing Tefluthrin with the Pesticidal combination of cyromazine, it is applied to Chinese chive field preventing and treating fragrant-flowered garlic maggot.
It is a kind of containing Tefluthrin with the Pesticidal combination of cyromazine that the present invention provides, and generally uses at Folium Allii tuberosi trophophase Drench root or before Folium Allii tuberosi is transplanted, spread fertilizer over the fields the method use of granule, it is also possible to using other uses agriculturally applied as required Technology.
The one that the present invention provides contains Tefluthrin and cyromazine compositions has the advantages that:
1, the Pesticidal combination that the present invention provides, shows obvious potentiation, compositions in certain ratio range The prevention effect of fragrant-flowered garlic maggot is significantly improved than single dose, reduces the using dosage of pesticide, decrease times for spraying, reduce Drug cost, decreases the pesticide adverse effect to ecological environment.
2, the Pesticidal combination that the present invention provides, two kinds of active ingredient mechanism of action are not quite identical, can overcome long-term Single use easily produces the shortcoming of resistance, extends the service life of medicament, and the comprehensive control to pest resistance has important meaning Justice.
3, the Pesticidal combination that the present invention provides, drug effect plays rapidly, and the lasting period is long, and use cost is low, easy to use, saves Shi Shengli, its popularization and application have huge economic benefit and social benefit.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage more short and sweet, present invention specific examples below Illustrate, but the present invention is only limitted to absolutely not these embodiments.The following stated is only the preferable embodiment of the present invention, is used only for The present invention is described, it is impossible to be interpreted as limiting the scope of the present invention.It should be pointed out that, it is all in the spirit and principles in the present invention Within any amendment, equivalent and the improvement etc. made, should be included within the scope of the present invention.Therefore, this The protection domain of bright patent should be as the criterion with claims.
Content described in embodiment is all weight percentage.
Example of formulations case: the preparation method of present composition pesticidal preparations
Pesticidal combination described in embodiment 1 is suspending agent, and each component percentages is respectively as follows:
Concrete operation step is: first mixed by other auxiliary agent, and in cutter, shear-mixed is uniform, is subsequently adding seven fluorine chrysanthemums Ester and cyromazine, grind 2～3h in ball crusher, make a diameter all at below 5mm, can be prepared by 32% Tefluthrin fly eradication Amine aqueous suspension formulations.
Pesticidal combination described in embodiment 2 is aqueous emulsion, and each component percentages is respectively as follows:
Concrete operation step is: first Tefluthrin and cyromazine, trimethylbenzene, Sorbitan fatty acid ester are blended in one Rise, dissolve and become uniform oil phase.Again part water and other auxiliary agents are mixed, dissolve and become uniform aqueous phase.Then While high-speed stirred, oil phase is added aqueous phase in a kettle., slowly adds water to reach phase inversion point, carry out high speed shear afterwards, And add remaining water, shear about 30min, can be prepared by 22% Tefluthrin cyromazine aqueous emulsion preparation.
Pesticidal combination described in embodiment 3 is microemulsion, and each component percentages is respectively as follows:
Concrete operation step is: first Tefluthrin and cyromazine fatty acid methyl ester is completely dissolved, then adds it Its auxiliary agent, mix homogeneously, it is eventually adding water, after being sufficiently stirred for, can be prepared by 18% Tefluthrin cyromazine microemulsion formulation.
Pesticidal combination described in embodiment 4 is wettable powder, and each component percentages is respectively as follows:
Concrete operation step is: be sufficiently stirred for, Tefluthrin and cyromazine, other auxiliary agent through air-flow powder in stirred tank Mix homogeneously after the pulverizing of broken machine, can be prepared by 40% Tefluthrin cyromazine wettable powder formulation.
Pesticidal combination described in embodiment 5 is water dispersible granules, and each component percentages is respectively as follows:
Concrete operation step is: will have Tefluthrin and cyromazine, other auxiliary agent mix homogeneously, and use ultra micro comminution by gas stream Machine is pulverized, and adds in fluidized-bed granulation dryer and carry out pelletize, be dried, after screening, can be prepared by 60% 7 fluorine chrysanthemum after mediating Ester cyromazine water-dispersible grain agent formulation.
Pesticidal combination described in embodiment 6 is micro-capsule suspension, and each component percentages is respectively as follows:
Concrete operation step is: by Tefluthrin and cyromazine, macromolecule cyst material, solvent mixing, make to be dissolved into all Even oil phase, in a shear condition, oil phase is joined containing emulsifying agent, dispersant aqueous phase solution in, add mannitol adjust Joint pH value is to 6.5, and surplus deionized water is supplied, and bi-material reacts at oil-water interfaces, forms macromolecule cyst wall, Prepare 20% Tefluthrin cyromazine micro-capsule suspension.
Pesticidal combination described in embodiment 7 is ultra low volume liquids, and each component percentages is respectively as follows:
Concrete operation step is: after Tefluthrin and cyromazine stirring solvent being dissolved, add other auxiliary agent, fully It is uniformly mixed, can be prepared by 12% Tefluthrin cyromazine ultra low volume liquids.
Pesticidal combination described in embodiment 8 is water dispersible granules, and each component percentages is respectively as follows:
Concrete operation step is: will have Tefluthrin and cyromazine, other auxiliary agent mix homogeneously, and use micro jet Pulverize, add in fluidized-bed granulation dryer after mediating and carry out pelletize, be dried, after screening, can be prepared by 55% 7 fluorine chrysanthemum Ester cyromazine water-dispersible grain agent formulation.
Pesticidal combination described in embodiment 9 is granule, and each component percentages is respectively as follows:
Concrete operation step is: by Tefluthrin, cyromazine and above-mentioned auxiliary agent mix homogeneously in airtight compounding kettle, bag Embrane method pelletize, is dried to granule water content less than 3%, screening, particle size range 2000-4000 μm, warp under the conditions of 110-120 DEG C The most i.e. obtain 1.6% Tefluthrin cyromazine granule.
In above dosage form, auxiliary agent is selected from the following stated:
Solvent can be solvent naphtha S-200, trimethylbenzene, durene, methyl naphthalene, methyl oleate, fatty acid methyl ester, Song Ji One or more in oil, soybean oil, biodiesel, sec-Butyl Acetate, dimethyl carbonate, diesel oil, white oil, machine oil etc..
Emulsifying agent can be calcium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether, triphenoethyl benzene phenol polyoxypropylene gather Oxygen ethylene block polymer, dibenzyl xenyl polyoxyethylene ether, phenethyl phenol polyethenoxy ether, castor oil polyoxyethylene ether, Phenethyl fluosite polyoxyethylene ether, phenethyl phenol polyoxyethylene polyoxypropylene ether, alkylaryl polyoxypropylene polyoxy Vinyl Ether, phenethyl phenol formaldehyde resin polyoxyethylene ether, Sorbitan fatty acid ester, sorbitan fatty acid ester polyoxy Vinyl Ether, natural fatty alcohol and ethylene oxide adduct, fatty acid with in ethylene oxide condensate, polyoxyethylene fatty acid ester etc. One or more.
Wetting agent can be sodium butylnaphthalenesulfonate, sodium lauryl sulphate, aliphatic alcohol polyethenoxy (6-7) ether, sulfonation amber One or more in amber dioctyl phthalate sodium salt, Morwet EFW, alkylnaphthalene sulfonate etc..
Disintegrating agent can be compound sodium nitrophenolate, sodium bicarbonate, magnesium chloride, aluminum chloride, sodium chloride, carbamide, ammonium sulfate, bentonite One or more in Deng.
Dispersant can be polycarboxylate, the formaldehyde condensation products of methyl naphthalene sulfonic acid sodium, sodium lignin sulfonate, lignin sulfonic acid Calcium, to methoxyl group fatty acyl anilinesulfonic acid, desaccharide the sodium lignin sulfonate of classification, naphthalene sulfonic acid condensate sodium salt, alkylnaphthalene One or more in sulfonic acid condensation polymer sodium salt, alkylphenol polyoxyethylene formaldehyde condensation products sulphuric acid etc..
Thickening agent can be one or more in xanthan gum, aluminium-magnesium silicate, bentonite, white carbon etc..
PH adjusting agent can be in ammonium hydroxide, potassium hydroxide, sodium hydroxide, hydrochloric acid, acetic acid, citric acid, phosphoric acid etc. One or more.
Stabilizer can be dibutyl phthalate, hexamethylene diisocyanate, epoxy soybean oil, epoxy chloropropionate One or more in alkane, Butylated hydroxyanisole, dibenzylatiooluene, propylgallate, tert-butylhydroquinone etc..
Defoamer can be one or more in silicone compound, methanol, silicone oil, azone etc..
Antifreezing agent can be one or more in glycerol, ethylene glycol, propylene glycol, sorbitol, Polyethylene Glycol etc..
Carrier can be Kaolin, kieselguhr, bentonite, white carbon, precipitated calcium carbonate, attapulgite, clay, Talcum One or more in powder, quartz sand, starch, APG, carbamide, potassium chloride, ammonium chloride etc..
Slow releasing agent can be one or both in polyvinyl alcohol, arabic gum.
Binding agent can be one or both in Polyethylene Glycol, industrial gelatine.
Assays Example case
Nebulization with reference to raw mark quasi-NY/T 1154.9-2008；First with ether by the examination worm anesthesia of fragrant-flowered garlic maggot larva, then use Brush pen is chosen the consistent examination worm of growth conditions 30 and is put in culture dish, then culture dish is placed in potter spray tower tower tray carries out Metered dose, spouting liquid is 1mL, and medicinal liquid takes out examination worm after settling 1 minute, put into fresh foodstuff and raise, and every concentration processes 4 Secondary repetition, if the solution without medicament is as blank.Checking examination worm death condition after 72h, and carry out record, examination worm is dead Worm is reactionless is calculated as death in order to contact examination gently with brush pen for criterion.
Statistical analysis is carried out, by calculating the LC of each medicament with DPS statistical analysis software50The parasite killing evaluating each medicament is lived Property, and the co-toxicity coefficient (CTC value) of mixture is calculated according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100
Percentage composition+B medicament the toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed The percentage composition of B in agent
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theory toxicity index (TTI)] × 100
According to the NY/T11547.7-2006 insecticide combination effect criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as Potentiation；Co-toxicity coefficient (CTC)≤80 shows as antagonism；80 ＜ co-toxicity coefficient (CTC) ＜ 120 show as being added and make With.
The synergy of fragrant-flowered garlic maggot larva is measured by table 1 Tefluthrin with cyromazine
As can be seen from Table 1, Tefluthrin and cyromazine are compounding, to Folium Allii tuberosi fragrant-flowered garlic maggot larva in the range of 1:15～15:1 Show as potentiation.
Leading case is implemented in field: the present composition is for preventing and treating the field test of Folium Allii tuberosi fragrant-flowered garlic maggot larva
Test site is positioned at Yang Lin Village, Songming County, Kunming, Yunnan Province Folium Allii tuberosi ground, with 30% Tefluthrin WP, 60% Cyromazine WDG compares medicine, and example of formulations 1-8 and comparison medicament use in Folium Allii tuberosi trophophase and drench root method, example of formulations 9 in Folium Allii tuberosi uses soil treatment before transplanting.Test sets 11 chemicals treatment altogether, and each process repeats for 4 times, after dispenser 5 days, 30 days Respectively investigating and record insect population radix, calculate preventive effect, result of the test is as shown in table 2.
Table 2 Tefluthrin and cyromazine combination preventing and treating Folium Allii tuberosi fragrant-flowered garlic maggot field test results
As can be seen from Table 2, example of formulations 1-9, the effect of preventing and treating is better than each comparison single dose and processes, Tefluthrin is described Compounding with cyromazine and can effectively control Folium Allii tuberosi fragrant-flowered garlic maggot, quick-acting and lasting period are superior to compare medicine.

Claims (8)

1. one kind contains Tefluthrin and the Pesticidal combination of cyromazine, it is characterised in that: containing effective ingredient Tefluthrin and The ratio of weight and number of cyromazine, Tefluthrin and cyromazine is 1:15～15:1.
Pesticidal combination the most according to claim 1, it is characterised in that: the ratio of weight and number of Tefluthrin and cyromazine is 1:10～10:1.
Pesticidal combination the most according to claim 1, it is characterised in that: the ratio of weight and number of Tefluthrin and cyromazine is 1:5～5:1.
Pesticidal combination the most according to claim 1, it is characterised in that: the ratio of weight and number of Tefluthrin and cyromazine is 1:15～1:10.
Pesticidal combination the most according to claim 1, it is characterised in that: the ratio of weight and number of Tefluthrin and cyromazine is 1: 1。
The most according to claim 1 containing Tefluthrin with the Pesticidal combination of cyromazine, Tefluthrin and cyromazine weight Summation percentage by weight in the composition is 2～80%.
The most according to claim 1 containing Tefluthrin with the Pesticidal combination of cyromazine, can be prepared as suspending agent, micro-glue The one of capsule suspending agent, aqueous emulsion, microemulsion, ultra low volume liquids, wettable powder, water dispersible granules or granule.
8. according to a kind of described in claim 1 containing Tefluthrin with the Pesticidal combination of cyromazine, at preventing and treating Chinese chive field Application on fragrant-flowered garlic maggot.
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CN108338171A (en) * 2017-07-26 2018-07-31 江苏辉丰农化股份有限公司 Composition pesticide with synergistic effect

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CN108338171A (en) * 2017-07-26 2018-07-31 江苏辉丰农化股份有限公司 Composition pesticide with synergistic effect

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