CN106083439A - A kind of Semen Ziziphi Spinosae selenium-rich grape special medicated fertilizer - Google Patents
A kind of Semen Ziziphi Spinosae selenium-rich grape special medicated fertilizer Download PDFInfo
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- CN106083439A CN106083439A CN201610455353.XA CN201610455353A CN106083439A CN 106083439 A CN106083439 A CN 106083439A CN 201610455353 A CN201610455353 A CN 201610455353A CN 106083439 A CN106083439 A CN 106083439A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
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Abstract
The invention discloses a kind of Semen Ziziphi Spinosae selenium-rich grape special medicated fertilizer, be made up of following material: carbamide, Diammonium phosphate (DAP), potassium dihydrogen phosphate, potassium sulfate, zinc sulfate, amino-acid chelate, Semen Ziziphi Spinosae, apple leaf, Carambola leaves, Pericarpium Vitis viniferae, Pericarpium Granati, watermelon vine, Fructus Chaenomelis skin, Pericarpium Citri Reticulatae, the Rhizoma Atractylodis Macrocephalae, Radix Scutellariae, Radix Glycyrrhizae, Fructus Toosendan, Herba Sophorae alopecuroidis, modified zeolite.Fertilizer nutrient of the present invention equalizes, there is again the effect of pest-resistant sterilization, meet the growth rhythm of Fructus Vitis viniferae, the per mu yield of final Fructus Vitis viniferae improves 23 ~ 28%, pol improves 3 ~ 4 degree, and every hectogram Se content improves more than 15 times, and every hectogram Vitamin C content improves 1 ~ 2 times, and thin of Pericarpium Vitis viniferae is big, mellow and full full, has the extremely strong market competitiveness.
Description
Technical field
The present invention relates to a kind of fertilizer, be specifically related to a kind of Semen Ziziphi Spinosae selenium-rich grape special medicated fertilizer.
Background technology
Fructus Vitis viniferae is called: Jambul, grass Herba Tubocapsici Anomali, mountain calabash, Li Tao etc..Belong to the fruit of vitaceae Fructus Vitis viniferae.For fallen leaves liana
Plant, is one of the most ancient plant in the world.Fructus Vitis viniferae originates in Europe, West Asia and north African one band.According to archaeological materials, cultivate the earliest
The area of Fructus Vitis viniferae is between the Caspian Sea, Asia Minor and Black Sea and bank area, south.About before 7000, south Caucasus, in
The area such as Asia, Syria, Iraq has also begun to the cultivation of Fructus Vitis viniferae.Most historians think Persian (i.e. today Iran)
It it is the country made grape wine the earliest.Europe early start plantation Fructus Vitis viniferae the country carrying out wine production are Greece.At me
To the north of the state Yangtze river basin, all there is product various places.Stem is climing is up to 10 ~ 20 meters.Dan Ye, alternate.Spend little, yellow green, composition circular cone flower
Sequence.Berry is circular or oval, because kind is different, has the different fruit colors such as white, blue or green, red, brown, purple, black.8 ~ October of fructescence, in
Existing more than the 2000 year history of state's cultivating grape, passes on from one to another and introduces for Han dynasty people Zhang Qian.
Agricultural production needs soil to provide nutrient substance and the living environment of plant growth.For many years, the executing of chemical fertilizer
Pivotal role is served with to getting agricultural profit.But, due to chronic administration chemical fertilizer, fertilizer is under-supply, all kinds of nutrients
Out of proportion, causing farmland ecological environment, soil physical and chemical property and soil is the destruction that biota receives in various degree,
Have impact on the quality of agricultural product to a certain extent.Therefore, chemical fertilizer pollution has become the big public hazards in the world today one, and China is current
Soil resource present situation is in the urgent need to supplementing the soil organism by artificial measure, it is ensured that agricultural planting level and crop products product
Matter.Ten big countermeasures of China's ecological environmental protection are clearly advocated and to promote " ecological agriculture ", preserve the ecological environment and farmland
Soil, promotes the production of pollution-free healthy food, it is ensured that have sufficient amount organic matter to return soil, raw to promote in ecosystem
Thing circulates, and reaches to keep and strengthen soil fertility and biological activity purpose.
The quality of the growth of the plants such as Fructus Vitis viniferae is relevant with many factors, such as the acid-base value of soil, water content, a great number of elements
Content, content of beary metal, content of microorganisms etc., and mutually restrict between various factors, influence each other, the finally work to Fructus Vitis viniferae
Being ever-changing by effect, this is also the difficult institute that soil property or fertilizer character are optimized by those skilled in the art
?.
People's plantation now there is also the problem that cannot effectively utilize plant additament, after wine-growing maturation,
For plantation grape leaf, edible after Pericarpium Vitis viniferae etc. deal with improperly, although part is used as feed adding component, fertilizer adds
Composition, Chinese medicine ingredients etc., but most utilization rate is the highest or not utilized, not only causes the wasting of resources, is unfavorable for again protecting
Retaining ring border.
Summary of the invention
In order to solve the problems referred to above, the invention provides a kind of Semen Ziziphi Spinosae selenium-rich grape special medicated fertilizer.
The present invention is achieved through the following technical solutions:
A kind of Semen Ziziphi Spinosae selenium-rich grape special medicated fertilizer, is made up of the material of following weight portion:
100 parts of carbamide, 32 parts of Diammonium phosphate (DAP), 11 parts of potassium dihydrogen phosphates, 18 parts of potassium sulfate, 3 parts of zinc sulfate, 2 parts of chelating amino acids
Thing, 6 parts of Semen Ziziphi Spinosaes, 4 parts of apple leafs, 3 parts of Carambola leaves, 3 parts of Pericarpium Vitis viniferaes, 2 parts of Pericarpium Granatis, 1 part of watermelon vine, 2 parts of Fructus Chaenomelis skins, 1 part
Pericarpium Citri Reticulatae, 2 parts of Rhizoma Atractylodis Macrocephalaes, 3 parts of Radix Scutellariaes, 2 parts of Radix Glycyrrhizaes, 2 parts of Fructus Toosendans, 2 parts of Herba Sophorae alopecuroidiss, 3 parts of modified zeolites, described modified zeolite is by such as
The material of lower weight portion is made: 100 parts of zeolites, 2 parts of polyoxyethylene aliphatic alcohol ethers, 1.5 parts of sodium carboxymethyl cellulose, 1.5 parts of seas
Algin, 2 parts of polyacrylic acid potassiums, 1 part of sodium polyacrylate, 1 part of ammonium citrate, described amino-acid chelate by iron-amino acid chelate,
Chelating amino acids manganese, chelating amino acids molybdenum form by weight 3:2:1.
Further, the preparation method of described special medicated fertilizer comprises the steps:
(1), after Pericarpium Citri Reticulatae, the Rhizoma Atractylodis Macrocephalae, Radix Scutellariae, Radix Glycyrrhizae, Fructus Toosendan and Herba Sophorae alopecuroidis being mixed jointly, first put into water in boiling water and scald 4 ~ 6min,
After taking-up, the clear water with its gross mass 3 times mixes jointly, then boiling water decocts 25 ~ 30min, and the A and filtering residue a that filters to get filtrate is standby；
(2) Pericarpium Vitis viniferae, Pericarpium Granati and Fructus Chaenomelis skin are mixed jointly, and the clear water adding its gross mass 0.8 times is pulled an oar jointly, heating
Keeping slurry temperature is 40 ~ 42 DEG C, and the B and filtering residue b that filters to get filtrate after 15 ~ 20min is standby；
(3) put into Semen Ziziphi Spinosae to fill in the marmite of Semen setariae and carry out parch, when Semen Ziziphi Spinosae produces dense delicate fragrance, stop parch, take out
Pulverize 120 mesh, obtain meter Semen Ziziphi Spinosae (parched) powder standby；
(4) after apple leaf, Carambola leaves and watermelon vine combination drying being dehydrated, then pulverizing 80 mesh, to obtain mixed powder standby；
(5) filtering residue a, filtering residue b and mixed powder are mixed jointly, after adding the clear water of its gross mass 2 times, add clear water quality
The composite bacteria agent capable of 2%, obtains fermentation material standby after fermenting 5 ~ 8 days, it is 43 ~ 45 DEG C that period controls fermentation temperature, in described composite bacteria agent capable
Containing yeast, lactic acid bacteria, photosynthetic bacteria and bacillus subtilis；
(6) after filtrate A and liquor B being mixed jointly, then by carbamide, Diammonium phosphate (DAP), potassium dihydrogen phosphate, potassium sulfate, zinc sulfate and
Amino-acid chelate is added thereto, and heating keeps solution temperature to be 45 ~ 47 DEG C, is stirred continuously after uniformly, then by rice Semen Ziziphi Spinosae (parched) powder,
Modified zeolite and fermentation material add, and are again stirring for uniformly, obtaining mixed serum standby；
(7) mixed serum carrying out conventional pelletize, the final grain diameter prepared is not more than 4mm, and moisture is not more than 10% i.e.
Can.
Further, the preparation method of described modified zeolite comprises the steps:
(1) zeolite being put into immersion treatment 3h in the hydrochloric acid solution that mass fraction is 10%, placing into mass fraction after taking-up is
Immersion treatment 2h in the sodium hydroxide solution of 11%, rinses well standby with clear water after taking-up；
(2) zeolite after cleaning puts into calcining 2h in the environment of temperature is 820 DEG C, then is warming up to 960 DEG C of calcining 1.5h, finally
It is warming up to 1170 DEG C of calcining 1h, is cooled to room temperature after taking-up standby；
(3) zeolite after cooling is mixed jointly with the clear water of its quality 1 times, and add polyoxyethylene aliphatic alcohol ether, carboxymethyl
Sodium cellulosate, alginate jelly, polyacrylic acid potassium, sodium polyacrylate and ammonium citrate, be heated to 47 DEG C and with 2100 ~ 2200rpm's
It is standby that rotating speed obtains zeolite mixture after stirring；
(4) after zeolite mixture is dried being 8 ~ 10% to water content, then it is milled to after granular size is 1200 ~ 1400 mesh
Obtain modified zeolite.Zeolite is modified, is conducive to strengthening its adsorptivity, stability, water-retaining property etc., after pulverizing be beneficial to its
The uniformity of distribution in soil, improves the harmful substances such as its Adsorption of Heavy Metals, and the ability of slow control nutritional labeling.
There is advantages that the present invention is by plant additament such as Fructus Vitis viniferae and the leaf of the crop same period, rattan, skins
Carry out extracting, the mode such as fermentation makes green organic manure, not only solves plantation family and processes difficult problem, the most scientific general
It returns Tian Zuofei, improves the utilization rate of material, and the growth for Fructus Vitis viniferae provides the nutrient substance enriched together with inorganic fertilizer；Add
The medicinal herb components added can play the effect that sterilization is pest-resistant, can be again that Fructus Vitis viniferae provides unique nutrient substance；The modification added
Zeolite serve in fertilizer homogenize, adsorb, the effect such as slow release, change the overall permanence of fertilizer, itself has again necessarily
Water conservation, antibacterial and anti-oxidation effect, the growth promoter of Fructus Vitis viniferae rhizome can be promoted.Under the common effect of above-mentioned each composition,
The per mu yield of Fructus Vitis viniferae improves 23 ~ 28%, and pol improves 3 ~ 4 degree, and every hectogram Se content improves more than 15 times, and every hectogram is tieed up
Raw element C content improves 1 ~ 2 times, and thin of Pericarpium Vitis viniferae is big, mellow and full full, has the extremely strong market competitiveness.
Detailed description of the invention
Embodiment 1
A kind of Semen Ziziphi Spinosae selenium-rich grape special medicated fertilizer, is made up of the material of following weight portion:
100 parts of carbamide, 32 parts of Diammonium phosphate (DAP), 11 parts of potassium dihydrogen phosphates, 18 parts of potassium sulfate, 3 parts of zinc sulfate, 2 parts of chelating amino acids
Thing, 6 parts of Semen Ziziphi Spinosaes, 4 parts of apple leafs, 3 parts of Carambola leaves, 3 parts of Pericarpium Vitis viniferaes, 2 parts of Pericarpium Granatis, 1 part of watermelon vine, 2 parts of Fructus Chaenomelis skins, 1 part
Pericarpium Citri Reticulatae, 2 parts of Rhizoma Atractylodis Macrocephalaes, 3 parts of Radix Scutellariaes, 2 parts of Radix Glycyrrhizaes, 2 parts of Fructus Toosendans, 2 parts of Herba Sophorae alopecuroidiss, 3 parts of modified zeolites, described modified zeolite is by such as
The material of lower weight portion is made: 100 parts of zeolites, 2 parts of polyoxyethylene aliphatic alcohol ethers, 1.5 parts of sodium carboxymethyl cellulose, 1.5 parts of seas
Algin, 2 parts of polyacrylic acid potassiums, 1 part of sodium polyacrylate, 1 part of ammonium citrate, described amino-acid chelate by iron-amino acid chelate,
Chelating amino acids manganese, chelating amino acids molybdenum form by weight 3:2:1.
Further, the preparation method of described special medicated fertilizer comprises the steps:
(1), after Pericarpium Citri Reticulatae, the Rhizoma Atractylodis Macrocephalae, Radix Scutellariae, Radix Glycyrrhizae, Fructus Toosendan and Herba Sophorae alopecuroidis being mixed jointly, first put into water in boiling water and scald 4 ~ 6min,
After taking-up, the clear water with its gross mass 3 times mixes jointly, then boiling water decocts 25 ~ 30min, and the A and filtering residue a that filters to get filtrate is standby；
(2) Pericarpium Vitis viniferae, Pericarpium Granati and Fructus Chaenomelis skin are mixed jointly, and the clear water adding its gross mass 0.8 times is pulled an oar jointly, heating
Keeping slurry temperature is 40 ~ 42 DEG C, and the B and filtering residue b that filters to get filtrate after 15 ~ 20min is standby；
(3) put into Semen Ziziphi Spinosae to fill in the marmite of Semen setariae and carry out parch, when Semen Ziziphi Spinosae produces dense delicate fragrance, stop parch, take out
Pulverize 120 mesh, obtain meter Semen Ziziphi Spinosae (parched) powder standby；
(4) after apple leaf, Carambola leaves and watermelon vine combination drying being dehydrated, then pulverizing 80 mesh, to obtain mixed powder standby；
(5) filtering residue a, filtering residue b and mixed powder are mixed jointly, after adding the clear water of its gross mass 2 times, add clear water quality
The composite bacteria agent capable of 2%, obtains fermentation material standby after fermenting 5 ~ 8 days, it is 43 ~ 45 DEG C that period controls fermentation temperature, in described composite bacteria agent capable
Containing yeast, lactic acid bacteria, photosynthetic bacteria and bacillus subtilis；
(6) after filtrate A and liquor B being mixed jointly, then by carbamide, Diammonium phosphate (DAP), potassium dihydrogen phosphate, potassium sulfate, zinc sulfate and
Amino-acid chelate is added thereto, and heating keeps solution temperature to be 45 ~ 47 DEG C, is stirred continuously after uniformly, then by rice Semen Ziziphi Spinosae (parched) powder,
Modified zeolite and fermentation material add, and are again stirring for uniformly, obtaining mixed serum standby；
(7) mixed serum carrying out conventional pelletize, the final grain diameter prepared is not more than 4mm, and moisture is not more than 10% i.e.
Can.
Further, the preparation method of described modified zeolite comprises the steps:
(1) zeolite being put into immersion treatment 3h in the hydrochloric acid solution that mass fraction is 10%, placing into mass fraction after taking-up is
Immersion treatment 2h in the sodium hydroxide solution of 11%, rinses well standby with clear water after taking-up；
(2) zeolite after cleaning puts into calcining 2h in the environment of temperature is 820 DEG C, then is warming up to 960 DEG C of calcining 1.5h, finally
It is warming up to 1170 DEG C of calcining 1h, is cooled to room temperature after taking-up standby；
(3) zeolite after cooling is mixed jointly with the clear water of its quality 1 times, and add polyoxyethylene aliphatic alcohol ether, carboxymethyl
Sodium cellulosate, alginate jelly, polyacrylic acid potassium, sodium polyacrylate and ammonium citrate, be heated to 47 DEG C and with 2100 ~ 2200rpm's
It is standby that rotating speed obtains zeolite mixture after stirring；
(4) after zeolite mixture is dried being 8 ~ 10% to water content, then it is milled to after granular size is 1200 ~ 1400 mesh
Obtain modified zeolite.
Comparative example 1
Compared with Example 1, the common zeolite of the quality such as use replaces modified zeolite to this comparative example 1, does not enters zeolite
Row modification, method step in addition is the most identical.
Comparative example 2
This comparative example 2 compared with Example 1, does not contains modified zeolite composition, and method step in addition is the most identical.
Matched group
Commercially available compound fertilizer.
Above-mentioned four kinds of fertilizer are carried out native fish experiment, and following table is correction data:
| Embodiment 1 | Comparative example 1 | Comparative example 2 | Matched group | |
| 24h nutrient release rate (%) | 8.37 | 12.24 | 31.79 | 42.28 |
Respectively Fructus Vitis viniferae being carried out fertilizing and planting experiment with above-mentioned four kinds of fertilizer, following table is correction data:
| Embodiment 1 | Comparative example 1 | Comparative example 2 | Matched group | |
| Per mu yield (kg) | 3740 | 3620 | 3410 | 3000 |
| Every hectogram Vitamin C content (mg) | 52.8 | 42.7 | 36.5 | 24.3 |
| Every hectogram Se content (μ g) | 9.4 | 6.7 | 2.3 | 0.6 |
Claims (3)
1. a Semen Ziziphi Spinosae selenium-rich grape special medicated fertilizer, it is characterised in that be made up of the material of following weight portion:
100 parts of carbamide, 32 parts of Diammonium phosphate (DAP), 11 parts of potassium dihydrogen phosphates, 18 parts of potassium sulfate, 3 parts of zinc sulfate, 2 parts of chelating amino acids
Thing, 6 parts of Semen Ziziphi Spinosaes, 4 parts of apple leafs, 3 parts of Carambola leaves, 3 parts of Pericarpium Vitis viniferaes, 2 parts of Pericarpium Granatis, 1 part of watermelon vine, 2 parts of Fructus Chaenomelis skins, 1 part
Pericarpium Citri Reticulatae, 2 parts of Rhizoma Atractylodis Macrocephalaes, 3 parts of Radix Scutellariaes, 2 parts of Radix Glycyrrhizaes, 2 parts of Fructus Toosendans, 2 parts of Herba Sophorae alopecuroidiss, 3 parts of modified zeolites, described modified zeolite is by such as
The material of lower weight portion is made: 100 parts of zeolites, 2 parts of polyoxyethylene aliphatic alcohol ethers, 1.5 parts of sodium carboxymethyl cellulose, 1.5 parts of seas
Algin, 2 parts of polyacrylic acid potassiums, 1 part of sodium polyacrylate, 1 part of ammonium citrate, described amino-acid chelate by iron-amino acid chelate,
Chelating amino acids manganese, chelating amino acids molybdenum form by weight 3:2:1.
A kind of Semen Ziziphi Spinosae selenium-rich grape special medicated fertilizer the most according to claim 1, it is characterised in that the system of described special medicated fertilizer
Preparation Method comprises the steps:
(1), after Pericarpium Citri Reticulatae, the Rhizoma Atractylodis Macrocephalae, Radix Scutellariae, Radix Glycyrrhizae, Fructus Toosendan and Herba Sophorae alopecuroidis being mixed jointly, first put into water in boiling water and scald 4 ~ 6min,
After taking-up, the clear water with its gross mass 3 times mixes jointly, then boiling water decocts 25 ~ 30min, and the A and filtering residue a that filters to get filtrate is standby；
(2) Pericarpium Vitis viniferae, Pericarpium Granati and Fructus Chaenomelis skin are mixed jointly, and the clear water adding its gross mass 0.8 times is pulled an oar jointly, heating
Keeping slurry temperature is 40 ~ 42 DEG C, and the B and filtering residue b that filters to get filtrate after 15 ~ 20min is standby；
(3) put into Semen Ziziphi Spinosae to fill in the marmite of Semen setariae and carry out parch, when Semen Ziziphi Spinosae produces dense delicate fragrance, stop parch, take out
Pulverize 120 mesh, obtain meter Semen Ziziphi Spinosae (parched) powder standby；
(4) after apple leaf, Carambola leaves and watermelon vine combination drying being dehydrated, then pulverizing 80 mesh, to obtain mixed powder standby；
(5) filtering residue a, filtering residue b and mixed powder are mixed jointly, after adding the clear water of its gross mass 2 times, add clear water quality
The composite bacteria agent capable of 2%, obtains fermentation material standby after fermenting 5 ~ 8 days, it is 43 ~ 45 DEG C that period controls fermentation temperature, in described composite bacteria agent capable
Containing yeast, lactic acid bacteria, photosynthetic bacteria and bacillus subtilis；
(6) after filtrate A and liquor B being mixed jointly, then by carbamide, Diammonium phosphate (DAP), potassium dihydrogen phosphate, potassium sulfate, zinc sulfate and
Amino-acid chelate is added thereto, and heating keeps solution temperature to be 45 ~ 47 DEG C, is stirred continuously after uniformly, then by rice Semen Ziziphi Spinosae (parched) powder,
Modified zeolite and fermentation material add, and are again stirring for uniformly, obtaining mixed serum standby；
(7) mixed serum carrying out conventional pelletize, the final grain diameter prepared is not more than 4mm, and moisture is not more than 10% i.e.
Can.
A kind of Semen Ziziphi Spinosae selenium-rich grape special medicated fertilizer the most according to claim 1 and 2, it is characterised in that described modified zeolite
Preparation method comprise the steps:
(1) zeolite being put into immersion treatment 3h in the hydrochloric acid solution that mass fraction is 10%, placing into mass fraction after taking-up is
Immersion treatment 2h in the sodium hydroxide solution of 11%, rinses well standby with clear water after taking-up；
(2) zeolite after cleaning puts into calcining 2h in the environment of temperature is 820 DEG C, then is warming up to 960 DEG C of calcining 1.5h, finally
It is warming up to 1170 DEG C of calcining 1h, is cooled to room temperature after taking-up standby；
(3) zeolite after cooling is mixed jointly with the clear water of its quality 1 times, and add polyoxyethylene aliphatic alcohol ether, carboxymethyl
Sodium cellulosate, alginate jelly, polyacrylic acid potassium, sodium polyacrylate and ammonium citrate, be heated to 47 DEG C and with 2100 ~ 2200rpm's
It is standby that rotating speed obtains zeolite mixture after stirring；
(4) after zeolite mixture is dried being 8 ~ 10% to water content, then it is milled to after granular size is 1200 ~ 1400 mesh
Obtain modified zeolite.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106588376A (en) * | 2016-12-22 | 2017-04-26 | 安徽康坶国际化肥股份有限公司 | Fertilizer with balanced nutrients and high absorption rate |
| CN107253878A (en) * | 2017-06-30 | 2017-10-17 | 来安县世外桃园生态农业专业合作社 | A kind of peach organic slow-release fertilizer and preparation method thereof |
| CN108401806A (en) * | 2018-04-26 | 2018-08-17 | 贵州九鼎生物科技有限公司 | The implantation methods of gynostemma pentaphylla |
| CN114988952A (en) * | 2022-07-08 | 2022-09-02 | 云南勐牛生物技术有限公司 | Nano silicon liquid fertilizer and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106588376A (en) * | 2016-12-22 | 2017-04-26 | 安徽康坶国际化肥股份有限公司 | Fertilizer with balanced nutrients and high absorption rate |
| CN107253878A (en) * | 2017-06-30 | 2017-10-17 | 来安县世外桃园生态农业专业合作社 | A kind of peach organic slow-release fertilizer and preparation method thereof |
| CN108401806A (en) * | 2018-04-26 | 2018-08-17 | 贵州九鼎生物科技有限公司 | The implantation methods of gynostemma pentaphylla |
| CN114988952A (en) * | 2022-07-08 | 2022-09-02 | 云南勐牛生物技术有限公司 | Nano silicon liquid fertilizer and preparation method thereof |
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Application publication date: 20161109 |