CN106009954A - Electric iron high-stability paint and preparation method thereof - Google Patents
Electric iron high-stability paint and preparation method thereof Download PDFInfo
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- CN106009954A CN106009954A CN201610663200.4A CN201610663200A CN106009954A CN 106009954 A CN106009954 A CN 106009954A CN 201610663200 A CN201610663200 A CN 201610663200A CN 106009954 A CN106009954 A CN 106009954A
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- parts
- electric iron
- iron high
- synergist
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/10—Homopolymers or copolymers of propene
- C09D123/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses electric iron high-stability paint. The electric iron high-stability paint comprises the following raw materials: polypropylene resin, an elastic emulsion, fluorocarbon resin, polycaprolactone, terephthalic acid, montmorillonite powder, n-butyl alcohol, glycol ether, a proper amount of water, a catalyst, a synergist, nano titanium dioxide, urethane acrylate, and rosin-modified resin. A preparation method comprises the following steps: 1) preparing a preliminary mixing solution; 2) preparing an intermediate solution; 3) preparing a mixing solution; and 4) putting the mixing solution obtained in the step 3) in a bowl mill for grinding treatment, and sieving the material to obtain the finished product. The preparation method has the advantages of scientific and reasonable performance, by employing the organic polymer materials with good comprehensive properties and performing optimization and combination, stabilization performance of the composition is increased, cost is low, production period is short, and the high-stability paint is adapted to industrial batch production.
Description
Technical field
The invention belongs to coating industry technical field, particularly relate to a kind of electric iron high stability coating and preparation method thereof.
Background technology
Coating, at the entitled paint of Chinese tradition, refer to coat body surface can form thin film under certain conditions and rise protection,
One class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because of coating in early days
Mostly with vegetable oil as primary raw material, therefore also referred to as paint.Now synthetic resin instead of vegetable oil, therefore referred to as coating.It is coated with
Material belongs to organic chemical industry's macromolecular material, and the film formed belongs to macromolecular compound type.The chemical industry current according to the modern times produces
The classification of product, coating belongs to fine chemical product.Modern coating the most progressively becomes a polyfunctional engineering material of class, is
An important industry in chemical industry.At present, the coating industry of China is the most ripe, and market is close to saturated, in addition in green
Under the overall situation of economic globalization, people become more concerned with economy the most flourishing after, environment is by great destruction.Along with new " ring
Guarantor's method " to promulgate, the environmental protection such as country's " environmental protection, beautiful China " advocates the most no longer to stay on slogan, but implements
Perform, implement to promote energetically the development of green science and technology industry.
At present, the covering with paint of household electrical appliance has had bigger change, and traditional thermohardening lacquer is by the water paint of environmental protection
Deng substituting, but different electrical equipment has different requirements due to the difference of the aspects such as function to coating, and more environmentally friendly, more individual character is
Become the pursuit direction of household electrical appliances coating.The market demand huge in the face of household electrical appliances coating and ever-increasing application prospect, strengthen
R&D intensity, updates and improving product performance, accelerates product quality upgrading, develop technically, on cost, performance
On more show the household electrical appliances coating of powerful competitive advantage there is the meaning of reality and the wide market space.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of electric iron high stability coating and system thereof
Preparation Method, this coating products excellent performance, there are good stability, and energy-conserving and environment-protective, possess preferable economic benefit and
Social benefit.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of electric iron high stability coating, is prepared by the raw materials in: acrylic resin 35~45 parts, elastic emulsion
10~15 parts, fluorocarbon resin 2~5 parts, polycaprolactone 5~12 parts, p-phthalic acid 8~15 parts, montmorillonite powder 2~6 parts,
N-butyl alcohol 1~3 parts, glycol ether 6~12 parts, water are appropriate, catalyst 1.5~3 parts, synergist 1.5~2.5 parts, nanometer
Titanium dioxide 1~5 parts, urethane acrylate 5~10 parts, modified rosin resin 5~12 parts;
Its preparation method in turn includes the following steps:
(1) p-phthalic acid, montmorillonite powder, n-butyl alcohol, glycol ether, nano titanium oxide and suitable quantity of water are joined reaction
In container, it is heated to 50~65 DEG C, stirs 20~30 minutes under 900~1200 revs/min, after mix homogeneously, obtain the most mixed liquid;
(2) acrylic resin, elastic emulsion, fluorocarbon resin, polycaprolactone and urethane acrylate are mixed to join step
(1) in the first mixed liquid obtained, it is heated to 65~80 DEG C, continues stirring 30~40 minutes, obtain intermediate liquid;
(3) intermediate liquid that step (2) obtains is cooled to 40~50 DEG C, adds catalyst, synergist and Abietyl modified tree
Fat, mix and blend 50~80 minutes, obtain mixed liquor;
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
Preferably, described catalyst is sodium sulfonate.
Preferably, described synergist is diethylin sulfur trifluoride.
The beneficial effects of the present invention is:
Preparation method of the present invention is scientific and reasonable, by using combination property preferably high-molecular organic material and carrying out optimum organization,
Improve the stability of compositions, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, stretching
The indexs such as intensity are superior to common coating, and can meet coated-body the most comprehensively uses requirement;Cost of the present invention is relatively low, it is achieved
Making full use of of resource and the energy, production process is environment friendly and pollution-free, with short production cycle, is suitable to industrialized mass production, possess
Preferably economic benefit and social benefit.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of electric iron high stability coating, is prepared by the raw materials in: acrylic resin 35 parts, elastic emulsion 10
Part, fluorocarbon resin 2 parts, polycaprolactone 5 parts, p-phthalic acid 8 parts, montmorillonite powder 2 parts, n-butyl alcohol 1 part, dihydroxylic alcohols
6 parts of ether, water are appropriate, catalyst 1.5 parts, synergist 1.5 parts, nano titanium oxide 1 part, urethane acrylate 5 parts,
Modified rosin resin 5 parts;
Its preparation method in turn includes the following steps:
(1) p-phthalic acid, montmorillonite powder, n-butyl alcohol, glycol ether, nano titanium oxide and suitable quantity of water are joined reaction
In container, it is heated to 50~65 DEG C, stirs 20 minutes under 900~1200 revs/min, after mix homogeneously, obtain the most mixed liquid;
(2) acrylic resin, elastic emulsion, fluorocarbon resin, polycaprolactone and urethane acrylate are mixed to join step
(1) in the first mixed liquid obtained, it is heated to 65~80 DEG C, continues stirring 30 minutes, obtain intermediate liquid;
(3) intermediate liquid that step (2) obtains is cooled to 40~50 DEG C, adds catalyst, synergist and Abietyl modified tree
Fat, mix and blend 50 minutes, obtain mixed liquor;
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
Embodiment 2:
A kind of electric iron high stability coating, is prepared by the raw materials in: acrylic resin 45 parts, elastic emulsion 15
Part, fluorocarbon resin 5 parts, polycaprolactone 12 parts, p-phthalic acid 15 parts, montmorillonite powder 6 parts, n-butyl alcohol 3 parts, binary
Alcohol ether 12 parts, water are appropriate, catalyst 3 parts, synergist 2.5 parts, nano titanium oxide 5 parts, urethane acrylate 10
Part, modified rosin resin 12 parts;
Its preparation method in turn includes the following steps:
(1) p-phthalic acid, montmorillonite powder, n-butyl alcohol, glycol ether, nano titanium oxide and suitable quantity of water are joined reaction
In container, it is heated to 50~65 DEG C, stirs 30 minutes under 900~1200 revs/min, after mix homogeneously, obtain the most mixed liquid;
(2) acrylic resin, elastic emulsion, fluorocarbon resin, polycaprolactone and urethane acrylate are mixed to join step
(1) in the first mixed liquid obtained, it is heated to 65~80 DEG C, continues stirring 40 minutes, obtain intermediate liquid;
(3) intermediate liquid that step (2) obtains is cooled to 40~50 DEG C, adds catalyst, synergist and Abietyl modified tree
Fat, mix and blend 80 minutes, obtain mixed liquor;
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
In the above embodiment of the present invention:
Described catalyst is sodium sulfonate;
Described synergist is diethylin sulfur trifluoride.
During the present invention implements, by using combination property preferably high-molecular organic material and carrying out optimum organization, improve combination
The stability of thing, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, the indexs such as gloss retention is good, hot strength
Being superior to common coating, can meet coated-body the most comprehensively uses requirement;Cost of the present invention is relatively low, it is achieved that resource and energy
Making full use of of source, production process is environment friendly and pollution-free, with short production cycle, is suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although with reference to above-mentioned reality
Execute example the present invention has been described in detail, it will be appreciated by those skilled in the art that still the present invention can be modified or
Equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should contain the power in the present invention
In profit claimed range.
Claims (3)
1. an electric iron high stability coating, it is characterised in that be prepared by the raw materials in: acrylic resin 35~
45 parts, elastic emulsion 10~15 parts, fluorocarbon resin 2~5 parts, polycaprolactone 5~12 parts, p-phthalic acid 8~15 parts,
Montmorillonite powder 2~6 parts, n-butyl alcohol 1~3 parts, glycol ether 6~12 parts, water are appropriate, catalyst 1.5~3 parts, synergist
1.5~2.5 parts, nano titanium oxide 1~5 parts, urethane acrylate 5~10 parts, modified rosin resin 5~12 parts;
Its preparation method in turn includes the following steps:
(1) p-phthalic acid, montmorillonite powder, n-butyl alcohol, glycol ether, nano titanium oxide and suitable quantity of water are joined reaction
In container, it is heated to 50~65 DEG C, stirs 20~30 minutes under 900~1200 revs/min, after mix homogeneously, obtain the most mixed liquid;
(2) acrylic resin, elastic emulsion, fluorocarbon resin, polycaprolactone and urethane acrylate are mixed to join step
(1) in the first mixed liquid obtained, it is heated to 65~80 DEG C, continues stirring 30~40 minutes, obtain intermediate liquid;
(3) intermediate liquid that step (2) obtains is cooled to 40~50 DEG C, adds catalyst, synergist and Abietyl modified tree
Fat, mix and blend 50~80 minutes, obtain mixed liquor;
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
A kind of electric iron high stability coating the most according to claim 1, it is characterised in that described catalyst is sodium sulfonate.
A kind of electric iron high stability coating the most according to claim 1, it is characterised in that described synergist is diethylamine
Base sulfur trifluoride.
Priority Applications (1)
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CN201610663200.4A CN106009954A (en) | 2016-08-12 | 2016-08-12 | Electric iron high-stability paint and preparation method thereof |
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CN201610663200.4A CN106009954A (en) | 2016-08-12 | 2016-08-12 | Electric iron high-stability paint and preparation method thereof |
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CN201610663200.4A Pending CN106009954A (en) | 2016-08-12 | 2016-08-12 | Electric iron high-stability paint and preparation method thereof |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101412889A (en) * | 2008-11-26 | 2009-04-22 | 湖南平桂制塑科技实业有限公司 | Acrylic ester modified high-weatherability paint and preparation thereof |
CN102993836A (en) * | 2012-11-23 | 2013-03-27 | 高凡 | Preparation method of novel aqueous acrylic acid modified high chlorinated polyethylene anticorrosive coating |
CN102993837A (en) * | 2012-11-23 | 2013-03-27 | 高凡 | Novel aqueous acrylic acid modified high chlorinated polyethylene anticorrosive coating |
CN103540196A (en) * | 2013-09-29 | 2014-01-29 | 青岛博玉特橡塑制品有限公司 | Anticorrosive paint composition |
CN103992699A (en) * | 2014-05-19 | 2014-08-20 | 安徽嘉木橡塑工业有限公司 | White fluorocarbon coating |
-
2016
- 2016-08-12 CN CN201610663200.4A patent/CN106009954A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101412889A (en) * | 2008-11-26 | 2009-04-22 | 湖南平桂制塑科技实业有限公司 | Acrylic ester modified high-weatherability paint and preparation thereof |
CN102993836A (en) * | 2012-11-23 | 2013-03-27 | 高凡 | Preparation method of novel aqueous acrylic acid modified high chlorinated polyethylene anticorrosive coating |
CN102993837A (en) * | 2012-11-23 | 2013-03-27 | 高凡 | Novel aqueous acrylic acid modified high chlorinated polyethylene anticorrosive coating |
CN103540196A (en) * | 2013-09-29 | 2014-01-29 | 青岛博玉特橡塑制品有限公司 | Anticorrosive paint composition |
CN103992699A (en) * | 2014-05-19 | 2014-08-20 | 安徽嘉木橡塑工业有限公司 | White fluorocarbon coating |
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Application publication date: 20161012 |