CN105961386A - Glutaraldehyde foam disinfectant and preparation method thereof - Google Patents
Glutaraldehyde foam disinfectant and preparation method thereof Download PDFInfo
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- CN105961386A CN105961386A CN201610295689.4A CN201610295689A CN105961386A CN 105961386 A CN105961386 A CN 105961386A CN 201610295689 A CN201610295689 A CN 201610295689A CN 105961386 A CN105961386 A CN 105961386A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
- C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
- C11D3/202—Monohydric alcohols branched fatty or with at least 8 carbon atoms in the alkyl chain
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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Abstract
The invention discloses a glutaraldehyde foam disinfectant and a preparation method thereof. The glutaraldehyde foam disinfectant comprises glutaraldehyde and a foaming agent. Through various foaming agents and auxiliary agents nonreactive with glutaraldehyde, the glutaraldehyde foam disinfectant has a glutaraldehyde content reduction rate less than or equal to 1% in one year, can be stably preserved, effectively improves a foaming agent cleaning capability and has very excellent practicality.
Description
Technical field
The present invention relates to chemical technology field, particularly relate to a kind of glutaraldehyde foamaseptic and preparation method thereof.
Background technology
In agricultural breeding bio-safety field, environmental health is mainly reflected in cleaning and sterilization the two important step.Clearly
Clean, refer to harmful microorganism present in environment and house refuse are cleared up;Sterilization, refers to life micro-to the cause of disease in environment
Thing is killed as far as possible.In animal living enviroment, the existence of appropriate microorganism is the most necessary, and it is exempted from for keeping animal
The alertness of epidemic disease system is highly beneficial.But, excessive sterilization certainly will bring a large amount of chemical drugs to enter environment, in environment
Microorganism drastically reduces, and makes the immunologic function of animal body gradually degenerate, while causing even more serious environmental pollution, right
Animal living enviroment also results in destruction greatly.
At present, the cleaning mode that plant of China uses is mainly High-Pressure Water and rinses, and the disinfection way of employing is mainly
Pressure atomization is sprayed, but this traditional cleaning and disinfection way are all difficult to get a desired effect.For overcome tradition cleaning and
The shortcomings and deficiencies of disinfection way, domestic market is being gradually introducing foamed cleaning disinfection technology, and Related product constantly comes out.Bubble
The cleaning and sterilizing agent of liquid is converted into gas phase form of foam by relevant foam device by foam cleaning-sterilizing technology, and foam solution passes through
Moistening, emulsifying, permeate, disperse and the model of action such as solubilising, effectively remove the oils and fats of disinfecting surface to be cleaned, protein, dirt,
Biomembranes etc., to reach the purpose of simultaneously cleaning and sterilization.But presently commercially available foam all can not be together with disinfectant
Stably deposit, even can reduce the Disinfection Effect of disinfectant.
Therefore, prior art has yet to be improved and developed.
Summary of the invention
In view of above-mentioned the deficiencies in the prior art, it is an object of the invention to provide a kind of glutaraldehyde foamaseptic and system thereof
Preparation Method, it is intended to solve current foam and all stably can not deposit together with disinfectant, even can reduce disinfectant sterilization effect
The problem of fruit.
Technical scheme is as follows:
A kind of glutaraldehyde foamaseptic, wherein, described glutaraldehyde foamaseptic is made up of glutaraldehyde and foam;Press
Mass percent, includes:
Glutaraldehyde 0.1%-15%;
Foam 85%-99.9%.
Described glutaraldehyde foamaseptic, wherein, in described foam, by mass percentage, includes:
Main foaming agent 20%-30%;
Auxiliary blowing agent 5%-20;
Foam stabilizer 0.5%-5%;
Suds booster 1%-10%;
Antifreeze 0.1%-5%;
PH value regulator 0.05-5%;
Deionized water: 30-75%;
The percentage ratio sum of above-mentioned each component is 100%.
Described glutaraldehyde foamaseptic, wherein, described main foaming agent is nonionic surfactant, including polyalcohols
One or more in surfactant or polyethenoxy ether class surfactant.
Described glutaraldehyde foamaseptic, wherein, described auxiliary blowing agent is anionic surfactant, including 12
One or more in sodium alkyl benzene sulfonate, dodecyl sodium sulfate, lauryl sulphate acid acid sodium or AES.
Described glutaraldehyde foamaseptic, wherein, described foam stabilizer is the fatty alcohol of C8-C22, including capryl alcohol, isooctanol
Or one or more in lauryl alcohol.
Described glutaraldehyde foamaseptic, wherein, described suds booster is nonionic polymer surfactant, including such as the Chinese
Rubber or, one or more in Radix Acaciae senegalis, carboxymethyl cellulose, hydroxypropyl cellulose or etherification starch.
Described glutaraldehyde foamaseptic, wherein, described antifreeze is the lower alcohol of C2-C5, including ethanol, isopropanol,
One or more in ethylene glycol or glycerol.
Described glutaraldehyde foamaseptic, wherein, described pH adjusting agent is mineral acid or organic acid, including hydrochloric acid, sulphuric acid
Or one or more in acetic acid.
Described glutaraldehyde foamaseptic, wherein, described glutaraldehyde foamaseptic in use, by following percent mass
Ratio mixes with water:
Glutaraldehyde foamaseptic: 0.5-3%;
Water: 97%-99.5%.
The preparation method of a kind of glutaraldehyde foamaseptic described above, wherein, comprises the following steps:
First deionized water is heated to 40-60C °, be then sequentially added into main foaming agent, auxiliary blowing agent,
Foam stabilizer, suds booster and antifreeze, after stirring and dissolving, add pH value regulator, after pH value regulation to 2-4, cold
But to room temperature, it is subsequently adding glutaraldehyde, prepares described glutaraldehyde foamaseptic.
Beneficial effect: a kind of glutaraldehyde foamaseptic of the present invention and preparation method thereof, it is by using not with penta
Various foaming agent and the auxiliary agent of dialdehyde generation chemical reaction are prepared from, glutaraldehyde in prepared glutaraldehyde foamaseptic
Reduction rate is less than 1% in 1 year for content, and it can stably preserve, and is effectively increased the cleaning capacity of foam, has pole
Good practicality.
Detailed description of the invention
The present invention provides a kind of glutaraldehyde foamaseptic and preparation method thereof, for making the purpose of the present invention, technical scheme
And effect is clearer, clear and definite, the present invention is described in more detail below.Should be appreciated that described herein being embodied as
Example only in order to explain the present invention, is not intended to limit the present invention.
The present invention provides a kind of glutaraldehyde foamaseptic being made up of glutaraldehyde and foam, overcomes current city
The foam sold stably can not be deposited together with disinfectant, even can reduce the deficiency of disinfectant Disinfection Effect.In the present invention
In, by mass percentage, include: glutaraldehyde 0.1%-15%;
And foam 85%-99.9%.Specifically, described glutaraldehyde can be the thing of the different purity such as analytical pure or chemical pure
Matter, it plays disinfective action in described glutaraldehyde foamaseptic.It addition, described foam specifically refer to will not be with described penta 2
The material of aldehyde generation chemical reaction, it is after mixing with glutaraldehyde, still can stably preserve.
In the prior art, foam and disinfectant typically cannot mix stable preservation, occur the most on the market
The foamaseptic containing glutaraldehyde, such as the glutaraldehyde disinfectant in Patent No. 201110201916.X, all be use
Glutaraldehyde and foam separate packaging, mix during use again.And heretofore described glutaraldehyde foamaseptic will be without will
Component independent packaging, it is mixed and chemical reaction will not occur, and can at room temperature stablize preservation, only need in proportion during use
Mix with water and can use, easy to operate, and store method is easy.
In preferred embodiment, in described foam, by mass percentage, include: main foaming agent 20%-30%;Auxiliary
Blowing promotor 5%-20;Foam stabilizer 0.5%-5%;Suds booster 1%-10%;Antifreeze 0.1%-5%;PH value regulator 0.05-5%;Go
Ionized water 30-75%;The percentage ratio sum of above-mentioned each component is 100%.
Specifically, described main foaming agent is nonionic surfactant, including polyol surfactant or polyoxy second
One or more in alkene ether surfactant, such as sucrose fatty acid ester, NPE or octyl phenol polyoxy
Vinyl Ether.Described main foaming agent is as producing the main matter of foam, and it has and does not react with glutaraldehyde, stable in properties etc.
Feature.In the present invention, described main foaming agent uses nonionic surfactant, and it does not exists with ionic condition,
So stability is high, it is susceptible to the impact that strong electrolyte exists, is not easy to be affected, with other types surface activity by acid, alkali
Agent can be used in mixed way, and the compatibility is good.
In embodiments of the present invention, described auxiliary blowing agent is anionic surfactant, including detergent alkylate sulphur
One or more in acid sodium, dodecyl sodium sulfate, lauryl sulphate acid acid sodium or AES.The work of described auxiliary blowing agent
With being to strengthen the foaming effect of main foaming agent.Wherein, described dodecylbenzene sodium sulfonate is particularly easy to produce with other materials
Synergism (can produce than the most respective more preferable using effect of performance synergism after the mixing of two kinds of materials), therefore it
Often use compounding with nonionic surfactant and inorganic builders, to improve clean effect.Described dodecyl sodium sulfate is again
Claiming or sodium lauryl sulfate, it has infiltration, washing, moistening, decontamination and the emulsification of excellence.The acid of described lauryl sulphate acid
Sodium is soluble in water, good with anion, the multiple compatibility of nonionic, have good emulsifying, foam, permeate, decontamination and dispersive property.
Described AES is also known as polyoxyethylenated alcohol sodium sulfate, and it has excellent decontamination, emulsifying, moistening, solubilising and foam performance,
Dissolubility is good, and thickening effect is good, and compatibility is wide, and hard water resistance property is strong, and biological degradability is high, humble to skin and eye irritation.
Foam stabilizer can improve the stability of foam, extends the bubble burst half-life.In the present invention, described foam stabilizer is
The fatty alcohol of C8-C22, i.e. carbon number are the fatty alcohol of 8-22, including capryl alcohol, isooctanol or lauryl alcohol etc., it is also possible to be point
Son amount is the polyoxyethylene ether of more than 2000.
Heretofore described suds booster is nonionic polymer surfactant, including as HANSHENGJIAO or, Radix Acaciae senegalis,
One or more in carboxymethyl cellulose, hydroxypropyl cellulose or etherification starch.Described HANSHENGJIAO is also known as xanthan gum, and it can have
Effect strengthens the stability of foam, has good suspension effect to insoluble solid and oil droplet, and xanthan gum colloidal sol molecule can be formed
The spiral copolymer of superjunction crossed belt shape, constitutes the network structure of fragile similar glue, it is possible to support solid particle, drop and
The form of bubble, demonstrates the strongest stable emulsifying effect and higher suspension ability.
It addition, antifreeze is also known as antifreezing agent, it is that a class joins in other liquid (generally water) to reduce its freezing point, to carry
The material of high anti-freezing ability.Heretofore described antifreeze is rudimentary between 2-5 of the lower alcohol of C2-C5, i.e. carbon number
Alcohol, including one or more in ethanol, isopropanol, ethylene glycol or glycerol, wherein the anti-freezing property of ethylene glycol is excellent, is
Topmost antifreeze.
Heretofore described pH adjusting agent is mineral acid or organic acid, including the one in hydrochloric acid, sulphuric acid or acetic acid or
Multiple.In the present invention, described pH adjusting agent is for regulating the pH value in glutaraldehyde foamaseptic, is regulated to pH and is
2-4 so that it is can stably preserve in acid condition.And after the deionized water added in the present invention refers to deionizing form impurity
Pure water.
It addition, glutaraldehyde foamaseptic of the present invention is in use, it is mixed with water by following mass percent
Close: glutaraldehyde foamaseptic: 0.5-3%;Water: 97%-99.5%.The most in use, by described glutaraldehyde foamaseptic and water
It is mixed, just can be used for cleaning-sterilizing.It is easy and simple to handle, provides the user great convenience.
Further, the present invention also provides for the preparation method of a kind of glutaraldehyde foamaseptic described above, it include with
Lower step:
First deionized water is heated to 40-60C °, be then sequentially added into main foaming agent, auxiliary blowing agent,
Foam stabilizer, suds booster and antifreeze, after stirring and dissolving, add pH value regulator, after pH value regulation to 2-4, cold
But to room temperature, it is subsequently adding glutaraldehyde, prepares described glutaraldehyde foamaseptic.
The foam that the present invention provides is except stably can depositing in addition to together with glutaraldehyde, it is also possible to and other disinfectant
As: chlorine-containing disinfectant and peroxide sterilants composition foam-type disinfectant, however it is necessary that and add in foam solution in use,
After addition, its effective shelf-life is 24 hours.
Below by specific embodiment, the present invention program is expanded on further:
Embodiment 1
A, the preparation of 2% glutaraldehyde foamaseptic (2% refers to that mass fraction is 2%): in 100ml beaker, add 30g deionization
Water, is heated to 50 C °, is then sequentially added into: 20g NPE, 10g dodecylbenzene sodium sulfonate, 2g 12
Alcohol, 3g xanthan gum and 5g ethylene glycol.After being stirred and heated to be completely dissolved, dropping hydrochloric acid to pH value is 4.Cool down etc. above-mentioned solution
To room temperature, add 2g analytical pure glutaraldehyde, be eventually adding deionized water constant volume to 100ml, it is thus achieved that described 2% glutaraldehyde foam
Disinfectant.In prepared glutaraldehyde foamaseptic, reduction rate is less than 1% in 1 year for the content of glutaraldehyde, and it can be stablized
Preserve, and be effectively increased the cleaning capacity of foam.
B, the use of 2% glutaraldehyde foamaseptic: take above-mentioned 2% glutaraldehyde foamaseptic 2g, add water and be diluted to
100g, can produce with special-purpose foaming equipment and stablize lasting sterilization foam.
Embodiment 2
A, the preparation of 1% glutaraldehyde foamaseptic: in 100kg reactor, add 30kg deionized water, be heated to 40 C °, so
Rear order add: 22kg dodecyl phenol polyethenoxy ether, 11kg sodium lauryl sulphate, 3kg isooctanol, 4kg xanthan gum with
And 2kg isopropanol.After being stirred and heated to be completely dissolved, dropping acetic acid to pH value is 2.After being cooled to room temperature etc. above-mentioned solution, add
Enter 3kg analytical pure glutaraldehyde.It is eventually adding deionized water and quantitatively arrives 100kg, prepare glutaraldehyde foamaseptic.Prepared penta
In dialdehyde foamaseptic, reduction rate is less than 1% in 1 year for the content of glutaraldehyde, and it can stably preserve, and is effectively improved
The cleaning capacity of foam,
B, the use of 1% glutaraldehyde foamaseptic: take above-mentioned glutaraldehyde foamaseptic 1kg, be diluted to 100kg, with special
Bubble equipment can produce stablizes lasting sterilization foam.
Embodiment 3
A, the preparation of 0.5% glutaraldehyde foamaseptic: in 100kg reactor, add 10kg deionized water, be heated to 60 C °,
Then be sequentially added into: 20kg NPE, 10kg dodecyl sodium sulfate, 0.5kg capryl alcohol, 3kg HANSHENGJIAO with
And 5kg ethylene glycol.After being stirred and heated to be completely dissolved, dropping salt acid for adjusting pH value is 2.After above-mentioned solution is cooled to room temperature,
Add 1kg analytical pure glutaraldehyde.It is eventually adding deionized water and quantitatively arrives 100kg, prepare glutaraldehyde foamaseptic.Prepared
In glutaraldehyde foamaseptic, reduction rate is less than 1% in 1 year for the content of glutaraldehyde, and it can stably preserve, and effectively carries
The high cleaning capacity of foam.
B, the use of 0.5% glutaraldehyde foamaseptic: take above-mentioned foam solution 0.5kg and be diluted to 100kg, use special-purpose foaming
Equipment can produce stablizes lasting sterilization foam.
Embodiment 4
A, the preparation of 2% glutaraldehyde foamaseptic: in 100kg beaker, add 30kg deionized water, be heated to 50 C °, then
Order adds: 20kg poly lauryl glucosyl, 10kg sodium lauryl sulphate, 2kg capryl alcohol, 3kg HANSHENGJIAO and 5kg
Ethylene glycol.After being stirred and heated to be completely dissolved, dropping hydrochloric acid to pH value is 4.After it is cooled to room temperature, add 1kg analytical pure
Glutaraldehyde.It is eventually adding water and quantitatively arrives 100kg, prepare glutaraldehyde foamaseptic.In prepared glutaraldehyde foamaseptic
Reduction rate is less than 1% in 1 year for the content of glutaraldehyde, and it can stably preserve, and is effectively increased the cleaning energy of foam
Power.
B, the use of 2% glutaraldehyde foamaseptic: take above-mentioned glutaraldehyde foamaseptic 2kg and be diluted to 100kg, with specially
Can produce with foaming machine and stablize lasting sterilization foam.
Embodiment 5
A, the preparation of foam: adding 30kg deionized water in 100kg reactor, be heated to 50 C °, then order adds:
20kg poly lauryl glucosyl, 10kg sodium lauryl sulphate, 2kg capryl alcohol, 3kg HANSHENGJIAO and 5kg ethylene glycol.Stir
Mix after being heated to be completely dissolved, be cooled to room temperature, be eventually adding water and quantitatively arrive 100kg.
B, the use of 5% hydrogen peroxide foam disinfectant: take above-mentioned foam solution 3kg, add the hydrogen peroxide 15kg of 30%, dilute
Release 100kg, can produce with special-purpose foaming equipment and stablize lasting sterilization foam.
C, the use of 5% sodium hypochlorite foamaseptic: take above-mentioned foam solution 3kg, add sodium hypochlorite 5kg, be diluted to
100kg, can produce with special-purpose foaming equipment and stablize lasting sterilization foam.
In sum, a kind of glutaraldehyde foamaseptic of the present invention and preparation method thereof, it is by using not with penta
Various foaming agent and the auxiliary agent of dialdehyde generation chemical reaction are prepared from, glutaraldehyde in prepared glutaraldehyde foamaseptic
Reduction rate is less than 1% in 1 year for content, and it can stably preserve, and is effectively increased the cleaning capacity of foam, has pole
Good practicality.
It should be appreciated that the application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can
To be improved according to the above description or to convert, all these modifications and variations all should belong to the guarantor of claims of the present invention
Protect scope.
Claims (10)
1. a glutaraldehyde foamaseptic, it is characterised in that described glutaraldehyde foamaseptic is by glutaraldehyde and foam
Formed;Wherein, by mass percentage, include:
Glutaraldehyde 0.1%-15%;
Foam 85%-99.9%.
Glutaraldehyde foamaseptic the most according to claim 1, it is characterised in that in described foam, by mass percentage
Meter, includes:
Main foaming agent 20%-30%;
Auxiliary blowing agent 5%-20;
Foam stabilizer 0.5%-5%;
Suds booster 1%-10%;
Antifreeze 0.1%-5%;
PH value regulator 0.05-5%;
Deionized water 30-75%;
The percentage ratio sum of above-mentioned each component is 100%.
Glutaraldehyde foamaseptic the most according to claim 2, it is characterised in that described main foaming agent is that non-ionic surface is lived
Property agent, including one or more in polyol surfactant or polyethenoxy ether class surfactant.
Glutaraldehyde foamaseptic the most according to claim 2, it is characterised in that described auxiliary blowing agent is anionic table
Face activating agent, including the one in dodecylbenzene sodium sulfonate, dodecyl sodium sulfate, lauryl sulphate acid acid sodium or AES
Or it is multiple.
Glutaraldehyde foamaseptic the most according to claim 2, it is characterised in that described foam stabilizer is the fat of C8-C22
Alcohol, including one or more in capryl alcohol, isooctanol or lauryl alcohol.
Glutaraldehyde foamaseptic the most according to claim 2, it is characterised in that described suds booster is non ionic polymer table
Face activating agent, including such as the one in HANSHENGJIAO, Radix Acaciae senegalis, carboxymethyl cellulose, hydroxypropyl cellulose or etherification starch
Or it is multiple.
Glutaraldehyde foamaseptic the most according to claim 2, it is characterised in that described antifreeze is the lower alcohol of C2-C5,
Including one or more in ethanol, isopropanol, ethylene glycol or glycerol.
Glutaraldehyde foamaseptic the most according to claim 2, it is characterised in that described pH adjusting agent is mineral acid or organic
Acid, including one or more in hydrochloric acid, sulphuric acid or acetic acid.
Glutaraldehyde foamaseptic the most according to claim 2, it is characterised in that described glutaraldehyde foamaseptic is using
Time, mix with water by following mass percent:
Glutaraldehyde foamaseptic: 0.5-3%;
Water: 97%-99.5%.
10. the preparation method of glutaraldehyde foamaseptic as described in any one of claim 1-8, it is characterised in that include
Following steps:
First deionized water is heated to 40-60C °, be then sequentially added into main foaming agent, auxiliary blowing agent,
Foam stabilizer, suds booster and antifreeze, after stirring and dissolving, add pH value regulator, after pH value regulation to 2-4, cold
But to room temperature, it is subsequently adding glutaraldehyde, prepares described glutaraldehyde foamaseptic.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108739857A (en) * | 2018-07-06 | 2018-11-06 | 江西傲新生物科技有限公司 | A kind of farm's foam-type disinfectant and the preparation method and application thereof |
CN110839621A (en) * | 2019-11-01 | 2020-02-28 | 上海康臣生物科技有限公司 | Foam type auxiliary agent of disinfectant and preparation method thereof |
CN113331186A (en) * | 2021-04-26 | 2021-09-03 | 广州迈高化学有限公司 | Foam disinfectant and preparation method thereof |
CN114711228A (en) * | 2021-01-06 | 2022-07-08 | 山东菏泽三仪生物工程有限公司 | Preparation of strong-adhesion disinfection foaming matrix |
WO2024026235A1 (en) * | 2022-07-29 | 2024-02-01 | Gojo Industries, Inc. | Polymer enhanced hydroalcoholic disinfecting composition |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101579330A (en) * | 2009-06-25 | 2009-11-18 | 中国农业大学 | Disinfectant for animals and preparation method thereof |
CN104940183A (en) * | 2015-06-03 | 2015-09-30 | 山东信得科技股份有限公司 | Disinfectant and preparation method thereof |
-
2016
- 2016-05-06 CN CN201610295689.4A patent/CN105961386A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101579330A (en) * | 2009-06-25 | 2009-11-18 | 中国农业大学 | Disinfectant for animals and preparation method thereof |
CN104940183A (en) * | 2015-06-03 | 2015-09-30 | 山东信得科技股份有限公司 | Disinfectant and preparation method thereof |
Non-Patent Citations (2)
Title |
---|
方亮: "《药剂学》", 31 March 2016, 中国医药科技出版社 * |
苗建华等: "一例甲醛熏蒸和泡沫消毒的效果比较", 《现代农业科技》 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108739857A (en) * | 2018-07-06 | 2018-11-06 | 江西傲新生物科技有限公司 | A kind of farm's foam-type disinfectant and the preparation method and application thereof |
CN110839621A (en) * | 2019-11-01 | 2020-02-28 | 上海康臣生物科技有限公司 | Foam type auxiliary agent of disinfectant and preparation method thereof |
CN114711228A (en) * | 2021-01-06 | 2022-07-08 | 山东菏泽三仪生物工程有限公司 | Preparation of strong-adhesion disinfection foaming matrix |
CN113331186A (en) * | 2021-04-26 | 2021-09-03 | 广州迈高化学有限公司 | Foam disinfectant and preparation method thereof |
WO2024026235A1 (en) * | 2022-07-29 | 2024-02-01 | Gojo Industries, Inc. | Polymer enhanced hydroalcoholic disinfecting composition |
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