JP2013001860A - Detergent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a compounding method with which dispersibility of a water-soluble polymer to improve foam quality is improved in a detergent composition including as a principal component, a surfactant such as a fatty acid soap.SOLUTION: The water-soluble polymer is granulated together with other dispersible particles, and the produced granules are uniformly dispersed in a melt soap liquid. The detergent composition includes a fatty acid soap portion which is to be a principal ingredient and granules formed by mixing and granulating the water-soluble polymer and the dispersible particles, wherein the granules are uniformly dispersed in the fatty acid soap portion. The dispersible particles preferably include polyethylene powder, talc, and ethyl cellulose.

Description

  The present invention relates to an improvement in a method for blending a detergent composition, particularly a water-soluble polymer.

  A so-called cleaning composition is formed with a surfactant such as fatty acid soap as a main component, and when other moisturizing components are included, the amount of moisture is usually 50% or less in many cases.

  On the other hand, a cleaning composition intended for the human body has a great commercial value, and many studies have been made on foam quality, foam amount, foam hardness, foam retention, and the like. Furthermore, the foam having elasticity and spinnability is recognized as a very good quality foam, but the improvement of the foam quality is still insufficient by the above various studies.

  One reason for this is the difficulty in blending water-soluble polymers. That is, a technique for blending various water-soluble polymers into a detergent as a foam improver is known, but adding a water-soluble polymer directly to a molten soap solution results in so-called “dama”. In addition, water-soluble polymers usually have a high thickening ability, so even if they are dissolved in a small amount of water in advance and added to the molten soap solution, they become a highly viscous gel, and in any case, they are uniformly dispersed in the molten soap solution. It was extremely difficult to do.

  Therefore, in the past, various water-soluble polymers have been studied for improving the foam quality (Patent Document 1), but an amount sufficient to improve the foam quality or to reduce the feeling of skin crispness after washing. It was difficult to blend uniformly.

Japanese Patent No. 3970861

  The present invention has been made in view of the above prior art, and an object to be solved is to uniformly disperse a water-soluble polymer in a molten soap solution.

  As a result of studying the method of adding a water-soluble polymer to a melt detergent, the present inventors have granulated the water-soluble polymer together with other easily dispersible particles, and the granulated product in the molten soap solution It has been found that a relatively large amount of water-soluble polymer can be dispersed uniformly by adding to the above.

That is, the cleaning composition according to the present invention is:
Fatty acid soap part as the main agent,
A granulated product obtained by mixing and granulating a water-soluble polymer and easily dispersible particles in the fatty acid soap part;
The granulated product is characterized by being uniformly dispersed in the fatty acid soap part.

Moreover, it is preferable that the easily dispersible particles of the granulated product include any of polyethylene powder, talc, ethyl cellulose, zinc white, and hydroxyapatite.
In addition, the water-soluble polymer of the granulated product preferably contains any of sodium polyacrylate, dimethylallyl ammonium chloride / acrylamide copolymer, highly polymerized polyethylene glycol, carboxyvinyl polymer, and fucoidan.

Moreover, it is suitable that 3-15 mass% of water-soluble polymers are mix | blended in the said granulated material.
Furthermore, when the cleaning composition according to the present invention is a solid soap, it is preferable to contain crystalline cellulose.

Hereafter, each structure of this invention is explained in full detail.
[Fatty acid soap part]
Examples of the fatty acid in the fatty acid salt used as a main component in the cleaning composition of the present invention include saturated or unsaturated fatty acids having 8 to 20 carbon atoms, more preferably 12 to 18 carbon atoms. It may be a chain or a branched chain. Specific examples include, for example, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, isostearic acid and the like, and beef tallow fatty acid, coconut oil fatty acid, palm kernel oil fatty acid and the like which are mixtures thereof.

  Examples of fatty acid counterions include sodium, potassium, ethanolamine and the like.

The content of the fatty acid salt in the cleaning composition of the present invention is not particularly limited, but when it is a transparent solid soap, it is preferably 20 to 50% by mass, particularly 30 to 40% by mass. When this content is less than 20% by mass, the transparency is lowered or the freezing point is lowered, so that when stored for a long period of time, the surface melts and the commercial value may be impaired. On the other hand, if it exceeds 50% by mass, the transparency may be lowered, or there may be a feeling of tension after use.
The total amount of lauric acid soap and oleic acid soap is preferably 20% by mass or less in the total composition.

  When the detergent composition is solid, the molar ratio of sodium and potassium constituting the salt (sodium / potassium ratio) is 100/0 (that is, fatty acid sodium) to 70/30, particularly 90. It is preferable that it is / 10-80 / 20. If the sodium / potassium ratio exceeds 70/30 and the proportion of potassium increases, the freezing point becomes low, and the surface may melt when stored for a long period of time, thereby impairing the commercial value. Moreover, there is a possibility that the hardness decreases, the dissolution during use increases, the sweating occurs under high temperature and high humidity conditions, or the surface becomes clouded during use.

[Granulated product]
The granulated product characteristic in the present invention includes a water-soluble polymer and easily dispersible particles.
As a water-soluble polymer,
Acrylic polymers such as sodium polyacrylate, dimethylallyl ammonium chloride / acrylamide copolymer, dimethylallyl ammonium chloride / acrylamide / acrylic acid copolymer,
Carboxyvinyl polymers, alkyl-modified carboxyvinyl polymers, vinyl polymers such as polyvinylpyrrolidone,
Polyethylene glycol polymers such as highly polymerized polyethylene glycol,
Cellulose polymers such as methylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose, cationized cellulose,
Examples include fucoidan, carrageenan, sodium alginate, seaweed derived materials such as agar, xanthan gum, gum arabic, gellan gum, pullulan, quince, sodium hyaluronate, sodium polyglutamate, and the like.

  Among these, sodium polyacrylate, dimethylallyl ammonium chloride / acrylamide copolymer, high degree of polymerization polyethylene glycol, carboxyvinyl polymer, fucoidan, which can obtain a foam with elasticity and elasticity, in particular. preferable.

  These water-soluble polymers can be uniformly dispersed in the molten soap solution without the granulation of the present invention if the viscosity is low when dissolved in water. In particular, it is particularly effective when the viscosity at 25 ° C. is 100 mPa · S or more.

  In addition, as the easily dispersible particles suitably used in the present invention, polyethylene powder, talc, ethyl cellulose, zinc white, hydroxyapatite and the like are preferably exemplified from the viewpoint of dispersibility in a fatty acid melt.

  The granulation method is not particularly limited, but the granulated product needs to be in a state in which the water-soluble polymer can be eluted at least when the detergent is used. For this reason, for example, it is preferable to mix each powder with a Henschel mixer or the like, wet with ethanol or the like, and then granulate with a granulator such as an onlator.

  Under the present circumstances, it is preferable that the water-soluble polymer compounding quantity in a granulated material is 3-15 mass%. If the content is 3% by mass or less, the content of the water-soluble polymer is relatively small, so that a large amount of the granulated product needs to be blended. On the other hand, if the content is 15% by mass or more, the granulation suitability may be lowered.

[Sugar / Polyol part]
In the present invention, sugars / polyols suitably used for obtaining a transparent soap include maltitol, sorbitol, glycerin, 1,3-butylene glycol, propylene glycol, polyethylene glycol, sugar, pyrrolidone carboxylic acid, sodium pyrrolidone carboxylate , Hyaluronic acid, polyoxyethylene alkyl glucoside ether and the like are exemplified, and it is preferable to blend 20 to 60% by mass in the composition.
In particular, in order to obtain good usability as well as transparency, the ratio of sugar and sugar alcohol to polyol in the sugar / polyol part is preferably 40-60: 60-40.

[Crystalline cellulose part]
When the detergent composition of the present invention is used as a solid soap, as a swelling / disintegration preventing agent when using soap, crystalline cellulose powder, sea surface powder, silica powder, aloezil, kaolin, smecton, zeolite, laponite, etc. It is desirable to blend powder. In particular, crystalline cellulose having a high water absorption and a high effect of preventing swelling and melting is preferable. The blending amount is desirably 1 to 10.

[Amphoteric surfactant]
In the present invention, the transparent soap suitably used for obtaining the transparent soap preferably contains the following amphoteric surfactant as a non-fatty acid soap-based surfactant.
Examples of the amphoteric surfactant that can be used in the transparent soap of the present invention include amphoteric surfactants represented by the following chemical formulas (A) to (C).

[Wherein, R ₁ represents an alkyl group or alkenyl group having 7 to 21 carbon atoms, n and m are the same or different and represent an integer of 1 to 3, and Z represents a hydrogen atom or (CH ₂ ) _p COOY (where p is an integer of 1 to 3, and Y is an alkali metal, alkaline earth metal or organic amine). ],

[Wherein R ₂ represents an alkyl group or alkenyl group having 7 to 21 carbon atoms, R ₃ and R ₄ are the same or different and represent a lower alkyl group, and A represents a lower alkylene group. . ],and

[Wherein, R ₅ represents an alkyl group or alkenyl group having 8 to 22 carbon atoms, and R ₆ and R ₇ are the same or different and represent a lower alkyl group. ].

In the chemical formula (A), the “alkyl group having 7 to 21 carbon atoms” of R ₁ may be linear or branched, and the number of carbon atoms is preferably 7 to 17. The “alkenyl group having 7 to 21 carbon atoms” of R ₁ may be linear or branched, and the number of carbon atoms is preferably 7 to 17. Examples of the “alkali metal” of Y include sodium and potassium, examples of the “alkaline earth metal” include calcium and magnesium, and examples of the “organic amine” include monoethanolamine, diethanolamine and trimethylamine. Examples include ethanolamine.

Specific examples of the amphoteric surfactant represented by the chemical formula (A) include imidazolinium betaine type, for example, 2-undecyl-N-carboxymethyl-N-hydroxyethylimidazolium betaine (synthesized from lauric acid) Hereinafter, for convenience, it is also referred to as “lauroiylimidazolinium betaine”), 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolium betaine (synthesized from stearic acid), 2-synthesized from coconut oil fatty acid. Alkyl or alkenyl-N-carboxymethyl-N-hydroxyethylimidazolium betaine (R ₁ is a mixture of C _{7 to} C ₁₇ , hereinafter, also referred to as “cocoyl imidazolinium betaine” for convenience) and the like.

In formula (B), and "alkenyl group having a carbon number of 7 to 21""alkyl group having a carbon number of 7 to 21" of R ₂ is the same as R ₁ of formula (A). The “lower alkyl group” for R ₃ and R ₄ is a linear or branched alkyl group having preferably 1 to 3 carbon atoms. Furthermore, the “lower alkylene group” of A is a linear or branched alkylene group having preferably 3 to 5 carbon atoms.

Specific examples of the amphoteric surfactant (amide alkyl betaine type) represented by the chemical formula (B) include amidopropyl betaine type, for example, coconut oil fatty acid amidopropyldimethylaminoacetic acid betaine (R ₂ is C _{7 to} C ₁₇ . Mixture).

In the chemical formula (C), the “alkyl group having 8 to 22 carbon atoms” of R ₅ may be linear or branched, and the number of carbon atoms is preferably 8 to 18. The “alkenyl group having 8 to 22 carbon atoms” of R ₅ may be linear or branched, and the number of carbon atoms is preferably 8 to 18. Furthermore, the “lower alkyl group” of R ₆ and R ₇ is the same as R ₃ and R _{4 in} the chemical formula (B).

Specific examples of the amphoteric surface active agents represented by the chemical formula (C) (alkyl betaine type), lauryl betaine, synthesized from coconut fatty alkyl or alkenyl acid betaine (R ₅ is C ₈ ~ C ₁₈ mixture).

  In the present invention, at least one selected from the group consisting of amphoteric surfactants represented by the above chemical formulas (A) to (C) can be used. When a plurality of amphoteric surfactants represented by the chemical formula (A) are used, a plurality of amphoteric surfactants represented by the chemical formula (B) may be used. A plurality of amphoteric surfactants represented by

  Among the amphoteric surfactants described above, imidazolinium betaine type, particularly cocoylimidazolinium betaine, among the amphoteric surfactants represented by the chemical formula (A) is particularly preferably used.

  In the transparent soap of the present invention, fatty acid soap (fatty acid sodium or a mixed salt of fatty acid sodium / potassium) and an amphoteric surfactant form a composite salt by adding the above amphoteric surfactant, thereby improving hardness. The effect of performing is demonstrated.

  The content of the amphoteric surfactant in the transparent soap of the present invention is preferably 2 to 10% by mass, particularly 4 to 8% by mass. If this content is less than 2% by mass, the freezing point will be low, and if stored for a long period of time, the surface will melt and the commercial value may be impaired. Moreover, there exists a possibility that hardness may fall. On the other hand, if it exceeds 10% by mass, a sticky feeling is produced after use, and if stored for a long period of time, the surface may be browned and the commercial value may be impaired.

[Hydroxyalkyl ether carboxylate type surfactant]
It is preferable to add a hydroxyalkyl ether carboxylate type surfactant to the soap according to the present invention, and improvement in foaming is recognized.
A suitable hydroxyalkyl ether carboxylate type surfactant in the present invention has the following structure (D).

(In the formula, R ¹ represents a saturated or unsaturated hydrocarbon group having 4 to 34 carbon atoms; ^one of X ¹ and X ² represents —CH ₂ COOM ¹ and the other represents a hydrogen atom; M ¹ represents a hydrogen atom, an alkali metal, an alkaline earth metal, ammonium, a lower alkanolamine cation, a lower alkylamine cation, or a basic amino acid cation.)

In the formula, R ¹ may be an aromatic hydrocarbon, a linear or branched aliphatic hydrocarbon, but is preferably an aliphatic hydrocarbon, particularly an alkyl group or an alkenyl group. For example, butyl, octyl, decyl, dodecyl, tetradecyl, hexadecyl, octadecyl, docosyl, 2-ethylhexyl, 2-hexyldecyl, 2-octylundecyl, 2-decyltetradecyl , 2-undecylhexadecyl group, decenyl group, dodecenyl group, tetradecenyl group, hexadecenyl group and the like are preferable examples, and among them, decyl group and dodecyl group are excellent in terms of surface active ability.

In the formula, any one of X ¹ and X ² is represented by —CH ₂ COOM ¹ , and as M ¹ , a hydrogen atom, lithium, potassium, sodium, calcium, magnesium, ammonium, monoethanolamine, Examples include diethanolamine and triethanolamine.

Specifically, among the above (A) hydroxyalkyl ether carboxylate type surfactants, dodecane-1, in which H of any OH group of dodecane-1,2-diol is substituted with —CH ₂ COONa, 2-diol sodium ether acetate is most preferred in the present invention.
In the present invention, the hydroxyalkyl ether carboxylate type surfactant may be blended in an amount of 0.5 to 10% by mass, preferably 0.7 to 5% by mass from the viewpoint of improving foaming.

[Nonionic surfactant]
When applying this invention to transparent soap, you may mix | blend a nonionic surfactant further as a non-fatty-acid soap-type surfactant used suitably. Nonionic surfactants that can be used include polyoxyethylene (hereinafter also referred to as POE) hydrogenated castor oil, polyoxyethylene 2-octyldodecyl ether, polyoxyethylene lauryl ether, propylene oxide ethylene oxide copolymer block polymer, polyoxyethylene Polyoxypropylene cetyl ether, polyoxyethylene polyoxypropylene glycol, polyethylene glycol diisostearate, alkyl glucoside, polyoxyethylene-modified silicon (for example, polyoxyethylene alkyl-modified dimethyl silicon), polyoxyethylene glycerin monostearate, polyoxyethylene Examples include alkyl glucoside.

These may be used alone or in combination of two or more. Among the above nonionic surfactants, polyoxyethylene hydrogenated castor oil and propylene oxide ethylene oxide copolymer block polymer can be suitably used.

  In the transparent soap of the present invention, a non-ionic surfactant is added to exert a stimulating lowering effect derived from fatty acid soap.

  The content of the nonionic surfactant in the transparent soap of the present invention is preferably 2 to 15% by mass, particularly preferably 6 to 12% by mass. If this content is less than 2% by mass, a feeling of tension may occur after use. On the other hand, if it exceeds 15% by mass, the freezing point is lowered, so that when stored for a long period of time, the surface may melt and the commercial value may be impaired. Furthermore, a sticky feeling may occur after use.

[Chelating agent]
Further, it is preferable to add a chelating agent such as edetate trisodium dihydrate to the cleaning composition according to the present invention.

  Moreover, as a chelating agent used suitably in this invention, hydroxyethane diphosphonic acid and its salt are mentioned, More preferably, it is hydroxyethane diphosphonic acid. As a compounding quantity, it is 0.001-1.0 mass%, More preferably, it is 0.1-0.5 mass%. When the amount of hydroxyethanediphosphonic acid and its salt is less than 0.001% by mass, the chelate effect is insufficient, causing inconveniences such as yellowing over time. The irritation increases, which is undesirable.

[Others]
As other additives that can be blended in the present invention, the following components can be arbitrarily blended within the range not impairing the above-described action. This optional component includes fungicides such as trichlorocarbanilide and hinokitiol; oils; fragrances; dyes; UV absorbers; antioxidants; Extract; nonionic, cationic or anionic water-soluble polymer; usability improver such as lactic acid ester.

[moisture]
In the present invention, the detergent composition to be blended with the granule is premised on a composition in which it is difficult to directly add a water-soluble polymer, and the water content is 50% by mass or less in the composition, In particular, when it is 30% or less, the effect is remarkably exhibited.

  Although the manufacturing method of the cleaning composition of this invention is not specifically limited, When it becomes solid soap, general methods, such as a frame kneading method and a mechanical kneading method, can be applied to the mixture of each component.

  As described above, according to the soap according to the present invention, since the water-soluble polymer is granulated and added together with the easily dispersible particles, the uniformity, feeling of use, and foam quality can be improved. .

Hereinafter, preferred embodiments of the present invention will be described.
In order to study the blending suitability of a water-soluble polymer into a detergent composition, the present inventors have studied using the following basic formulation. In addition, a compounding quantity is shown by the mass%.

  First, the present inventors tried to produce a transparent soap by using a soap having a basic formulation comprising the following soap part, sugar / polyol part, water-soluble polymer and others.

Basic prescription 1
Fatty acid soap part 30.0%
Lauric acid 20 parts Myristic acid 40 parts Palmitic acid 10 parts Stearic acid 20 parts Isostearic acid 5 parts Neutralized with sodium hydroxide
Sugar / polyol part 39.0%
Sorbitol 15 parts Sucrose 14 parts Glycerin 10 parts
Others 11.1%
Edetate 0.1 part Lauryl glycol acetate 5 parts POE (30) hydrogenated castor oil 5 parts Fragrance 1 part
Water-soluble polymer 0.5%
Ion exchange water balance

First, in the basic formulation 1, the present inventors directly added various water-soluble polymers to produce a transparent soap and evaluated it.
The results are shown in Table 1.

Table 1
Test Example 1-1 1-2 1-3 1-4 1-4
Water-soluble polymer Sodium polyacrylate 0.5----
Dimethylallylammonium chloride / acrylamide copolymer − 0.5 − − −
High polymerization degree polyethylene glycol--0.5--
Fucoidan---0.5-
Evaluation Transparency × △ × × ◎
Uniformity × △ × × ◎
Foam quality (elasticity) ◎ ◎ ◎ ◎ ×
Moist feeling ◎ ◎ ◎ ◎ △
Foaming ◎ ◎ ◎ ◎ △

In the test examples shown in Table 1, the soap was produced according to a conventional method, and the water-soluble polymer was preliminarily dissolved in an appropriate amount of ion-exchanged water and then added to the molten soap solution.
As apparent from Table 1, in Test Examples 1-1 to 1-4 in which 0.5% of the water-soluble polymer was added, compared to Test Example 1-5 in which no water-soluble polymer was added, In each evaluation of moist feeling and foaming, it was excellent, but on the other hand, transparency and uniformity were lowered. This is because the water-soluble polymer is not uniformly dispersed.
Therefore, the inventors made soap by forming the granulated product shown in Table 2 and adding the granulated product to the molten soap solution.

Table 2
A B C D E
Polyethylene powder 60 60 60 60 60
Talc 25 25 25 25 25
Ethylcellulose 5 5 5 5 5
Water-soluble polymer
Sodium polyacrylate 10 − − − −
Dimethylallylammonium chloride / acrylamide copolymer-10---
High polymerization degree polyethylene glycol − − 10 − −
Fucoidan---10-
Carboxyvinyl polymer---10

In addition, after mixing and pulverizing the above compositions A to D uniformly using a hencial mixer, 20 parts of 95% ethanol was added to and mixed with 100 parts of powder, extruded with 20 mesh using an oscillator, dried, The size was adjusted with 24 mesh. And the particle | grains which pass 20 meshes using a sieve and do not pass 60 meshes were obtained.
Test Examples 1-6 to 1-9, in which these granulated products A to D were blended so that the water-soluble polymer was the same as those of Test Examples 1-1 to 1-4, were prepared and evaluated.
The results are shown in Table 3 below.

Table 3
Test Example 1-6 1-7 1-8 1-9 1-10
Granulated product A 5 − − − −
B-5---
C − − 5 − −
D − − − 5 −
E − − − − 5
Evaluation
Transparency ○ ○ ○ ○ ○
Uniformity ○ ○ ○ ○ ○
Foam quality (elasticity) ◎ ◎ ◎ ◎ ◎
Moist feeling ◎ ◎ ◎ ◎ ◎
Foaming ◎ ◎ ◎ ◎ ◎

From Table 3 above, all of Test Examples 1-6 to 1-10 had slightly reduced transparency when compared with Test Example 1-5 due to the blending of talc and the like, but the uniformity was good, and When compared with Test Examples 1-1 to 1-4, a significant improvement in transparency was observed.

Next, the present inventors also confirmed the effect of adding a granulated product to the paste soap formulation.

Basic prescription 2
Fatty acid soap part 25.0%
Lauric acid 23 parts Myristic acid 57 parts Stearic acid 20 parts Neutralized with potassium hydroxide
Amphoteric, nonionic surfactant 7.0%
Acylmethyl taurate salt 5.0 parts Fatty acid monoglyceryl 2.0 parts
Sugar / polyol part 35.0%
Glycerin 20.0 parts Sorbitol 5.0 parts PEG 1500 10.0 parts
Water-soluble polymer 0.5%
Other 0.3%
Fragrance 0.2 parts Edetate 0.1 parts
Ion exchange water balance

The results are shown in Tables 4 and 5.

Table 4
Test Example 2-1 2-2 2-3 2-4 2-5
Water-soluble polymer Sodium polyacrylate 0.5----
Dimethylallylammonium chloride / acrylamide copolymer − 0.5 − − −
High polymerization degree polyethylene glycol--0.5--
Fucoidan---0.5-
Evaluation Uniformity △ △ × × ◎
Foam quality (elasticity) ◎ ◎ ◎ ◎ △
Moist feeling ◎ ◎ ◎ ◎ △
Foaming ◎ ◎ ◎ ◎ △

Table 5
Test Example 2-6 2-7 2-8 2-9 2-10
Granulated product A 5 − − − −
B-5---
C − − 5 − −
D − − − 5 −
E − − − − 5
Evaluation
Uniformity ○ ○ ○ ○ ○
Foam quality (elasticity) ◎ ◎ ◎ ◎ ◎
Moist feeling ◎ ◎ ◎ ◎ ◎
Foaming ◎ ◎ ◎ ◎ ◎

In the system of Basic Formula 2, there was a tendency that the uniformity was slightly improved even in the system in which the water-soluble polymer was directly added because the viscosity was low. Showed a significant improvement in uniformity.
Hereinafter, the specific composition of the cleaning composition according to the present invention will be described.

Composition Example 1: Solid soap lauric acid 5.0
Myristic acid 10.0
Palmitic acid 5.0
Stearic acid 5.0
Dynamite Glycerin 14.1
Silicon KF-6011 5.0
Polyethylene glycol 1500 2.0
95% ethanol 6.0
Etidronic acid 4Na 0.05
EDTA-3Na 0.05
Potassium hydroxide 1.23
Sodium hydroxide 3.03
Lauryl glycol acetate Na 9.7
Sodium chloride 0.5
Sucrose / sorbitol 10.3
Imidazolinium betaine 6.1
Marcote 100 0.5
PEG-60 hydrogenated castor oil 2.6
Crystalline cellulose 5.0
BHT 0.05
Ion exchange water
Fragrance 2.0
Granulated product 5.0

The granulated product has the following composition.
Talc 21.0
Ethylcellulose 2.5
Polyacrylic acid Na 10.0
Polyethylene 66.5

Claims (5)

Fatty acid soap part as the main agent,
A granulated product obtained by mixing and granulating water-soluble polymer and particles that are easily dispersible in the fatty acid soap part,
And the granulated product is uniformly dispersed in the fatty acid soap part.   The composition according to claim 1, wherein the easily dispersible particles of the granulated product contain any one of polyethylene powder, talc, and ethyl cellulose.   3. The composition according to claim 1 or 2, wherein the water-soluble polymer of the granulated product is any one of sodium polyacrylate, dimethylallyl ammonium chloride / acrylamide copolymer, highly polymerized polyethylene glycol, carboxyvinyl polymer, and fucoidan. A cleaning composition comprising:   The composition in any one of Claims 1-3 WHEREIN: 3-15 mass% of water-soluble polymers are mix | blended in the granulated material, The cleaning composition characterized by the above-mentioned.   The composition according to any one of claims 1 to 4, wherein the composition is a soap bar and contains crystalline cellulose.