CN105948972A - Amino acid fertilizer and preparation method and application thereof - Google Patents
Amino acid fertilizer and preparation method and application thereof Download PDFInfo
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- CN105948972A CN105948972A CN201610265678.1A CN201610265678A CN105948972A CN 105948972 A CN105948972 A CN 105948972A CN 201610265678 A CN201610265678 A CN 201610265678A CN 105948972 A CN105948972 A CN 105948972A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F1/00—Fertilisers made from animal corpses, or parts thereof
- C05F1/005—Fertilisers made from animal corpses, or parts thereof from meat-wastes or from other wastes of animal origin, e.g. skins, hair, hoofs, feathers, blood
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F1/00—Fertilisers made from animal corpses, or parts thereof
- C05F1/007—Fertilisers made from animal corpses, or parts thereof from derived products of animal origin or their wastes, e.g. leather, dairy products
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Molecular Biology (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses an amino acid fertilizer including the components in parts by mass: 1-2 parts of enzyme bacteria, 5-10 parts of pineapple pomace, 10-20 parts of oyster shells, 30-40 parts of waste molasses, 5-10 parts of a shrimp head paste, and 10-20 parts of soy bean residues. The invention also provides a preparation method and application of the amino acid fertilizer. The amino acid fertilizer is prepared from the enzyme bacteria and a plurality of wastes, is rich in nutrients and rich in organic matters, organic nitrogen, phosphorus and potassium, humic acid and amino acid, can increase the crop yield after application, improves the crop quality, and also can improve soil effects.
Description
Technical field
The invention belongs to agrochemical field, particularly a kind of amino acid fertilizer and its preparation method and application.
Background technology
Fertilizer is broadly divided into inorganic fertilizer, organic fertilizer and biological germ fertilizer three kinds.Inorganic fertilizer low price,
Obvious to the effect of increasing production of crop in a short time, but life-time service can cause soil compaction, air-and water-permeable performance
Differ from and finally affect crop yield.Although common are machine fertilizer in the market and biological germ fertilizer can changing
Good soil, but the most relatively costly, and peasant is difficult to undertake, and is difficult to reach what peasant devoted exclusive attention to output
Requirement.
Have substantial amounts of Concha Ostreae resource in coastal area, they are the garbages after extracting Carnis ostreae.Prawn is
People love to hear the dining table cuisines taken delight in talking about, and prawn head is its garbage.Prawn head cream the prawn of refrigeration plant's process has
A lot, for paste garbage.Soy sauce factory can produce a large amount of Semen Glycines slag after preparing soy sauce, is a kind of rich in plant
The castaway slag of albumen.Processing fruits factory can produce a large amount of marc, such as yellow peach marc, Fructus Ananadis comosi marc, Pericarpium Citri tangerinae
Marc etc..The garbage in sugar refinery is blackstrap.There are these garbages a large amount of at southern china, environment is made
Become the biggest pollution, a kind of method being therefore badly in need of these garbages of Appropriate application, it is achieved turn waste into wealth.
Summary of the invention
It is an object of the invention to overcome deficiency of the prior art, it is provided that one mainly utilizes organic waste
Fertilizer of composition and preparation method thereof.Concrete technical scheme is: the present invention provides a kind of amino acid fertilizer,
Including enzymatic microorganism, Fructus Ananadis comosi marc, Concha Ostreae, blackstrap, prawn head cream and Semen Glycines slag.Preferably, also include
Beer residue, ammonium sulfate, magnesium sulfate, potassium sulfate, calcium superphosphate.
Further, in parts by mass: enzymatic microorganism 1-2 part, Fructus Ananadis comosi marc 5-10 part, Concha Ostreae 10-20
Part, blackstrap 30-40 part, prawn head cream 5-10 part, Semen Glycines slag 10-20 part.
Preferably, in parts by mass: enzymatic microorganism 1-2 part, Fructus Ananadis comosi marc 10 parts, Concha Ostreae 20 parts, useless
40 parts of molasses, prawn head cream 10 parts, Semen Glycines slag 18-19 part.
Further, enzymatic microorganism includes bacillus subtilis and yeast.Preferably, bacillus subtilis is
Bacillus subtilis RB, in enzymatic microorganism, bacillus subtilis RB and saccharomycetic mass ratio are 1:1-2.5.
The present invention has also stated that the preparation method of this amino acid fertilizer, comprises the following steps: by enzymatic microorganism, phoenix
Melonidum slag, prawn head cream, Semen Glycines slag and blackstrap are mixed by proportioning, ferment 6-7 days；Powdery is added by proportioning
Concha Ostreae mixing, obtain amino acid fertilizer.
Further, comprise the following steps: by enzymatic microorganism, Fructus Ananadis comosi marc, prawn head cream, Semen Glycines slag and useless sugar
Honey is mixed by proportioning, ferments 6-7 days；Add the Concha Ostreae mixing of powdery by proportioning, filter, filter residue and drying,
Pelletize, obtains amino acid fertilizer.
Further, comprise the following steps: by enzymatic microorganism, Fructus Ananadis comosi marc, prawn head cream, Semen Glycines slag and useless sugar
Honey was mixed by proportioning, 35-40 DEG C of bottom fermentation 6-7 days；Add the Concha Ostreae mixing of powdery by proportioning, filter,
Filter residue and drying, pelletize, obtain amino acid fertilizer.
Further, reclaim the filtrate being filtrated to get, be used for preparing fertile the punching with paste of the aminoacid page and apply fertilizer.
The invention also discloses the purposes of this amino acid fertilizer, can be used for preparing Chemical Mixed Fertilizer.Especially this amino acid fertilizer
Material is allocated common fertilizer into and is made Chemical Mixed Fertilizer.
The material composition of Concha Ostreae is divided into inanimate matter and organic two parts.Inanimate matter part with calcium carbonate is
Main, account for more than the 90% of Concha Ostreae quality, wherein calcium constituent accounts for about 40%, additionally contain copper, ferrum,
20 various trace elements such as zinc, manganese, strontium.The organic principle of Concha Ostreae accounts for about the 4% of Concha Ostreae quality,
Containing 17 kinds of aminoacid such as glycine, cystine, methionine.
Prawn head cream not only contains several amino acids, and may advantageously facilitate root system life containing chitin, chitosan
Long, significantly induce plant disease-resistant resistance thus reduce chemical pesticide consumption, improve soil.Also it is alive simultaneously
The important sources of property calcium.The 3,4,3',4'-tetraketo-.beta.-carotene wherein contained and shrimp cephalin, the former is natural antioxidant and sky
So coloring agent, can prevent plant senilism glossy with vegetables and fruits lovely luster in season, promotes that fruit color is uniform；
Latter dimmable saves the opening width of Stoma of Leaves, reduces moisture transpiration when arid, it is provided that as drought-resistant ability.
Enzymatic microorganism, Fructus Ananadis comosi marc, prawn head cream, Semen Glycines slag and blackstrap together ferment and can generate high concentration
The type that becomes thoroughly decomposed organic matter, humic acids, biochemical class fulvic acid, several amino acids.In Fructus Ananadis comosi marc, moisture is high,
Also can well, ferment faster without adding extra water.
The present invention provide amino acid fertilizer, rich in nutrition content, rich in organic matter, organic nitrogen, phosphorus, potassium,
Humic acid and aminoacid, can improve the yield of crops, improving quality, have improvement soil simultaneously after using
Effect.
The present invention is by waste molasses of sugar plant, soy sauce factory bean dregs, brewery's beer residue, the height of marine products processing fent
Levels of nitrogen, high-load organic matter are turned waste into wealth, and use fermentable, prepare multi-functional compounded amino
Acid biological liquid fertilizer, adds oyster shell powder, is characteristic based on Concha Ostreae micropore, is lived by ion mould plate technique
Change, Concha Ostreae is transform as nitrogen, phosphorus, potassium plasma adsorbent, it is achieved the effect of slow control fertilizer efficiency, its advantage
It is to be effectively increased soil fertility, needs releasing of slow control nutrient according to growth and development of plants simultaneously
Put.The amino acid protein of the present invention can be as nuisanceless green fertilizer, and it can effectively eliminate because of chronic administration
Learn the problem that quality declines and residual nitrates pollutes that fertilizer brings to agricultural product, really realize agricultural product
Nuisanceless, soil can be improved simultaneously, improve planting environment.
Bacillus subtilis, yeast that the present invention uses pass through amount reproduction, producing strains body protein, produce
The article such as marine product leftover bits and pieces, bean dregs are carried out saccharifying decomposition by the strongest hydrolyzable enzyme at short notice,
Generate glucose, aminoacid etc. with breaks down proteins, cellulose decomposition, provide culture medium for beneficial microbe,
Prolific microorganism promotes that humic acid is formed, and has good cnmplexation adsorbability, and heavy metal has absorption
Power, thus form the strongest attenuating effects, can substantially improve soil, promote the growth of plant.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be further described, and following example are intended to this product is described
Rather than limitation of the invention further.All of equipment and raw material etc. are all commercially available or one's own profession
Industry is commonly used.Technical scheme used by the present invention or expression way, if not otherwise specified, be art technology
Well known to personnel.
Embodiment 1:
The preparation method of a kind of amino acid fertilizer of the present invention comprises the following steps:
By proportion by weight, by enzymatic microorganism 1 part, Fructus Ananadis comosi marc 5 parts, prawn head cream 5 parts, Semen Glycines slag 10
Part and blackstrap 30 parts mixing, ferment 6 days；The Concha Ostreae 10 parts mixing of powdery is added by proportion by weight,
Filter, filter residue and drying, pelletize, obtain amino acid fertilizer.Filtrate is used for preparing the aminoacid page after reclaiming fertile.
Enzymatic microorganism includes that bacillus subtilis and yeast, quality proportioning are 1:1, and is commercially available mycopowder.Specifically
It is: bacillus subtilis and yeast are all purchased from Guangdong Province's Culture Collection
(http://www.gimcc.net/prolist.aspWithhttp://www.gimcc.net/prolist.asp？Pid=&page=2) name of product: bacillus subtilis
Bacterium (yeast powder).Product description: 1. main component: bacillus subtilis；2. products characteristics: strain is pure,
Energetic, high temperature resistant, acid and alkali-resistance, breeding is fast, it is strong to adapt to.3. technical specification: bacillus subtilis is effective
Viable count (hundred million/g) >=200,000,000,000/gram；Miscellaneous bacteria rate≤0.001%；Product fineness >=80 mesh；Spore rate >=
98%.
Name of product: active yeast.Main component: yeast；Technical specification: yeast content (hundred million
/ g) >=20,000,000,000/gram.
Embodiment 2:
The preparation method of a kind of amino acid fertilizer of the present invention comprises the following steps:
By proportion by weight, by enzymatic microorganism 1 part, Fructus Ananadis comosi marc 10 parts, prawn head cream 10 parts, Semen Glycines slag 19
Part and blackstrap 40 parts mixing, ferment 6 days；The Concha Ostreae 20 parts mixing of powdery is added by proportion by weight,
Filter, filter residue and drying, pelletize, obtain amino acid fertilizer.Filtrate is used for preparing the aminoacid page after reclaiming fertile.
Enzymatic microorganism includes that bacillus subtilis and yeast, quality proportioning are 1:2.5, and is commercially available mycopowder, with
Embodiment 1.
Embodiment 3:
The preparation method of a kind of amino acid fertilizer of the present invention comprises the following steps:
By proportion by weight, by enzymatic microorganism 2 parts, Fructus Ananadis comosi marc 10 parts, prawn head cream 10 parts, Semen Glycines slag 18
Part and blackstrap 40 parts mixing, ferment 7 days；The Concha Ostreae 20 parts mixing of powdery is added by proportion by weight,
Filter, filter residue and drying, pelletize, obtain amino acid fertilizer.Filtrate is used for after reclaiming preparing paste punching fertilising.Ammonia
Base acid fertilizer and common fertilizer are configured to Chemical Mixed Fertilizer by quality proportioning 1:1.Enzymatic microorganism include bacillus subtilis and
Yeast, quality proportioning is 1:1.5, and is commercially available mycopowder, with embodiment 1.
Embodiment 4:
The preparation method of a kind of amino acid fertilizer of the present invention comprises the following steps:
By proportion by weight, by enzymatic microorganism 2 parts, Fructus Ananadis comosi marc 10 parts, prawn head cream 10 parts, Semen Glycines slag 20
Part and blackstrap 40 parts mixing, ferment 7 days；The Concha Ostreae 20 parts mixing of powdery is added by proportion by weight,
Filter, filter residue and drying, pelletize, obtain amino acid fertilizer.Filtrate is used for after reclaiming preparing paste punching fertilising.Ammonia
Base acid fertilizer and common fertilizer are configured to Chemical Mixed Fertilizer by quality proportioning 1:2.Enzymatic microorganism include bacillus subtilis and
Yeast, quality proportioning is 1:0.5, and is commercially available mycopowder, with embodiment 1.
After testing, amino acid fertilizer in embodiment 1-4, by The Ministry of Agriculture of the People's Republic of China, MOA's standard
NY1429-2010 is (micro-containing aminoacid water-soluble fertilizer (moderate-element type) and the water-soluble fertilizer in aminoacid
Secondary element type) technology requirement, test method, inspection rule detection, free aminoacid content 100
G/L, moderate-element (calcium, magnesium) content 30g/L, arsenic and compound (in terms of As)≤10g/L thereof,
Cadmium and compound (in terms of Cd)≤10g/L, lead and compound (in terms of Pb)≤50g/L thereof,
Chromium and compound (in terms of Cr)≤50g/L, mercury and mercuric compounds (in terms of Hg)≤5g/L,
Meet the requirement that NY1429-2010 standard specifies.
The results showed: increasing production of rice 10%～15%, wheat increase yield 10%, Folium Camelliae sinensis volume increase 11%,
Yield Increase In Cotton 10%～15%, melon volume increase 15%～25%.
Major function: 1. improve percentage of seedgermination, soaks seed with amino acid protein fertilizer, can break plant and stop
Sleep, improve percentage of seedgermination and Phase ofsprouting.
2. flower and fruit protecting, promotes flower bud development, improves setting percentage of bearing fruit.
3. optimizing fruit marketing quality, increase single fruit weight, improve sugar content, really color is beautiful glossy.
4. alleviate poisoning, the stagnant long phenomenon of mummy that alleviation insecticide, antibacterial improper use cause, allow
Plant recovery normal growth.
Application effect: as follows by Experimental Comparison:
Organic mass fraction >=35% of amino acid fertilizer in embodiment 1-4；Organic nitrogen, phosphorus, potassium
Mass fraction >=5%；Effectively bacterium reaches 2.5 hundred million, humic acid mass fraction >=15%；Amino acid masses
Mark >=10%.
Amino acid fertilizer embodiment 2 prepared is used as soil and fertilizer, uses 100 kilograms of these amino acid fertilizers for every mu,
Detecting heavy metal in soil content after 1 month, result is as shown in table 1；Soil.
Table 1, heavy metal in soil content detection result
From table 1, after using this amino acid fertilizer, heavy metal content in soil is obviously improved.Real
The amino acid fertilizer executing example 1,3,4 preparation have also been obtained similar results, repeats no more here.
Application examples 1
Amino acid fertilizer prepared by embodiment 2 is used for the base manure of crop, test fertile cost and routine
Equal with fertile cost, green cucumber mu throws the amino acid fertilizer of 150 yuan, and plant strain growth is healthy and strong, fruit shapes
And quality has clear improvement, output increased more than 15%.Radish planting mu throws 135 yuan of amino acid fertilizers, individual
Greatly, smooth, do not bend, yield increase by more than 20%.
As effect similar embodiment 2 in terms of volume increase in the amino acid fertilizer of embodiment 1,3,4 preparation,
Here repeat no more.
Application examples 2
Effect of the amino acid fertilizer degrading pesticide residues of embodiment 2 preparation:
1. through Caulis et Folium Lactucae Sativae, Fructus Lycopersici esculenti test, after using the amino acid fertilizer of embodiment 2 preparation, nitrate is average
The nutrient chemical fertilizer dispositions such as content is substantially less than, Fructus Lycopersici esculenti nitrate content reduces by 7.5%, and Caulis et Folium Lactucae Sativae reduces by 6.5%.
The nitrate average content of the amino acid fertilizer 2. using embodiment 2 preparation in green vegetable test is
416.6mg/kg, the average content using chemical fertilizer is 764.6mg/kg.
Effect similar embodiment 2 of the amino acid fertilizer degrading pesticide residues of embodiment 1,3,4 preparation, this
In repeat no more.
The preferred embodiment of the present invention described in detail above.Should be appreciated that those of ordinary skill in the art
Just many modifications and variations can be made according to the design of the present invention without creative work.Therefore, all technology neck
In territory, technical staff is the most on the basis of existing technology by logical analysis, reasoning or limited
Test available technical scheme, all should be in the protection domain being defined in the patent claims.
Claims (10)
1. an amino acid fertilizer, it is characterised in that include enzymatic microorganism, Fructus Ananadis comosi marc, Concha Ostreae, useless sugar
Honey, prawn head cream and Semen Glycines slag.
2. amino acid fertilizer as claimed in claim 1, it is characterised in that in parts by mass: described ferment
Element bacterium 1-2 part, described Fructus Ananadis comosi marc 5-10 part, described Concha Ostreae 10-20 part, described blackstrap 30-40
Part, described prawn head cream 5-10 part, described Semen Glycines slag 10-20 part.
3. amino acid fertilizer as claimed in claim 2, it is characterised in that in parts by mass: described ferment
Element bacterium 1-2 part, described Fructus Ananadis comosi marc 10 parts, described Concha Ostreae 20 parts, described blackstrap 40 parts, described
Prawn head cream 10 parts, described Semen Glycines slag 18-19 part.
4. amino acid fertilizer as claimed in claim 1, it is characterised in that described enzymatic microorganism includes hay
Bacillus cereus and yeast.
5. the preparation method of an amino acid fertilizer as claimed in claim 1, it is characterised in that include with
Lower step: enzymatic microorganism, Fructus Ananadis comosi marc, prawn head cream, Semen Glycines slag and blackstrap are mixed by proportioning, ferment 6-7
My god；Add the Concha Ostreae mixing of powdery by proportioning, obtain described amino acid fertilizer.
6. the preparation method of amino acid fertilizer as claimed in claim 5, it is characterised in that include following step
Rapid: enzymatic microorganism, Fructus Ananadis comosi marc, prawn head cream, Semen Glycines slag and blackstrap to be mixed by proportioning, ferments 6-7 days；
Add the Concha Ostreae mixing of powdery by proportioning, filter, filter residue and drying, pelletize, obtain described amino acid fertilizer.
7. the preparation method of amino acid fertilizer as claimed in claim 5, it is characterised in that include following step
Rapid: enzymatic microorganism, Fructus Ananadis comosi marc, prawn head cream, Semen Glycines slag and blackstrap to be mixed by proportioning, at 35-40 DEG C
Bottom fermentation 6-7 days；Add the Concha Ostreae mixing of powdery by proportioning, filter, filter residue and drying, pelletize, obtain institute
State amino acid fertilizer.
8. the preparation method of amino acid fertilizer as claimed in claim 6, it is characterised in that reclaim described mistake
The filtrate that filter obtains, is used for preparing fertile the punching with paste of the aminoacid page and applies fertilizer.
9. the purposes of an amino acid fertilizer as claimed in claim 1, it is characterised in that described amino acid fertilizer
Material is used for preparing Chemical Mixed Fertilizer.
10. the purposes of amino acid fertilizer as claimed in claim 9, it is characterised in that described amino acid fertilizer is joined
Enter common fertilizer and make Chemical Mixed Fertilizer.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108260489A (en) * | 2018-03-22 | 2018-07-10 | 佛山推启农业研究院（普通合伙） | A kind of burdock non-polluted planting method rich in various trace elements |
| CN108586139A (en) * | 2018-05-25 | 2018-09-28 | 合肥市风达农业有限责任公司 | A kind of fertilizer and preparation method thereof improving garlic bolt yield |
| CN109180378A (en) * | 2018-09-15 | 2019-01-11 | 湖南泰谷生态工程有限公司 | A method of Amino acid liquid fertilizer is prepared using dead fish shrimp |
| CN109422587A (en) * | 2017-08-28 | 2019-03-05 | 邹亚燕 | A kind of amino acid fertilizer and its preparation method and application |
| CN113666786A (en) * | 2021-08-13 | 2021-11-19 | 广东拉多美化肥有限公司 | Oyster shell activation method, mixed solution, oyster shell composition and preparation method of soil conditioner |
| CN114516770A (en) * | 2022-02-18 | 2022-05-20 | 陕西麦克斯农业科技股份有限公司 | Beautiful color sweetening type high-potassium composite liquid fertilizer and preparation method thereof |
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| CN109180378A (en) * | 2018-09-15 | 2019-01-11 | 湖南泰谷生态工程有限公司 | A method of Amino acid liquid fertilizer is prepared using dead fish shrimp |
| CN113666786A (en) * | 2021-08-13 | 2021-11-19 | 广东拉多美化肥有限公司 | Oyster shell activation method, mixed solution, oyster shell composition and preparation method of soil conditioner |
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