CN105862469A - 一种纺织印染助剂及其制备方法 - Google Patents
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Abstract
本发明公开了一种纺织印染助剂，具有下列重量份的原料配比：椰油酰胺丙基二甲胺50‑60份、聚乙烯吡啶45‑55份、十二烷基苯磺酸铵30‑40份、亚硫酸钠30‑40份、油酰氨基酸钠25‑35份、聚乙二醇二丙烯酸酯20‑30份、月桂酸酯20‑30份、苯乙烯马来酸酐树脂15‑25份、硫酸锌5‑15份、氯化钡5‑15份、交联剂5‑10份、柔软剂5‑10份，从而能够提高纺织品印染效果并减小对皮肤的刺激。同时，还公开了相应的制备方法。
Description
技术领域
本发明涉及纺织助剂技术领域，具体涉及一种纺织印染助剂及其制备方法。
背景技术
印染助剂是在织物印花和染色的过程中所使用的助剂，能够提高印花和染色的效果。印染助剂可分为印花助剂和染色助剂。印花助剂包括粘合剂、增稠剂、交联剂、乳化剂、柔软剂、扩散剂和消泡剂等，染色助剂包括匀染剂、固色剂、分散剂、荧光增白剂和柔顺剂等。
近年来，纺织业的快速发展大大提高了对染料纺织化学品的需求，国内外印染助剂行业的生产与市场发展十分迅速。但是，常规的印染助剂提升印染的性能不强，往往需要大量添加使用，能够对人体皮肤造成或多或少的刺激，并且在纺织品的生产成本上造成了一定负担。同时，大量印染助剂的使用也造成了工业废水、废气排放量的增加，加剧了环境上的污染。因此，急需开发一种具备优良特性的新型印染助剂。
发明内容
为解决上述技术问题，本发明提供一种纺织印染助剂及其制备方法，通过采用特定原料进行组合，配合相应的生产工艺，得到了一种新型印染助剂，其印染效果显著、对皮肤刺激小，具有良好的应用前景。
具体实施方式
本发明的目的可以通过以下技术方案实现：
一种纺织印染助剂，由下列重量份的原料制成：椰油酰胺丙基二甲胺
50-60
份、聚乙烯吡啶
45-55
份、十二烷基苯磺酸铵
30-40
份、亚硫酸钠
30-40
份、油酰氨基酸钠
25-35
份、聚乙二醇二丙烯酸酯
20-30
份、月桂酸酯
20-30
份、苯乙烯马来酸酐树脂
15-25
份、硫酸锌
5-15
份、氯化钡
5-15
份、交联剂
5-10
份、柔软剂
5-10
份。
优选地，所述的交联剂选自多异氰酸酯、聚醚氨基改性聚硅氧烷、封闭型水性异氰酸酯中的一种或几种。
优选地，所述的柔软剂选自硅油柔软剂、酯基季铵盐、双十八烷基二甲基氯化铵中的一种或几种。
所述纺织印染助剂的制备方法包括以下步骤：
（
1
）按照重量份称取各原料；
（
2
）将椰油酰胺丙基二甲胺、聚乙烯吡啶、十二烷基苯磺酸铵、聚乙二醇二丙烯酸酯、月桂酸酯、苯乙烯马来酸酐树脂混合，加入
10%
的
NaOH
溶液调节
pH
至
8.5
，在
7500-8500 r/m
的状态下搅拌
6-10h
；
（
3
）将搅拌后的混合液加热至
65-75
℃，然后加入亚硫酸钠、油酰氨基酸钠、硫酸锌、氯化钡，在超声机中进行第一次超声，随后加入交联剂、柔软剂，进行第二次超声，得到成品。
优选地，所述步骤（
3
）中第一次超声功率为
800w
，超声时间为
6-7h
，第二次超声功率为
950w
，超声时间为
4-5h
。
本发明与现有技术相比，其有益效果为：
（
1
）本发明的纺织助剂以椰油酰胺丙基二甲胺、聚乙烯吡啶、十二烷基苯磺酸铵、亚硫酸钠、油酰氨基酸钠为主要成分，通过加入聚乙二醇二丙烯酸酯、月桂酸酯、苯乙烯马来酸酐树脂、硫酸锌、氯化钡、交联剂、柔软剂，辅以改性、搅拌、加热、超声等工艺，使得制备而成的印染助剂具有良好的印染效果，且对皮肤刺激较小。
（
2
）本发明的印染助剂原料廉价、工艺简单，适于大规模工业化运用，实用性强。
具体实施方式
下面结合具体实施例对发明的技术方案进行详细说明。
实施例
1
（
1
）按照重量份称取椰油酰胺丙基二甲胺
50
份、聚乙烯吡啶
45
份、十二烷基苯磺酸铵
30
份、亚硫酸钠
30
份、油酰氨基酸钠
25
份、聚乙二醇二丙烯酸酯
20
份、月桂酸酯
20
份、苯乙烯马来酸酐树脂
15
份、硫酸锌
5
份、氯化钡
5
份、多异氰酸酯
5
份、硅油柔软剂
5
份；
（
2
）将椰油酰胺丙基二甲胺、聚乙烯吡啶、十二烷基苯磺酸铵、聚乙二醇二丙烯酸酯、月桂酸酯、苯乙烯马来酸酐树脂混合，加入
10%
的
NaOH
溶液调节
pH
至
8.5
，在
7500 r/m
的状态下搅拌
6h
；
（
3
）将搅拌后的混合液加热至
65
℃，然后加入亚硫酸钠、油酰氨基酸钠、硫酸锌、氯化钡，在超声机中进行第一次超声，超声功率为
800w
，超声时间为
6h
，随后加入多异氰酸酯、硅油柔软剂，进行第二次超声，超声功率为
950w
，超声时间为
4h
，得到成品。
制得的印染助剂的性能测试结果如表
1
所示。
实施例
2
（
1
）按照重量份称取椰油酰胺丙基二甲胺
55
份、聚乙烯吡啶
50
份、十二烷基苯磺酸铵
35
份、亚硫酸钠
35
份、油酰氨基酸钠
30
份、聚乙二醇二丙烯酸酯
25
份、月桂酸酯
25
份、苯乙烯马来酸酐树脂
20
份、硫酸锌
10
份、氯化钡
10
份、聚醚氨基改性聚硅氧烷
7
份、酯基季铵盐
7
份；
（
2
）将椰油酰胺丙基二甲胺、聚乙烯吡啶、十二烷基苯磺酸铵、聚乙二醇二丙烯酸酯、月桂酸酯、苯乙烯马来酸酐树脂混合，加入
10%
的
NaOH
溶液调节
pH
至
8.5
，在
8000 r/m
的状态下搅拌
8h
；
（
3
）将搅拌后的混合液加热至
70
℃，然后加入亚硫酸钠、油酰氨基酸钠、硫酸锌、氯化钡，在超声机中进行第一次超声，超声功率为
800w
，超声时间为
6.5h
，随后加入聚醚氨基改性聚硅氧烷、酯基季铵盐，进行第二次超声，超声功率为
950w
，超声时间为
4.5h
，得到成品。
制得的印染助剂的性能测试结果如表
1
所示。
实施例
3
（
1
）按照重量份称取椰油酰胺丙基二甲胺
60
份、聚乙烯吡啶
55
份、十二烷基苯磺酸铵
40
份、亚硫酸钠
40
份、油酰氨基酸钠
35
份、聚乙二醇二丙烯酸酯
30
份、月桂酸酯
30
份、苯乙烯马来酸酐树脂
25
份、硫酸锌
15
份、氯化钡
15
份、封闭型水性异氰酸酯
10
份、双十八烷基二甲基氯化铵
10
份；
（
2
）将椰油酰胺丙基二甲胺、聚乙烯吡啶、十二烷基苯磺酸铵、聚乙二醇二丙烯酸酯、月桂酸酯、苯乙烯马来酸酐树脂混合，加入
10%
的
NaOH
溶液调节
pH
至
8.5
，在
8500 r/m
的状态下搅拌
10h
；
（
3
）将搅拌后的混合液加热至
75
℃，然后加入亚硫酸钠、油酰氨基酸钠、硫酸锌、氯化钡，在超声机中进行第一次超声，超声功率为
800w
，超声时间为
7h
，随后加入封闭型水性异氰酸酯、双十八烷基二甲基氯化铵，进行第二次超声，超声功率为
950w
，超声时间为
5h
，得到成品。
制得的印染助剂的性能测试结果如表
1
所示。
实施例
4
（
1
）按照重量份称取椰油酰胺丙基二甲胺
50
份、聚乙烯吡啶
55
份、十二烷基苯磺酸铵
30
份、亚硫酸钠
40
份、油酰氨基酸钠
25
份、聚乙二醇二丙烯酸酯
30
份、月桂酸酯
20
份、苯乙烯马来酸酐树脂
25
份、硫酸锌
5
份、氯化钡
15
份、聚醚氨基改性聚硅氧烷
5
份、双十八烷基二甲基氯化铵
10
份；
（
2
）将椰油酰胺丙基二甲胺、聚乙烯吡啶、十二烷基苯磺酸铵、聚乙二醇二丙烯酸酯、月桂酸酯、苯乙烯马来酸酐树脂混合，加入
10%
的
NaOH
溶液调节
pH
至
8.5
，在
7500 r/m
的状态下搅拌
10h
；
（
3
）将搅拌后的混合液加热至
65
℃，然后加入亚硫酸钠、油酰氨基酸钠、硫酸锌、氯化钡，在超声机中进行第一次超声，超声功率为
800w
，超声时间为
7h
，随后加入聚醚氨基改性聚硅氧烷、双十八烷基二甲基氯化铵，进行第二次超声，超声功率为
950w
，超声时间为
4h
，得到成品。
制得的印染助剂的性能测试结果如表
1
所示。
对比例
1
（
1
）按照重量份称取椰油酰胺丙基二甲胺
50
份、聚乙烯吡啶
45
份、亚硫酸钠
30
份、油酰氨基酸钠
25
份、聚乙二醇二丙烯酸酯
20
份、月桂酸酯
20
份、苯乙烯马来酸酐树脂
15
份、氯化钡
5
份、多异氰酸酯
5
份、硅油柔软剂
5
份；
（
2
）将椰油酰胺丙基二甲胺、聚乙烯吡啶、聚乙二醇二丙烯酸酯、月桂酸酯、苯乙烯马来酸酐树脂混合，加入
10%
的
NaOH
溶液调节
pH
至
8.5
，在
7500 r/m
的状态下搅拌
6h
；
（
3
）将搅拌后的混合液加热至
65
℃，然后加入亚硫酸钠、油酰氨基酸钠、氯化钡，在超声机中进行第一次超声，超声功率为
800w
，超声时间为
6h
，随后加入多异氰酸酯、硅油柔软剂，进行第二次超声，超声功率为
950w
，超声时间为
4h
，得到成品。
制得的印染助剂的性能测试结果如表
1
所示。
对比例
2
（
1
）按照重量份称取椰油酰胺丙基二甲胺
60
份、十二烷基苯磺酸铵
40
份、亚硫酸钠
40
份、聚乙二醇二丙烯酸酯
30
份、月桂酸酯
30
份、苯乙烯马来酸酐树脂
25
份、硫酸锌
15
份、氯化钡
15
份、封闭型水性异氰酸酯
10
份、双十八烷基二甲基氯化铵
10
份；
（
2
）将椰油酰胺丙基二甲胺、十二烷基苯磺酸铵、聚乙二醇二丙烯酸酯、月桂酸酯、苯乙烯马来酸酐树脂混合，加入
10%
的
NaOH
溶液调节
pH
至
8.5
，在
8500 r/m
的状态下搅拌
10h
；
（
3
）将搅拌后的混合液加热至
75
℃，然后加入亚硫酸钠、硫酸锌、氯化钡，在超声机中进行第一次超声，超声功率为
800w
，超声时间为
7h
，随后加入封闭型水性异氰酸酯、双十八烷基二甲基氯化铵，进行第二次超声，超声功率为
950w
，超声时间为
5h
，得到成品。
制得的印染助剂的性能测试结果如表
1
所示。
将实施例
1-4
和对比例
1-2
的印染助剂在相同印染条件下分别测试其印染效果及对皮肤的刺激性。
表
1
| 花型轮廓清晰度 | 着色剂上色率 | 皮肤刺激情况 | |
| 实施例 1 | 非常清晰 | 95.7% | 无刺激 |
| 实施例 2 | 非常清晰 | 93.6% | 无刺激 |
| 实施例 3 | 非常清晰 | 95.5% | 无刺激 |
| 实施例 4 | 非常清晰 | 92.1% | 无刺激 |
| 对比例 1 | 较清晰 | 87.1% | 轻微刺激 |
| 对比例 2 | 较清晰 | 86.5% | 轻微刺激 |
本发明以椰油酰胺丙基二甲胺、聚乙烯吡啶、十二烷基苯磺酸铵、亚硫酸钠、油酰氨基酸钠为主要成分，通过加入聚乙二醇二丙烯酸酯、月桂酸酯、苯乙烯马来酸酐树脂、硫酸锌、氯化钡、交联剂、柔软剂，辅以改性、搅拌、加热、超声等工艺，使得制备而成的印染助剂具有良好的印染效果，且对皮肤刺激较小，应用前景好，具有良好的社会效益。
以上所述仅为本发明的实施例，并非因此限制本发明的专利范围，凡是利用本发明说明书内容所作的等效结构或等效流程变换，或直接或间接运用在其他相关的技术领域，均同理包括在本发明的专利保护范围内。
Claims (5)
1.一种纺织印染助剂，其特征在于：由下列重量份的原料制成：椰油酰胺丙基二甲胺50-60份、聚乙烯吡啶45-55份、十二烷基苯磺酸铵30-40份、亚硫酸钠30-40份、油酰氨基酸钠25-35份、聚乙二醇二丙烯酸酯20-30份、月桂酸酯20-30份、苯乙烯马来酸酐树脂15-25份、硫酸锌5-15份、氯化钡5-15份、交联剂5-10份、柔软剂5-10份。
2.根据权利要求1所述的纺织印染助剂，其特征在于：所述的交联剂选自多异氰酸酯、聚醚氨基改性聚硅氧烷、封闭型水性异氰酸酯中的一种或几种。
3.根据权利要求1所述的纺织印染助剂，其特征在于：所述的柔软剂选自硅油柔软剂、酯基季铵盐、双十八烷基二甲基氯化铵中的一种或几种。
4.根据权利要求1～3任一所述的纺织印染助剂的制备方法，其特征在于，包括以下步骤：
（1）按照重量份称取各原料；
（2）将椰油酰胺丙基二甲胺、聚乙烯吡啶、十二烷基苯磺酸铵、聚乙二醇二丙烯酸酯、月桂酸酯、苯乙烯马来酸酐树脂混合，加入10%的NaOH溶液调节pH至8.5，在7500-8500
r/m的状态下搅拌 6-10h；
（3）将搅拌后的混合液加热至65-75℃，然后加入亚硫酸钠、油酰氨基酸钠、硫酸锌、氯化钡，在超声机中进行第一次超声，随后加入交联剂、柔软剂，进行第二次超声，得到成品。
5.根据权利要求4所述的纺织印染助剂的制备方法，其特征在于，所述步骤（3）中第一次超声功率为800w，超声时间为6-7h，第二次超声功率为950w，超声时间为4-5h。
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