CN105803815B - 随温度变化调节抗湿滑性能的运动器材握把革的制备方法 - Google Patents

随温度变化调节抗湿滑性能的运动器材握把革的制备方法 Download PDF

Info

Publication number
CN105803815B
CN105803815B CN201610238714.5A CN201610238714A CN105803815B CN 105803815 B CN105803815 B CN 105803815B CN 201610238714 A CN201610238714 A CN 201610238714A CN 105803815 B CN105803815 B CN 105803815B
Authority
CN
China
Prior art keywords
handle leather
water
slurry
based dry
sports equipment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201610238714.5A
Other languages
English (en)
Other versions
CN105803815A (zh
Inventor
陈磊
戴家兵
李维虎
祝彬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lanzhou Ketian New Material Co Ltd
Original Assignee
Lanzhou Ketian New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lanzhou Ketian New Material Co Ltd filed Critical Lanzhou Ketian New Material Co Ltd
Priority to CN201610238714.5A priority Critical patent/CN105803815B/zh
Publication of CN105803815A publication Critical patent/CN105803815A/zh
Application granted granted Critical
Publication of CN105803815B publication Critical patent/CN105803815B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/145—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes two or more layers of polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0009—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using knitted fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
    • D06N3/0047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by incorporating air, i.e. froth
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042—Acrylic polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/121—Permeability to gases, adsorption
    • D06N2209/123—Breathable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/126—Permeability to liquids, absorption
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/28—Artificial leather

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

本发明涉及一种随温度变化调节抗湿滑性能的运动器材握把革的制备方法，该方法包括以下步骤：⑴配制水性干法握把革贝斯浆料：在水性聚氨酯树脂中依次加入分散剂、交联剂、自来水、填充粉体、发泡剂、泡沫稳定剂、水性色浆、增稠剂并搅拌，即得水性干法握把革贝斯浆料；⑵配制印刷浆料：在树脂中依次加入自来水、消泡剂、流平剂、增稠剂并搅拌，即得印刷浆料；⑶将水性干法握把革贝斯浆料通入发泡机进行物理发泡，即得具有空气微泡的水性干法握把革贝斯发泡浆料；⑷将水性干法握把革贝斯发泡浆料均匀涂覆在弹力针织布上，烘干，即得水性干法握把革贝斯；⑸将印刷浆料印刷到水性干法握把革贝斯上，烘干，即得。本发明工艺简单、易于实施。

Description

随温度变化调节抗湿滑性能的运动器材握把革的制备方法
技术领域
本发明涉及运动器材握把材料技术领域，尤其涉及随温度变化调节抗湿滑性能的运动器材握把革的制备方法。
背景技术
目前，市场上大多数运动器材握把都采用天然橡胶、合成物质橡胶、橡塑海绵或化合物材料，根据型号和表面的抓紧特性制作而成。天然橡胶具有一定的舒适性，但产量有限。橡塑海绵手感柔软，但长时间使用会导致性能降低，且容易脏污；合成橡胶是由不吸水的材质构成，当使用者的手部出汗或手上有水渍时，会造成握把湿滑，虽有部分握把设有小孔以供水分子渗入，但在实际长时间使用过程时，手心温度提高，出汗加剧，仍会造成握把湿滑，影响人们使用。
如何能让握把具有长时间抗汗滑或湿滑的效果，这也是目前市面绝大部分运动器材握把制品所面临的问题。因此，提供一种具有能随手心温度变化调节抗湿滑汗滑效果的环保、超强吸水透气性的运动器材握把制品成为了人们的追求。
发明内容
本发明所要解决的技术问题是提供一种工艺简单、易于实施的随温度变化调节抗湿滑性能的运动器材握把革的制备方法。
为解决上述问题，本发明所述的随温度变化调节抗湿滑性能的运动器材握把革的制备方法，包括以下步骤：
⑴配制水性干法握把革贝斯浆料：
按重量份计，在200~300份固含量为30%~50%的水性聚氨酯树脂中依次加入3~7份分散剂、1~3份交联剂、15~25份自来水、60~130份填充粉体、3~7份发泡剂、3~7份泡沫稳定剂、0.5~1份水性色浆、1~3份增稠剂，并以800~1000r/min的转速搅拌0.5~1h，即得粘度为10000~20000cps的水性干法握把革贝斯浆料；
⑵配制印刷浆料：
按重量份计，在100~200份固含量为30%~50%的树脂中依次加入30~60份自来水、0.5~1.5份消泡剂、0.5~1.5份流平剂、0.5~1.5份增稠剂，并以300~500r/min的转速搅拌0.1~0.5h，即得粘度为1000~5000cps的印刷浆料；
⑶将所述水性干法握把革贝斯浆料通入发泡机，同时，在所述发泡机内部注入空气进行物理发泡，即得具有空气微泡的水性干法握把革贝斯发泡浆料；
⑷将所述水性干法握把革贝斯发泡浆料均匀涂覆在50D或75D弹力针织布上，然后通过烘箱在100~140℃的范围内按分节梯度升温方式进行烘干，即得水性干法握把革贝斯，收卷备用；
⑸将所述印刷浆料通过印刷目数为60~150目的三版印刷机的印刷辊，将其印刷到所述水性干法握把革贝斯上，然后通过烘箱在100~140℃的范围内按分节梯度升温方式进行烘干，即得随温度变化调节抗湿滑性能的运动器材握把革。
所述步骤⑴中填充粉体为木质粉、滑石粉、重钙、轻钙中的一种或多种。
所述步骤⑴中水性聚氨酯树脂为芳香族异氰酸酯型水性聚氨酯树脂。
所述步骤⑴中分散剂为含颜料亲和基团的高分子型分散剂。
所述步骤⑴中发泡剂为阴离子表面活性剂类发泡剂。
所述步骤⑴中泡沫稳定剂为硅树脂聚醚乳液类稳泡剂。
所述步骤⑴中交联剂为封闭型异氰酸酯类交联剂。
所述步骤⑴中增稠剂为非离子缔合式增稠剂。
所述步骤⑵中树脂为脂肪族异氰酸酯型水性聚氨酯树脂或丙烯酸树脂。
所述步骤⑵中消泡剂为改性有机硅类或矿物油类消泡剂。
所述步骤⑵中流平剂为聚醚改性硅氧烷共聚物流平剂。
所述步骤⑵中增稠剂为碱溶涨型水性增稠剂。
本发明与现有技术相比具有以下优点：
1、本发明印刷浆料的主要成分树脂在烘干成膜后，常温情况下表面不会发生变化，但随着外界温度升高表面会逐渐发粘。利用这一特性，通过将其固含量降低，控制其发粘程度在人体能接受的范围之内以及不会迁移到手上，再印刷到水性握把革贝斯表面，制得的运动器材握把革常温情况下表面不会发粘，当人体运动后，手心会发热，随之手心温度升高，会促使握把表面轻微发粘，这样就会使手部更加牢固的握住运动器材，不会滑落。
2、针对市面上绝大部分合成革类握把器材，本发明采用干法发泡工艺，加入填充粉体，制得具有均匀分布微泡孔的水性干法握把革贝斯，随后直接通过印刷工艺在贝斯表面印刷制得成品，其过程中省去了传统工艺中贝斯表面的面层、中间层以及粘结层，不仅大大降低制造成本，而且没有了传统工艺中贝斯表面的面层、中间层以及粘结层的阻碍，更能充分发挥握把的透气性和吸水性。
3、本发明中水性干法握把革贝斯浆料发泡后体积会发生膨胀，从而质地会变得更加柔软，所涂覆的基布采用比市面上常见的涤纶基布要更加柔软和有弹性的75D或50D针织弹力布，使得所制得水性干法握把革贝斯较同类型的产品更加柔软以及更加富有质感，让人在使用过程中感到更加舒适。
4、本发明中所采用的原料均为环保产品，完全无毒无害，对身体和环境不会造成任何不良影响。
5、本发明工艺简单、易于实施。
具体实施方式
实施例1 随温度变化调节抗湿滑性能的运动器材握把革的制备方法，包括以下步骤：
⑴配制水性干法握把革贝斯浆料：
按重量份（kg）计，在256份固含量为41%的水性聚氨酯树脂KT702（合肥市科天化工有限公司）中依次加入3.5份分散剂1790（上海深竹化工科技有限公司）、1.2份交联剂UN-7038（上海尤恩化工有限公司）、19份自来水、82份填充粉体滑石粉、5.2份发泡剂K12（济南硕昌化工有限公司）、5.3份泡沫稳定剂207（青岛中宝化工有限公司）、0.7份水性色浆TSE-LR07(苏州世名科技股份有限公司)、1.2份增稠剂210（福州邦联化工有限公司），并以900r/min的转速搅拌0.5h，即得粘度为12000cps的水性干法握把革贝斯浆料。
⑵配制印刷浆料：
按重量份（kg）计，在121份固含量为38%的水性聚氨酯树脂KT632（合肥市科天化工有限公司）中依次加入38份自来水、0.5份消泡剂SN-6750（上海深竹化工科技有限公司）、0.6份流平剂Silok350（广州市斯洛柯化学有限公司）、0.5份增稠剂RHEOLATE-1（福州邦联化工有限公司），并以350r/min的转速搅拌0.1h，即得粘度为2000cps的印刷浆料。
⑶将水性干法握把革贝斯浆料通入发泡机，同时，在发泡机内部注入空气进行物理发泡，即得具有空气微泡的水性干法握把革贝斯发泡浆料。
⑷将水性干法握把革贝斯发泡浆料均匀涂覆在50D弹力针织布上，然后通过烘箱在100~140℃的范围内按分节梯度升温方式进行烘干，即得水性干法握把革贝斯，收卷备用。
⑸将印刷浆料通过印刷目数为60目的三版印刷机的印刷辊，将其印刷到水性干法握把革贝斯上，然后通过烘箱在100~140℃的范围内按分节梯度升温方式进行烘干，即得随温度变化调节抗湿滑性能的运动器材握把革。
实施例2 随温度变化调节抗湿滑性能的运动器材握把革的制备方法，包括以下步骤：
⑴配制水性干法握把革贝斯浆料：
按重量份（kg）计，在200份固含量为30%的水性聚氨酯树脂KT702（合肥市科天化工有限公司）中依次加入3份分散剂6005（天津市添立润化工有限公司）、1份交联剂UN-7038（上海尤恩化工有限公司）、15份自来水、60份填充粉体重钙、3份发泡剂K12（济南硕昌化工有限公司）、3份泡沫稳定剂207（青岛中宝化工有限公司）、0.5份水性色浆TSE-LR07(苏州世名科技股份有限公司)、1份增稠剂210（福州邦联化工有限公司），并以800r/min的转速搅拌1h，即得粘度为10000cps的水性干法握把革贝斯浆料。
⑵配制印刷浆料：
按重量份（kg）计，在100份固含量为30%的水性聚氨酯树脂KT632（合肥市科天化工有限公司）中依次加入30份自来水、0.5份消泡剂YCK-700（毅克化学公司）、0.5份流平剂YCK-1300（毅克化学公司）、0.5份增稠剂RHEOLATE-1（福州邦联化工有限公司），并以300r/min的转速搅拌0.5h，即得粘度为1000cps的印刷浆料。
⑶将水性干法握把革贝斯浆料通入发泡机，同时，在发泡机内部注入空气进行物理发泡，即得具有空气微泡的水性干法握把革贝斯发泡浆料。
⑷将水性干法握把革贝斯发泡浆料均匀涂覆在75D弹力针织布上，然后通过烘箱在100~140℃的范围内按分节梯度升温方式进行烘干，即得水性干法握把革贝斯，收卷备用。
⑸将印刷浆料通过印刷目数为150目的三版印刷机的印刷辊，将其印刷到水性干法握把革贝斯上，然后通过烘箱在100~140℃的范围内按分节梯度升温方式进行烘干，即得随温度变化调节抗湿滑性能的运动器材握把革。
实施例3 随温度变化调节抗湿滑性能的运动器材握把革的制备方法，包括以下步骤：
⑴配制水性干法握把革贝斯浆料：
按重量份（kg）计，在300份固含量为50%的水性聚氨酯树脂KT702（合肥市科天化工有限公司）中依次加入7份分散剂Silok778（广州市斯洛柯化学有限公司）、3份交联剂PZBI-25（广州市坚毅化工进出口有限公司）、25份自来水、130份填充粉体木质粉、7份发泡剂K12（济南硕昌化工有限公司）、7份泡沫稳定剂207（青岛中宝化工有限公司）、1份水性色浆TSE-LR07(苏州世名科技股份有限公司)、3份环保增稠剂210（福州邦联化工有限公司），并以1000r/min的转速搅拌0.5h，即得粘度为20000cps的水性干法握把革贝斯浆料。
⑵配制印刷浆料：
按重量份（kg）计，在200份固含量为50%的丙烯酸树脂RS-998A（巴德富实业有限公司）中依次加入60份自来水、1.5份消泡剂AP7010（德谦（上海）化学有限公司）、1.5份流平剂352（优美特（北京）环境材料科技股份公司）、1.5份增稠剂RHEOLATE-1（福州邦联化工有限公司），并以500r/min的转速搅拌0.1h，即得粘度为5000cps的印刷浆料。
⑶将水性干法握把革贝斯浆料通入发泡机，同时，在发泡机内部注入空气进行物理发泡，即得具有空气微泡的水性干法握把革贝斯发泡浆料。
⑷将水性干法握把革贝斯发泡浆料均匀涂覆在50D弹力针织布上，然后通过烘箱在100~140℃的范围内按分节梯度升温方式进行烘干，即得水性干法握把革贝斯，收卷备用。
⑸将印刷浆料通过印刷目数为70目的三版印刷机的印刷辊，将其印刷到水性干法握把革贝斯上，然后通过烘箱在100~140℃的范围内按分节梯度升温方式进行烘干，即得随温度变化调节抗湿滑性能的运动器材握把革。

Claims (11)

1.随温度变化调节抗湿滑性能的运动器材握把革的制备方法，包括以下步骤：
⑴配制水性干法握把革贝斯浆料：
按重量份计，在200~300份固含量为30%~50%的水性聚氨酯树脂中依次加入3~7份分散剂、1~3份交联剂、15~25份自来水、60~130份填充粉体、3~7份发泡剂、3~7份泡沫稳定剂、0.5~1份水性色浆、1~3份增稠剂，并以800~1000r/min的转速搅拌0.5~1h，即得粘度为10000~20000cps的水性干法握把革贝斯浆料；
⑵配制印刷浆料：
按重量份计，在100~200份固含量为30%~50%的树脂中依次加入30~60份自来水、0.5~1.5份消泡剂、0.5~1.5份流平剂、0.5~1.5份增稠剂，并以300~500r/min的转速搅拌0.1~0.5h，即得粘度为1000~5000cps的印刷浆料；所述树脂为在常温下不发粘、但可以随手心温度升高而发粘的脂肪族异氰酸酯型水性聚氨酯树脂或丙烯酸树脂；
⑶将所述水性干法握把革贝斯浆料通入发泡机，同时，在所述发泡机内部注入空气进行物理发泡，即得具有空气微泡的水性干法握把革贝斯发泡浆料；
⑷将所述水性干法握把革贝斯发泡浆料均匀涂覆在50D或75D弹力针织布上，然后通过烘箱在100~140℃的范围内按分节梯度升温方式进行烘干，即得水性干法握把革贝斯，收卷备用；
⑸将所述印刷浆料通过印刷目数为60~150目的三版印刷机的印刷辊，将其印刷到所述水性干法握把革贝斯上，然后通过烘箱在100~140℃的范围内按分节梯度升温方式进行烘干，即得随温度变化调节抗湿滑性能的运动器材握把革。
2.如权利要求1所述的随温度变化调节抗湿滑性能的运动器材握把革的制备方法，其特征在于：所述步骤⑴中填充粉体为木质粉、滑石粉、重钙、轻钙中的一种或多种。
3.如权利要求1所述的随温度变化调节抗湿滑性能的运动器材握把革的制备方法，其特征在于：所述步骤⑴中水性聚氨酯树脂为芳香族异氰酸酯型水性聚氨酯树脂。
4.如权利要求1所述的随温度变化调节抗湿滑性能的运动器材握把革的制备方法，其特征在于：所述步骤⑴中分散剂为含颜料亲和基团的高分子型分散剂。
5.如权利要求1所述的随温度变化调节抗湿滑性能的运动器材握把革的制备方法，其特征在于：所述步骤⑴中发泡剂为阴离子表面活性剂类发泡剂。
6.如权利要求1所述的随温度变化调节抗湿滑性能的运动器材握把革的制备方法，其特征在于：所述步骤⑴中泡沫稳定剂为硅树脂聚醚乳液类稳泡剂。
7.如权利要求1所述的随温度变化调节抗湿滑性能的运动器材握把革的制备方法，其特征在于：所述步骤⑴中交联剂为封闭型异氰酸酯类交联剂。
8.如权利要求1所述的随温度变化调节抗湿滑性能的运动器材握把革的制备方法，其特征在于：所述步骤⑴中增稠剂为非离子缔合式增稠剂。
9.如权利要求1所述的随温度变化调节抗湿滑性能的运动器材握把革的制备方法，其特征在于：所述步骤⑵中消泡剂为改性有机硅类或矿物油类消泡剂。
10.如权利要求1所述的随温度变化调节抗湿滑性能的运动器材握把革的制备方法，其特征在于：所述步骤⑵中流平剂为聚醚改性硅氧烷共聚物流平剂。
11.如权利要求1所述的随温度变化调节抗湿滑性能的运动器材握把革的制备方法，其特征在于：所述步骤⑵中增稠剂为碱溶胀 型水性增稠剂。
CN201610238714.5A 2016-04-18 2016-04-18 随温度变化调节抗湿滑性能的运动器材握把革的制备方法 Expired - Fee Related CN105803815B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610238714.5A CN105803815B (zh) 2016-04-18 2016-04-18 随温度变化调节抗湿滑性能的运动器材握把革的制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610238714.5A CN105803815B (zh) 2016-04-18 2016-04-18 随温度变化调节抗湿滑性能的运动器材握把革的制备方法

Publications (2)

Publication Number Publication Date
CN105803815A CN105803815A (zh) 2016-07-27
CN105803815B true CN105803815B (zh) 2018-02-02

Family

ID=56460257

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610238714.5A Expired - Fee Related CN105803815B (zh) 2016-04-18 2016-04-18 随温度变化调节抗湿滑性能的运动器材握把革的制备方法

Country Status (1)

Country Link
CN (1) CN105803815B (zh)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106638016B (zh) * 2016-12-12 2019-09-13 合肥科天水性科技有限责任公司 一种水性聚氨酯装饰革及其制造方法
CN107401060B (zh) * 2017-07-05 2020-08-04 兰州科天新材料股份有限公司 一种具有抗压变高回弹性能的水性贝斯的制备方法
CN108995306A (zh) * 2018-08-22 2018-12-14 石狮龙祥制革有限公司 一种握把革及其加工方法
CN110218514A (zh) * 2019-04-26 2019-09-10 合肥科天水性科技有限责任公司 一种水性聚氨酯涂层剂及其制备方法和应用

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1311160C (en) * 1985-06-13 1992-12-08 Asok Sengupta Intersection markings
CN1064827C (zh) * 1993-11-10 2001-04-25 K.斯威斯公司 防滑鞋带及其制造方法
CN2278506Y (zh) * 1996-10-30 1998-04-15 翰柏企业股份有限公司 运动用具握把护带
US7347792B2 (en) * 2006-05-22 2008-03-25 Ben Huang Decorative golf club grip
CN201510702U (zh) * 2009-08-31 2010-06-23 赵国强 握把带
KR20110008146U (ko) * 2010-02-11 2011-08-18 차준형 안전 지팡이
US8800174B2 (en) * 2010-07-13 2014-08-12 Mission Product Holdings, Inc. Shoe soles for enhancing gripping with a smooth hard surface
CN102797165B (zh) * 2012-09-10 2014-11-12 合肥市科天化工有限公司 水性聚氨酯合成革贝斯的制备方法
CN104088160B (zh) * 2014-07-06 2016-03-30 嘉兴市博尔塑胶有限公司 一种篮球革
CN105064034A (zh) * 2015-08-04 2015-11-18 合肥市科天化工有限公司 一种合成革表面处理剂

Also Published As

Publication number Publication date
CN105803815A (zh) 2016-07-27

Similar Documents

Publication Publication Date Title
CN105803815B (zh) 随温度变化调节抗湿滑性能的运动器材握把革的制备方法
CN103835145B (zh) 一种环保防水透气服装革及其制备方法
CN104153241B (zh) Pvc发泡壁纸用高硬高韧耐刮擦pvc糊料及其制备方法
CN102409554B (zh) 一种基于水性聚氨酯的发泡合成革制造方法
CN104328690A (zh) 一种导热型聚氨酯合成革的生产方法
CN102747611A (zh) 一种环保箱包涂层面料的制备方法
CN105064034A (zh) 一种合成革表面处理剂
CN106118034A (zh) 一种干法服装革贝斯及其制备工艺
CN106012564A (zh) 一种水性干法发泡雨衣革及其制备方法
CN105951466A (zh) 水性触屏手套革及其制备方法
CN104499293B (zh) 一种防水透湿格栅印花织物及其制备方法
CN105926308A (zh) 一种石墨烯改性水性聚氨酯生产合成革的配方及工艺
CN102433765A (zh) 一种环境友好的半聚氨酯革的制造方法
CN103410009A (zh) 高透气型超细纤维聚氨酯绒面合成革、制备工艺及其制品
CN105672052A (zh) 仿磨砂发泡墙纸制备工艺
CN101914253B (zh) 聚氯乙烯组合物
CN101613451A (zh) 高含量水性聚氨酯乳液及制备方法
CN107401060A (zh) 一种具有抗压变高回弹性能的水性贝斯的制备方法
CN112760992B (zh) 一种耐磨篮球革及其制备方法
CN104371534A (zh) 一种木器用镭射辊涂亮光清面漆涂料及其制备方法
CN104775306B (zh) 一种环保透气耐水解鞋里革的制作方法
CN108546467B (zh) 一种高硬度耐磨水性木器实色漆及其制备方法
WO2016086717A1 (zh) 变色皮革的生产工艺
CN103657981A (zh) 麂皮绒皮膜涂层的处理方法
CN106544884A (zh) 一种仿真皮水性聚氨酯发泡合成革的配方及生产工艺

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180202

CF01 Termination of patent right due to non-payment of annual fee