CN105803782A - 一种纳米防水涂层材料及其制备方法 - Google Patents
一种纳米防水涂层材料及其制备方法 Download PDFInfo
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Abstract
本发明公开了一种纳米防水涂层材料及其制备方法，上述纳米防水涂层材料，由包含以下重量份的组分制成：聚丙烯酰胺30‑40份、低密度聚乙烯8‑14份、聚乙烯醇20‑30份、丙烯基苯基异戊烯醚11‑15份、聚丙烯腈纤维6‑8份、多聚氧化乙烯十八烯基醇醚5‑9份、聚乙烯蜡5‑7份、3‑亚甲基‑6（1‑甲乙基）‑环巳烯1‑3份、纳米氧化钡1‑2份、过氧化苯甲酰醋酸丁酯1‑2份和三甲铵乙酸盐0.5‑0.8份。本发明还提供了一种纳米防水涂层材料的制备方法。
Description
技术领域
本发明属于涂层材料领域，特别涉及一种纳米防水涂层材料及其制备方法。
背景技术
随着新材料技术的不断发展，需要具有各类特殊性能的纺织面料，例如具有阻燃、防静电、防油、防水等性能。
其中，防水纺织面料不仅要求具有良好的防水性能，而且需要具有耐久性、舒适性和可呼吸性。常用的防水类纺织物的原料大都由丙烯酸树脂类、聚氨酯类、聚氯乙烯、橡胶基树脂和聚四氟乙烯等组成。但是这些新型纺织材料的耐水压、耐洗牢度、耐磨牢度较差，水洗后各项性能更是不佳。
发明内容
针对上述的需求，本发明特别提供了一种纳米防水涂层材料及其制备方法。
本发明的目的可以通过以下技术方案实现：
一种纳米防水涂层材料，由包含以下重量份的组分制成：
聚丙烯酰胺 30-40份
低密度聚乙烯 8-14份，
聚乙烯醇 20-30份，
丙烯基苯基异戊烯醚 11-15份，
聚丙烯腈纤维 6-8份，
多聚氧化乙烯十八烯基醇醚 5-9份，
聚乙烯蜡 5-7份，
3-亚甲基-6（1-甲乙基）-环巳烯 1-3份，
纳米氧化钡 1-2份，
过氧化苯甲酰醋酸丁酯 1-2份，
三甲铵乙酸盐 0.5-0.8份。
所述组分还包括聚碳酸丁二酸亚丙酯0-2重量份。
所述组分还包括氯化石蜡0-1重量份。
所述纳米氧化钡的粒径为20-30纳米。
一种纳米防水涂层材料的制备方法，该方法包括以下步骤：
（1）称取聚丙烯酰胺 30-40重量份、低密度聚乙烯8-14重量份、聚乙烯醇20-30重量份、丙烯基苯基异戊烯醚11-15重量份、多聚氧化乙烯十八烯基醇醚5-9重量份、3-亚甲基-6（1-甲乙基）-环巳烯1-3重量份、过氧化苯甲酰醋酸丁酯1-2重量份、三甲铵乙酸盐0.5-0.8重量份、聚碳酸丁二酸亚丙酯0-2重量份和氯化石蜡0-1重量份，混合均匀，在80-90℃下，搅拌1-2小时；
（2）将步骤1的产物的pH调节到5.5-6，加入聚丙烯腈纤维6-8重量份、聚乙烯蜡5-7重量份和纳米氧化钡1-2重量份，加入高压均质机中混合20-40分钟，得到纳米防水涂层材料。
所述高压均质机中的混合条件为100-110℃、20-22MPa。
本发明与现有技术相比，其有益效果为：
（1）本发明制得的纳米防水涂层材料以聚丙烯酰胺为主要原料，通过加入低密度聚乙烯、聚乙烯醇、丙烯基苯基异戊烯醚、聚丙烯腈纤维、多聚氧化乙烯十八烯基醇醚、聚乙烯蜡、3-亚甲基-6（1-甲乙基）-环巳烯、纳米氧化钡、过氧化苯甲酰醋酸丁酯和三甲铵乙酸盐，制得的纳米防水涂层材料具有良好的附着力，且涂覆后表面平整，本发明的涂层材料具有良好的隔绝性能，能够隔绝空气和水，从而起到良好的保护织机表面的作用。
（2）本发明制得的纳米防水涂层材料具有良好的稳定性，能够在高热和高湿度环境下长期对织机表面起到保护作用。
（3）本发明的纳米防水涂层材料，其制备方法简单，易于工业化生产。
具体实施方式
以下结合实施例对本发明作进一步的说明。
实施例1
（1）称取聚丙烯酰胺 30kg、低密度聚乙烯8kg、聚乙烯醇20kg、丙烯基苯基异戊烯醚11kg、多聚氧化乙烯十八烯基醇醚5kg、3-亚甲基-6（1-甲乙基）-环巳烯1kg、过氧化苯甲酰醋酸丁酯1kg和三甲铵乙酸盐0.5kg，混合均匀，在80℃下，搅拌1小时；
（2）将步骤1的产物的pH调节到5.5，加入聚丙烯腈纤维6kg、聚乙烯蜡5kg和粒径20纳米的氧化钡1kg，加入高压均质机中100℃、20MPa下混合20分钟，得到纳米防水涂层材料。
制得纳米防水涂层材料的性能测试结果如表1所示。
实施例2
（1）称取聚丙烯酰胺 30kg、低密度聚乙烯8kg、聚乙烯醇20kg、丙烯基苯基异戊烯醚11kg、多聚氧化乙烯十八烯基醇醚5kg、3-亚甲基-6（1-甲乙基）-环巳烯1kg、过氧化苯甲酰醋酸丁酯1kg、三甲铵乙酸盐0.5kg、聚碳酸丁二酸亚丙酯2kg和氯化石蜡1kg，混合均匀，在80℃下，搅拌1小时；
（2）将步骤1的产物的pH调节到5.5，加入聚丙烯腈纤维6kg、聚乙烯蜡5kg和粒径20纳米的氧化钡1kg，加入高压均质机中100℃、20MPa下混合20分钟，得到纳米防水涂层材料。
制得纳米防水涂层材料的性能测试结果如表1所示。
实施例3
（1）称取聚丙烯酰胺 40kg、低密度聚乙烯14kg、聚乙烯醇30kg、丙烯基苯基异戊烯醚15kg、多聚氧化乙烯十八烯基醇醚9kg、3-亚甲基-6（1-甲乙基）-环巳烯3kg、过氧化苯甲酰醋酸丁酯2kg、三甲铵乙酸盐0.8kg、聚碳酸丁二酸亚丙酯2kg和氯化石蜡1kg，混合均匀，在90℃下，搅拌2小时；
（2）将步骤1的产物的pH调节到6，加入聚丙烯腈纤维8kg、聚乙烯蜡7kg和粒径30纳米的氧化钡2kg，加入高压均质机中110℃、22MPa下混合40分钟，得到纳米防水涂层材料。
制得纳米防水涂层材料的性能测试结果如表1所示。
实施例4
（1）称取聚丙烯酰胺 40kg、低密度聚乙烯14kg、聚乙烯醇30kg、丙烯基苯基异戊烯醚15kg、多聚氧化乙烯十八烯基醇醚9kg、3-亚甲基-6（1-甲乙基）-环巳烯1kg、过氧化苯甲酰醋酸丁酯2kg、三甲铵乙酸盐0.5kg、聚碳酸丁二酸亚丙酯2kg和氯化石蜡1kg，混合均匀，在90℃下，搅拌2小时；
（2）将步骤1的产物的pH调节到6，加入聚丙烯腈纤维8kg、聚乙烯蜡7kg和粒径30纳米的氧化钡2kg，加入高压均质机中110℃、22MPa下混合40分钟，得到纳米防水涂层材料。
制得纳米防水涂层材料的性能测试结果如表1所示。
实施例5
（1）称取聚丙烯酰胺 35kg、低密度聚乙烯12kg、聚乙烯醇25kg、丙烯基苯基异戊烯醚13kg、多聚氧化乙烯十八烯基醇醚7kg、3-亚甲基-6（1-甲乙基）-环巳烯2kg、过氧化苯甲酰醋酸丁酯1.5kg、三甲铵乙酸盐0.7kg、聚碳酸丁二酸亚丙酯1kg和氯化石蜡0.5kg，混合均匀，在85℃下，搅拌1.5小时；
（2）将步骤1的产物的pH调节到5.7，加入聚丙烯腈纤维7kg、聚乙烯蜡6kg和粒径25纳米的氧化钡1.5kg，加入高压均质机中105℃、21MPa下混合30分钟，得到纳米防水涂层材料。
制得纳米防水涂层材料的性能测试结果如表1所示。
对比例1
（1）称取聚丙烯酰胺 40kg、低密度聚乙烯14kg、聚乙烯醇30kg、丙烯基苯基异戊烯醚15kg、多聚氧化乙烯十八烯基醇醚9kg、过氧化苯甲酰醋酸丁酯2kg、三甲铵乙酸盐0.8kg、聚碳酸丁二酸亚丙酯2kg和氯化石蜡1kg，混合均匀，在90℃下，搅拌2小时；
（2）将步骤1的产物的pH调节到6，加入聚丙烯腈纤维8kg、聚乙烯蜡7kg和粒径30纳米的氧化钡2kg，加入高压均质机中110℃、22MPa下混合40分钟，得到纳米防水涂层材料。
制得纳米防水涂层材料的性能测试结果如表1所示。
对比例2
（1）称取聚丙烯酰胺 40kg、低密度聚乙烯14kg、聚乙烯醇30kg、丙烯基苯基异戊烯醚15kg、多聚氧化乙烯十八烯基醇醚9kg、3-亚甲基-6（1-甲乙基）-环巳烯3kg、过氧化苯甲酰醋酸丁酯2kg、聚碳酸丁二酸亚丙酯2kg和氯化石蜡1kg，混合均匀，在90℃下，搅拌2小时；
（2）将步骤1的产物的pH调节到6，加入聚丙烯腈纤维8kg、聚乙烯蜡7kg和粒径30纳米的氧化钡2kg，加入高压均质机中110℃、22MPa下混合40分钟，得到纳米防水涂层材料。
制得纳米防水涂层材料的性能测试结果如表1所示。
对比例3
（1）称取聚丙烯酰胺 40kg、低密度聚乙烯14kg、聚乙烯醇30kg、多聚氧化乙烯十八烯基醇醚9kg、3-亚甲基-6（1-甲乙基）-环巳烯3kg、过氧化苯甲酰醋酸丁酯2kg、三甲铵乙酸盐0.8kg、聚碳酸丁二酸亚丙酯2kg和氯化石蜡1kg，混合均匀，在90℃下，搅拌2小时；
（2）将步骤1的产物的pH调节到6，加入聚丙烯腈纤维8kg、聚乙烯蜡7kg和氧化钡2kg，加入高压均质机中110℃、22MPa下混合40分钟，得到防水涂层材料。
制得纳米防水涂层材料的性能测试结果如表1所示。
表1
| 测试项目 | 初始耐水压(KPa) | 30次水洗后耐水压(KPa) | 拉伸强度（MPa） |
| 实施例1 | 203 | 190 | 66 |
| 实施例2 | 210 | 198 | 67 |
| 实施例3 | 256 | 239 | 74 |
| 实施例4 | 247 | 220 | 72 |
| 实施例5 | 263 | 248 | 75 |
| 对比例1 | 160 | 85 | 33 |
| 对比例2 | 170 | 96 | 29 |
| 对比例3 | 165 | 104 | 35 |
本发明不限于这里的实施例，本领域技术人员根据本发明的揭示，不脱离本发明范畴所做出的改进和修改都应该在本发明的保护范围之内。
Claims (6)
1.一种纳米防水涂层材料，其特征在于，由包含以下重量份的组分制成：
聚丙烯酰胺 30-40份
低密度聚乙烯 8-14份，
聚乙烯醇 20-30份，
丙烯基苯基异戊烯醚 11-15份，
聚丙烯腈纤维 6-8份，
多聚氧化乙烯十八烯基醇醚 5-9份，
聚乙烯蜡 5-7份，
3-亚甲基-6（1-甲乙基）-环巳烯 1-3份，
纳米氧化钡 1-2份，
过氧化苯甲酰醋酸丁酯 1-2份，
三甲铵乙酸盐 0.5-0.8份。
2.根据权利要求1所述纳米防水涂层材料，其特征在于，所述组分还包括聚碳酸丁二酸亚丙酯0-2重量份。
3.根据权利要求1所述纳米防水涂层材料，其特征在于，所述组分还包括氯化石蜡0-1重量份。
4.根据权利要求1所述纳米防水涂层材料，其特征在于，所述纳米氧化钡的粒径为20-30纳米。
5.一种纳米防水涂层材料的制备方法，其特征在于，该方法包括以下步骤：
（1）称取聚丙烯酰胺 30-40重量份、低密度聚乙烯8-14重量份、聚乙烯醇20-30重量份、丙烯基苯基异戊烯醚11-15重量份、多聚氧化乙烯十八烯基醇醚5-9重量份、3-亚甲基-6（1-甲乙基）-环巳烯1-3重量份、过氧化苯甲酰醋酸丁酯1-2重量份、三甲铵乙酸盐0.5-0.8重量份、聚碳酸丁二酸亚丙酯0-2重量份和氯化石蜡0-1重量份，混合均匀，在80-90℃下，搅拌1-2小时；
（2）将步骤1的产物的pH调节到5.5-6，加入聚丙烯腈纤维6-8重量份、聚乙烯蜡5-7重量份和纳米氧化钡1-2重量份，加入高压均质机中混合20-40分钟，得到纳米防水涂层材料。
6.根据权利要求5所述的纳米防水涂层材料的制备方法，其特征在于，所述高压均质机中的混合条件为100-110℃、20-22MPa。
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106637978A (zh) * | 2016-12-15 | 2017-05-10 | 吴江市北厍盛源纺织品助剂厂 | 一种纺织上浆专用浆料及其制备方法 |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1068354A (zh) * | 1992-07-22 | 1993-01-27 | 张世生 | 复合防水粉及其配制方法 |
| KR20100024119A (ko) * | 2008-08-25 | 2010-03-05 | 코오롱패션머티리얼 (주) | 나노섬유를 이용한 방수원단 |
| CN104212249A (zh) * | 2014-09-24 | 2014-12-17 | 句容市给力包装制品厂 | 一种防水涂料 |
| CN104673028A (zh) * | 2013-11-27 | 2015-06-03 | 胡建辉 | 一种防水纳米水性涂料 |
| CN104893465A (zh) * | 2015-05-26 | 2015-09-09 | 康圣科 | 一种防紫外线纤维涂料 |
| CN104910812A (zh) * | 2015-05-26 | 2015-09-16 | 江苏高科物流科技股份有限公司 | 一种防水涂料 |
| CN104962155A (zh) * | 2015-07-14 | 2015-10-07 | 常州市盈顺电子有限公司 | 一种建筑用防水涂料 |
| CN104962116A (zh) * | 2015-05-29 | 2015-10-07 | 广东华兹卜化学工业有限公司 | 一种环境友好型水性纳米无机涂料及其制备方法 |
| CN105220265A (zh) * | 2015-10-20 | 2016-01-06 | 湖州博润实业有限公司 | 一种新型天然纤维纺织材料及其制备方法 |
| CN105400376A (zh) * | 2015-12-23 | 2016-03-16 | 青岛麦科三维高新技术有限公司 | 一种抗菌防水涂料 |
-
2016
- 2016-04-05 CN CN201610206285.3A patent/CN105803782A/zh active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1068354A (zh) * | 1992-07-22 | 1993-01-27 | 张世生 | 复合防水粉及其配制方法 |
| KR20100024119A (ko) * | 2008-08-25 | 2010-03-05 | 코오롱패션머티리얼 (주) | 나노섬유를 이용한 방수원단 |
| CN104673028A (zh) * | 2013-11-27 | 2015-06-03 | 胡建辉 | 一种防水纳米水性涂料 |
| CN104212249A (zh) * | 2014-09-24 | 2014-12-17 | 句容市给力包装制品厂 | 一种防水涂料 |
| CN104893465A (zh) * | 2015-05-26 | 2015-09-09 | 康圣科 | 一种防紫外线纤维涂料 |
| CN104910812A (zh) * | 2015-05-26 | 2015-09-16 | 江苏高科物流科技股份有限公司 | 一种防水涂料 |
| CN104962116A (zh) * | 2015-05-29 | 2015-10-07 | 广东华兹卜化学工业有限公司 | 一种环境友好型水性纳米无机涂料及其制备方法 |
| CN104962155A (zh) * | 2015-07-14 | 2015-10-07 | 常州市盈顺电子有限公司 | 一种建筑用防水涂料 |
| CN105220265A (zh) * | 2015-10-20 | 2016-01-06 | 湖州博润实业有限公司 | 一种新型天然纤维纺织材料及其制备方法 |
| CN105400376A (zh) * | 2015-12-23 | 2016-03-16 | 青岛麦科三维高新技术有限公司 | 一种抗菌防水涂料 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106637978A (zh) * | 2016-12-15 | 2017-05-10 | 吴江市北厍盛源纺织品助剂厂 | 一种纺织上浆专用浆料及其制备方法 |
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