CN105799280A - 一种耐磨复合布及其制备方法 - Google Patents
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Abstract
本发明公开了一种耐磨复合布及其制备方法，上述耐磨复合布，包括基层、耐磨层；所述基层由尼龙40wt%‑50wt%、壳聚糖纤维20wt%‑30wt%、棉纤维15wt%‑20wt%和亚麻纤维5wt%‑10wt%经纬交织而成；其中，经线为尼龙制成的纱线，纬线为壳聚糖纤维、棉纤维和亚麻纤维混纺制成的纱线；所述耐磨层通过热压方式覆盖在所述基层的表面。本发明还提供了一种耐磨复合布的耐磨层的制备方法。
Description
技术领域
本发明属于复合布材料领域，特别涉及一种耐磨复合布及其制备方法。
背景技术
随着纺织行业的不断发展，越来越多的企业将目光转向各种功能性布料的加工，以尽可能使产品的应用领域更加广泛，满足不同的需求。
尼龙(Nylon)学名为聚酰胺﹐聚酰胺纤维是第一个商业化高分子合成纤维制品。聚酰胺纤维最突出的优点为耐磨性较其它纤维优越﹐同时其弹性佳﹐其弹性回复率可与羊毛相近﹐且尼龙同聚酯纤维一样具有良好的耐腐性﹐不怕虫蛀﹐不怕发霉等优点。
但尼龙在拥有众多优点的同时，其在室外长时间受日照时，易变黄﹐强度下降﹐与聚酯相比其保型形性较差。
发明内容
针对上述的需求，本发明特别提供了一种耐磨复合布及其制备方法。
本发明的目的可以通过以下技术方案实现：
一种耐磨复合布，包括基层、耐磨层；所述基层由尼龙40wt%-50wt%、壳聚糖纤维20wt%-30wt%、棉纤维15wt%-20wt%和亚麻纤维5wt%-10wt%经纬交织而成；其中，经线为尼龙制成的纱线，纬线为壳聚糖纤维、棉纤维和亚麻纤维混纺制成的纱线；所述耐磨层通过热压方式覆盖在所述基层的表面。
所述耐磨层由包含以下重量份的组分制成：
聚甲基丙烯酸甲酯55-60份，
聚偏二氯乙烯 15-20份，
聚乙烯蜡 5-8份，
环氧丙烷丁基醚3-5份，
过氧化苯甲酰醋酸丁酯 2-4份，
褐煤蜡酸乙二酯 2-4份，
聚二甲基硅氧烷二季胺盐0.5-1份，
季戊四醇硬脂酸酯 0.5-1份，
N-甲基石斛碱 0.5-0.8份，
硼酸锌0.2-0.8份。
所述耐磨层还包括磷酸苯酯二缩水甘油酯0-0.5重量份。
一种耐磨复合布的耐磨层的制备方法，该方法包括以下步骤：
（1）称取聚甲基丙烯酸甲酯55-60重量份、聚偏二氯乙烯15-20重量份、聚乙烯蜡5-8重量份、环氧丙烷丁基醚3-5重量份、过氧化苯甲酰醋酸丁酯2-4重量份、褐煤蜡酸乙二酯2-4重量份、聚二甲基硅氧烷二季胺盐0.5-1重量份、季戊四醇硬脂酸酯0.5-1重量份、N-甲基石斛碱0.5-0.8重量份、硼酸锌0.2-0.8重量份和磷酸苯酯二缩水甘油酯0-0.5重量份；
（2）将上述组分混合均匀后，加热，保温2-4小时，延压成膜，自然冷却至室温，得到耐磨复合布的耐磨层。
步骤（2）中所述加热的温度为250-270℃。
本发明与现有技术相比，其有益效果为：
（1）本发明制得的耐磨复合布以尼龙、壳聚糖纤维、棉纤维和亚麻纤维座位基层材料，通过在基层材料表面热压有聚甲基丙烯酸甲酯、聚偏二氯乙烯、聚乙烯蜡、环氧丙烷丁基醚、过氧化苯甲酰醋酸丁酯、褐煤蜡酸乙二酯、聚二甲基硅氧烷二季胺盐、季戊四醇硬脂酸酯、N-甲基石斛碱、硼酸锌和磷酸苯酯二缩水甘油酯，制得的耐磨复合布具有良好的力学强度，具有良好的耐刮、耐磨性能，且具有较长的使用寿命。
（2）本发明的耐磨复合布具有良好的表面性能，具有良好的防水透气性。
（3）本发明的耐磨复合布，其制备方法简单，易于工业化生产。
具体实施方式
以下结合实施例对本发明作进一步的说明。
实施例1
耐磨层:
（1）称取聚甲基丙烯酸甲酯55kg、聚偏二氯乙烯15kg、聚乙烯蜡5kg、环氧丙烷丁基醚3kg、过氧化苯甲酰醋酸丁酯2kg、褐煤蜡酸乙二酯2kg、聚二甲基硅氧烷二季胺盐0.5kg、季戊四醇硬脂酸酯0.5kg、N-甲基石斛碱0.5kg和硼酸锌0.2kg；
（2）将上述组分混合均匀后，在250℃下保温4小时，延压成膜，自然冷却至室温，得到耐磨复合布的耐磨层。
制得耐磨复合布的耐磨层的性能测试结果如表1所示。
实施例2
耐磨层:
（1）称取聚甲基丙烯酸甲酯60kg、聚偏二氯乙烯20kg、聚乙烯蜡8kg、环氧丙烷丁基醚5kg、过氧化苯甲酰醋酸丁酯4kg、褐煤蜡酸乙二酯4kg、聚二甲基硅氧烷二季胺盐1kg、季戊四醇硬脂酸酯1kg、N-甲基石斛碱0.8kg、硼酸锌0.8kg和磷酸苯酯二缩水甘油酯0.5kg；
（2）将上述组分混合均匀后，在270℃下保温2小时，延压成膜，自然冷却至室温，得到耐磨复合布的耐磨层。
制得耐磨复合布的耐磨层的性能测试结果如表1所示。
实施例3
耐磨层:
（1）称取聚甲基丙烯酸甲酯58kg、聚偏二氯乙烯18kg、聚乙烯蜡7kg、环氧丙烷丁基醚4kg、过氧化苯甲酰醋酸丁酯3kg、褐煤蜡酸乙二酯3kg、聚二甲基硅氧烷二季胺盐0.8kg、季戊四醇硬脂酸酯0.8kg、N-甲基石斛碱0.6kg、硼酸锌0.5kg和磷酸苯酯二缩水甘油酯0.2kg；
（2）将上述组分混合均匀后，在260℃下保温3小时，延压成膜，自然冷却至室温，得到耐磨复合布的耐磨层。
制得耐磨复合布的耐磨层的性能测试结果如表1所示。
实施例4
耐磨复合布，包括基层、实施例1的耐磨层；其中基层由尼龙50wt%、壳聚糖纤维20wt%、棉纤维20wt%和亚麻纤维10wt%经纬交织而成；其中，经线为尼龙制成的纱线，纬线为壳聚糖纤维、棉纤维和亚麻纤维混纺制成的纱线；并将实施例1中得到的耐磨层通过热压方式覆盖在基层的表面，得到耐磨复合布。
制得耐磨复合布的性能测试结果如表1所示。
实施例5
耐磨复合布，包括基层、实施例2的耐磨层；其中基层由尼龙40wt%、壳聚糖纤维30wt%、棉纤维20wt%和亚麻纤维10wt%经纬交织而成；其中，经线为尼龙制成的纱线，纬线为壳聚糖纤维、棉纤维和亚麻纤维混纺制成的纱线；并将实施例2中得到的耐磨层通过热压方式覆盖在基层的表面，得到耐磨复合布。
制得耐磨复合布的性能测试结果如表1所示。
实施例6
耐磨复合布，包括基层、实施例3的耐磨层；其中基层由尼龙45wt%、壳聚糖纤维25wt%、棉纤维20wt%和亚麻纤维10wt%经纬交织而成；其中，经线为尼龙制成的纱线，纬线为壳聚糖纤维、棉纤维和亚麻纤维混纺制成的纱线；并将实施例3中得到的耐磨层通过热压方式覆盖在基层的表面，得到耐磨复合布。
制得耐磨复合布的性能测试结果如表1所示。
对比例1
（1）称取聚甲基丙烯酸甲酯60kg、聚偏二氯乙烯20kg、聚乙烯蜡8kg、环氧丙烷丁基醚5kg、过氧化苯甲酰醋酸丁酯4kg、聚二甲基硅氧烷二季胺盐1kg、季戊四醇硬脂酸酯1kg、N-甲基石斛碱0.8kg、硼酸锌0.8kg和磷酸苯酯二缩水甘油酯0.5kg；
（2）将上述组分混合均匀后，在270℃下保温2小时，延压成膜，自然冷却至室温，得到耐磨复合布的耐磨层；
（3）将上述得到的耐磨层通过热压方式覆盖在基层的表面，得到耐磨复合布；其中，基层由尼龙50wt%、壳聚糖纤维20wt%、棉纤维20wt%和亚麻纤维10wt%经纬交织而成；其中，经线为尼龙制成的纱线，纬线为壳聚糖纤维、棉纤维和亚麻纤维混纺制成的纱线。
制得耐磨复合布的性能测试结果如表1所示。
对比例2
（1）称取聚甲基丙烯酸甲酯60kg、聚偏二氯乙烯20kg、聚乙烯蜡8kg、环氧丙烷丁基醚5kg、过氧化苯甲酰醋酸丁酯4kg、褐煤蜡酸乙二酯4kg、季戊四醇硬脂酸酯1kg、N-甲基石斛碱0.8kg、硼酸锌0.8kg和磷酸苯酯二缩水甘油酯0.5kg；
（2）将上述组分混合均匀后，在270℃下保温2小时，延压成膜，自然冷却至室温，得到耐磨复合布的耐磨层；
（3）将上述得到的耐磨层通过热压方式覆盖在基层的表面，得到耐磨复合布；其中，基层由尼龙50wt%、壳聚糖纤维20wt%、棉纤维20wt%和亚麻纤维10wt%经纬交织而成；其中，经线为尼龙制成的纱线，纬线为壳聚糖纤维、棉纤维和亚麻纤维混纺制成的纱线。
制得耐磨复合布的性能测试结果如表1所示。
对比例3
（1）称取聚甲基丙烯酸甲酯60kg、聚偏二氯乙烯20kg、聚乙烯蜡8kg、环氧丙烷丁基醚5kg、过氧化苯甲酰醋酸丁酯4kg、褐煤蜡酸乙二酯4kg、聚二甲基硅氧烷二季胺盐1kg、季戊四醇硬脂酸酯1kg和磷酸苯酯二缩水甘油酯0.5kg；
（2）将上述组分混合均匀后，在270℃下保温2小时，延压成膜，自然冷却至室温，得到耐磨复合布的耐磨层；
（3）将上述得到的耐磨层通过热压方式覆盖在基层的表面，得到耐磨复合布；其中，基层由尼龙50wt%、壳聚糖纤维20wt%、棉纤维20wt%和亚麻纤维10wt%经纬交织而成；其中，经线为尼龙制成的纱线，纬线为壳聚糖纤维、棉纤维和亚麻纤维混纺制成的纱线。
制得耐磨复合布的性能测试结果如表1所示。
表1
| 测试项目 | 表面硬度 | 拉伸强度(MPa) |
| 实施例1 | H | 38 |
| 实施例2 | H | 42 |
| 实施例3 | H | 46 |
| 实施例4 | H | 78 |
| 实施例5 | H | 78 |
| 实施例6 | H | 81 |
| 对比例1 | B | 54 |
| 对比例2 | B | 50 |
| 对比例3 | B | 51 |
本发明不限于这里的实施例，本领域技术人员根据本发明的揭示，不脱离本发明范畴所做出的改进和修改都应该在本发明的保护范围之内。
Claims (5)
1.一种耐磨复合布，其特征在于，包括基层、耐磨层；所述基层由尼龙40wt%-50wt%、壳聚糖纤维20wt%-30wt%、棉纤维15wt%-20wt%和亚麻纤维5wt%-10wt%经纬交织而成；其中，经线为尼龙制成的纱线，纬线为壳聚糖纤维、棉纤维和亚麻纤维混纺制成的纱线；所述耐磨层通过热压方式覆盖在所述基层的表面。
2.根据权利要求1所述耐磨复合布，其特征在于，所述耐磨层由包含以下重量份的组分制成：
聚甲基丙烯酸甲酯55-60份，
聚偏二氯乙烯 15-20份，
聚乙烯蜡 5-8份，
环氧丙烷丁基醚3-5份，
过氧化苯甲酰醋酸丁酯 2-4份，
褐煤蜡酸乙二酯 2-4份，
聚二甲基硅氧烷二季胺盐0.5-1份，
季戊四醇硬脂酸酯 0.5-1份，
N-甲基石斛碱 0.5-0.8份，
硼酸锌0.2-0.8份。
3.根据权利要求2所述耐磨复合布，其特征在于，所述耐磨层还包括磷酸苯酯二缩水甘油酯0-0.5重量份。
4.一种耐磨复合布的耐磨层的制备方法，其特征在于，该方法包括以下步骤：
（1）称取聚甲基丙烯酸甲酯55-60重量份、聚偏二氯乙烯15-20重量份、聚乙烯蜡5-8重量份、环氧丙烷丁基醚3-5重量份、过氧化苯甲酰醋酸丁酯2-4重量份、褐煤蜡酸乙二酯2-4重量份、聚二甲基硅氧烷二季胺盐0.5-1重量份、季戊四醇硬脂酸酯0.5-1重量份、N-甲基石斛碱0.5-0.8重量份、硼酸锌0.2-0.8重量份和磷酸苯酯二缩水甘油酯0-0.5重量份；
（2）将上述组分混合均匀后，加热，保温2-4小时，延压成膜，自然冷却至室温，得到耐磨复合布的耐磨层。
5.根据权利要求4所述的耐磨复合布的的耐磨层制备方法，其特征在于，步骤（2）中所述加热的温度为250-270℃。
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| CN112522831A (zh) * | 2020-11-05 | 2021-03-19 | 浙江蒂彩工艺品股份有限公司 | 一种防折痕不霉变易保存生态棉布的生产方法 |
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