CN105802117A - 改性abs新能源蓄电池外壳专用材料及其制备方法 - Google Patents
改性abs新能源蓄电池外壳专用材料及其制备方法 Download PDFInfo
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- CN105802117A CN105802117A CN201610284314.8A CN201610284314A CN105802117A CN 105802117 A CN105802117 A CN 105802117A CN 201610284314 A CN201610284314 A CN 201610284314A CN 105802117 A CN105802117 A CN 105802117A
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- 239000000463 material Substances 0.000 title claims abstract description 110
- 238000002360 preparation method Methods 0.000 title claims abstract description 31
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 claims abstract description 14
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 12
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 11
- 239000002270 dispersing agent Substances 0.000 claims abstract description 9
- 239000004014 plasticizer Substances 0.000 claims abstract description 9
- 239000012745 toughening agent Substances 0.000 claims abstract description 9
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical class C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 45
- 238000003756 stirring Methods 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 4
- 229920000459 Nitrile rubber Polymers 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- VOWAEIGWURALJQ-UHFFFAOYSA-N Dicyclohexyl phthalate Chemical compound C=1C=CC=C(C(=O)OC2CCCCC2)C=1C(=O)OC1CCCCC1 VOWAEIGWURALJQ-UHFFFAOYSA-N 0.000 claims description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 2
- 229920005549 butyl rubber Polymers 0.000 claims description 2
- 239000003292 glue Substances 0.000 claims description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical group CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 2
- 235000019359 magnesium stearate Nutrition 0.000 claims description 2
- 150000008301 phosphite esters Chemical group 0.000 claims description 2
- 229920001897 terpolymer Polymers 0.000 claims description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical group [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 2
- 235000006708 antioxidants Nutrition 0.000 claims 4
- 238000000465 moulding Methods 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 10
- 230000007797 corrosion Effects 0.000 abstract description 10
- 230000003712 anti-aging effect Effects 0.000 abstract 1
- 239000002861 polymer material Substances 0.000 abstract 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 19
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 16
- 229920001707 polybutylene terephthalate Polymers 0.000 description 15
- 238000005336 cracking Methods 0.000 description 11
- 238000005452 bending Methods 0.000 description 10
- 238000001514 detection method Methods 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- 230000009467 reduction Effects 0.000 description 6
- 230000032683 aging Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000956 alloy Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 101100191138 Arabidopsis thaliana DOT4 gene Proteins 0.000 description 1
- -1 Polybutylene terephthalate Polymers 0.000 description 1
- 101100427348 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) UBP10 gene Proteins 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
Description
制备例1 | 制备例2 | 制备例3 | 制备例4 | 制备例5 | |
缺口冲击强度(kg·cm/cm) | 60 | 45 | 52 | 57 | 49 |
拉伸强度(Mpa) | 42 | 38 | 45 | 43 | 40 |
伸长率(%) | 28 | 30 | 26 | 25 | 31 |
弯曲强度(Mpa) | 125 | 118 | 129 | 127 | 123 |
耐腐蚀性 | 未开裂 | 未开裂 | 未开裂 | 未开裂 | 未开裂 |
耐寒性 | 未开裂 | 未开裂 | 未开裂 | 未开裂 | 未开裂 |
制备例1 | 实验组1 | 实验组2 | 实验组3 | |
ABS再生料 | 40 | 40 | 40 | 40 |
PETG再生料 | 15 | 30 | - | 25 |
PBT再生料 | 15 | - | 30 | 5 |
制备例1 | 实验组1 | 实验组2 | 实验组3 | 市售材料 | |
缺口冲击强度(kg·cm/cm) | 60 | 35 | 32 | 50 | 78 |
拉伸强度(Mpa) | 42 | 25 | 45 | 20 | 45 |
伸长率(%) | 28 | 50 | 15 | 25 | 17 |
弯曲强度(Mpa) | 125 | 65 | 122 | 100 | 124 |
耐腐蚀性 | 未开裂 | 开裂 | 开裂 | 未开裂 | 开裂 |
耐寒性 | 未开裂 | 未开裂 | 开裂 | 开裂 | 开裂 |
Claims (9)
Priority Applications (1)
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CN201610284314.8A CN105802117B (zh) | 2016-04-29 | 2016-04-29 | 改性abs新能源蓄电池外壳专用材料及其制备方法 |
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CN201610284314.8A CN105802117B (zh) | 2016-04-29 | 2016-04-29 | 改性abs新能源蓄电池外壳专用材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN105802117A true CN105802117A (zh) | 2016-07-27 |
CN105802117B CN105802117B (zh) | 2018-05-08 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106117954A (zh) * | 2016-07-28 | 2016-11-16 | 广东天保新材料有限责任公司 | 一种耐油、耐低温再生abs/pbt合金材料 |
CN110256823A (zh) * | 2019-06-20 | 2019-09-20 | 江苏金发科技新材料有限公司 | 经济型耐寒低气味玻纤增强复合材料及其制备方法 |
CN111961310A (zh) * | 2020-07-21 | 2020-11-20 | 界首市南都华宇电源有限公司 | 一种动力电池外壳材料 |
CN112646277A (zh) * | 2020-12-25 | 2021-04-13 | 盐城工学院 | 一种聚丙烯蓄电池外壳专用料及其制备方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102134369A (zh) * | 2011-02-24 | 2011-07-27 | 金发科技股份有限公司 | 一种abs/pet/共聚酯三元合金及其制备方法 |
CN102352088A (zh) * | 2011-09-07 | 2012-02-15 | 金发科技股份有限公司 | 一种热塑性无卤阻燃合金及其制备方法 |
CN102477208A (zh) * | 2010-11-30 | 2012-05-30 | 深圳市亚塑科技有限公司 | 耐蓄电池溶液腐蚀的阻燃abs复合材料及其制备方法 |
CN102558746A (zh) * | 2011-12-13 | 2012-07-11 | 天津金发新材料有限公司 | 一种热塑性无卤阻燃合金及其制备方法 |
CN103059498A (zh) * | 2012-12-24 | 2013-04-24 | 安徽科聚新材料有限公司 | 一种abs/pet复合材料及其制备方法 |
CN104341736A (zh) * | 2013-07-30 | 2015-02-11 | 青岛欣展塑胶有限公司 | 一种具有无卤阻燃的pet和abs合金材料 |
CN104672751A (zh) * | 2013-12-02 | 2015-06-03 | 青岛佳亿阳工贸有限公司 | 一种abs/pet复合材料及其制备方法 |
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2016
- 2016-04-29 CN CN201610284314.8A patent/CN105802117B/zh active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102477208A (zh) * | 2010-11-30 | 2012-05-30 | 深圳市亚塑科技有限公司 | 耐蓄电池溶液腐蚀的阻燃abs复合材料及其制备方法 |
CN102134369A (zh) * | 2011-02-24 | 2011-07-27 | 金发科技股份有限公司 | 一种abs/pet/共聚酯三元合金及其制备方法 |
CN102352088A (zh) * | 2011-09-07 | 2012-02-15 | 金发科技股份有限公司 | 一种热塑性无卤阻燃合金及其制备方法 |
CN102558746A (zh) * | 2011-12-13 | 2012-07-11 | 天津金发新材料有限公司 | 一种热塑性无卤阻燃合金及其制备方法 |
CN103059498A (zh) * | 2012-12-24 | 2013-04-24 | 安徽科聚新材料有限公司 | 一种abs/pet复合材料及其制备方法 |
CN104341736A (zh) * | 2013-07-30 | 2015-02-11 | 青岛欣展塑胶有限公司 | 一种具有无卤阻燃的pet和abs合金材料 |
CN104672751A (zh) * | 2013-12-02 | 2015-06-03 | 青岛佳亿阳工贸有限公司 | 一种abs/pet复合材料及其制备方法 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106117954A (zh) * | 2016-07-28 | 2016-11-16 | 广东天保新材料有限责任公司 | 一种耐油、耐低温再生abs/pbt合金材料 |
CN106117954B (zh) * | 2016-07-28 | 2018-11-09 | 广东天保新材料有限责任公司 | 一种耐油、耐低温再生abs/pbt合金材料 |
CN110256823A (zh) * | 2019-06-20 | 2019-09-20 | 江苏金发科技新材料有限公司 | 经济型耐寒低气味玻纤增强复合材料及其制备方法 |
CN111961310A (zh) * | 2020-07-21 | 2020-11-20 | 界首市南都华宇电源有限公司 | 一种动力电池外壳材料 |
CN112646277A (zh) * | 2020-12-25 | 2021-04-13 | 盐城工学院 | 一种聚丙烯蓄电池外壳专用料及其制备方法 |
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