CN105801177B - Light-weight environment-friendly imitates rock glaze ceramics and preparation process - Google Patents

Light-weight environment-friendly imitates rock glaze ceramics and preparation process Download PDF

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Publication number
CN105801177B
CN105801177B CN201610186288.5A CN201610186288A CN105801177B CN 105801177 B CN105801177 B CN 105801177B CN 201610186288 A CN201610186288 A CN 201610186288A CN 105801177 B CN105801177 B CN 105801177B
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light
friendly
overglaze
weight
imitates
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CN105801177A (en
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郑忠诚
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Fujian Dehua Shangpin Ceramics Co Ltd
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Fujian Dehua Shangpin Ceramics Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/963Surface properties, e.g. surface roughness

Abstract

The present invention relates to ceramic technology field, it is specifically related to a kind of light-weight environment-friendly and imitates rock glaze ceramics and preparation process.Light-weight environment-friendly imitates rock glaze ceramics, and it includes ceramic body, ground coat enamel and overglaze that light-weight environment-friendly, which imitates rock glaze ceramics: the ground coat enamel is made of feldspar, white clouds soil, kaolin, talcum, iron oxide, manganese oxide, pelelith, dry powder, sepiolite;Overglaze is made of feldspar, quartz, dry powder, zinc oxide, white clouds soil, limonite, medical stone, zirconium silicate, iron oxide.Light-weight environment-friendly imitate rock glaze ceramics be similar to common basalt and limestone, glaze paint sense of touch is coarse, gives thick mad, simple and unsophisticated visual experience, the green body quality that this kind of light-weight environment-friendly imitates rock glaze ceramics is light, it is combined with the appearance of rock glaze, forms distinct conflict, there is unique effect.Imitative rock glaze ceramics strength provided by the invention is high, good toughness, once-firing, and energy conservation and environmental protection reduces production cost.

Description

Light-weight environment-friendly imitates rock glaze ceramics and preparation process
Technical field
The present invention relates to ceramic technology field, it is specifically related to a kind of light-weight environment-friendly and imitates rock glaze ceramics and preparation process.
Background technique
With the progress of society and the development of science and technology, to environmental protection and also increasingly stronger, the crockery using safe consciousness Have many advantages, such as that wearability is good compared to plastic tableware, be readily cleaned, durable, but brittleness of ceramics is big, impact resistance ability is low, It is frangible and broken rear difficult to degrade, therefore be badly in need of developing a kind of raising toughness of environment-friendly type, it is easy the ceramics of degradation.
Light ceramics have the characteristics that plasticity is strong, ornamental value is high, environmentally friendly, safe, are the potteries in the world by favor Porcelain category.The light ceramics feature of environmental protection is good, different from other ceramics, it is embedded in degradable after soil, is a kind of environment-friendly materials, generally China, high ceramic whiteware, reinforcing porcelain etc. all do not have the characteristic of this respect;Furthermore light ceramics are using safe, due to white clouds porcelain be through High temperature biscuiting is crossed, the venomous injurants such as lead, cadmium inside ceramic product can evaporate to the maximum extent, to guarantee when in use Safety.
There are following two disadvantages for existing light china: first is that kiln burning twice is needed, second is that the quality of light china is more crisp, easily It is broken.If solve green body by the formula and manufacture craft of improvement reduces the gas largely to volatilize in sintering process, realize light The once-firing of matter ceramics, the intensity for improving ceramic product can reduce production cost, reduce energy consumption, improve Production of Ceramics The benefit of enterprise, with positive Social benefit and economic benefit.
Summary of the invention
In order to overcome the shortcomings in the prior art, the present invention provides a kind of light-weight environment-friendly and imitates rock glaze ceramics and preparation process.
To achieve the above object, The technical solution adopted by the invention is as follows:
Light-weight environment-friendly imitate rock glaze ceramics, which is characterized in that the light-weight environment-friendly imitate rock glaze ceramics include ceramic body, Ground coat enamel and overglaze: the ground coat enamel is prepared by the raw material of following parts by weight: feldspar 20-30, white clouds soil 20-30, kaolin 10- 20, talcum 5-10, iron oxide 5-10, manganese oxide 1-10, pelelith 5-10, dry powder 1-5, sepiolite 1-5;The overglaze by with The raw material of lower parts by weight is prepared: feldspar 20-30, quartz 15-30, dry powder 10-20, zinc oxide 10-20, white clouds soil 5- 10, limonite 5-10, medical stone 5-10, zirconium silicate 5-10, iron oxide 1-5.
Optimization, ground coat enamel is prepared by the raw material of following parts by weight: feldspar 28, white clouds soil 23, kaolin 12, talcum 6, iron oxide 10, manganese oxide 10, pelelith 5, dry powder 2, sepiolite 4.
Optimization, overglaze is prepared by the raw material of following parts by weight: feldspar 22, quartzy 20, dry powder 18, zinc oxide 11, white clouds soil 6, limonite 6, medical stone 8, zirconium silicate 7, iron oxide 2.
Optimization, ground coat enamel is prepared by the raw material of following parts by weight: feldspar 22, white clouds soil 27, kaolin 18, talcum 6, iron oxide 6, manganese oxide 5, pelelith 8, dry powder 3, sepiolite 5.
Optimization, overglaze is prepared by the raw material of following parts by weight: feldspar 25, quartzy 16, dry powder 12, zinc oxide 18, white clouds soil 8, limonite 5, medical stone 6, zirconium silicate 5, iron oxide 5.
Optimization, ground coat enamel is prepared by the raw material of following parts by weight: feldspar 25, white clouds soil 24, kaolin 20, talcum 8, iron oxide 7, manganese oxide 3, pelelith 6, dry powder 5, sepiolite 2.
Optimization, overglaze is prepared by the raw material of following parts by weight: feldspar 24, quartzy 17, dry powder 16, zinc oxide 10, white clouds soil 8, limonite 6, medical stone 7, zirconium silicate 8, iron oxide 4.
Light-weight environment-friendly imitates the preparation process of rock glaze ceramics, which is characterized in that imitates rock glazed pottery using above-mentioned light-weight environment-friendly Porcelain, the specific steps of which are as follows:
Step 1, according to ground coat enamel and the raw material of overglaze, ground coat enamel and overglaze are prepared respectively;
Step 2, light china green body is prepared;
Step 3, apply ground coat enamel on green body after light china body drying of making pottery;
Step 4, applying overglaze after ground coat enamel is adsorbed on green body;
Step 5, furnace heating-up, under reducing atmosphere is, firing temperature is 900-1050 DEG C;
Step 6, blow-on obtains light-weight environment-friendly and imitates rock glaze ceramics after cooling.
Further, ground coat enamel described in step 1 is milled into using wet bulb, wherein material: ball: water=1:2:0.7, the overglaze make It is milled into wet bulb, wherein material: ball: water=0.8:2:1.
Further, the glazing mode of ground coat enamel is leaching glaze, and the glazing mode of overglaze is to apply glaze.
By the above-mentioned description of this invention it is found that light-weight environment-friendly provided by the invention imitates rock glaze ceramics with caesious It is formed with amygdaloidal spot on background color and glazing effect russet and overglaze, is similar to and common basalt and lime Rock, glaze paint sense of touch is coarse, gives thick mad, simple and unsophisticated visual experience, this kind of light-weight environment-friendly imitates the green body quality of rock glaze ceramics Gently, it is combined with the appearance of rock glaze, forms distinct conflict, there is unique effect.Light-weight environment-friendly provided by the invention is imitative Rock glaze ceramics ground coat enamel and overglaze mutually merge, and double-deck glaze is greatly improved the intensity of light china, are added in ground coat enamel tool Mushy raw material such as pelelith, the sepiolite of strong adsorption, can infiltrate through in light china green body, to enhance the tough of light china Property, it is once-firing that the present invention, which provides light-weight environment-friendly and imitates rock glaze ceramics, and energy conservation and environmental protection reduces production cost.
Specific embodiment
Below by way of specific embodiment, the invention will be further described.
Light-weight environment-friendly imitates rock glaze ceramics, and it includes ceramic body, ground coat enamel and overglaze that the light-weight environment-friendly, which imitates rock glaze ceramics:
The ground coat enamel is prepared by the raw material of following parts by weight: feldspar 20-30, white clouds soil 20-30, kaolin 10-20, Talcum 5-10, iron oxide 5-10, manganese oxide 1-10, pelelith 5-10, dry powder 1-5, sepiolite 1-5;
The overglaze is prepared by the raw material of following parts by weight: feldspar 20-30, quartz 15-30, dry powder 10-20, Zinc oxide 10-20, white clouds soil 5-10, limonite 5-10, medical stone 5-10, zirconium silicate 5-10, iron oxide 1-5.
Specific embodiment one:
Light-weight environment-friendly imitates rock glaze ceramics, and the ground coat enamel is prepared by the raw material of following parts by weight: feldspar 28, white clouds soil 23, kaolin 12, talcum 6, iron oxide 10, manganese oxide 10, pelelith 5, dry powder 2, sepiolite 4;Overglaze is by following parts by weight Raw material be prepared: feldspar 22, quartzy 20, dry powder 18, zinc oxide 11, white clouds soil 6, limonite 6, medical stone 8, zirconium silicate 7, iron oxide 2.
Specific embodiment two:
Light-weight environment-friendly imitates rock glaze ceramics, and the ground coat enamel is prepared by the raw material of following parts by weight: feldspar 22, white clouds soil 27, kaolin 18, talcum 6, iron oxide 6, manganese oxide 5, pelelith 8, dry powder 3, sepiolite 5;Overglaze is by following parts by weight Raw material is prepared: feldspar 25, quartz 16, dry powder 12, zinc oxide 18, white clouds soil 8, limonite 5, medical stone 6, zirconium silicate 5, Iron oxide 5.
Specific embodiment three:
Light-weight environment-friendly imitates rock glaze ceramics, and the ground coat enamel is prepared by the raw material of following parts by weight: feldspar 25, white clouds soil 24, kaolin 20, talcum 8, iron oxide 7, manganese oxide 3, pelelith 6, dry powder 5, sepiolite 2;The overglaze is by following weight The raw material of part is prepared: feldspar 24, quartzy 17, dry powder 16, zinc oxide 10, white clouds soil 8, limonite 6, medical stone 7, silicic acid Zirconium 8, iron oxide 4.
Light-weight environment-friendly imitates the preparation process of rock glaze ceramics, which is characterized in that using in above-mentioned specific embodiment one to three Light-weight environment-friendly described in any one imitates rock glaze ceramics, the specific steps of which are as follows:
Step 1, according to ground coat enamel and the raw material of overglaze, ground coat enamel and overglaze are prepared respectively, ground coat enamel is milled into using wet bulb, wherein Material: ball: water=1:2:0.7, the overglaze are milled into using wet bulb, wherein material: ball: water=0.8:2:1;
Step 2, light china green body is prepared;
Step 3, apply ground coat enamel on green body after light china body drying of making pottery, the glazing mode of ground coat enamel is leaching glaze;
Step 4, applying overglaze after ground coat enamel is adsorbed on green body, the glazing mode of overglaze is to apply glaze;
Step 5, furnace heating-up, under reducing atmosphere is, firing temperature is 900-1050 DEG C;
Step 6, blow-on obtains light-weight environment-friendly and imitates rock glaze ceramics after cooling.
Imitating rock glaze ceramics using light-weight environment-friendly prepared by the above method has caesious background color and glaze russet Amygdaloidal spot is formed in face effect and overglaze, be similar to common basalt and limestone, glaze paint sense of touch is coarse, Give thick mad, simple and unsophisticated visual experience, the green body quality that this kind of light-weight environment-friendly imitates rock glaze ceramics is light, the appearance with rock glaze It combines, forms distinct conflict, there is unique effect.The present invention provides ground coat enamel and the face that light-weight environment-friendly imitates rock glaze ceramics Glaze mutually merges, and double-deck glaze is greatly improved the intensity of light china, and pelelith, the sea of strong adsorption are added in ground coat enamel tool Mushy raw material such as afrodite, can infiltrate through in light china green body, to enhance the toughness of light china;The present invention provides light-weight environment-friendly Imitative rock glaze ceramics are once-firing, and energy conservation and environmental protection reduces production cost.
It above are only several specific embodiments of the invention, but the design concept of the present invention is not limited to this, all benefits It is made a non-material change to the present invention, should all be belonged to behavior that violates the scope of protection of the present invention with this design.

Claims (9)

1. light-weight environment-friendly imitates rock glaze ceramics, which is characterized in that it includes ceramic body, bottom that the light-weight environment-friendly, which imitates rock glaze ceramics, Glaze and overglaze:
The ground coat enamel is prepared by the raw material of following parts by weight: feldspar 20-30, white clouds soil 20-30, kaolin 10-20, talcum 5-10, iron oxide 5-10, manganese oxide 1-10, pelelith 5-10, dry powder 1-5, sepiolite 1-5;
The overglaze is prepared by the raw material of following parts by weight: feldspar 20-30, quartz 15-30, dry powder 10-20, zinc oxide 10-20, white clouds soil 5-10, limonite 5-10, medical stone 5-10, zirconium silicate 5-10, iron oxide 1-5;
Preparation process is as follows:
Step 1, according to ground coat enamel and the raw material of overglaze, ground coat enamel and overglaze are prepared respectively;
Step 2, light china green body is prepared;
Step 3, apply ground coat enamel on green body after light china body drying of making pottery;
Step 4, apply overglaze again after ground coat enamel is adsorbed on green body;
Step 5, furnace heating-up, under reducing atmosphere, firing temperature is 900-1050 DEG C;
Step 6, blow-on obtains light-weight environment-friendly and imitates rock glaze ceramics after cooling.
2. light-weight environment-friendly according to claim 1 imitates rock glaze ceramics, which is characterized in that the ground coat enamel is by following parts by weight Raw material be prepared: feldspar 28, white clouds soil 23, kaolin 12, talcum 6, iron oxide 10, manganese oxide 10, pelelith 5, round trip flight Powder 2, sepiolite 4.
3. light-weight environment-friendly according to claim 1 or 2 imitates rock glaze ceramics, which is characterized in that the overglaze is by following heavy The raw material of amount part is prepared: feldspar 22, quartzy 20, dry powder 18, zinc oxide 11, white clouds soil 6, limonite 6, medical stone 8, silicon Sour zirconium 7, iron oxide 2.
4. light-weight environment-friendly according to claim 1 imitates rock glaze ceramics, which is characterized in that the ground coat enamel is by following parts by weight Raw material be prepared: feldspar 22, white clouds soil 27, kaolin 18, talcum 6, iron oxide 6, manganese oxide 5, pelelith 8, dry powder 3, sepiolite 5.
5. light-weight environment-friendly according to claim 1 or 4 imitates rock glaze ceramics, which is characterized in that the overglaze is by following heavy The raw material of amount part is prepared: feldspar 25, quartzy 16, dry powder 12, zinc oxide 18, white clouds soil 8, limonite 5, medical stone 6, silicon Sour zirconium 5, iron oxide 5.
6. light-weight environment-friendly according to claim 1 imitates rock glaze ceramics, which is characterized in that the ground coat enamel is by following parts by weight Raw material be prepared: feldspar 25, white clouds soil 24, kaolin 20, talcum 8, iron oxide 7, manganese oxide 3, pelelith 6, dry powder 5, sepiolite 2.
7. light-weight environment-friendly according to claim 1 or 6 imitates rock glaze ceramics, which is characterized in that the overglaze is by following heavy The raw material of amount part is prepared: feldspar 24, quartzy 17, dry powder 16, zinc oxide 10, white clouds soil 8, limonite 6, medical stone 7, silicon Sour zirconium 8, iron oxide 4.
8. light-weight environment-friendly according to claim 1 imitates rock glaze ceramics, it is characterised in that: ground coat enamel described in step 1 uses wet Ball milling is made, wherein material: ball: water=1:2:0.7, the overglaze are milled into using wet bulb, wherein material: ball: water=0.8:2:1.
9. light-weight environment-friendly according to claim 1 imitates rock glaze ceramics, it is characterised in that: the glazing mode of the ground coat enamel is Glaze is soaked, the glazing mode of overglaze is to apply glaze.
CN201610186288.5A 2016-03-29 2016-03-29 Light-weight environment-friendly imitates rock glaze ceramics and preparation process Active CN105801177B (en)

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CN106365448A (en) * 2016-08-26 2017-02-01 福建泉州顺美集团有限责任公司 Multi-void imitated stone glaze porcelain and preparation process
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CN107151151A (en) * 2017-04-20 2017-09-12 张绍明 A kind of manufacture craft of glazing volcano stone manufacture
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CN104860723A (en) * 2015-05-18 2015-08-26 青岛百千川海洋生态科技有限公司 Improved ceramic glaze
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Denomination of invention: Light environmental protection rock like glaze ceramics and its preparation technology

Effective date of registration: 20200824

Granted publication date: 20190201

Pledgee: Dehua County Rural Credit Cooperatives

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Registration number: Y2020980005284