CN105461284B - A kind of Antique Imitation Tiles - Google Patents

A kind of Antique Imitation Tiles Download PDF

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Publication number
CN105461284B
CN105461284B CN201510798839.9A CN201510798839A CN105461284B CN 105461284 B CN105461284 B CN 105461284B CN 201510798839 A CN201510798839 A CN 201510798839A CN 105461284 B CN105461284 B CN 105461284B
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antique imitation
imitation tiles
temperature
tiles
antique
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CN105461284A (en
Inventor
何成焱
何源
杨红军
朱超江
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Hubei Xingcheng Pottery Building Ltd By Share Ltd
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Hubei Xingcheng Pottery Building Ltd By Share Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/22Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions containing two or more distinct frits having different compositions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • C04B33/34Burning methods combined with glazing
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite

Abstract

The present invention discloses a kind of Antique Imitation Tiles, belongs to Ceramic Tiles technical field, the blank of Antique Imitation Tiles prepare as following weight percent by component:Bauxite 21%, bentonite 6%, stops preceding sand 11%, too Lee's sand 18%, Ruichang soil 12%, mica 15%, Hu sand head 10% at magnesium soil 7%;The firing temperature of Antique Imitation Tiles is preceding warm area:860 ~ 1015 DEG C of face temperature, 960 ~ 1010 DEG C of bottom temperature;Middle warm area:1035 ~ 1128 DEG C of face temperature, 1025 ~ 1120 DEG C of bottom temperature;High-temperature region:1125 ~ 1200 DEG C of face temperature, 1130 ~ 1205 DEG C of bottom temperature.The present invention by adjusting Antique Imitation Tiles blank component and proportioning, make the Antique Imitation Tiles of different size can be fired in same kiln, it avoids building multiple kilns, reduce investment amount, the present invention has many advantages, such as that color is good, hardness is high, water absorption rate is low, wearability is strong with the Antique Imitation Tiles that kiln is fired, and greatly improves the firing quality of Antique Imitation Tiles.

Description

A kind of Antique Imitation Tiles
Technical field
The present invention relates to Ceramic Tiles technical fields, and in particular to a kind of Antique Imitation Tiles.
Background technology
With the growth of national economy, the increasingly raising of people's living standard, the estheticism of people and to living environment Requirement also improve therewith, especially the requirement of Antique Imitation Tiles for being used for indoor and outdoor decoration is even more increasingly improved.It is existing modelled after an antique Brick achieves larger progress in appearance, color and luster, hardness, water absorption rate, abrasion resistance etc., simultaneously with the development of technique The acquirement of above-mentioned progress also leads to the huge investment amount of the production requirement of Antique Imitation Tiles, and production cost also remains high, moreover, existing Some Antique Imitation Tiles still remain deficiency in terms of color, quality.Therefore it provides a kind of low cost that color is good, quality is high Antique Imitation Tiles become urgent problem to be solved at this stage.
Invention content
It is an object of the invention to overcome above-mentioned technical deficiency, a kind of Antique Imitation Tiles are proposed, solve Antique Imitation Tiles in the prior art Color is poor, the technical issues of quality low production cost is high.
To reach above-mentioned technical purpose, technical scheme of the present invention provides a kind of Antique Imitation Tiles, the fired including same kiln The blank of one specification Antique Imitation Tiles and the second specification Antique Imitation Tiles, the first specification Antique Imitation Tiles and the second specification Antique Imitation Tiles is by as follows Components in weight percent is prepared:Bauxite 21%, magnesium soil 7%, bentonite 6%, stop before sand 11%, too Lee's sand 18%, Ruichang soil 12%, Mica 15%, Hu sand head 10%;Wherein, the Antique Imitation Tiles are preceding warm area in the firing temperature in kiln:860 ~ 1015 DEG C of face temperature, 960 ~ 1010 DEG C of bottom temperature;Middle warm area:1035 ~ 1128 DEG C of face temperature, 1025 ~ 1120 DEG C of bottom temperature;High-temperature region:1125 ~ 1200 DEG C of face temperature, 1130 ~ 1205 DEG C of bottom temperature.
Preferably, the glaze material of the first specification Antique Imitation Tiles and the second specification Antique Imitation Tiles group as following weight percent Part is prepared:801 frits 3%, 815 frits 16%, kaolin 8%, lithium feldspar 30%, talcum 3%, calcite 8%, zinc oxide 2%, potassium are long Stone 4%, barium carbonate 2%, earth burning 16%, zirconium silicate 8%;Wherein, every 100 grams of glaze materials add 0.75 gram of sodium tripolyphosphate, methyl 0.35 Gram.
Preferably, the ground-coat enamel material of the first specification Antique Imitation Tiles as following weight percent prepare by component:Kaolin 8%, lithium Feldspar 17%, talcum 40%, quartz 6%, earth burning 20%, zirconium silicate 6%, high boron powder 3%, and every 100 grams of ground-coat enamel material addition tripolyphosphate 0.4 gram of sodium, 0.2 gram of methyl.
Preferably, the ground-coat enamel material of the second specification Antique Imitation Tiles as following weight percent prepare by component:Kaolin 8%, lithium Feldspar 18%, talcum 51%, aluminium oxide 3%, quartz 6%, earth burning 8%, zirconium silicate 6%, and every 100 grams of ground-coat enamel material addition sodium tripolyphosphate 0.4 gram, 0.2 gram of methyl.
Preferably, the size into parison brick of the first specification Antique Imitation Tiles and the second specification Antique Imitation Tiles is respectively 657* 657mm and 867*867mm.
Preferably, the Antique Imitation Tiles are alternately arranged by the first specification Antique Imitation Tiles and the second specification Antique Imitation Tiles into burning in kiln System.
Preferably, the first specification Antique Imitation Tiles are often arranged as three pieces, often arrange the second specification Antique Imitation Tiles as two panels.
Preferably, the Antique Imitation Tiles further include colouring matter, and the colouring matter includes red material and white material, the red material and white material Weight percent be 20 ~ 40%:80~60%.
Compared with prior art, beneficial effects of the present invention include:By adjusting the blank component and proportioning of Antique Imitation Tiles, make The the first specification Antique Imitation Tiles and the second specification Antique Imitation Tiles of different size can be fired in same kiln, avoid and build multiple kilns Stove reduces investment amount, and the present invention is respectively provided with the first specification Antique Imitation Tiles of kiln firing and the second specification Antique Imitation Tiles The advantages that color is good, hardness is high, water absorption rate is low, wearability is strong greatly improves the firing quality of Antique Imitation Tiles.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to Limit the present invention.
The embodiment provides a kind of Antique Imitation Tiles, the first specification Antique Imitation Tiles fired including same kiln and the second rule The blank of lattice Antique Imitation Tiles, the first specification Antique Imitation Tiles and the second specification Antique Imitation Tiles prepare as following weight percent by component: Bauxite 21%, bentonite 6%, stops preceding sand 11%, too Lee's sand 18%, Ruichang soil 12%, mica 15%, Hu sand head 10% at magnesium soil 7%; Wherein, the Antique Imitation Tiles are preceding warm area in the firing temperature in kiln:860 ~ 1015 DEG C of face temperature, 960 ~ 1010 DEG C of bottom temperature;Medium temperature Area:1035 ~ 1128 DEG C of face temperature, 1025 ~ 1120 DEG C of bottom temperature;High-temperature region:1125 ~ 1200 DEG C of face temperature, 1130 ~ 1205 DEG C of bottom temperature.
The present embodiment makes the first specification Antique Imitation Tiles and of different size by adjusting the blank component and proportioning of Antique Imitation Tiles Two specification Antique Imitation Tiles can be fired in same kiln, avoid and build multiple kilns, reduce investment amount, and the present invention is same The the first specification Antique Imitation Tiles and the second specification Antique Imitation Tiles that kiln is fired are respectively provided with that color is good, hardness is high, water absorption rate is low, wearability The advantages that strong, greatly improves the firing quality of Antique Imitation Tiles.
The specific preparation method of above-mentioned Antique Imitation Tiles is as follows:
(1)Component prepares blank as following weight percent:Bauxite 21%, bentonite 6%, stops preceding sand at magnesium soil 7% 11%th, too Lee's sand 18%, Ruichang soil 12%, mica 15%, Hu sand head 10%;
(2)By above-mentioned blank ball milling into slurry, then slurry, which is sieved, and passes through spray tower is made powder;
(3)By step(2)Powder is made, compression moulding in press is delivered to behind in feed bin aging 2 ~ 3 days, be molded specification Respectively the first specification 657*657mm and the second specification 867*867mm;
(4)The base of processing, the first specification and the second specification is dried in the base brick of above-mentioned compression moulding in dry kiln Layer arrangement above and below brick;
(5)Glazing is carried out to dried base brick by different fancy and stamp is handled;
(6)Glazing and stamp treated base brick are alternately arranged by the first specification and the second specification into firing in kiln Into Antique Imitation Tiles, the firing temperature of kiln is preceding warm area:860 ~ 1015 DEG C of face temperature, 960 ~ 1010 DEG C of bottom temperature;Middle warm area:Face temperature 1035 ~ 1128 DEG C, 1025 ~ 1120 DEG C of bottom temperature;High-temperature region:1125 ~ 1200 DEG C of face temperature, 1130 ~ 1205 DEG C of bottom temperature;
(7)By step(6)The kiln brick of the kiln brick progress edging processing of firing, the first specification and the second specification is worn into respectively 600*600mm and 800*800mm carries out sorting packaging after edging processing.
The present invention by adjusting blank component and proportioning, and fire when adjustment fire temperature and glaze surface expansion system Number, makes the base brick of different size can fire under the same conditions as qualified Antique Imitation Tiles;The present invention is burnt in same kiln Two kinds of Antique Imitation Tiles of different size processed, save investment, reduce production cost, and the Antique Imitation Tiles for the two kinds of specifications fired The advantages that color is good, hardness is high, water absorption rate is low, wearability is strong is respectively provided with, greatly improves the firing quality of Antique Imitation Tiles.
The present embodiment is preferably by step(5)In the glaze material of the first specification and the second specification base brick press following weight percent It is prepared than component:801 frits 3%, 815 frits 16%, kaolin 8%, lithium feldspar 30%, talcum 3%, calcite 8%, zinc oxide 2%, Potassium feldspar 4%, barium carbonate 2%, earth burning 16%, zirconium silicate 8%;Wherein, every 100 grams of glaze materials add 0.75 gram of sodium tripolyphosphate, methyl 0.35 gram.Further, the step(5)In the first specification base brick ground-coat enamel material as following weight percent component prepare:It is high Ridge soil 8%, lithium feldspar 17%, talcum 40%, quartz 6%, earth burning 20%, zirconium silicate 6%, high boron powder 3%, and every 100 grams of ground-coat enamel material add 0.4 gram of sodium tripolyphosphate, 0.2 gram of methyl.And the step(5)In the second specification base brick ground-coat enamel material as following weight percent Component is prepared:Kaolin 8%, lithium feldspar 18%, talcum 51%, aluminium oxide 3%, quartz 6%, earth burning 8%, zirconium silicate 6%, and every 100 grams 0.4 gram of sodium tripolyphosphate of ground-coat enamel material addition, 0.2 gram of methyl.By the setting of above-mentioned ground-coat enamel material and glaze material, be conducive to what is fired Antique Imitation Tiles have better shrinking percentage and flatness.
It is of different sizes due to the first specification and the second specification base brick, it is distributed density between the base bricks of inevitable different rows Inconsistent, in order to reduce the density difference between base brick, the present embodiment is in step(7)In often arrange base brick and be set as 3 first Specification or 2 second specifications.But still remaining can cause temperature, air-flow to fluctuate up and down, stability is poor, easily leads base brick and fired Its degree of deformation is unable to control in journey, therefore the zero-pressure position of the present embodiment adjustment kiln is reset, and high-temperature region is extended 1 ~ 1.5 Times.
In order to improve the aesthetics of the Antique Imitation Tiles of firing, the step of the present embodiment(2)It further includes and mixes slurry and colouring matter Coloring is closed, the colouring matter includes red material and white material, and the red material and the weight percent expected in vain are 20 ~ 40%:80~60%.
The specific embodiment of present invention described above, is not intended to limit the scope of the present invention..Any basis The various other corresponding changes and deformation that the technical concept of the present invention is made, should be included in the guarantor of the claims in the present invention In the range of shield.

Claims (5)

1. a kind of Antique Imitation Tiles, which is characterized in that including the first specification Antique Imitation Tiles and the second specification Antique Imitation Tiles that same kiln is fired, institute State the blank component preparation as following weight percent of the first specification Antique Imitation Tiles and the second specification Antique Imitation Tiles:Bauxite 21%, magnesium Matter soil 7%, bentonite 6% stop preceding sand 11%, too Lee's sand 18%, Ruichang soil 12%, mica 15%, Hu sand head 10%;Wherein, it is described modelled after an antique Brick is preceding warm area in the firing temperature in kiln:860 ~ 1015 DEG C of face temperature, 960 ~ 1010 DEG C of bottom temperature;Middle warm area:Face temperature 1035 ~ 1128 DEG C, 1025 ~ 1120 DEG C of bottom temperature;High-temperature region:1125 ~ 1200 DEG C of face temperature, 1130 ~ 1205 DEG C of bottom temperature.
2. Antique Imitation Tiles according to claim 1, which is characterized in that the first specification Antique Imitation Tiles and the second specification Antique Imitation Tiles The size into parison brick be respectively 657*657mm and 867*867mm.
3. Antique Imitation Tiles according to claim 2, which is characterized in that the Antique Imitation Tiles are by the first specification Antique Imitation Tiles and the second rule Lattice Antique Imitation Tiles are alternately arranged into firing in kiln.
4. Antique Imitation Tiles according to claim 3, which is characterized in that often arrange the first specification Antique Imitation Tiles as three pieces, often arrange The second specification Antique Imitation Tiles are two panels.
5. Antique Imitation Tiles according to claim 4, which is characterized in that the Antique Imitation Tiles further include colouring matter, the colouring matter Including red material and white material, the red material and the weight percent expected in vain are 20 ~ 40%:80~60%.
CN201510798839.9A 2015-11-19 2015-11-19 A kind of Antique Imitation Tiles Active CN105461284B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108046603B (en) * 2017-12-18 2020-07-31 广东永航新材料实业股份有限公司 Method for manufacturing one-type ceramic tiles
CN108373320A (en) * 2018-03-14 2018-08-07 合肥尚涵装饰工程有限公司 A kind of energy saving and environment friendly Antique Imitation Tiles and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87100421A (en) * 1987-01-24 1988-08-03 张晶庭 Glazed coloured brick and tile and manufacture method thereof
CN101224980A (en) * 2008-01-28 2008-07-23 关锐华 Method for producing ceramic surface archaizing brick
CN102795847A (en) * 2012-08-21 2012-11-28 湖北兴成建陶有限公司 Production method for manufacturing full-body archaized tile by one-time torch firing of multiple toner
CN103044009A (en) * 2012-12-26 2013-04-17 李建顺 Archaized bricks produced by using polished brick factory waste materials and preparation method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6743383B2 (en) * 2002-03-26 2004-06-01 Council Of Scientific And Industrial Research Process for the production of ceramic tiles

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87100421A (en) * 1987-01-24 1988-08-03 张晶庭 Glazed coloured brick and tile and manufacture method thereof
CN101224980A (en) * 2008-01-28 2008-07-23 关锐华 Method for producing ceramic surface archaizing brick
CN102795847A (en) * 2012-08-21 2012-11-28 湖北兴成建陶有限公司 Production method for manufacturing full-body archaized tile by one-time torch firing of multiple toner
CN103044009A (en) * 2012-12-26 2013-04-17 李建顺 Archaized bricks produced by using polished brick factory waste materials and preparation method thereof

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