CN111204976A - Imitated basalt glaze and preparation method thereof - Google Patents
Imitated basalt glaze and preparation method thereof Download PDFInfo
- Publication number
- CN111204976A CN111204976A CN202010034580.1A CN202010034580A CN111204976A CN 111204976 A CN111204976 A CN 111204976A CN 202010034580 A CN202010034580 A CN 202010034580A CN 111204976 A CN111204976 A CN 111204976A
- Authority
- CN
- China
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- parts
- glaze
- mixture
- basalt
- blank
- Prior art date
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- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 34
- 239000000463 material Substances 0.000 claims abstract description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 9
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims abstract description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 5
- 229910052656 albite Inorganic materials 0.000 claims abstract description 5
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052796 boron Inorganic materials 0.000 claims abstract description 5
- 239000000049 pigment Substances 0.000 claims abstract description 5
- 239000010453 quartz Substances 0.000 claims abstract description 5
- 229910052642 spodumene Inorganic materials 0.000 claims abstract description 5
- 239000011787 zinc oxide Substances 0.000 claims abstract description 5
- 229910000514 dolomite Inorganic materials 0.000 claims abstract description 4
- 239000010459 dolomite Substances 0.000 claims abstract description 4
- 239000002689 soil Substances 0.000 claims abstract description 4
- 239000002002 slurry Substances 0.000 claims description 21
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000010304 firing Methods 0.000 claims description 6
- 238000007873 sieving Methods 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 238000000498 ball milling Methods 0.000 claims description 3
- 229910052681 coesite Inorganic materials 0.000 claims description 3
- 229910052593 corundum Inorganic materials 0.000 claims description 3
- 229910052906 cristobalite Inorganic materials 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 229910052682 stishovite Inorganic materials 0.000 claims description 3
- 229910052905 tridymite Inorganic materials 0.000 claims description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 6
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 239000007788 liquid Substances 0.000 abstract description 3
- 230000007246 mechanism Effects 0.000 abstract description 3
- 238000010791 quenching Methods 0.000 abstract description 2
- 230000000171 quenching effect Effects 0.000 abstract description 2
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/18—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing free metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Structural Engineering (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses an imitation basalt glaze and a preparation method thereof, wherein glaze used for the imitation basalt glaze comprises overglaze and ground glaze; the ground glaze comprises the following components in parts by mass: potassium feldspar: 12 parts of (1); aluminum powder: 2 parts of (1); the blank mud comprises the following steps: 85 parts of a mixture; black pigment: 7 parts; iron oxide red: 3.2 parts of a mixture; the overglaze comprises the following components in parts by mass: potassium feldspar: 20 parts of (1); quartz: 8 parts of a mixture; albite: 20 parts of (1); barium carbonate: 4 parts of a mixture; calcite: 10 parts of (A); spodumene: 5 parts of a mixture; aluminum powder: 9 parts of (1); zinc oxide: 4 parts of a mixture; dolomite: 5 parts of a mixture; boundary plate mud: 4 parts of a mixture; guizhou soil: 3 parts of a mixture; high boron frit: 11 parts. The method adopts a volatile matter brewing mechanism added in the ground glaze, adds a large amount of volatile materials to form basalt type brewing in a high-temperature state, simultaneously keeps the high viscosity of molten liquid by the surface glaze, and rapidly enters a quenching state to be solidified in the reaction process, so that the basalt effect is formed.
Description
Technical Field
The invention relates to an imitation basalt glaze and a preparation method thereof.
Background
At present, the conventional imitation basalt effect is to decorate on an imitation blank, but the blank is separately processed, the material cost of waste of the blank is high, and the large-scale production is not facilitated; in addition, the existing glaze has single decorative effect.
Disclosure of Invention
The technical problem to be solved by the invention is to overcome the defects of the prior art and provide an imitation basalt glaze, which adopts a mechanism of adding volatile substances into a ground glaze to brew, adds a large amount of volatile materials to form basalt type brewing in a high-temperature state, simultaneously keeps high viscosity of molten liquid by a cover glaze, and rapidly enters a quenching state to be solidified in a reaction process to form a basalt effect.
The technical scheme for solving the technical problem of the invention is as follows: an imitation basalt glaze, wherein the glaze used in the imitation basalt glaze comprises overglaze and ground glaze; wherein,
the ground coat comprises the following components in parts by mass:
potassium feldspar: 12 parts of (1);
aluminum powder: 2 parts of (1);
the blank mud comprises the following steps: 85 parts of a mixture;
black pigment: 7 parts;
iron oxide red: 3.2 parts.
The overglaze comprises the following components in parts by mass:
potassium feldspar: 20 parts of (1);
quartz: 8 parts of a mixture;
albite: 20 parts of (1);
barium carbonate: 4 parts of a mixture;
calcite: 10 parts of (A);
spodumene: 5 parts of a mixture;
aluminum powder: 9 parts of (1);
zinc oxide: 4 parts of a mixture;
dolomite: 5 parts of a mixture;
boundary plate mud: 4 parts of a mixture;
guizhou soil: 3 parts of a mixture;
high boron frit: 11 parts.
Further, the blank mud comprises the following components in percentage by mass:
SiO2：68.04％；Al2O3：20.42％；Fe2O3：1.31％；TiO2：0.18％；CaO：0.2％；MgO：0.26％；K2O：1.33％；Na2o: 2.39 percent; ignition decrement: 5.87 percent.
The invention also provides a preparation method of the imitation basalt glaze, which comprises the following steps:
respectively preparing a ground glaze slurry and a surface glaze slurry;
the preparation processes of the ground glaze slurry and the surface glaze slurry are respectively as follows: preparing the components according to the mass parts of the components; ball milling is carried out after material preparation; sieving the ball-milled material; sieving the materials to prepare glaze slurry;
taking a clean blank, applying a base glaze on the blank by adopting base glaze slurry, and then applying a surface glaze on the blank by using surface glaze slurry;
and firing the glazed blank in a kiln at 1215 ℃, wherein the heat preservation time is required to be more than 20 minutes in the firing process.
After the technical scheme is adopted, a volatile matter brewing mechanism is added in the ground glaze, a large amount of volatile materials are added, basalt type brewing is formed in a high-temperature state, meanwhile, the overglaze keeps high viscosity of molten liquid, and the overglaze is rapidly quenched in the reaction process and enters a rapid cooling state for solidification, so that a basalt effect is formed.
Detailed Description
The invention provides an imitation basalt glaze and a preparation method thereof, and a person skilled in the art can appropriately improve process parameters by referring to the content. It is expressly intended that all such similar substitutes and modifications apparent to those skilled in the art are deemed to be within the scope of the invention. While the methods and applications of this invention have been described in terms of preferred embodiments, it will be apparent to those of ordinary skill in the art that variations and modifications in the methods and applications described herein, as well as other suitable variations and combinations, may be made to implement and use the techniques of this invention without departing from the spirit and scope of the invention.
An imitation basalt glaze, wherein the glaze used in the imitation basalt glaze comprises overglaze and ground glaze; wherein,
the ground coat comprises the following components in parts by mass:
potassium feldspar: 12 parts of (1);
aluminum powder: 2 parts of (1);
the blank mud comprises the following steps: 85 parts of a mixture;
black pigment: 7 parts;
iron oxide red: 3.2 parts.
The overglaze comprises the following components in parts by mass:
potassium feldspar: 20 parts of (1);
quartz: 8 parts of a mixture;
albite: 20 parts of (1);
barium carbonate: 4 parts of a mixture;
calcite: 10 parts of (A);
spodumene: 5 parts of a mixture;
aluminum powder: 9 parts of (1);
zinc oxide: 4 parts of a mixture;
dolomite: 5 parts of a mixture;
boundary plate mud: 4 parts of a mixture;
guizhou soil: 3 parts of a mixture;
high boron frit: 11 parts.
The blank mud comprises the following components in percentage by mass:
SiO2：68.04％；Al2O3：20.42％；Fe2O3：1.31％；TiO2：0.18％；CaO：0.2％；MgO：0.26％；K2O：1.33％；Na2o: 2.39 percent; ignition decrement: 5.87 percent.
In this example, potassium feldspar was from the state, aluminum powder was from the east of the mountain, black pigment was from the south of the lake, iron red was from the state of tidal, quartz was from the yang of the mountain, albite was from the yang of the zhong, calcite was from the cantonese, spodumene was from australia, zinc oxide was from the sea, boundary plate mud was from the yang of the zhong, high boron frit was commercially available from the east of the mountain.
The preparation method of the imitation basalt glaze comprises the following steps:
respectively preparing a ground glaze slurry and a surface glaze slurry;
the preparation processes of the ground glaze slurry and the surface glaze slurry are respectively as follows: preparing the components according to the mass parts of the components; ball milling is carried out after material preparation; sieving the ball-milled material; sieving the materials to prepare glaze slurry;
taking a clean blank, applying a base glaze on the blank by adopting base glaze slurry, and then applying a surface glaze on the blank by using surface glaze slurry;
and firing the glazed blank in a kiln at 1215 ℃, wherein the heat preservation time is required to be more than 20 minutes in the firing process.
Observation shows that the imitated basalt glaze prepared by the embodiment can show a good imitated basalt effect, and meets design expectations.
The above-mentioned embodiments are intended to illustrate the objects, technical solutions and advantages of the present invention in further detail, and it should be understood that the above-mentioned embodiments are only exemplary embodiments of the present invention, and are not intended to limit the present invention, and any modifications, equivalents, improvements and the like made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (3)
1. The imitation basalt glaze is characterized in that the glaze used by the imitation basalt glaze comprises overglaze and ground glaze; wherein,
the ground coat comprises the following components in parts by mass:
potassium feldspar: 12 parts of (1);
aluminum powder: 2 parts of (1);
the blank mud comprises the following steps: 85 parts of a mixture;
black pigment: 7 parts;
iron oxide red: 3.2 parts of a mixture;
the overglaze comprises the following components in parts by mass:
potassium feldspar: 20 parts of (1);
quartz: 8 parts of a mixture;
albite: 20 parts of (1);
barium carbonate: 4 parts of a mixture;
calcite: 10 parts of (A);
spodumene: 5 parts of a mixture;
aluminum powder: 9 parts of (1);
zinc oxide: 4 parts of a mixture;
dolomite: 5 parts of a mixture;
boundary plate mud: 4 parts of a mixture;
guizhou soil: 3 parts of a mixture;
high boron frit: 11 parts.
2. The imitation basalt glaze according to claim 1,
the blank mud comprises the following components in percentage by mass:
SiO2：68.04％；Al2O3：20.42％；Fe2O3：1.31％；TiO2：0.18％；CaO：0.2％；MgO：0.26％；K2O：1.33％；Na2o: 2.39 percent; ignition decrement: 5.87 percent.
3. The method for producing an imitation basalt glaze according to claim 1 or 2, characterized in that the steps of the method comprise:
respectively preparing a ground glaze slurry and a surface glaze slurry;
the preparation processes of the ground glaze slurry and the surface glaze slurry are respectively as follows: preparing the components according to the mass parts of the components; ball milling is carried out after material preparation; sieving the ball-milled material; sieving the materials to prepare glaze slurry;
taking a clean blank, applying a base glaze on the blank by adopting base glaze slurry, and then applying a surface glaze on the blank by using surface glaze slurry;
and firing the glazed blank in a kiln at 1215 ℃, wherein the heat preservation time is required to be more than 20 minutes in the firing process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010034580.1A CN111204976A (en) | 2020-01-14 | 2020-01-14 | Imitated basalt glaze and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010034580.1A CN111204976A (en) | 2020-01-14 | 2020-01-14 | Imitated basalt glaze and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111204976A true CN111204976A (en) | 2020-05-29 |
Family
ID=70783397
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010034580.1A Pending CN111204976A (en) | 2020-01-14 | 2020-01-14 | Imitated basalt glaze and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111204976A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113800775A (en) * | 2021-10-22 | 2021-12-17 | 天长市康美达新型绝热材料有限公司 | Preparation method of low-density rock wool board |
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Application publication date: 20200529 |