CN105754186A - 一种高性能ldpe/pet共混增容新方法 - Google Patents
一种高性能ldpe/pet共混增容新方法 Download PDFInfo
- Publication number
- CN105754186A CN105754186A CN201610213988.9A CN201610213988A CN105754186A CN 105754186 A CN105754186 A CN 105754186A CN 201610213988 A CN201610213988 A CN 201610213988A CN 105754186 A CN105754186 A CN 105754186A
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- Prior art keywords
- ldpe
- pet
- dap
- grafting
- blended
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 229920001684 low density polyethylene Polymers 0.000 title claims abstract description 120
- 239000004702 low-density polyethylene Substances 0.000 title claims abstract description 120
- 238000000034 method Methods 0.000 title claims abstract description 23
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 6
- 239000004641 Diallyl-phthalate Substances 0.000 claims abstract description 48
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 38
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000000203 mixture Substances 0.000 claims abstract description 20
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 239000000178 monomer Substances 0.000 claims abstract description 12
- 239000003999 initiator Substances 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 4
- 230000001988 toxicity Effects 0.000 claims abstract 2
- 231100000419 toxicity Toxicity 0.000 claims abstract 2
- 238000002360 preparation method Methods 0.000 claims description 8
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 7
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 7
- -1 Alcohol ester Chemical class 0.000 claims description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 3
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 claims description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical group 0.000 claims description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims 1
- 238000005809 transesterification reaction Methods 0.000 abstract 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 64
- 239000005020 polyethylene terephthalate Substances 0.000 description 64
- 230000035484 reaction time Effects 0.000 description 13
- 238000001035 drying Methods 0.000 description 12
- 238000005304 joining Methods 0.000 description 12
- 238000000635 electron micrograph Methods 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000004067 bulking agent Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002338 polyhydroxyethylmethacrylate Polymers 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 229920013730 reactive polymer Polymers 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
DAP接枝率(%) | 拉伸强度(MPa) | 断裂伸长率(%) | |
实例一 | 2.64 | 11±0.4 | 290±5 |
实例二 | 3.37 | 11±0.8 | 285±6 |
实例三 | 2.51 | 10±0.6 | 325±4 |
实例四 | 2.05 | 10±0.3 | 330±3 |
实例五 | 3.31 | 10±0.2 | 270±2 |
实例六 | 2.19 | 11±0.4 | 275±2 |
实例七 | 3.01 | 11±0.1 | 300±2 |
实例八 | 2.57 | 11±0.2 | 310±8 |
实例九 | 2.14 | 10±0.8 | 345±7 |
实例十 | 3.25 | 10±0.4 | 345±2 |
实例十一 | 3.28 | 9±0.6 | 280±6 |
实例十二 | 3.16 | 10±0.3 | 285±5 |
LDPE(2101)/PET简单共混样 | 0 | 7±0.6 | 610±3 |
LDPE(7050)/PET简单共混样 | 0 | 8±0.4 | 575±2 |
LDPE(9020)/PET简单共混样 | 0 | 8±0.8 | 615±5 |
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610213988.9A CN105754186B (zh) | 2016-04-07 | 2016-04-07 | 一种高性能ldpe/pet共混增容新方法 |
Applications Claiming Priority (1)
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CN201610213988.9A CN105754186B (zh) | 2016-04-07 | 2016-04-07 | 一种高性能ldpe/pet共混增容新方法 |
Publications (2)
Publication Number | Publication Date |
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CN105754186A true CN105754186A (zh) | 2016-07-13 |
CN105754186B CN105754186B (zh) | 2018-06-26 |
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CN201610213988.9A Active CN105754186B (zh) | 2016-04-07 | 2016-04-07 | 一种高性能ldpe/pet共混增容新方法 |
Country Status (1)
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106519410A (zh) * | 2016-10-28 | 2017-03-22 | 常州大学怀德学院 | 一种高性能lldpe/pet微纤增强共混物的制备方法 |
CN106519387A (zh) * | 2016-10-28 | 2017-03-22 | 常州大学怀德学院 | 一种高性能ldpe/pet微纤增强共混物的制备方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1226576A (zh) * | 1998-12-25 | 1999-08-25 | 清华大学 | 添加多官能单体对聚丙烯共混物反应增容的方法 |
-
2016
- 2016-04-07 CN CN201610213988.9A patent/CN105754186B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1226576A (zh) * | 1998-12-25 | 1999-08-25 | 清华大学 | 添加多官能单体对聚丙烯共混物反应增容的方法 |
Non-Patent Citations (2)
Title |
---|
YE LING ZHU,CHANGSHENG LIANG,YANG BO,SHIAI XU: ""Compatibilization of polypropylene/recycled polyethylene"", 《JOURNAL OF POLYMER RESEARCH》 * |
高宁,叶苗,张景春,谢续明: ""多单体接枝聚丙烯对PBT/PP共混体系的形态结构"", 《高分子学报》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106519410A (zh) * | 2016-10-28 | 2017-03-22 | 常州大学怀德学院 | 一种高性能lldpe/pet微纤增强共混物的制备方法 |
CN106519387A (zh) * | 2016-10-28 | 2017-03-22 | 常州大学怀德学院 | 一种高性能ldpe/pet微纤增强共混物的制备方法 |
CN106519387B (zh) * | 2016-10-28 | 2020-11-17 | 常州大学怀德学院 | 一种高性能ldpe/pet微纤增强共混物的制备方法 |
CN106519410B (zh) * | 2016-10-28 | 2020-12-22 | 常州大学怀德学院 | 一种高性能lldpe/pet微纤增强共混物的制备方法 |
Also Published As
Publication number | Publication date |
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CN105754186B (zh) | 2018-06-26 |
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Effective date of registration: 20240423 Address after: 101200 room 205-211526, No. 40, Fuqian West Street, Pinggu town, Pinggu District, Beijing (cluster registration) Patentee after: BEIJING YONGBO TECHNOLOGY CO.,LTD. Country or region after: China Address before: Gehu Lake Road Wujin District 213164 Jiangsu city of Changzhou province No. 1 Patentee before: CHANGZHOU University Country or region before: China |
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Effective date of registration: 20240511 Address after: Room 101, Building 2, No. 19 Shenzhou Road, Huangpu District, Guangzhou City, Guangdong Province, 510000 Patentee after: Guangzhou Alpha Precision Mold Co.,Ltd. Country or region after: China Address before: 101200 room 205-211526, No. 40, Fuqian West Street, Pinggu town, Pinggu District, Beijing (cluster registration) Patentee before: BEIJING YONGBO TECHNOLOGY CO.,LTD. Country or region before: China |