CN105733389A - LED-UV-cured transfer printing adhesive and preparation method thereof - Google Patents
LED-UV-cured transfer printing adhesive and preparation method thereof Download PDFInfo
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- CN105733389A CN105733389A CN201610226513.3A CN201610226513A CN105733389A CN 105733389 A CN105733389 A CN 105733389A CN 201610226513 A CN201610226513 A CN 201610226513A CN 105733389 A CN105733389 A CN 105733389A
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- led
- transfer printing
- transfer glue
- acrylate
- solidification
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses an LED-ultraviolet light (LED-UV)-cured transfer printing adhesive and a preparation method thereof.The transfer printing adhesive is prepared from, by mass, 10%-15% of modified epoxy acrylate, 20%-35% of aliphatic urethane acrylate, 30%-40% of specially functional acrylic ester, 10%-20% of active diluent, 4%-6% of photoinitiator and 2%-5% of an adhesion promoter.A using method of the prepared transfer printing adhesive comprises the steps that firstly, the transfer printing adhesive is applied to a workpiece; secondly, a transfer printing adhesive coating is covered with a transfer printing ink film, and then the pattern transfer printing effect is achieved through LED ultraviolet light curing.The prepared transfer printing adhesive is a total-solid-content UV adhesive, effectively utilizes an LED-UV low-energy curing light source, is quick in deep curing and low in energy consumption, has the excellent adhesion and the good water resistance and can be widely applied to various workpieces needing pattern transfer printing.
Description
Technical field
Present invention relates to ultraviolet photocureable material field, is specifically related to a kind of LED ultraviolet light for ink transfer
(LED-UV) solidification glue and preparation method thereof.
Background technology
Traditional solvent type adhesive contains substantial amounts of VOC solvent, and curing rate is slow, and production efficiency is low, produces and uses
During the health of people is caused very major injury.Along with environmental conservation cry grows to even greater heights, the environmental protection of adhesive becomes one
Important development trend.Ultraviolet light (UV) curing transfer glue is with advantages such as its environmental protection, efficient, high-quality, wide adaptabilities in recent years
Become novel environment friendly adhesive of greatest concern, have huge development prospect.LED ultraviolet light (LED-UV) in the present invention is solid
Changing adhesive is a kind of novel optic-solidified adhesive grown up on the basis of former ordinary high pressure mercury lamp ultraviolet light polymerization gluing agent
Glutinous agent.
Ultraviolet light (UV) curing transfer glue typically uses ordinary high pressure mercury lamp UV light source curing, and high voltage mercury lamp is at work shape
The UV energy accounting about 30% occurred under state, is wherein infrared energy greatly.Due to a large amount of infrared energies
Generation makes workpiece surface temperature in solidification process too high and causes workpiece impaired.The ultraviolet that high voltage mercury lamp is launched is concentrated mainly on
280-320nm wave-length coverage, the ultraviolet ray intensity in specific band do not concentrates, and penetration capacity is low, especially at dark colour ink
During transfer, during curing of coatings, cause coating interlayer poor adhesive force owing to ultraviolet light penetration power is unable to reach deep cure not
Problem, and the ultraviolet light that LED-UV light source produces can concentrate on required particular range of wavelengths, and there is good coating penetrate
When card dark colour ink of trying hard to keep transfers, coating deep cure is complete.Additionally, LED-UV curing apparatus caloric value in the course of the work
Low, surface of the work is not caused hot injury.In conjunction with the plurality of advantages of LED-UV solidification, the present invention provides a kind of and solidifies with LED-UV
The LED-UV transfer glue matched, it is good and excellent that this transfer glue has high solids content, rapid deep zone solidification, Lower Energy Consumption Curing, adhesive force
The features such as different resistance to water, can be widely applicable to various needs and transfer on the workpiece of pattern.
Summary of the invention
It is desirable to provide a kind of LED-UV solidification transfer glue, this glue have high solids content, rapid deep zone solidification, low
The features such as energy solidification, the resistance to water that adhesive force is good and excellent, can be widely applicable to various needs and transfer on the workpiece of pattern.
The above-mentioned purpose of the present invention is achieved by following scheme: a kind of LED-UV photocuring transfer glue, its formula by
The raw material of following each percentage by weight is constituted:
Modified epoxy acrylic ester: 10-15%
Aliphatic urethane acrylate 20-35%
Special functional group acrylate 30-40%
Reactive diluent 10-20%
Light trigger 4-6%
Adhesion promoter 2-5%,
Wherein: modified epoxy acrylic ester is fatty acid or anhydride modified Epocryl, modified epoxy third
The advantage that olefin(e) acid ester has viscosity solidification low, fast, pliability is good, adhesive force is good；Aliphatic urethane acrylate is two senses
Or the aliphatic urethane acrylate of polyfunctionality；Special functional group's acrylate is a kind of adhesive force resin；Described light
Initiator is mainly 365, the two or more of the light trigger of 395nm characteristic absorption wavelength.
The preparation method of the transfer glue of a kind of LED-UV of the present invention solidification is as follows:
By modified epoxy acrylic ester resin, aliphatic urethane acrylate, special functional group's acrylate, activity dilute
Release agent mixing, under the mixing speed of 800-1000r/min, be heated to 60 DEG C of dispersion 1h, add light trigger, treat solid-state light
Initiator adds adhesion promoter after being completely dissolved, i.e. can get the transfer of the LED-UV solidification of the present invention after dispersion 1-2h
Glue.
The performance requirement of the transfer glue of a kind of LED-UV solidification according to the present invention, raw material is carried out widely by the present invention
Test screen, carries out performance test and evaluation to the modified epoxy acrylic ester of Multiple Type, finally gives and be suitable for the present invention
The modified epoxy acrylic ester resin required, for a kind of fatty acid modified Epocryl, this resin has fast solid
Change, the feature that pliability is good, adhesive force is good；Its role is to the paint film for final transfer glue and toughness and adhesive force are provided, promote
Transfer glue reaches performance requirement in terms of curing rate and adhesive force.Above-mentioned modified epoxy acrylic ester resin uses commercially available prod
All can realize the present invention, HY217 type resin as the most on sale in our company or the 6100D of commercially available Jiangmen Heng Guang new material company limited
Deng.
Above-mentioned aliphatic urethane acrylate, as the matrix resin of transfer glue, is a kind of two senses or polyfunctionality
Aliphatic urethane acrylate resin, itself there is low viscosity, fast solidification, lower shrinkage stress, pliability are good, adhesive force is good
Feature；In this resin aliphatic Long carbon chain structure can reduce film forming coatings when fast setting produced internal contraction should
After the film forming coatings film-forming of power, beneficially transfer glue, transfer ink is had preferable adhesive force；The fat of polyfunctionality simultaneously
Fat adoption urethane acrylate resin crosslink density when film forming coatings solidifies is big, and curing rate is fast, meets film forming coatings further
The performance requirement of rapid deep zone solidification.Above-mentioned aliphatic urethane acrylate resin uses commercially available prod can realize the present invention,
5104D etc. such as Changxing chemical industry.
Above-mentioned special functional group's acrylate is a kind of adhesive force resin, in its strand containing substantial amounts of-
OH ,-COOH isopolarity group, it is possible to transfer ink thin film is had good spreading wetting, has good after film forming coatings solidification
Chemical bonds；Film forming coatings is made to have the adhesive force of excellence after hardening；The curing rate of resin own is fast simultaneously, after film forming
Water resistance excellent；Its effect is to make film forming coatings realize excellent adhesive force and the characteristic of water resistance.Above-mentioned special official
Commercially available prod can be used can to realize the present invention by base acrylate, JS402 type resin as the most on sale in our company.
Above-mentioned reactive diluent is propylene glycol diacrylate, tripropylene glycol diacrylate, 1,6-HD two
Acrylate, ethoxylated neopentylglycol diacrylate, the one of ethoxylated trimethylolpropane triacrylate or many
Kind.It mainly provides diluting effect in formula, improves the crosslink density of paint film simultaneously and has certain adhesive force, for transfer
Glue provides good workability and levelability.
Above-mentioned light trigger be two kinds in the light trigger that crack type photoinitiator is special with LED-UV and two kinds with
On, described light trigger is 2-hydroxy-2-methyl-phenylacetone-1(1173), 1-hydroxy-cyciohexyl benzophenone (184), 2,
4,6-trimethylbenzoy-dipheny phosphine oxide (TPO), double (2,4,6-trimethylbenzoyl) phenyl phosphine oxide (819),
2,4,6-trimethylbenzoyl-radical initiator such as phenyl phosphine oxide (TEPO), LED-UV dedicated optical initiator.Above-mentioned
LED-UV dedicated optical initiator uses commercially available prod all can realize the present invention, 27 series of products of day as long in Tianjin.
Above-mentioned adhesion promoter is one or more of Special Resin that can strengthen adhesive force；Above-mentioned adhesive force promotes
Agent uses commercially available prod can realize the present invention, such as the CD-9051 etc. of Sartomer.
Coating technique method of the present invention is as follows: → application UV is filled and led up in dalle → application UV common priming paint bottoming
At the bottom of color → ultraviolet light polymerization after sanding → application LED-UV transfer glue → transfer ink thin film overlay film → LED-UV solidify → tear oil
Follow-up protection application and coating finish → finished product after protecting film on ink thin film.
Compared with prior art, there is advantages that
1. the modified epoxy acrylate resin that the present invention uses fast solidification, pliability is good, adhesive force is good is as matrix resin, for turning
The paint film of print glue provides toughness and adhesive force, promotes that the film forming coatings of transfer glue reaches performance in terms of curing rate and adhesive force
Requirement；
2. the present invention uses aliphatic polyurethane acrylic resin and special functional group's acrylate as matrix resin, fat
The aliphatic Long carbon chain structure of fat adoption urethane acrylate resin reduces film forming coatings produced internal receipts when fast setting
Containing substantial amounts of-OH ,-COOH isopolarity group in stress under compression and special functional group's acrylate Middle molecule chain, it is possible to right
Transfer ink thin film has good spreading wetting, has good chemical bonds, it is achieved that film forming coatings after film forming coatings solidification
Excellent adhesive force and the characteristic of good water resistance；
3. the present invention with the addition of a small amount of adhesion promoter, further enhancing transfer glue film-forming coating to transfer ink
Adhesion of thin film；
4. the transfer glue of the LED-UV solidification of the present invention compares common UV curing transfer glue, uses LED dedicated optical initiator, effectively
The ultraviolet light utilizing LED-UV light source to produce concentrates on required particular range of wavelengths, has good coating penetration power and ensures deep
During color ink transfer, completely and LED-UV curing apparatus caloric value in the course of the work is low, to workpiece table for coating deep cure
Hot injury is not caused in face.Advantage in sum, the transfer glue of the LED-UV solidification of the present invention can be widely applicable to various needs
On the workpiece of transfer pattern.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be further described, but the present invention is not appointed by specific embodiment
What limits.
Embodiment 1
A kind of transfer glue of LED-UV solidification, including following component, by mass percentage:
Modified epoxy acrylic ester: 12%
Aliphatic urethane acrylate 30%
Special functional group's acrylate 36%
HDDA 15%
Light trigger 4%
Adhesion promoter 3%,
Above-mentioned modified epoxy acrylic ester resin uses our company to sell HY-217；
Above-mentioned aliphatic urethane acrylate resin uses Changxing chemical industry 5104D；
Above-mentioned special functional group's acrylate uses the JS402 that company is self-produced；
Above-mentioned light trigger uses the oxidation of 1-hydroxy-cyciohexyl benzophenone (184), 2,4,6-trimethylbenzoy-dipheny
Phosphine (TPO), double (2,4,6-trimethylbenzoyl) phenyl phosphine oxide (819), 27 series of products of Tianjin long day；
Above-mentioned adhesion promoter uses the CD-9051 of Sartomer.
Embodiment 2
A kind of transfer glue of LED-UV solidification, including following component, by mass percentage:
Modified epoxy acrylic ester: 15%
Aliphatic urethane acrylate 20%
Special modification acrylate 36%
HDDA 20%
Light trigger 5%
Adhesion promoter 4%,
Above-mentioned modified epoxy acrylic ester resin uses our company to sell HY-217；
Above-mentioned aliphatic urethane acrylate resin uses Changxing chemical industry 5104D；
Above-mentioned special functional group's acrylate uses the JS402 that company is self-produced；
Above-mentioned light trigger uses the oxidation of 1-hydroxy-cyciohexyl benzophenone (184), 2,4,6-trimethylbenzoy-dipheny
Phosphine (TPO), double (2,4,6-trimethylbenzoyl) phenyl phosphine oxide (819), 27 series of products of Tianjin long day；
Above-mentioned adhesion promoter uses the CD-9051 of Sartomer.
Embodiment 3
A kind of transfer glue of LED-UV solidification, including following component, by mass percentage:
Modified epoxy acrylic ester: 10%
Aliphatic urethane acrylate 32%
Special modification acrylate 40%
HDDA 12%
Light trigger 4%
Adhesion promoter 2%,
Above-mentioned modified epoxy acrylic ester resin uses our company to sell HY-217；
Above-mentioned aliphatic urethane acrylate resin uses Changxing chemical industry 5104D；
Above-mentioned special functional group's acrylate uses the JS402 that company is self-produced；
Above-mentioned light trigger uses the oxidation of 1-hydroxy-cyciohexyl benzophenone (184), 2,4,6-trimethylbenzoy-dipheny
Phosphine (TPO), double (2,4,6-trimethylbenzoyl) phenyl phosphine oxide (819), 27 series of products of Tianjin long day；
Above-mentioned adhesion promoter uses the CD-9051 of Sartomer.
The preparation method of the transfer glue of above-mentioned LED-UV solidification is as follows:
By modified epoxy acrylic ester resin, aliphatic urethane acrylate, special functional group's acrylate, HDDA mixing,
Under the mixing speed of 800-1000r/min, it is heated to 60 DEG C of dispersion 1h, adds light trigger, treat that solid-state light initiator is complete
Add adhesion promoter after dissolving, after dispersion 1-2h, i.e. can get the transfer glue of a kind of LED-UV solidification of the present invention.
The transfer glue of the LED-UV solidification obtained by being prepared by the present embodiment carries out performance measurement, by its performance test with general
Logical UV curing transfer glue contrasts, and result is as shown in table 1:
Table 1
Coming as can be seen from Table 1, the LED-UV curing transfer glue in the present embodiment has bright relative to common UV curing transfer glue
Aobvious comprehensive advantage.In the present invention, common UV curing transfer glue compared by LED-UV curing transfer glue, uses LED-UV curing apparatus
Solidifying, without preheating during use, service life is long, and solidification energy is low, and energy consumption is low, and LED-UV curing light source does not produce too much
Heat can reduce the temperature of surface of the work, prevent from causing workpiece that mass defect occurs owing to temperature is too high；LED-UV solidification turns
Print glue uses large arch dam, fast solidification, modified epoxy acrylic ester that adhesive force is good, aliphatic urethane acrylate, special official
The raw materials such as energy base acrylate, improve the toughness of film forming coatings, increase the curing rate of film forming coatings, reduce film forming coatings
Shrinkage stress, and film forming coatings has significant advantage in terms of adhesive force and water resistance.
Claims (7)
1. the transfer glue of a LED-UV solidification, it is characterised in that its composition of raw materials is by each component group of following percentage by weight
Become:
Modified epoxy acrylic ester: 10-15%
Aliphatic urethane acrylate 20-35%
Special functional group acrylate 30-40%
Reactive diluent 10-20%
Light trigger 4-6%
Adhesion promoter 2-5%,
Wherein: modified epoxy acrylic ester is fatty acid or anhydride modified Epocryl；Aliphatic polyurethane third
Olefin(e) acid ester is the aliphatic urethane acrylate of two senses or polyfunctionality；Special functional group's acrylate is a kind of adhesive force
Resin；Described light trigger is mainly 365, the two or more of the light trigger of 395nm characteristic absorption wavelength.
2. the transfer glue solidified according to a kind of LED-UV described in claim 1, it is characterised in that described activity dilution
Agent is one or more in difunctional or multi-functional propylene acid esters.
3. the transfer glue solidified according to a kind of LED-UV described in claim 1,2, it is characterised in that described acrylate
Class monomer includes propylene glycol diacrylate (DPGDA), tripropylene glycol diacrylate (TPGDA), 1,6-hexanediol dipropyl
Olefin(e) acid ester (HDDA), ethoxylated neopentylglycol diacrylate (NPG2PODA), ethoxyquin trimethylolpropane tris acrylic acid
One or more of ester (TMP3EOTA).
4. the transfer glue solidified according to a kind of LED-UV described in claim 1, it is characterised in that: described light trigger is
Crack type photoinitiator and two or more collocation in LED-UV dedicated optical initiator.
5. the transfer glue solidified according to a kind of LED-UV described in claim 1,4, it is characterised in that: described light trigger
For 2-hydroxy-2-methyl-phenylacetone-1(1173), 1-hydroxy-cyciohexyl benzophenone (184), 2,4,6-trimethylbenzoyl
Base-diphenyl phosphine oxide (TPO), double (2,4,6-trimethylbenzoyl) phenyl phosphine oxide (819), 2,4,6-trimethylbenzene first
Two or more in the radical initiators such as l-phenvl phosphine oxide (TEPO), LED-UV dedicated optical initiator.
6. the transfer glue solidified according to a kind of LED-UV described in claim 1, it is characterised in that: described adhesive force promotes
Agent is one or more of Special Resin that can strengthen adhesive force.
7. the preparation method of transfer glue of a kind of LED-UV solidification described in a claim 1, it is characterised in that include as
Lower step: according to composition of raw materials described in claim 1, by modified epoxy acrylate resin, aliphatic polyurethane acrylic resin,
Special functional group's acrylic resin, reactive diluent mix, and are heated to 60 DEG C of dispersions under the mixing speed of 800-1000r/min
1h, adds light trigger, adds adhesion promoter after solid-state light initiator is completely dissolved, the most available after dispersion 1-2h
The transfer glue of LED-UV solidification.
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| CN105733389B CN105733389B (en) | 2018-11-27 |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105968942A (en) * | 2016-07-12 | 2016-09-28 | 昆山市曙光照明器材有限公司 | LED-solidified water transfer printing ink and preparation method thereof |
| CN106046927A (en) * | 2016-07-12 | 2016-10-26 | 昆山市曙光照明器材有限公司 | Hydrographic transfer printing ink and preparation method thereof |
| CN106118385A (en) * | 2016-08-23 | 2016-11-16 | 佛山阳光逸采涂料科技有限公司 | A kind of UV LED low-yield solidification mahogany furniture coating and preparation method thereof |
| CN106189487A (en) * | 2016-07-12 | 2016-12-07 | 昆山市曙光照明器材有限公司 | A kind of water transfer inking front cover oil of LED solidification and preparation method thereof |
| CN106280689A (en) * | 2016-08-26 | 2017-01-04 | 佛山市高明绿色德化工有限公司 | A kind of LED UV ink and preparation method thereof, using method |
| CN106564313A (en) * | 2016-10-27 | 2017-04-19 | 广东星弛光电科技有限公司 | UV texture transfer print preparing technology for 3D glass window protection screen |
| CN108192420A (en) * | 2017-11-28 | 2018-06-22 | 湖南互力达涂料科技有限公司 | A kind of aqueous light emitting diode photocuring digital ink-jet and preparation method thereof |
| CN108485480A (en) * | 2016-12-13 | 2018-09-04 | 君子兰化工（上海）有限公司 | Improved UVLED photocureable coating |
| CN109957368A (en) * | 2017-12-22 | 2019-07-02 | 比亚迪股份有限公司 | A kind of LED-UV solidification Optical adhesive composition, preparation method and its solidify coating |
| CN110027339A (en) * | 2019-05-10 | 2019-07-19 | 广东阿特斯科技有限公司 | A kind of sheet printing technology without spraying forced fluid |
| CN110083012A (en) * | 2018-01-25 | 2019-08-02 | 比亚迪股份有限公司 | A kind of ultraviolet light transfer glue composition, solidify coating and application and transfer fine pattern form body and its manufacturing method |
| CN110582176A (en) * | 2019-10-12 | 2019-12-17 | Oppo广东移动通信有限公司 | Shell, manufacturing method thereof and electronic equipment |
| CN111564435A (en) * | 2020-04-23 | 2020-08-21 | 宁波维真显示科技股份有限公司 | 3D-LED (three-dimensional-light-emitting diode) fitting method based on photoinitiation mechanism |
| CN111849245A (en) * | 2020-07-14 | 2020-10-30 | 北京化工大学常州先进材料研究院 | Ultraviolet curing offset printing composition based on epoxy oleate acrylate oligomer |
| CN112266715A (en) * | 2020-11-22 | 2021-01-26 | 湖南省金海科技有限公司 | Special heat-resistant solvent-resistant LED-UV (light-emitting diode-ultraviolet) curing elastic coating system for wood veneer and preparation and coating methods |
| CN113174229A (en) * | 2021-03-30 | 2021-07-27 | 江门市久冠松高分子材料有限公司 | UV-LED impression adhesive for glass product surface transfer printing and preparation method thereof |
| CN114672189A (en) * | 2022-04-13 | 2022-06-28 | 佳化化学科技发展（上海）有限公司 | Ultraviolet curing ink and preparation method and product thereof |
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| CN105968942A (en) * | 2016-07-12 | 2016-09-28 | 昆山市曙光照明器材有限公司 | LED-solidified water transfer printing ink and preparation method thereof |
| CN106046927A (en) * | 2016-07-12 | 2016-10-26 | 昆山市曙光照明器材有限公司 | Hydrographic transfer printing ink and preparation method thereof |
| CN106189487A (en) * | 2016-07-12 | 2016-12-07 | 昆山市曙光照明器材有限公司 | A kind of water transfer inking front cover oil of LED solidification and preparation method thereof |
| CN106118385A (en) * | 2016-08-23 | 2016-11-16 | 佛山阳光逸采涂料科技有限公司 | A kind of UV LED low-yield solidification mahogany furniture coating and preparation method thereof |
| CN106280689B (en) * | 2016-08-26 | 2019-04-02 | 佛山市高明绿色德化工有限公司 | A kind of LED-UV ink and preparation method thereof, application method |
| CN106280689A (en) * | 2016-08-26 | 2017-01-04 | 佛山市高明绿色德化工有限公司 | A kind of LED UV ink and preparation method thereof, using method |
| CN106564313A (en) * | 2016-10-27 | 2017-04-19 | 广东星弛光电科技有限公司 | UV texture transfer print preparing technology for 3D glass window protection screen |
| CN108485480A (en) * | 2016-12-13 | 2018-09-04 | 君子兰化工（上海）有限公司 | Improved UVLED photocureable coating |
| CN108192420A (en) * | 2017-11-28 | 2018-06-22 | 湖南互力达涂料科技有限公司 | A kind of aqueous light emitting diode photocuring digital ink-jet and preparation method thereof |
| CN109957368A (en) * | 2017-12-22 | 2019-07-02 | 比亚迪股份有限公司 | A kind of LED-UV solidification Optical adhesive composition, preparation method and its solidify coating |
| CN110083012A (en) * | 2018-01-25 | 2019-08-02 | 比亚迪股份有限公司 | A kind of ultraviolet light transfer glue composition, solidify coating and application and transfer fine pattern form body and its manufacturing method |
| CN110027339A (en) * | 2019-05-10 | 2019-07-19 | 广东阿特斯科技有限公司 | A kind of sheet printing technology without spraying forced fluid |
| CN110582176A (en) * | 2019-10-12 | 2019-12-17 | Oppo广东移动通信有限公司 | Shell, manufacturing method thereof and electronic equipment |
| CN111564435A (en) * | 2020-04-23 | 2020-08-21 | 宁波维真显示科技股份有限公司 | 3D-LED (three-dimensional-light-emitting diode) fitting method based on photoinitiation mechanism |
| CN111564435B (en) * | 2020-04-23 | 2023-04-18 | 宁波维真显示科技股份有限公司 | 3D-LED (three-dimensional-light-emitting diode) fitting method based on photoinitiation mechanism |
| CN111849245A (en) * | 2020-07-14 | 2020-10-30 | 北京化工大学常州先进材料研究院 | Ultraviolet curing offset printing composition based on epoxy oleate acrylate oligomer |
| CN112266715A (en) * | 2020-11-22 | 2021-01-26 | 湖南省金海科技有限公司 | Special heat-resistant solvent-resistant LED-UV (light-emitting diode-ultraviolet) curing elastic coating system for wood veneer and preparation and coating methods |
| CN113174229A (en) * | 2021-03-30 | 2021-07-27 | 江门市久冠松高分子材料有限公司 | UV-LED impression adhesive for glass product surface transfer printing and preparation method thereof |
| CN114672189A (en) * | 2022-04-13 | 2022-06-28 | 佳化化学科技发展（上海）有限公司 | Ultraviolet curing ink and preparation method and product thereof |
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