CN107459865A - One kind printing reverse gloss oil ink of UV and preparation method thereof - Google Patents

One kind printing reverse gloss oil ink of UV and preparation method thereof Download PDF

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Publication number
CN107459865A
CN107459865A CN201710673795.6A CN201710673795A CN107459865A CN 107459865 A CN107459865 A CN 107459865A CN 201710673795 A CN201710673795 A CN 201710673795A CN 107459865 A CN107459865 A CN 107459865A
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CN
China
Prior art keywords
reverse
printing
oil
gloss oil
ink
Prior art date
Application number
CN201710673795.6A
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Chinese (zh)
Inventor
唐文宏
褚书宝
褚波
Original Assignee
中山市博海精细化工有限公司
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Priority to CN201710673795.6A priority Critical patent/CN107459865A/en
Publication of CN107459865A publication Critical patent/CN107459865A/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/101Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

Abstract

The invention discloses one kind printing reverse gloss oil ink of UV and preparation method thereof, it is made up of reverse base oil and reverse face oil, its drip irrigation device is to include the component of following parts by weight:The reverse base oil includes following components by weight percent:45 80 parts of UV-cured resin A, 10 25 parts of property diluent A, 59 parts of initiator A, 26 parts of filler A, 35 parts of auxiliary agent A;The reverse face oil includes following components by weight percent:30 55 parts of 30 42 parts of UV-cured resin B, reactive diluent B, 8 15 parts of photosensitivity promotor B, 5 10 parts of photoinitiator b, 01 parts of auxiliary agent B.It is an object of the invention to provide one kind printing reverse gloss oil ink of UV, reacts on surface by cohesion and produces frosting effect.

Description

One kind printing reverse gloss oil ink of UV and preparation method thereof
【Technical field】
The invention belongs to printing-ink field, and in particular to one kind printing reverse gloss oil ink of UV and preparation method thereof.
【Background technology】
UV glazing ink refers in the case where ultraviolet irradiates, and is connected gloss oil ink with the ultraviolet light of energy using different wave length Monomer in material aggregates into polymer.Because UV gloss oil has without volatile solvent, odorless, non-stimulated, curing rate is fast, The features such as cured film is tough and tensile, solvent resistant and be widely used in print field.UV printing varnish species is various, generally there is UV offset printing light Oil, UV silk-screen printings gloss oil, UV intaglio printings gloss oil, UV flexographic printing gloss oil etc., and the reverse glazing ink of UV is by reverse Base oil and inversely upper smooth surface oil combined printing, the reverse glazing ink of UV is mainly the printing of reverse effect, and it is mainly used in respectively On eka-gold silver foil printed matter, all kinds of high-grade packing boxes, decoration painting, high-grade label etc. can be produced, is that high-grade printing is led in recent years The research emphasis in domain.
【The content of the invention】
It is an object of the invention to provide one kind printing reverse gloss oil ink of UV.
It is a further object of the present invention to provide a kind of preparation method printed with the reverse gloss oil ink of UV.
One kind printing reverse gloss oil ink of UV, is made up of reverse base oil and reverse face oil, includes the group of following parts by weight Point:
The reverse base oil includes following components by weight percent:
The reverse face oil includes following components by weight percent:
Preferably, the UV-cured resin A is obtained by thermosetting hard resin and polyester acrylate mixed dissolution. Epoxy acrylic resin and multifunctional urethane acrylate curing rate are fast.
Preferably, the reactive diluent A is glycerol propoxylate triacrylate (G3.5POTA), 2- Phenoxyethyls third One or more mixing in olefin(e) acid ester, 1,6- hexylene glycols double methacrylate, the acrylate of dipentaerythritol five/six (DPHA) Thing.
Preferably, the light trigger A is methyl o-benzoylbenzoate (OMBB), 2,4- diethyl thioxanthones (DETX), one kind in 2- methyl isophthalic acids-(4- methyl mercaptos phenyl) -2- morpholine -1- acetone (907), 4- methyl benzophenones (MBP) Or a variety of mixtures.
Preferably, the filler A is the mixture of light magnesium carbonate, wax powder and both-end hydroxy polyethers modified silicon oil, described Auxiliary agent A is defoamer and levelling agent.Described defoamer in BYK-034, BYK-035, BYK-037, BYK-038 one Kind, the levelling agent is one kind in dimethyl silicone polymer, PSI, acrylate, when base oil and face oil After printing, both institute's contact areas are because of component generation cohesion reaction in filler A and face oil, and produce mutual exclusion and form transparent small Grain, shows pitted skin frosted finish effect.
Preferably, the UV-cured resin B is modified epoxy acrylate resin and multifunctional urethane acrylate Mix.The region of no face oil contact at base oil covering, because UV-cured resin B forms the mirror effect of high glaze.
Preferably, the reactive diluent B be propylene glycol diacrylate (DPGDA), two contracting propane diols pair acrylic acid Ester, double pentaerythritol C5 methacrylate, ethoxylated trimethylolpropane triacrylate and ethoxyquin trimethylolpropane tris One or more mixtures in acrylate (TMP3EOTA).
Preferably, the photoinitiator b is 2,4- diethyl thioxanthones (DETX), 1- hydroxycyclohexyl phenyl ketones (184) one or more mixtures in, 2,4,6- trimethylbenzoyl phosphinic acid ethyl esters (TPO), the photosensitivity promotor are One or more mixtures in special tertiary amine acrylate and response type tertiary amine aided initiating.
A kind of preparation method printed with the reverse gloss oil ink of UV, comprises the following steps:
(1) UV-cured resin A, reactive diluent A, light trigger A, filler A and auxiliary agent A are mixed and stirred in proportion Mix uniformly, obtain just mixed thing A;
(2) first mixed thing A is ground 2-3 times with three-roller, it is 5 below μ to be ground to fineness, and the UV for producing the present invention is inverse To gloss oil base oil ink, the reverse gloss oil base oil ink of UV obtained is ecru opaque fluid;
(3) in proportion UV-cured resin B, reactive diluent B, photosensitivity promotor B are mixed and stirred for uniformly, obtaining Just mixed thing B;
(4) added after photoinitiator b being heated into abundant dissolving in just mixed thing B, add auxiliary agent B and disperse 40 minutes, produce The reverse gloss oil face oil ink of UV of the present invention, the reverse gloss oil face oil ink of UV obtained is light yellow clear fluid.
A kind of typography of the reverse gloss oil of gold and silver paperboard printing UV, comprises the following steps:
(1) it is PET light gold and silver paperboards, to select ground, it is desirable to dyne value on PET light gold and silver cards surface will reach 38, And surfacing, with offset press PS versions in the reverse base oils of paperboard surface printing UV, and pass through UV ultraviolet light dry solidifications;
(2) the reverse face oil of UV, is carried out by full version coating by last group of font of offset press again, afterwards by UV ultraviolet lights Dry solidification;
(3) highlighted bloom effect is presented in the region for, not printing base oil, and pitted skin mill is presented in base oil and the overlapping printing zone of face oil Sand effect.
Compared with prior art, the invention has the advantages that and advantage:
1) a kind of, printing reverse gloss oil ink of UV of the invention, UV-cured resin and auxiliary agent ratio during adjustment is formulated Example, the reverse base oils of the UV is had excellent printing adaptability, and the epoxy acrylic of smooth surface oil is inversely gone up with reference to the UV The advantages of resin and fast multifunctional urethane acrylate curing rate, make both print after institute contact area produce mutual exclusion and Transparent little particle is formed, shows pitted skin frosted finish effect, and non-contact area then shows the mirror effect of high glaze, is tradition Milled sand varnish ink institute it is irrealizable;
2) a kind of, printing reverse gloss oil ink of UV of the invention, does not add the PVC sand face in traditional frosted ink Powder, it is to make both contact areas produce mutual exclusion using reverse typography to realize frosted finish effect, and non-contacting light region, tool There is preferable tack, continuous printing demand can be met, printing efficiency is high, in material surface good fluidity, is not cracked, firmly Degree can reach what more than 3H, either traditional UV oil polishes, or water lustering oil can not all meet;
3) a kind of, printing reverse gloss oil ink of UV of the invention, its glazing process and existing line printing coating technology Compare, the position by the printing of reverse base oil is not glossy, and the place by the printing of reverse base oil is due to base oil and oil polish Incompatible principle and cause rough effect, such as the little particle of transparent frosted finish effect so as to cause effect contrast, makes to hold Printing expressive force can be had more by printing thing, and image effect is suitable for printing technology extensively, save process, cost-effective, value Printing industry is obtained to promote;
4) a kind of, printing reverse gloss oil ink preparation methods of UV of the invention, technique is simple, easy to operate, and cost is low And can realize while line print production, being capable of high efficiency large-scale industrial production;
5) a kind of, production method of printing plate of reverse gloss oil of gold and silver paperboard printing UV of the invention, can by print speed come The thickness in sand face is controlled, the fast texture of speed is thick, and then texture is thin slowly for speed, can also pass through base oil and the upper fuel volume adjusting paint of face oil The thickness degree of film controls the thickness in sand face, and thinner frosted particle diameter is thicker otherwise thinner, can use just reverse and regurgitation to technique Printing, so-called just inversely to refer to carry out line printing on 5+1,6+1 or 7+1UV printing machine, regurgitation is offline to then referring to Printing, offline printing refer to the printed matter for printing color ink be first coating it is reverse on smooth surface oil, republish reverse base oil, draw Equal printing effect.
【Embodiment】
Further illustrate that one kind of the present invention prints reverse gloss oil ink in conjunction with specific embodiments:
Table 1:Embodiment 1-4 each components weight forms
(1) UV-cured resin A, reactive diluent A, light trigger A, filler A and auxiliary agent A are mixed and stirred in proportion Mix uniformly, obtain just mixed thing A;
(2) first mixed thing A is ground 2-3 times with three-roller, it is 5 below μ to be ground to fineness, and the UV for producing the present invention is inverse To gloss oil base oil ink, the reverse gloss oil base oil ink of UV obtained is ecru opaque fluid;
(3) in proportion UV-cured resin B, reactive diluent B, photosensitivity promotor B are mixed and stirred for uniformly, obtaining Just mixed thing B;
(4) added after photoinitiator b being heated into abundant dissolving in just mixed thing B, add auxiliary agent B and disperse 40 minutes, produce The reverse gloss oil face oil ink of UV of the present invention, the reverse gloss oil face oil ink of UV obtained is light yellow clear fluid.
A kind of typography of reverse gloss oil of gold and silver paperboard printing UV of the present invention, comprises the following steps:
(1) it is PET light gold and silver paperboards, to select ground, it is desirable to dyne value on PET light gold and silver cards surface will reach 38, And surfacing, with offset press PS versions in the reverse base oils of paperboard surface printing UV, and pass through UV ultraviolet light dry solidifications;
(2) the reverse face oil of UV, is carried out by full version coating by last group of font of offset press again, afterwards by UV ultraviolet lights Dry solidification;
(3) highlighted bloom effect is presented in the region for, not printing base oil, and pitted skin mill is presented in base oil and the overlapping printing zone of face oil Sand effect.
Base oil and face oil, are successively printed on stock by a kind of printing reverse gloss oil ink of UV of the present invention, both Overlapping region forms uniform frosting, and third dimension is strong, and can by control print speed printing speed control frosted granular size spacing, and Only brushing base oil region, surface are highlighted highlight area, and printing efficiency is high, and surface effect is good.
A kind of printing reverse gloss oil ink of UV of the present invention, is to be made using reverse glazing process on same printed matter simultaneously The highlighted light effect of minute surface and transparent pitted skin frosted finish effect be present, the reverse glazing ink of UV uses reverse base oil and reverse glazing Face oil is constructed on all kinds of gold and silver paperboard printed matters, and precondition is that gold and silver card printing product must print color ink through UV After illumination curing, reverse base oil and the print of reverse upper smooth surface oil are then carried out using line or offline reverse typography Brush, make reverse base oil and inversely upper smooth surface oil contact area produces cohesion reaction and forms the ink film of fine granularity, show Bright pitted skin frosted finish effect, non-contact area then form the mirror effect of high glaze, and generally speaking, reverse glazing solves commonly Key issue present in glazing process, and the contrast effect that common oil polish is not accomplished can be reached, imitate the printing of printed matter Fruit distinctness is beautiful, it is more exquisite, make packaging external appearance more bright and glittering.

Claims (10)

1. one kind printing reverse gloss oil ink of UV, is made up of reverse base oil and reverse face oil, it is characterised in that:Including following heavy Measure the component of part:
The reverse base oil includes following components by weight percent:
The reverse face oil includes following components by weight percent:
A kind of 2. printing reverse gloss oil ink of UV described in claim 1, it is characterised in that:The UV-cured resin A Obtained by thermosetting hard resin and polyester acrylate mixed dissolution.
A kind of 3. printing reverse gloss oil ink of UV described in claim 1, it is characterised in that:The reactive diluent A is third Aoxidize glycerol tri-acrylate (G3.5POTA), 2- phenoxyethyl acrylates, 1,6- hexylene glycols double methacrylate, two seasons penta One or more mixtures in the acrylate of tetrol five/six (DPHA).
A kind of 4. printing reverse gloss oil ink of UV described in claim 1, it is characterised in that:The light trigger A is adjacent benzene Carbamoyl benzoate methyl esters (OMBB), 2,4- diethyl thioxanthones (DETX), 2- methyl isophthalic acids-(4- methyl mercaptos phenyl) -2- morpholines - One or more mixtures in 1- acetone (907), 4- methyl benzophenones (MBP).
A kind of 5. printing reverse gloss oil ink of UV described in claim 1, it is characterised in that:The filler A is lightweight carbonic acid The mixture of magnesium, wax powder and both-end hydroxy polyethers modified silicon oil, the auxiliary agent A are defoamer and levelling agent.
A kind of 6. printing reverse gloss oil ink of UV described in claim 1, it is characterised in that:The UV-cured resin B For modified epoxy acrylate resin and multifunctional urethane acrylate mixture.
A kind of 7. printing reverse gloss oil ink of UV described in claim 1, it is characterised in that:The reactive diluent B is two Propylene glycol diacrylate (DPGDA), two contracting propane diols double methacrylates, double pentaerythritol C5 methacrylate, ethoxylation three One or more in hydroxymethyl-propane triacrylate and ethoxyquin trimethylolpropane trimethacrylate (TMP3EOTA) are mixed Compound.
A kind of 8. printing reverse gloss oil ink of UV described in claim 1, it is characterised in that:The photoinitiator b is 2,4- Diethyl thioxanthone (DETX), 1- hydroxycyclohexyl phenyl ketones (184), 2,4,6- trimethylbenzoyl phosphinic acid ethyl esters (TPO) one or more mixtures in, the photosensitivity promotor B are that special tertiary amine acrylate and response type tertiary amine help One or more mixtures in initiator.
9. a kind of preparation method printed with the reverse gloss oil ink of UV, it is characterised in that comprise the following steps:
(1), UV-cured resin A, reactive diluent A, light trigger A, filler A and auxiliary agent A are mixed and stirred in proportion Uniformly, just mixed thing A is obtained;
(2), first mixed thing A is ground 2-3 times with three-roller, it is 5 below μ to be ground to fineness, and the UV for producing the present invention is reverse Gloss oil base oil ink, the reverse gloss oil base oil ink of UV obtained are ecru opaque fluid;
(3), in proportion UV-cured resin B, reactive diluent B, photosensitivity promotor B are mixed and stirred for uniformly, obtaining just Mixed thing B;
(4) added after photoinitiator b, is heated into abundant dissolving in just mixed thing B, add auxiliary agent B and disperse 40 minutes, produce this hair The reverse gloss oil face oil ink of bright UV, the reverse gloss oil face oil ink of UV obtained are light yellow clear fluid.
10. a kind of typography of the reverse gloss oil of gold and silver paperboard printing UV, it is characterised in that comprise the following steps:
(1) it is PET light gold and silver paperboards, to select ground, it is desirable to which dyne value on PET light gold and silver cards surface will reach 38, and table Face is smooth, with offset press PS versions in the reverse base oils of paperboard surface printing UV, and passes through UV ultraviolet light dry solidifications;
(2) the reverse face oil of UV, is carried out by full version coating by last group of font of offset press again, dried afterwards by UV ultraviolet lights Solidification;
(3) highlighted bloom effect is presented in the region for, not printing base oil, and pitted skin frosted effect is presented in base oil and the overlapping printing zone of face oil Fruit.
CN201710673795.6A 2017-08-09 2017-08-09 One kind printing reverse gloss oil ink of UV and preparation method thereof CN107459865A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108070293A (en) * 2018-02-05 2018-05-25 浙江美浓材料科技有限公司 A kind of reverse light ink and preparation method thereof
CN108587309A (en) * 2018-07-26 2018-09-28 惠州市至上新材料有限公司 With the big online reverse ink of gravure UV in gold and silver cardboard material
CN109263324A (en) * 2018-09-05 2019-01-25 河南省防伪保密印刷公司(河南省邮电印刷厂) A kind of processing technology of reverse glazing
CN109278435A (en) * 2018-09-10 2019-01-29 河南省防伪保密印刷公司(河南省邮电印刷厂) A kind of environmental protection sense of touch oil glazing process
CN110217008A (en) * 2019-06-23 2019-09-10 贵州西牛王印务有限公司 A kind of method of gift package surface light and dumb light combined printing
CN110228306A (en) * 2019-06-29 2019-09-13 青岛红杉包装有限公司 The reverse frosted printing technology of packing box
CN110303783A (en) * 2019-07-06 2019-10-08 陆良福牌彩印有限公司 A kind of reverse gloss oil printing packaging paper of UV meets the technology of high speed auto packer adaptability
CN110819213A (en) * 2019-11-16 2020-02-21 湖北劲佳包装有限公司 UV reverse gloss oil and preparation method of printed matter applying UV reverse gloss oil
CN110920284A (en) * 2019-11-25 2020-03-27 东莞市信彩包装有限公司 Printing method for mimeograph matte texture

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108070293A (en) * 2018-02-05 2018-05-25 浙江美浓材料科技有限公司 A kind of reverse light ink and preparation method thereof
CN108587309A (en) * 2018-07-26 2018-09-28 惠州市至上新材料有限公司 With the big online reverse ink of gravure UV in gold and silver cardboard material
CN109263324A (en) * 2018-09-05 2019-01-25 河南省防伪保密印刷公司(河南省邮电印刷厂) A kind of processing technology of reverse glazing
CN109278435A (en) * 2018-09-10 2019-01-29 河南省防伪保密印刷公司(河南省邮电印刷厂) A kind of environmental protection sense of touch oil glazing process
CN110217008A (en) * 2019-06-23 2019-09-10 贵州西牛王印务有限公司 A kind of method of gift package surface light and dumb light combined printing
CN110228306A (en) * 2019-06-29 2019-09-13 青岛红杉包装有限公司 The reverse frosted printing technology of packing box
CN110303783A (en) * 2019-07-06 2019-10-08 陆良福牌彩印有限公司 A kind of reverse gloss oil printing packaging paper of UV meets the technology of high speed auto packer adaptability
CN110819213A (en) * 2019-11-16 2020-02-21 湖北劲佳包装有限公司 UV reverse gloss oil and preparation method of printed matter applying UV reverse gloss oil
CN110920284A (en) * 2019-11-25 2020-03-27 东莞市信彩包装有限公司 Printing method for mimeograph matte texture

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