CN105731869B - Surface defoamer mother liquor and surface defoamer for inorganic decorating board - Google Patents
Surface defoamer mother liquor and surface defoamer for inorganic decorating board Download PDFInfo
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- CN105731869B CN105731869B CN201511030777.3A CN201511030777A CN105731869B CN 105731869 B CN105731869 B CN 105731869B CN 201511030777 A CN201511030777 A CN 201511030777A CN 105731869 B CN105731869 B CN 105731869B
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- mother liquor
- clear water
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- 239000013530 defoamer Substances 0.000 title claims abstract description 69
- 239000012452 mother liquor Substances 0.000 title claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims abstract description 14
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920000570 polyether Polymers 0.000 claims abstract description 13
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 13
- 239000010703 silicon Substances 0.000 claims abstract description 13
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 10
- -1 alcohol ethers Chemical class 0.000 claims abstract description 8
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 11
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 9
- 238000013329 compounding Methods 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 5
- 235000011152 sodium sulphate Nutrition 0.000 claims description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 239000005864 Sulphur Substances 0.000 claims description 4
- 238000001802 infusion Methods 0.000 claims description 4
- ZXRRHFSTAFVGOC-UHFFFAOYSA-N [AlH3].[K] Chemical compound [AlH3].[K] ZXRRHFSTAFVGOC-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000004568 cement Substances 0.000 abstract description 12
- 239000000463 material Substances 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 9
- 238000005507 spraying Methods 0.000 abstract description 8
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 6
- 239000011575 calcium Substances 0.000 abstract description 6
- 229910052791 calcium Inorganic materials 0.000 abstract description 6
- 241000195493 Cryptophyta Species 0.000 abstract description 5
- 239000010440 gypsum Substances 0.000 abstract description 5
- 229910052602 gypsum Inorganic materials 0.000 abstract description 5
- 239000007921 spray Substances 0.000 abstract description 4
- 238000005096 rolling process Methods 0.000 abstract description 2
- 239000006260 foam Substances 0.000 description 9
- 239000002002 slurry Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229940037003 alum Drugs 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000000465 moulding Methods 0.000 description 4
- 238000000053 physical method Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000700647 Variola virus Species 0.000 description 1
- ZEMWIYASLJTEHQ-UHFFFAOYSA-J aluminum;sodium;disulfate;dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZEMWIYASLJTEHQ-UHFFFAOYSA-J 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009415 formwork Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical class CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/50—Defoamers, air detrainers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a kind of surface defoamer mother liquor and surface defoamer for inorganic decorating board, the surface defoamer mother liquor provided, compounded by the component of following parts by weight and obtained：26~42 parts of fatty acid methyl ester ethoxylates, 15~28 parts of isomery alcohol ethers, 3~8 parts of butyl glycol ethers, 0.1~0.3 part of organic silicon modified by polyether and 21.7~55.9 parts of clear water；The surface defoamer provided is compounded by the component of following parts by weight and obtained：1.95~3.6 parts of surface defoamer mother liquors, 0.48~3.6 part of sulfate, 92.8~97.57 parts of clear water；The surface debubbling method provided uses aforementioned surfaces defoamer, by coat, brush, apply rolling or pneumatic spraying mode spray in forming decorative board die surface and inner chamber.Above-mentioned surface defoamer mother liquor and surface defoamer can be used for the defoaming of the inorganic decorating sheet material decorative cover such as algae calcium base, gypsum base, cement base, have that defoaming is rapid, stablizes the advantages of thorough.
Description
Technical field
The present invention relates to a kind of inorganic decorating plate surface defoaming technology, belongs to fine chemistry industry auxiliary agent field.
Background technology
Using algae calcium base, gypsum base, cement base as the algae calcium ecological ornamental plate of binder materials, high-strength crystalline substance in inorganic decorative panel
Body decorated gypsum board, pre-injection type glass fiber reinforced gypsum composite (GRG), cement base decorative panel such as glass fibre are surged mud
Composite (GRC), and inorganic mineral base low-temp ceramics plate (CBC), pour into a mould or suppress by inorganic coagulation material normal temperature or
Extruding or injection molding.Because of its excellent plastic and pliability, the geometries such as single-curved surface, hyperboloid, three-dimensional clad can be formed,
And the design such as hollow out decorative pattern, embossing pattern, non-linearity.While with plastic decoration expressive force, also with non-ignitable
Fire prevention, and absorbing sound and lowering noise, the environment-friendly function, especially algae such as insulation assigned because porous existing for microcosmic in various degree
The ecological functions such as also there is calcium ecological ornamental plate formaldehyde/benzene cleaning harmful gas, negative oxygen ion to induce, automatic humidity-regulating, it is full well
Foot people make the life better, the demand of working space environment, the field such as medical treatment, administrative, finance, education as decorative wall panels,
Smallpox, floor, outer curtain wall etc. are widely applied.
One of existing industry issue is inorganic decorative panel always in the application：It is strong in order to improve production efficiency and product
Degree, semi-automatic stirring is converted by stirring by hand in production technology, or even continuously stirred, thus slurry is carried secretly in whipping process
Air and contain a large amount of bubbles, in addition adding of fiber enhancing in general technology, improve cement viscosity and also cause the stream of slurry
Dynamic property declines, after the two aspects cause slurry to enter in mould, in die face because of the work of the surface tension of liquid-vapor interface
With when the spontaneous illiquidity of slurry or under mode of vibration, when being not enough to destroy this tension force, in localized interface retention stomata
Or defect, and product surface is with the presence or absence of the primary outward appearance matter that the stomata or micropore for influenceing decorative effect are aforementioned applications products
Amount.At present, a part of producer is confined to artificial stirring at low speed, falls mould, die surface coating prime cement face in industry, and it is strong to form work
The pernicious production models such as degree is high, operating environment slurry splashes.Another part producer is then using spraying organic silicon emulsion and vibration work
Skill defoams, and the defects of antifoaming speed is slow on the one hand be present, is not suitable for rapid-hardening binder materials, and mixes tributyl phosphate class
Defoamer, then erosion can be produced to surface texture, make the easy efflorescence of product surface；On the other hand, to the requirement of the mobility of slurry compared with
Height, defoaming effect is extremely unstable, and only 70~80%, the later stage needs a large amount of product front pore-free (or micropore) appearance yield
Manpower go to select and repair.
The content of the invention
It is an object of the invention to provide a kind of surface defoamer mother liquor and surface defoamer for inorganic decorating board, fits
The dicoration of the rapid hardenings of the binder materials slurries such as Ying Yuzao calcium base, gypsum base, cement base, production technology and product surface will
Ask.
To achieve the above object, the surface defoamer mother liquor provided by the present invention for inorganic decorating board, by following heavy
The component of amount part is compounded and obtained：26~42 parts of fatty acid methyl ester ethoxylates (FMEE), 15~28 parts of isomery alcohol ethers (can be selected
TO-10), 3~8 parts of butyl glycol ethers, 0.1~0.3 part of organic silicon modified by polyether and 21.7~55.9 parts of clear water.
The structural formula of the isomery alcohol ether is：RO-(C2H4O)n- H, wherein, R is generally C8, C10, C11 or C13, and n is general
For 3,5,6,7,8,10,12,15 or 20, it is preferred to use BASF TO-10.
Preferably, 30 points are mixed after the surface defoamer mother liquor is measured respectively in proportion at normal temperatures by each component
Clock compounding forms.
Preferably, for the pH value of the surface defoamer mother liquor between 6.5~7.1, outward appearance is colourless transparent solution.
Preferably, the surface defoamer mother liquor by fatty acid methyl ester ethoxylate, isomery alcohol ether, butyl glycol ether,
Organic silicon modified by polyether, clear water are by weight 40:20:5:0.1:34.9 compound and obtain.
Preferably, the surface defoamer mother liquor by fatty acid methyl ester ethoxylate, isomery alcohol ether, butyl glycol ether,
Organic silicon modified by polyether, clear water are by weight 40:20:5:0.1:34.9 compound and obtain.
Invention also provides a kind of surface defoamer for inorganic decorating board, is compounded by the component of following parts by weight
And obtain：1.95~3.6 parts of surface defoamer mother liquors, 0.48~3.6 part of sulfate, 92.8~97.57 parts of clear water, the surface disappears
Infusion mother liquor is aforementioned surfaces defoamer mother liquor.
Preferably, the surface defoamer is stirred by the surface defoamer mother liquor, sulfate, clear water through metering, normal temperature mixing
Mix 3 minutes compoundings and obtain.
Preferably, the sulfate is one or both of alum, sodium sulphate.Industry or agricultural sulphur can be selected
Sour aluminium potassium, sodium sulphate.
Preferably, the surface defoamer is by weight by 2.0 parts of surface defoamer mother liquors, 1.9 parts of alums, 94.7
Part clear water is compounded and obtained.
During concrete application, aforementioned surfaces defoamer mother liquor is prepared first and (step is omitted when having ready-made surface defoamer mother liquor
Suddenly aforementioned surfaces defoamer (step is omitted when having ready-made surface defoamer)), then by surface defoamer mother liquor is prepared, is finally led to
Cross coating, brushing, painting rolling or pneumatic spraying mode to spray in forming decorative board die surface and inner chamber, it is preferred to use air pressure sprays
Painting mode.
The beneficial effects of the invention are as follows：
(1) the surface defoamer mother liquor for inorganic decorating board provided, its all components are all water-soluble component, female
For liquid pH value between 6.5~7.1, appearance color is colourless transparent solution, inorganic decorating plate surface will not be caused any greasy dirt,
Variegated and surface erosion influences, and retains the moist defoaming effect of plaque surface texture, also the water paint to the later stage,
The water base property system such as water-based ink has good wetting compatibility, no film coated surface defect；
(2) the surface defoamer for inorganic decorating board provided, introduce such as industry or agricultural alum, sulphur
The sulfate such as sour sodium, there is peptizaiton to solution-air surface tension between slurry and mould, effectively reduce surface tension, at the same it is right
Have in inorganic coagulation material and promote solidifying humidification；
(3) surface that the surface defoamer provided is used for inorganic decorating board defoams, with existing traditional inorganic decorating board table
Compared in the defoaming technology of face by the way of bottoming slurry, at least reduce prime cement powder feed, prime cement liquid feed, prime cement material and mix
Stirring, prime cement material coating (spray) four procedure are closed, reduces labor intensity, while it also avoid shadow of the prime cement to operating environment
Ring；In used surface defoamer, all components all can water-soluble, water white transparency, neutral solution, without any excitant taste,
Pneumatic spraying can be carried out continuously, application is convenient and simple.
Brief description of the drawings
Fig. 1 is that surface defoamer is prepared in the embodiment of the present invention and carries out the process chart of surface defoaming.
Embodiment
The present invention is described in further detail with specific embodiment below in conjunction with the accompanying drawings.However, the scope of the present invention
It is not limited to following embodiments.
Embodiment 1：Defoamed applied to algae calcium ecological decoration sheet material surface
1st, formula composition (physical measurement unit is parts by weight)：
(1) 2.0 parts of defoamer mother liquor, changed by fatty acid methyl ester ethoxylate, isomery alcohol ether, butyl glycol ether, polyethers
Property organosilicon, clear water press 40:20:5:0.1:34.9 compound and obtain；
(2) agricultural uses 1.9 parts of alum
(3) 96.1 parts of clear water
2nd, prepared by production, and technological process is as shown in Figure 1：
(1) defoamer mother liquor：By 40 parts of fatty acid methyl ester ethoxylate FMEE, 20 parts of isomery alcohol ether TO-10,5 parts of second
Glycol butyl ether, 0.1 part of organic silicon modified by polyether, 34.9 parts of clear water, metering mixes 30 minutes respectively in proportion at normal temperatures
Compounding forms.
(2) defoamer prepares application：2.0 parts of surface defoamer mother liquors, 1.9 parts of alums, 94.7 parts of clear water through metering,
Normal temperature is sprayed onto inorganic decorating board molding die surface application after mixing 3 minutes in a manner of pneumatic spraying.
Embodiment 2：Defoamed applied to high-strength crystal gauge stuff plate surface
1st, formula composition (physical measurement unit is parts by weight)：
(1) 3 parts of defoamer mother liquor, by fatty acid methyl ester ethoxylate, isomery alcohol ether, butyl glycol ether, polyether-modified
Organosilicon, clear water press 40:20:5:0.1:34.9 compound and obtain；
(2) agricultural uses 1.2 parts of sodium sulphate
(3) 97.57 parts of clear water
2nd, prepared by production, and technological process is as shown in Figure 1：
(1) defoamer mother liquor：By 40 parts of fatty acid methyl ester ethoxylate FMEE, 20 parts of isomery alcohol ether TO-10,5 parts of second
Glycol butyl ether, 0.1 part of organic silicon modified by polyether, 34.9 parts of clear water, metering mixes 30 minutes respectively in proportion at normal temperatures
Compounding forms.
(2) defoamer prepares application：3 parts of surface defoamer mother liquors, 1.2 parts of sodium sulphate, 97.57 parts of clear water, respectively through meter
Amount, normal temperature are sprayed onto inorganic decorating board molding die surface application after mixing 3 minutes in a manner of pneumatic spraying.
Embodiment 3
1st, formula composition (physical measurement unit is parts by weight)：
(1) 1.95 parts of defoamer mother liquor, changed by fatty acid methyl ester ethoxylate, isomery alcohol ether, butyl glycol ether, polyethers
Property organosilicon, clear water press 26:15:3:0.1:55.9 compound and obtain；
(2) agricultural uses 0.48 part of alum
(3) 97.57 parts of clear water
2nd, prepared by production, and technological process is as shown in Figure 1：
(1) defoamer mother liquor：By 26 parts of fatty acid methyl ester ethoxylate FMEE, 15 parts of isomery alcohol ether TO-10,3 parts of second
Glycol butyl ether, 0.1 part of organic silicon modified by polyether, 55.9 parts of clear water, metering mixes 30 minutes respectively in proportion at normal temperatures
Compounding forms.
(2) defoamer prepares application：1.95 parts of surface defoamer mother liquors, 0.48 part of alum, 97.57 parts of clear water are through meter
Amount, normal temperature are sprayed onto inorganic decorating board molding die surface application after mixing 3 minutes in a manner of pneumatic spraying.
Embodiment 4
1st, formula composition (physical measurement unit is parts by weight)：
(1) 3.6 parts of defoamer mother liquor, changed by fatty acid methyl ester ethoxylate, isomery alcohol ether, butyl glycol ether, polyethers
Property organosilicon, clear water press 42:28:8:0.3:21.7 compound and obtain；
(2) agricultural uses 3.6 parts of alum
(3) 92.8 parts of clear water
2nd, prepared by production, and technological process is as shown in Figure 1：
(1) defoamer mother liquor：By 42 parts of fatty acid methyl ester ethoxylate FMEE, 28 parts of isomery alcohol ether TO-10,8 parts of second
Glycol butyl ether, 0.3 part of organic silicon modified by polyether, 21.7 parts of clear water, metering mixes 30 minutes respectively in proportion at normal temperatures
Compounding forms.
(2) defoamer prepares application：3.6 parts of surface defoamer mother liquors, 3.6 parts of alums, 92.8 parts of clear water through metering,
Normal temperature is sprayed onto inorganic decorating board molding die surface application after mixing 3 minutes in a manner of pneumatic spraying.
Embodiment measure of merit
Defoamer performance test methods
1st, the product surface porosity
2nd, suds suppressing properties test is defoamed
Foam liquid neopelex：TX-10：Clear water=5:5:90
Antifoam performance：At room temperature, 50ml foam liquids are added in 100ml tool plug graduated cylinders, concussion 20 times up and down, foams
When product reaches 100ml, the defoamer of foam number 0.5% is added, while starts the time that stopwatch record foam is wholly absent, time
The antifoam performance of shorter explanation defoamer is better.
Suds suppressing properties：100ml foam liquids are added in 500ml graduated cylinders, add defoaming of the dosage for foaming liquid measure 0.5%
Agent, will be with N2Air-blowing bubble in the connected glass tube insertion foam liquid of bottle, controls N2Flow is 4L/min, and record foam volume reaches
Time needed for 500ml, the time is longer, illustrates that the suds suppressing properties of defoamer are better.
Test result see the table below：
For ease of comparing, conventional prime cement mode, conventional water-soluble organic silicon are chosen as a comparison.As can be known from the above table, implement
The apparent porosity of example 1 and embodiment 2, foam time, suds time are significantly better than conventional water-soluble organic silicon.
Claims (8)
1. a kind of surface defoamer mother liquor for inorganic decorating board, it is characterised in that by the component compounding of following parts by weight
：26~42 parts of fatty acid methyl ester ethoxylates, 15~28 parts of isomery alcohol ethers, 3~8 parts of butyl glycol ethers, 0.1~0.3 part
Organic silicon modified by polyether and 21.7~55.9 parts of clear water.
2. the surface defoamer mother liquor according to claim 1 for inorganic decorating board, it is characterised in that the surface disappears
Infusion mother liquor mixes 30 minutes compoundings and formed after being measured respectively in proportion at normal temperatures by each component.
3. the surface defoamer mother liquor according to claim 1 for inorganic decorating board, it is characterised in that the surface disappears
The pH value of infusion mother liquor is between 6.5~7.1.
4. the surface defoamer mother liquor according to claim 1 for inorganic decorating board, it is characterised in that the surface disappears
Infusion mother liquor by fatty acid methyl ester ethoxylate, isomery alcohol ether, butyl glycol ether, organic silicon modified by polyether, clear water by weight
Than 40:20:5:0.1:34.9 compound and obtain.
5. a kind of compound the surface defoamer formed using such as defoamer mother liquor in surface according to any one of claims 1 to 4,
Characterized in that, compounded by the component of following parts by weight and obtained：1.95~3.6 parts of surface defoamer mother liquors, 0.48~3.6 part of sulphur
Hydrochlorate and 92.8~97.57 parts of clear water.
6. the surface defoamer according to claim 5 for inorganic decorating board, it is characterised in that defoamed by the surface
Agent mother liquor, sulfate, clear water mix 3 minutes compoundings through metering, normal temperature and obtained.
7. the surface defoamer according to claim 5 for inorganic decorating board, it is characterised in that the sulfate is sulphur
One or both of sour aluminium potassium, sodium sulphate.
8. the surface defoamer according to claim 5 for inorganic decorating board, it is characterised in that the surface defoamer
Compounded and obtained by 2.0 parts of surface defoamer mother liquors, 1.9 parts of alums, 94.7 parts of clear water by weight.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511030777.3A CN105731869B (en) | 2015-12-31 | 2015-12-31 | Surface defoamer mother liquor and surface defoamer for inorganic decorating board |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511030777.3A CN105731869B (en) | 2015-12-31 | 2015-12-31 | Surface defoamer mother liquor and surface defoamer for inorganic decorating board |
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| Publication Number | Publication Date |
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| CN105731869A CN105731869A (en) | 2016-07-06 |
| CN105731869B true CN105731869B (en) | 2018-03-16 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106365681A (en) * | 2016-08-22 | 2017-02-01 | 湖北格林森绿色环保材料股份有限公司 | Ecologic foamed decoration plate containing alga and calcium, and production method and application thereof |
| CN106746889A (en) * | 2016-11-25 | 2017-05-31 | 罗雷 | A kind of gypsum base grouting material solid defoaming agent and preparation method thereof |
| CN108129128A (en) * | 2017-12-21 | 2018-06-08 | 温州中壹技术服务有限公司 | A kind of fire-resistant composite panel and its production technology |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2688078A1 (en) * | 2007-06-06 | 2008-12-11 | Valspar Sourcing, Inc. | Single pack low temperature bake coating composition |
| CN102294132A (en) * | 2011-06-29 | 2011-12-28 | 南京四新科技应用研究所有限公司 | Defoamer for cleaning printed circuit board |
| CN104017543A (en) * | 2014-05-23 | 2014-09-03 | 上海轶臣自动化科技有限公司 | Power plant coal conveying system environment-friendly type composite dust depositing agent |
| CN104946417A (en) * | 2015-06-19 | 2015-09-30 | 深圳市恒纬祥科技有限公司 | Washing agent |
| CN105199395A (en) * | 2015-09-28 | 2015-12-30 | 江苏惠丰润滑材料股份有限公司 | Organosilicon waterborne emulsion and preparation method thereof |
-
2015
- 2015-12-31 CN CN201511030777.3A patent/CN105731869B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2688078A1 (en) * | 2007-06-06 | 2008-12-11 | Valspar Sourcing, Inc. | Single pack low temperature bake coating composition |
| CN102294132A (en) * | 2011-06-29 | 2011-12-28 | 南京四新科技应用研究所有限公司 | Defoamer for cleaning printed circuit board |
| CN104017543A (en) * | 2014-05-23 | 2014-09-03 | 上海轶臣自动化科技有限公司 | Power plant coal conveying system environment-friendly type composite dust depositing agent |
| CN104946417A (en) * | 2015-06-19 | 2015-09-30 | 深圳市恒纬祥科技有限公司 | Washing agent |
| CN105199395A (en) * | 2015-09-28 | 2015-12-30 | 江苏惠丰润滑材料股份有限公司 | Organosilicon waterborne emulsion and preparation method thereof |
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