CN105713545A - Adhesive for handles of ceramic cups - Google Patents

Adhesive for handles of ceramic cups Download PDF

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Publication number
CN105713545A
CN105713545A CN201610196422.XA CN201610196422A CN105713545A CN 105713545 A CN105713545 A CN 105713545A CN 201610196422 A CN201610196422 A CN 201610196422A CN 105713545 A CN105713545 A CN 105713545A
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CN
China
Prior art keywords
parts
sufficiently mixed
add
adhesive
adhesion promoter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610196422.XA
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Chinese (zh)
Inventor
许纯荣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Blue And White Fang Ci Industry Limited-Liability Co
Original Assignee
Anhui Blue And White Fang Ci Industry Limited-Liability Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Blue And White Fang Ci Industry Limited-Liability Co filed Critical Anhui Blue And White Fang Ci Industry Limited-Liability Co
Priority to CN201610196422.XA priority Critical patent/CN105713545A/en
Publication of CN105713545A publication Critical patent/CN105713545A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J171/00—Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
    • C09J171/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J145/00—Adhesives based on homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic system; Adhesives based on derivatives of such polymers
    • C09J145/02—Coumarone-indene polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)
  • Dental Preparations (AREA)

Abstract

The invention discloses an adhesive for handles of ceramic cups and relates to the technical field of manufacturing of ceramic products. The adhesive is prepared from raw materials in parts by weight as follows: 15-20 parts of polyoxyethylene, 10-15 parts of terpene resin, 8-12 parts of fumed silica, 6-10 parts of sepiolite powder, 6-10 parts of polyacrylamide, 5-8 parts of an adhesion promoter, 4-6 parts of hydrogenated castor oil, 3-5 parts of molecular sieve raw powder, 3-5 parts of microcrystalline wax, 2-3 parts of gelatin and 60-80 parts of water. The adhesive is moderate in viscosity, clear, bright and good in high-temperature resistance, the handles can be firmly bonded to ceramic cup bodies, harmful substances and gases cannot be produced after the adhesive is subjected to high-temperature sintering, and the phenomenon of peeling-off of the handles under the effect of high temperatures can be avoided.

Description

A kind of ceramic cup is bonding agent
Technical field:
The present invention relates to ceramic article manufacturing technology field, be specifically related to a kind of ceramic cup bonding agent.
Background technology:
Ceramic cup is the conventional ceramic of one way of life, and safe and harmless, main component is Kaolin, clay, porcelain stone, china clay, coloring agent, blue and white material, lime glaze, Calx alkali glaze etc., has significantly high corrosion resistance and scour resistance.In ceramic cup manufacture process, generally first manufacture cup, finally by cup bonding on cup.Traditional handicraft be directly by cup bonding to after moistening on cup, it is easy to cup occurs dropping phenomenon.
Summary of the invention:
The technical problem to be solved is in that to provide a kind of viscosity is suitable, caking property is good, easy to use ceramic cup bonding agent.
The technical problem to be solved adopts following technical scheme to realize:
A kind of ceramic cup, bonding agent, is made up of the raw material of following parts by weight:
Polyethylene glycol oxide 15-20 part, terpene resin 10-15 part, gas-phase silica 8-12 part, sepiolite powder 6-10 part, polyacrylamide 6-10 part, adhesion promoter 5-8 part, castor oil hydrogenated 4-6 part, molecular screen primary powder 3-5 part, microwax 3-5 part, gelatin 2-3 part, water 60-80 part；
Its preparation method is as follows:
(1) terpene resin and microwax are added to the water, be then heated to fluidized state insulation 15min, add polyethylene glycol oxide and gelatin, after being sufficiently mixed under microwave frequency 2450MHz, power 800W microwave treatment 10min, obtain material I；
(2) gas-phase silica, sepiolite powder and molecular screen primary powder are sufficiently mixed, first heat to 100-110 DEG C of insulation mixing 15min, at 0-5 DEG C, stand 30min, obtain material II；
(3) in material I, add material II, polyacrylamide, adhesion promoter and castor oil hydrogenated, be sufficiently mixed after uniformly and add in ball mill, be milled to fineness less than 50 μm.
Described adhesion promoter is made up of the raw material of following parts by weight: stearic acid 9-13 part, spermol 7-11 part, butadiene rubber 5-8 part, polyoxyethylene lauryl ether 3-6 part, emulsified silicone oil 3-6 part, fluorocarbon resin 2-4 part, tributyl citrate 1-2 part, vaseline 1-2 part, carbamide 0.5-1 part, rare earth 0.05-0.1 part, its preparation method is: by stearic acid, spermol and vaseline are slowly heated after being sufficiently mixed, add butadiene rubber and tributyl citrate until completely melted, mixture is in supersonic frequency 40kHz, supersound process 15min under power 50W, then at microwave frequency 2450MHz, microwave treatment 10min under power 800W, it is subsequently adding emulsified silicone oil and fluorocarbon resin, continue microwave treatment 10min, after temperature is down to 60-70 DEG C naturally, finally add polyoxyethylene lauryl ether, carbamide and rare earth, it is sufficiently mixed uniformly.
The invention has the beneficial effects as follows: the present invention, with polyethylene glycol oxide and terpene resin for primary raw material, is aided with multiple auxiliary agent and prepares bonding agent, this binding agent modest viscosity, clarify bright, steady for cup adhering can be connected on pottery cup；Heat-resisting quantity is good, will not produce harmful substance and gas, and do not have because high temperature affects cup peeling phenomenon after high temperature sintering, and the cup of made ceramic cup finished product is firmly, easy to use.
Detailed description of the invention:
For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be easy to understand, below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
(1) 10 parts of terpene resins and 3 parts of microwaxes are added in 60 parts of water, it is then heated to fluidized state insulation 15min, add 18 parts of polyethylene glycol oxides and 2 parts of gelatin, after being sufficiently mixed under microwave frequency 2450MHz, power 800W microwave treatment 10min, obtain material I；
(2) 8 parts of gas-phase silicas, 8 parts of sepiolite powders and 3 parts of molecular screen primary powders are sufficiently mixed, first heat to 100-110 DEG C of insulation mixing 15min, at 0-5 DEG C, stand 30min, obtain material II；
(3) in material I, add material II, 6 parts of polyacrylamides, 7 parts of adhesion promoters and 4 parts of castor oil hydrogenated, be sufficiently mixed after uniformly and add in ball mill, be milled to fineness less than 50 μm.
The preparation of adhesion promoter: by 12 parts of stearic acid, 9 parts of spermols and 1 part of vaseline are slowly heated after being sufficiently mixed, add 6 parts of butadiene rubbers and 2 parts of tributyl citrate until completely melted, mixture is in supersonic frequency 40kHz, supersound process 15min under power 50W, then at microwave frequency 2450MHz, microwave treatment 10min under power 800W, it is subsequently adding 6 parts of emulsified silicone oils and 2 parts of fluorocarbon resins, continue microwave treatment 10min, after temperature is down to 60-70 DEG C naturally, finally add 5 parts of polyoxyethylene lauryl ether, 1 part of carbamide and 0.05 part of rare earth, it is sufficiently mixed uniformly.
Embodiment 2
(1) 15 parts of terpene resins and 5 parts of microwaxes are added in 80 parts of water, it is then heated to fluidized state insulation 15min, add 15 parts of polyethylene glycol oxides and 3 parts of gelatin, after being sufficiently mixed under microwave frequency 2450MHz, power 800W microwave treatment 10min, obtain material I；
(2) 10 parts of gas-phase silicas, 6 parts of sepiolite powders and 4 parts of molecular screen primary powders are sufficiently mixed, first heat to 100-110 DEG C of insulation mixing 15min, at 0-5 DEG C, stand 30min, obtain material II；
(3) in material I, add material II, 8 parts of polyacrylamides, 5 parts of adhesion promoters and 5 parts of castor oil hydrogenated, be sufficiently mixed after uniformly and add in ball mill, be milled to fineness less than 50 μm.
The preparation of adhesion promoter: by 10 parts of stearic acid, 7 parts of spermols and 2 parts of vaseline are slowly heated after being sufficiently mixed, add 5 parts of butadiene rubbers and 1 part of tributyl citrate until completely melted, mixture is in supersonic frequency 40kHz, supersound process 15min under power 50W, then at microwave frequency 2450MHz, microwave treatment 10min under power 800W, it is subsequently adding 4 parts of emulsified silicone oils and 3 parts of fluorocarbon resins, continue microwave treatment 10min, after temperature is down to 60-70 DEG C naturally, finally add 3 parts of polyoxyethylene lauryl ether, 0.5 part of carbamide and 0.05 part of rare earth, it is sufficiently mixed uniformly.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.Skilled person will appreciate that of the industry; the present invention is not restricted to the described embodiments; described in above-described embodiment and description is that principles of the invention is described; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements both fall within the claimed scope of the invention.Claimed scope is defined by appending claims and equivalent thereof.

Claims (2)

1. a ceramic cup is bonding agent, it is characterised in that be made up of the raw material of following parts by weight:
Polyethylene glycol oxide 15-20 part, terpene resin 10-15 part, gas-phase silica 8-12 part, sepiolite powder 6-10 part, polyacrylamide 6-10 part, adhesion promoter 5-8 part, castor oil hydrogenated 4-6 part, molecular screen primary powder 3-5 part, microwax 3-5 part, gelatin 2-3 part, water 60-80 part；
Its preparation method is as follows:
(1) terpene resin and microwax are added to the water, be then heated to fluidized state insulation 15min, add polyethylene glycol oxide and gelatin, after being sufficiently mixed under microwave frequency 2450MHz, power 800W microwave treatment 10min, obtain material I；
(2) gas-phase silica, sepiolite powder and molecular screen primary powder are sufficiently mixed, first heat to 100-110 DEG C of insulation mixing 15min, at 0-5 DEG C, stand 30min, obtain material II；
(3) in material I, add material II, polyacrylamide, adhesion promoter and castor oil hydrogenated, be sufficiently mixed after uniformly and add in ball mill, be milled to fineness less than 50 μm.
2. ceramic cup according to claim 1 is bonding agent, it is characterized in that, described adhesion promoter is made up of the raw material of following parts by weight: stearic acid 9-13 part, spermol 7-11 part, butadiene rubber 5-8 part, polyoxyethylene lauryl ether 3-6 part, emulsified silicone oil 3-6 part, fluorocarbon resin 2-4 part, tributyl citrate 1-2 part, vaseline 1-2 part, carbamide 0.5-1 part, rare earth 0.05-0.1 part, its preparation method is: by stearic acid, spermol and vaseline are slowly heated after being sufficiently mixed, add butadiene rubber and tributyl citrate until completely melted, mixture is in supersonic frequency 40kHz, supersound process 15min under power 50W, then at microwave frequency 2450MHz, microwave treatment 10min under power 800W, it is subsequently adding emulsified silicone oil and fluorocarbon resin, continue microwave treatment 10min, after temperature is down to 60-70 DEG C naturally, finally add polyoxyethylene lauryl ether, carbamide and rare earth, it is sufficiently mixed uniformly.
CN201610196422.XA 2016-03-30 2016-03-30 Adhesive for handles of ceramic cups Pending CN105713545A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610196422.XA CN105713545A (en) 2016-03-30 2016-03-30 Adhesive for handles of ceramic cups

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610196422.XA CN105713545A (en) 2016-03-30 2016-03-30 Adhesive for handles of ceramic cups

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Publication Number Publication Date
CN105713545A true CN105713545A (en) 2016-06-29

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107698265A (en) * 2017-09-09 2018-02-16 安徽青花坊瓷业股份有限公司 A kind of adhesive of ceramic batch
CN108587561A (en) * 2018-05-06 2018-09-28 汪涛 Convenient for the aqueous labeling agent of separation label paper when a kind of beer bottle recycling
CN108624284A (en) * 2018-05-06 2018-10-09 汪涛 A kind of technique preparing aqueous labeling agent using ultrasonic-microwave collaboration method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1381059A (en) * 1972-08-07 1975-01-22 Kahla Veb Porzellan Attaching handles to cups or the like
CN1338445A (en) * 2000-08-10 2002-03-06 湖南省工艺品进出口公司 Technique for dry linking ceramics
CN102775950A (en) * 2012-07-05 2012-11-14 江苏碧松照明电气有限公司 Automobile sealant

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1381059A (en) * 1972-08-07 1975-01-22 Kahla Veb Porzellan Attaching handles to cups or the like
CN1338445A (en) * 2000-08-10 2002-03-06 湖南省工艺品进出口公司 Technique for dry linking ceramics
CN102775950A (en) * 2012-07-05 2012-11-14 江苏碧松照明电气有限公司 Automobile sealant

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李子东等: "《胶黏剂助剂》", 30 June 2009, 化学工业出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107698265A (en) * 2017-09-09 2018-02-16 安徽青花坊瓷业股份有限公司 A kind of adhesive of ceramic batch
CN108587561A (en) * 2018-05-06 2018-09-28 汪涛 Convenient for the aqueous labeling agent of separation label paper when a kind of beer bottle recycling
CN108624284A (en) * 2018-05-06 2018-10-09 汪涛 A kind of technique preparing aqueous labeling agent using ultrasonic-microwave collaboration method

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Application publication date: 20160629

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