CN107698265A - A kind of adhesive of ceramic batch - Google Patents

A kind of adhesive of ceramic batch Download PDF

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Publication number
CN107698265A
CN107698265A CN201710808667.8A CN201710808667A CN107698265A CN 107698265 A CN107698265 A CN 107698265A CN 201710808667 A CN201710808667 A CN 201710808667A CN 107698265 A CN107698265 A CN 107698265A
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parts
adhesive
heated
ceramic batch
modifying agent
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许纯荣
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Anhui Blue And White Fang Ci Industry Limited-Liability Co
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Anhui Blue And White Fang Ci Industry Limited-Liability Co
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
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    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/632Organic additives
    • C04B35/634Polymers
    • C04B35/63404Polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
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    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
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    • C04B35/63448Polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B35/63456Polyurethanes; Polyisocyanates
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
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    • C04B35/634Polymers
    • C04B35/63448Polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B35/63488Polyethers, e.g. alkylphenol polyglycolether, polyethylene glycol [PEG], polyethylene oxide [PEO]
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/632Organic additives
    • C04B35/636Polysaccharides or derivatives thereof

Abstract

The invention discloses a kind of adhesive of ceramic batch, it is related to ceramic fabrication technique field, the present invention is using flake asbestos, paraffin, sepiolite powder as primary raw material, plus polyurethane, oxidic polyethylene, activated carbon, nitrile rubber, and it is aided with the auxiliary materials such as rosin, epoxidized soybean oil, lignin fiber, modifying agent, obtained adhesive viscosities are high, fine and smooth, the feature of environmental protection is good, and has preferable heat-resisting quantity and fastness.

Description

A kind of adhesive of ceramic batch
Technical field:
The present invention relates to ceramic fabrication technique field, and in particular to a kind of adhesive of ceramic batch.
Background technology:
Ceramics are the general names of pottery and porcelain.Common ceramic material has clay, aluminum oxide, kaolin etc..Ceramic material General hardness is higher, but plasticity is poor.Except being used in feeder, on decoration in addition to, ceramics science, technology development in also play the part of Drill key player.Ceramic raw material is that the original ample resources clay of the earth forms by quenching to take.And the property tool toughness of clay, Normal temperature chance water is plastic, and micro- do can carve, absolutely dry to grind;Water can be filled into pottery by burning to 700 degree;Burn to 1230 degree of then porcelain, can be several Do not absorb water completely and corrosion-and high-temp-resistant.The elasticity of its usage, there is the application of various intention in culture today science and technology.
Ceramic batch is in manufacturing process, it is necessary to which stronger viscosity is in order to the shaping of blank, the higher blank warp of viscosity After calcining, toughness is high, and wearability is good, is not easy to break.
The content of the invention:
The technical problems to be solved by the invention are to provide a kind of adhesive of ceramic batch.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of adhesive of ceramic batch, is made up of the raw material of following parts by weight:
Flake asbestos 25-30 parts, paraffin 12-15 parts, sepiolite powder 10-15 parts, polyurethane 8-11 parts, oxidic polyethylene 6-10 Part, activated carbon 5-8 parts, nitrile rubber 5-8 parts, curing accelerator 4-6 parts, rosin 3-5 parts, epoxidized soybean oil 3-5 parts, lignin are fine Tie up 2-3 parts, sulphur 1-2 parts, modifying agent 3-6 parts, water 100-150 parts.
Further, the adhesive of the ceramic batch, it is made up of the raw material of following parts by weight:
28 parts of flake asbestos, 13 parts of paraffin, 12 parts of sepiolite powder, 10 parts of polyurethane, 8 parts of oxidic polyethylene, 7 parts of activated carbon, 7 parts of nitrile rubber, 5 parts of curing accelerator, 4 parts of rosin, 4 parts of epoxidized soybean oil, 3 parts of lignin fiber, 2 parts of sulphur, modifying agent 5 Part, 125 parts of water.
Further, the modifying agent is made up of the component of following parts by weight:Potato starch 3-5 parts, cornstarch 3-5 Part, tapioca 3-5 parts, wheat bran 1-3 parts, glutinous rice flour 2-4 parts, alkali lye 4-8 parts, borax 2-3 parts.
Further, the component of the preferably following parts by weight of the modifying agent is formed:4 parts of potato starch, 4 parts of cornstarch, 4 parts of tapioca, 2 parts of wheat bran, 3 parts of glutinous rice flour, 6 parts of alkali lye, 2 parts of borax.
Its preparation method comprises the following steps:
(1) flake asbestos and sepiolite powder are added into water, immersion 30min is heated to reflux state isothermal holding 15min, then Lignin fiber and rosin are added, continues isothermal holding 10min, produces material I;
(2) paraffin, polyurethane and oxidic polyethylene are sufficiently mixed, add nitrile rubber and epoxidized soybean oil, carried out Heating stirring, 120-140 DEG C of insulated and stirred 10min is first heated to, then proceedes to be heated to 150-180 DEG C of insulated and stirred 5min, Mixing speed is 400-500r/min, produces material II;
(3) material II, activated carbon, curing accelerator, modifying agent are added into material I, with stirring after being sufficiently mixed uniformly Machine is quickly stirred, mixing speed 1000-1200r/min;
(4) material being stirred is added in ball mill, is milled to fineness less than 15 μm.
Further, the preparation method of the modifying agent comprises the following steps:
Potato starch, cornstarch, tapioca, wheat bran, glutinous rice flour, alkali lye, borax are mixed, mixture is beaten Breakdown mill processing, the mixture after grinding is heated, and heating-up temperature is 120-150 degree, and the heat time is 20-30 minutes, The mixture heated is added in agitator and carries out insulated and stirred, mixing speed 1200-1400r/min, keeping temperature is 80-90 degree.
The beneficial effects of the invention are as follows:The present invention using flake asbestos, paraffin, sepiolite powder as primary raw material, plus polyurethane, Oxidic polyethylene, activated carbon, nitrile rubber, and it is aided with the auxiliary materials such as rosin, epoxidized soybean oil, lignin fiber, modifying agent, it is obtained Adhesive viscosities are high, and fine and smooth, the feature of environmental protection is good, and has preferable heat-resisting quantity and fastness.
Embodiment:
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of adhesive of ceramic batch, is made up of the raw material of following parts by weight:
25 parts of flake asbestos, 12 parts of paraffin, 10 parts of sepiolite powder, 8 parts of polyurethane, 6 parts of oxidic polyethylene, 5 parts of activated carbon, fourth Fine 5 parts of rubber, 4 parts of curing accelerator, 3 parts of rosin, 3 parts of epoxidized soybean oil, 2 parts of lignin fiber, 1 part of sulphur, 3 parts of modifying agent, 100 parts of water.
Further, the modifying agent is made up of the component of following parts by weight:3 parts of potato starch, 3 parts of cornstarch, wood 3 parts of sweet potato starch, 1 part of wheat bran, 2 parts of glutinous rice flour, 4 parts of alkali lye, 2 parts of borax.
Its preparation method comprises the following steps:
(1) flake asbestos and sepiolite powder are added into water, immersion 30min is heated to reflux state isothermal holding 15min, then Lignin fiber and rosin are added, continues isothermal holding 10min, produces material I;
(2) paraffin, polyurethane and oxidic polyethylene are sufficiently mixed, add nitrile rubber and epoxidized soybean oil, carried out Heating stirring, 120 DEG C of insulated and stirred 10min are first heated to, then proceed to be heated to 150 DEG C of insulated and stirred 5min, mixing speed For 400r/min, material II is produced;
(3) material II, activated carbon, curing accelerator, modifying agent are added into material I, with stirring after being sufficiently mixed uniformly Machine is quickly stirred, mixing speed 1000r/min;
(4) material being stirred is added in ball mill, is milled to fineness less than 15 μm.
Further, the preparation method of the modifying agent comprises the following steps:
Potato starch, cornstarch, tapioca, wheat bran, glutinous rice flour, alkali lye, borax are mixed, mixture is beaten Breakdown mill processing, the mixture after grinding is heated, and heating-up temperature is 120 degree, and the heat time is 20 minutes, will be heated Mixture add in agitator and carry out insulated and stirred, mixing speed 1200r/min, keeping temperature is 80 degree.
Embodiment 2
A kind of adhesive of ceramic batch, is made up of the raw material of following parts by weight:
30 parts of flake asbestos, 15 parts of paraffin, 15 parts of sepiolite powder, 11 parts of polyurethane, 10 parts of oxidic polyethylene, 8 parts of activated carbon, 8 parts of nitrile rubber, 6 parts of curing accelerator, 5 parts of rosin, 5 parts of epoxidized soybean oil, 3 parts of lignin fiber, 2 parts of sulphur, modifying agent 6 Part, 150 parts of water.
Further, the modifying agent is made up of the component of following parts by weight:5 parts of potato starch, 5 parts of cornstarch, wood 5 parts of sweet potato starch, 3 parts of wheat bran, 4 parts of glutinous rice flour, 8 parts of alkali lye, 3 parts of borax.
Its preparation method comprises the following steps:
(1) flake asbestos and sepiolite powder are added into water, immersion 30min is heated to reflux state isothermal holding 15min, then Lignin fiber and rosin are added, continues isothermal holding 10min, produces material I;
(2) paraffin, polyurethane and oxidic polyethylene are sufficiently mixed, add nitrile rubber and epoxidized soybean oil, carried out Heating stirring, 140 DEG C of insulated and stirred 10min are first heated to, then proceed to be heated to 180 DEG C of insulated and stirred 5min, mixing speed For 500r/min, material II is produced;
(3) material II, activated carbon, curing accelerator, modifying agent are added into material I, with stirring after being sufficiently mixed uniformly Machine is quickly stirred, mixing speed 1200r/min;
(4) material being stirred is added in ball mill, is milled to fineness less than 15 μm.
Further, the preparation method of the modifying agent comprises the following steps:
Potato starch, cornstarch, tapioca, wheat bran, glutinous rice flour, alkali lye, borax are mixed, mixture is beaten Breakdown mill processing, the mixture after grinding is heated, and heating-up temperature is 150 degree, and the heat time is 30 minutes, will be heated Mixture add in agitator and carry out insulated and stirred, mixing speed 1400r/min, keeping temperature is 90 degree.
Control group 1
A kind of adhesive of ceramic batch, is made up of the raw material of following parts by weight:
25 parts of flake asbestos, 12 parts of paraffin, 10 parts of sepiolite powder, 8 parts of polyurethane, 6 parts of oxidic polyethylene, 5 parts of activated carbon, fourth Fine 5 parts of rubber, 4 parts of curing accelerator, 3 parts of rosin, 3 parts of epoxidized soybean oil, 2 parts of lignin fiber, 1 part of sulphur, 100 parts of water.
Its preparation method comprises the following steps:
(1) flake asbestos and sepiolite powder are added into water, immersion 30min is heated to reflux state isothermal holding 15min, then Lignin fiber and rosin are added, continues isothermal holding 10min, produces material I;
(2) paraffin, polyurethane and oxidic polyethylene are sufficiently mixed, add nitrile rubber and epoxidized soybean oil, carried out Heating stirring, 120 DEG C of insulated and stirred 10min are first heated to, then proceed to be heated to 150 DEG C of insulated and stirred 5min, mixing speed For 400r/min, material II is produced;
(3) material II, activated carbon, curing accelerator are added into material I, is carried out soon with mixer after being sufficiently mixed uniformly Speed stirring, mixing speed 1000r/min;
(4) material being stirred is added in ball mill, is milled to fineness less than 15 μm.
Control group 2
A kind of adhesive of ceramic batch, is made up of the raw material of following parts by weight:
30 parts of flake asbestos, 15 parts of paraffin, 15 parts of sepiolite powder, 11 parts of polyurethane, 10 parts of oxidic polyethylene, 8 parts of activated carbon, 8 parts of nitrile rubber, 6 parts of curing accelerator, 5 parts of rosin, 5 parts of epoxidized soybean oil, 3 parts of lignin fiber, 2 parts of sulphur, modifying agent 6 Part, 150 parts of water.
Further, the modifying agent is made up of the component of following parts by weight:5 parts of potato starch, 5 parts of cornstarch, wood 5 parts of sweet potato starch, 3 parts of wheat bran, 4 parts of glutinous rice flour, 8 parts of alkali lye, 3 parts of borax.
Its preparation method comprises the following steps:
(1) flake asbestos, sepiolite powder, lignin fiber and rosin are added into water, immersion 30min is heated to reflux state guarantor Temperature processing 15min, produces material I;
(2) paraffin, polyurethane and oxidic polyethylene are sufficiently mixed, add nitrile rubber and epoxidized soybean oil, carried out Heating, 180 DEG C of insulation 5min are heated to, produce material II;
(3) material II, activated carbon, curing accelerator, modifying agent are added into material I, is sufficiently mixed uniformly;
(4) material being stirred is added in ball mill, is milled to fineness less than 15 μm.
Further, the preparation method of the modifying agent comprises the following steps:
Potato starch, cornstarch, tapioca, wheat bran, glutinous rice flour, alkali lye, borax are mixed, mixture is beaten Heated after broken, heating-up temperature is 150 degree, and the heat time is 30 minutes.
Table 1 is the present invention and the Experimental Comparison result of control group
The adhesive for the ceramic batch that the present invention produces, viscosity is high, and fine and smooth, the feature of environmental protection is good, has preferable high temperature resistant Property and fastness, are a kind of adhesives of high-quality ceramic batch.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (6)

1. a kind of adhesive of ceramic batch, is made up of the raw material of following parts by weight:
Flake asbestos 25-30 parts, paraffin 12-15 parts, sepiolite powder 10-15 parts, polyurethane 8-11 parts, oxidic polyethylene 6-10 parts, Activated carbon 5-8 parts, nitrile rubber 5-8 parts, curing accelerator 4-6 parts, rosin 3-5 parts, epoxidized soybean oil 3-5 parts, lignin fiber 2-3 parts, sulphur 1-2 parts, modifying agent 3-6 parts, water 100-150 parts.
2. the adhesive of ceramic batch according to claim 1, it is characterised in that the adhesive of the ceramic batch, by The raw material of following parts by weight is made:28 parts of flake asbestos, 13 parts of paraffin, 12 parts of sepiolite powder, 10 parts of polyurethane, oxidic polyethylene 8 parts, 7 parts of activated carbon, 7 parts of nitrile rubber, 5 parts of curing accelerator, 4 parts of rosin, 4 parts of epoxidized soybean oil, 3 parts of lignin fiber, sulphur 2 parts of sulphur, 5 parts of modifying agent, 125 parts of water.
3. the adhesive of ceramic batch according to claim 1, it is characterised in that the modifying agent is by following parts by weight Component is formed:Potato starch 3-5 parts, cornstarch 3-5 parts, tapioca 3-5 parts, wheat bran 1-3 parts, glutinous rice flour 2-4 parts, alkali lye 4-8 parts, borax 2-3 parts.
4. the adhesive of ceramic batch according to claim 3, it is characterised in that 4 parts of potato starch, 4 parts of cornstarch, 4 parts of tapioca, 2 parts of wheat bran, 3 parts of glutinous rice flour, 6 parts of alkali lye, 2 parts of borax.
5. the adhesive of ceramic batch according to claim 1 or 2, it is characterised in that its preparation method includes following step Suddenly:
(1) flake asbestos and sepiolite powder are added into water, immersion 30min is heated to reflux state isothermal holding 15min, added Lignin fiber and rosin, continue isothermal holding 10min, produce material I;
(2) paraffin, polyurethane and oxidic polyethylene are sufficiently mixed, add nitrile rubber and epoxidized soybean oil, heated Stirring, is first heated to 120-140 DEG C of insulated and stirred 10min, then proceedes to be heated to 150-180 DEG C of insulated and stirred 5min, stirs Speed is 400-500r/min, produces material II;
(3) material II, activated carbon, curing accelerator, modifying agent are added into material I, is entered after being sufficiently mixed uniformly with mixer The quick stirring of row, mixing speed 1000-1200r/min;
(4) material being stirred is added in ball mill, is milled to fineness less than 15 μm.
6. the adhesive of the ceramic batch according to claim 3 or 4, it is characterised in that the preparation method of the modifying agent Comprise the following steps:Potato starch, cornstarch, tapioca, wheat bran, glutinous rice flour, alkali lye, borax are mixed, by mixture Carry out smashing milled processed, the mixture after grinding is heated, heating-up temperature is 120-150 degree, heat time 20-30 Minute, the mixture heated is added in agitator and carries out insulated and stirred, mixing speed 1200-1400r/min, keeps temperature Spend for 80-90 degree.
CN201710808667.8A 2017-09-09 2017-09-09 A kind of adhesive of ceramic batch Pending CN107698265A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022160075A1 (en) * 2021-01-30 2022-08-04 广东顺祥陶瓷有限公司 Bonding process for handle and body of medium-high temperature ceramic

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CN105713545A (en) * 2016-03-30 2016-06-29 安徽青花坊瓷业股份有限公司 Adhesive for handles of ceramic cups
CN105859268A (en) * 2016-03-30 2016-08-17 安徽青花坊瓷业股份有限公司 Blank material for manufacturing bone china tableware
CN106145890A (en) * 2016-06-30 2016-11-23 安徽智博新材料科技有限公司 A kind of ceramics ware for daily use handle binding agent
CN107140948A (en) * 2017-06-12 2017-09-08 安徽青花坊瓷业股份有限公司 A kind of daily bone china of high whiteness and preparation method thereof

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CN105713545A (en) * 2016-03-30 2016-06-29 安徽青花坊瓷业股份有限公司 Adhesive for handles of ceramic cups
CN105859268A (en) * 2016-03-30 2016-08-17 安徽青花坊瓷业股份有限公司 Blank material for manufacturing bone china tableware
CN106145890A (en) * 2016-06-30 2016-11-23 安徽智博新材料科技有限公司 A kind of ceramics ware for daily use handle binding agent
CN107140948A (en) * 2017-06-12 2017-09-08 安徽青花坊瓷业股份有限公司 A kind of daily bone china of high whiteness and preparation method thereof

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WO2022160075A1 (en) * 2021-01-30 2022-08-04 广东顺祥陶瓷有限公司 Bonding process for handle and body of medium-high temperature ceramic

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