CN107383715A - A kind of high-low temperature resistant fluorubber cable material - Google Patents
A kind of high-low temperature resistant fluorubber cable material Download PDFInfo
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- CN107383715A CN107383715A CN201710607889.3A CN201710607889A CN107383715A CN 107383715 A CN107383715 A CN 107383715A CN 201710607889 A CN201710607889 A CN 201710607889A CN 107383715 A CN107383715 A CN 107383715A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
- H01B3/445—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds from vinylfluorides or other fluoroethylenic compounds
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
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- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a kind of high-low temperature resistant fluorubber cable material, its raw material includes by weight：30 50 parts of modified silicon rubber, 80 100 parts of fluorubber, 50 70 parts of compounded mix, 30 50 parts of APP, 12 16 parts of Firebrake ZB, 35 parts of paraffin oil, 46 parts of epoxidized soybean oil, 1.5 2.5 parts of VTES, 1.7 2.5 parts of vulcanizing agent, 1.5 2 parts of accelerator, 24 parts of Ca/Zn compound stabilizers, 0.7 0.9 parts of anti-aging agent RD.High and low temperature resistance of the present invention is good, high mechanical strength, and incompressible permanent deformation performance is good.
Description
Technical field
The present invention relates to cable material technical field, more particularly to a kind of high-low temperature resistant fluorubber cable material.
Background technology
Fluorubber has the characteristics such as heat-resisting, oil resistant, solvent resistant, powerful oxidation corrosion resistance agent, while has good physical property, because
This is commonly used for cable material, but the poor processability of fluorubber, low temperature resistant difference, is not suitable for the big evil of some temperature differences
In bad environment, the use range of fluorubber cable material is limited.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of high-low temperature resistant fluorubber cable material, this
Invention high and low temperature resistance is good, high mechanical strength, and incompressible permanent deformation performance is good.
A kind of high-low temperature resistant fluorubber cable material proposed by the present invention, its raw material include by weight：Modified silicon rubber
30-50 parts, fluorubber 80-100 parts, compounded mix 50-70 parts, APP 30-50 parts, Firebrake ZB 12-16 parts, paraffin oil 3-
5 parts, epoxidized soybean oil 4-6 parts, VTES 1.5-2.5 parts, vulcanizing agent 1.7-2.5 parts, accelerator 1.5-2
Part, Ca/Zn compound stabilizer 2-4 parts, anti-aging agent RD 0.7-0.9 parts.
Preferably, fluorubber is inclined fluoroether rubber.
Preferably, in the preparation process of modified silicon rubber, by methyl vinyl silicone rubber and vinyl triethoxyl silicon
Alkane mixes, and heating, insulated and stirred, adds lauroyl peroxide, continues insulated and stirred, then adds p-methyl benzenesulfonic acid and 2,2- are double
To phenol propane, continue insulated and stirred, add acetone stirring, filter to take filter cake, wash, be dried to obtain modified silicon rubber.
Preferably, in the preparation process of modified silicon rubber, by methyl vinyl silicone rubber and vinyl triethoxyl silicon
Alkane mixes, and is warming up to 140-150 DEG C, with 400-600r/min speed insulated and stirred 10-14min, adds lauroyl peroxide,
Continue insulated and stirred 60-80min, then add p-methyl benzenesulfonic acid and 2,2- are double to phenol propane, continue insulated and stirred 3-4h, add
Acetone stirs 30-50min, filters to take filter cake, is washed with acetone, is dried to obtain modified silicon rubber.
Preferably, in the preparation process of modified silicon rubber, methyl vinyl silicone rubber, VTES,
The weight ratio of lauroyl peroxide is 10：2.5-3.3：0.15-0.2.
Preferably, in the preparation process of modified silicon rubber, methyl vinyl silicone rubber, p-methyl benzenesulfonic acid and 2,2- are double right
The weight ratio of phenol propane is 10：0.1-0.2：11-13.
Preferably, in the preparation process of modified silicon rubber, the bulking value (g/ of methyl vinyl silicone rubber and acetone
Ml) than being 1：3-5.
Preferably, compounded mix be organic montmorillonite, VTES modified carbon fiber, talcum powder, its
In, organic montmorillonite, VTES modified carbon fiber, the weight ratio of talcum powder are 3-5：1-1.5：2-3.
Preferably, vulcanizing agent is cumyl peroxide and double 25, wherein, cumyl peroxide and double 25 weight ratio
For 1：0.4-0.6.
Preferably, accelerator is accelerant CZ and accelerant B Z, wherein, accelerant CZ and accelerant B Z weight ratio are 1：
0.8-1。
The present invention preparation method be：After fluorubber banburying 5min, add modified silicon rubber and continue banburying 8min, Ran Houyi
Secondary addition paraffin oil, epoxidized soybean oil, VTES, compounded mix, APP, Firebrake ZB, Ca/Zn are compound
Stabilizer, anti-aging agent RD are kneaded 35min, add vulcanizing agent and accelerator sulfidization molding obtains high-low temperature resistant fluorubber cable material
Material.
The present invention has good high and low temperature resistance and relatively low compressive deformation from methyl vinyl silicone rubber；Ethene
The reaction copolymerization of ethyl triethoxy silicane alkane and methyl vinyl silicone rubber introduces hydroxyl on methyl vinyl silicone rubber, then with 2,2-
It is double phenol propane to be reacted so as to introduce phenolic hydroxyl group on methyl vinyl silicone rubber so that fluorubber and methyl vinyl silicone rubber
Blend graft, so as to while fluorubber resistance to elevated temperatures is kept, substantially improve processing characteristics, the resistance to low temperature of fluorubber
With incompressible permanent deformation performance；Can further it be increased from the fluorubber and methyl vinyl silicone rubber reaction of suitable species
The high and low temperature resistance and processing characteristics of the present invention；From organic montmorillonite, VTES modified carbon fiber,
Talcum powder coordinates paraffin oil, epoxidized soybean oil, VTES so that filler can be uniform with rubber as filler
It is scattered, so as to increase the mechanical strength and shock resistance of the present invention, and rubber can intercalation enter organic montmorillonite interlayer, can
Further to increase the impact flexibility of the present invention, VTES modified carbon fiber can cooperate with rubber, increase
Add the tear resistance of the present invention；APP, Firebrake ZB can increase the anti-flammability of the present invention；Ca/Zn compound stabilizers and
Epoxidized soybean oil cooperates, and can increase the thermal stability of the present invention；Suitable sulphur is selected according to fluorubber and silicon rubber
Agent and accelerator so that rubber cross vulcanizes to form cross-linked network, and each material is dispersed on cross-linked network, further increases
Add the mechanical performance and elasticity of the present invention；Above-mentioned each material cooperates so that the present invention have good high and low temperature resistance,
Mechanical performance and incompressible permanent deformation performance.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of high-low temperature resistant fluorubber cable material, its raw material include by weight：40 parts of modified silicon rubber, fluorubber 90
Part, 60 parts of compounded mix, 40 parts of APP, 14 parts of Firebrake ZB, 4 parts of paraffin oil, 5 parts of epoxidized soybean oil, the ethoxy of vinyl three
2 parts of base silane, 2.1 parts of vulcanizing agent, 1.7 parts of accelerator, 3 parts of Ca/Zn compound stabilizers, 0.8 part of anti-aging agent RD.
Embodiment 2
A kind of high-low temperature resistant fluorubber cable material, its raw material include by weight：30 parts of modified silicon rubber, inclined fluorine ether rubber
100 parts of glue, 50 parts of compounded mix, 50 parts of APP, 12 parts of Firebrake ZB, 5 parts of paraffin oil, 4 parts of epoxidized soybean oil, vinyl three
2.5 parts of Ethoxysilane, 1.7 parts of vulcanizing agent, 2 parts of accelerator, 2 parts of Ca/Zn compound stabilizers, 0.9 part of anti-aging agent RD；
Wherein, in the preparation process of modified silicon rubber, by methyl vinyl silicone rubber and VTES
Mix, be warming up to 140 DEG C, with 600r/min speed insulated and stirred 10min, add lauroyl peroxide, continue insulated and stirred
80min, then adds p-methyl benzenesulfonic acid and 2,2- are double to phenol propane, continues insulated and stirred 3h, adds acetone stirring 50min, mistake
Leaching filter cake, is washed with acetone, is dried to obtain modified silicon rubber, wherein, methyl vinyl silicone rubber, vinyl triethoxyl silicon
Alkane, the weight ratio of lauroyl peroxide are 10：2.5：0.2, methyl vinyl silicone rubber, p-methyl benzenesulfonic acid and 2,2- are double to phenol third
The weight ratio of alkane is 10：0.1：13, the bulking value (g/ml) of methyl vinyl silicone rubber and acetone is than being 1：3.
Embodiment 3
A kind of high-low temperature resistant fluorubber cable material, its raw material include by weight：50 parts of modified silicon rubber, inclined fluorine ether rubber
80 parts of glue, 70 parts of compounded mix, 30 parts of APP, 16 parts of Firebrake ZB, 3 parts of paraffin oil, 6 parts of epoxidized soybean oil, vinyl three
1.5 parts of Ethoxysilane, 2.5 parts of vulcanizing agent, 1.5 parts of accelerator, 4 parts of Ca/Zn compound stabilizers, 0.7 part of anti-aging agent RD；
Wherein, in the preparation process of modified silicon rubber, by methyl vinyl silicone rubber and VTES
Mix, be warming up to 150 DEG C, with 400r/min speed insulated and stirred 14min, add lauroyl peroxide, continue insulated and stirred
60min, then adds p-methyl benzenesulfonic acid and 2,2- are double to phenol propane, continues insulated and stirred 4h, adds acetone stirring 30min, mistake
Leaching filter cake, is washed with acetone, is dried to obtain modified silicon rubber, wherein, methyl vinyl silicone rubber, vinyl triethoxyl silicon
Alkane, the weight ratio of lauroyl peroxide are 10：3.3：0.15, methyl vinyl silicone rubber, p-methyl benzenesulfonic acid and 2,2- are double to phenol
The weight ratio of propane is 10：0.2：11, the bulking value (g/ml) of methyl vinyl silicone rubber and acetone is than being 1：5；
Compounded mix is organic montmorillonite, VTES modified carbon fiber, talcum powder, wherein, it is organic
Change montmorillonite, VTES modified carbon fiber, the weight ratio of talcum powder are 3：1.5：2；
Vulcanizing agent is cumyl peroxide and double 25, wherein, cumyl peroxide and double 25 weight ratio are 1：
0.6；
Accelerator is accelerant CZ and accelerant B Z, wherein, accelerant CZ and accelerant B Z weight ratio are 1：0.8.
Embodiment 4
A kind of high-low temperature resistant fluorubber cable material, its raw material include by weight：35 parts of modified silicon rubber, inclined fluorine ether rubber
95 parts of glue, 55 parts of compounded mix, 45 parts of APP, 13 parts of Firebrake ZB, 4.5 parts of paraffin oil, 4.5 parts of epoxidized soybean oil, ethene
2.2 parts of ethyl triethoxy silicane alkane, 1.9 parts of vulcanizing agent, 1.8 parts of accelerator, 2.5 parts of Ca/Zn compound stabilizers, anti-aging agent RD
0.85 part；
Wherein, in the preparation process of modified silicon rubber, by methyl vinyl silicone rubber and VTES
Mix, be warming up to 142 DEG C, with 550r/min speed insulated and stirred 11min, add lauroyl peroxide, continue insulated and stirred
75min, then adds p-methyl benzenesulfonic acid and 2,2- pairs are stirred 45min to phenol propane, continuation insulated and stirred 3.2h, addition acetone,
Filter cake is filtered to take, is washed with acetone, is dried to obtain modified silicon rubber, wherein, methyl vinyl silicone rubber, vinyl triethoxyl
Silane, the weight ratio of lauroyl peroxide are 10：2.7：0.18, methyl vinyl silicone rubber, p-methyl benzenesulfonic acid and 2,2- are double right
The weight ratio of phenol propane is 10：0.13：12.5, the bulking value (g/ml) of methyl vinyl silicone rubber and acetone is than being 1：3.5；
Compounded mix is organic montmorillonite, VTES modified carbon fiber, talcum powder, wherein, it is organic
Change montmorillonite, VTES modified carbon fiber, the weight ratio of talcum powder are 5：1：3；
Vulcanizing agent is cumyl peroxide and double 25, wherein, cumyl peroxide and double 25 weight ratio are 1：
0.4；
Accelerator is accelerant CZ and accelerant B Z, wherein, accelerant CZ and accelerant B Z weight ratio are 1：1.
Embodiment 5
A kind of high-low temperature resistant fluorubber cable material, its raw material include by weight：45 parts of modified silicon rubber, inclined fluorine ether rubber
85 parts of glue, 65 parts of compounded mix, 35 parts of APP, 15 parts of Firebrake ZB, 3.5 parts of paraffin oil, 5.5 parts of epoxidized soybean oil, ethene
1.8 parts of ethyl triethoxy silicane alkane, 2.3 parts of vulcanizing agent, 1.6 parts of accelerator, 3.5 parts of Ca/Zn compound stabilizers, anti-aging agent RD
0.75 part；
Wherein, in the preparation process of modified silicon rubber, by methyl vinyl silicone rubber and VTES
Mix, be warming up to 148 DEG C, with 450r/min speed insulated and stirred 13min, add lauroyl peroxide, continue insulated and stirred
65min, then adds p-methyl benzenesulfonic acid and 2,2- pairs are stirred 35min to phenol propane, continuation insulated and stirred 3.8h, addition acetone,
Filter cake is filtered to take, is washed with acetone, is dried to obtain modified silicon rubber, wherein, methyl vinyl silicone rubber, vinyl triethoxyl
Silane, the weight ratio of lauroyl peroxide are 10：3.1：0.16, methyl vinyl silicone rubber, p-methyl benzenesulfonic acid and 2,2- are double right
The weight ratio of phenol propane is 10：0.17：11.5, the bulking value (g/ml) of methyl vinyl silicone rubber and acetone is than being 1：4.5；
Compounded mix is organic montmorillonite, VTES modified carbon fiber, talcum powder, wherein, it is organic
Change montmorillonite, VTES modified carbon fiber, the weight ratio of talcum powder are 4：1.3：2.5；
Vulcanizing agent is cumyl peroxide and double 25, wherein, cumyl peroxide and double 25 weight ratio are 1：
0.5；
Accelerator is accelerant CZ and accelerant B Z, wherein, accelerant CZ and accelerant B Z weight ratio are 1：0.9.
Test example 1
Performance test is carried out to embodiment 1-5, and, is compared with commercially available common fluorubber cable material as a control group
Compared with as a result as follows：
As can be seen from the above table, high and low temperature resistance of the present invention is good, and incompressible permanent deformation performance is good.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (10)
1. a kind of high-low temperature resistant fluorubber cable material, it is characterised in that its raw material includes by weight：Modified silicon rubber 30-
50 parts, fluorubber 80-100 parts, compounded mix 50-70 parts, APP 30-50 parts, Firebrake ZB 12-16 parts, paraffin oil 3-5
Part, epoxidized soybean oil 4-6 parts, VTES 1.5-2.5 parts, vulcanizing agent 1.7-2.5 parts, accelerator 1.5-2 parts,
Ca/Zn compound stabilizer 2-4 parts, anti-aging agent RD 0.7-0.9 parts.
2. high-low temperature resistant fluorubber cable material according to claim 1, it is characterised in that fluorubber is inclined fluoroether rubber.
3. high-low temperature resistant fluorubber cable material according to claim 1 or claim 2, it is characterised in that in the system of modified silicon rubber
During standby, methyl vinyl silicone rubber and VTES are mixed, heating, insulated and stirred, add peroxidating
Lauroyl, continue insulated and stirred, then add p-methyl benzenesulfonic acid and 2,2- are double to phenol propane, continue insulated and stirred, add acetone
Stirring, filters to take filter cake, washs, is dried to obtain modified silicon rubber.
4. according to any one of the claim 1-3 high-low temperature resistant fluorubber cable materials, it is characterised in that in modified silicon rubber
Preparation process in, methyl vinyl silicone rubber and VTES are mixed, are warming up to 140-150 DEG C, with
400-600r/min speed insulated and stirred 10-14min, lauroyl peroxide is added, continue insulated and stirred 60-80min, then
Add p-methyl benzenesulfonic acid and 2,2- are double to phenol propane, continue insulated and stirred 3-4h, add acetone stirring 30-50min, filter to take filter
Cake, washed with acetone, be dried to obtain modified silicon rubber.
5. according to the high-low temperature resistant fluorubber cable material of claim 3 or 4, it is characterised in that in the system of modified silicon rubber
During standby, methyl vinyl silicone rubber, VTES, the weight ratio of lauroyl peroxide are 10：2.5-
3.3：0.15-0.2.
6. according to any one of the claim 3-5 high-low temperature resistant fluorubber cable materials, it is characterised in that in modified silicon rubber
Preparation process in, methyl vinyl silicone rubber, the double weight ratios to phenol propane of p-methyl benzenesulfonic acid and 2,2- are 10：0.1-0.2：
11-13。
7. according to any one of the claim 3-6 high-low temperature resistant fluorubber cable materials, it is characterised in that in modified silicon rubber
Preparation process in, the bulking value (g/ml) of methyl vinyl silicone rubber and acetone is than being 1：3-5.
8. according to any one of the claim 1-7 high-low temperature resistant fluorubber cable materials, it is characterised in that compounded mix is to have
Machine montmorillonite, VTES modified carbon fiber, talcum powder, wherein, organic montmorillonite, the ethoxy of vinyl three
Base silane modified carbon fiber, the weight ratio of talcum powder are 3-5：1-1.5：2-3.
9. according to any one of the claim 1-8 high-low temperature resistant fluorubber cable materials, it is characterised in that vulcanizing agent is peroxide
Change diisopropylbenzene (DIPB) and double 25, wherein, cumyl peroxide and double 25 weight ratio are 1：0.4-0.6.
10. according to any one of the claim 1-9 high-low temperature resistant fluorubber cable materials, it is characterised in that accelerator is rush
Enter agent CZ and accelerant B Z, wherein, accelerant CZ and accelerant B Z weight ratio are 1：0.8-1.
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| CN108530805A (en) * | 2018-05-23 | 2018-09-14 | 芜湖航天特种电缆厂股份有限公司 | High-strength anti-flaming compounded rubber and preparation method thereof |
| CN108623953A (en) * | 2018-05-23 | 2018-10-09 | 芜湖航天特种电缆厂股份有限公司 | Nontoxic fire-retardant compounded rubber of high intensity and preparation method thereof |
| CN113930078A (en) * | 2021-10-11 | 2022-01-14 | 安徽京鸿密封件技术有限公司 | Oil-resistant low-pressure-change durable silicone rubber material and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108530872A (en) * | 2018-05-02 | 2018-09-14 | 山东冬瑞高新技术开发有限公司 | A kind of cucurbit urea groups fire resistant flame retardant CABLE MATERIALS and preparation method thereof |
| CN108530805A (en) * | 2018-05-23 | 2018-09-14 | 芜湖航天特种电缆厂股份有限公司 | High-strength anti-flaming compounded rubber and preparation method thereof |
| CN108623953A (en) * | 2018-05-23 | 2018-10-09 | 芜湖航天特种电缆厂股份有限公司 | Nontoxic fire-retardant compounded rubber of high intensity and preparation method thereof |
| CN113930078A (en) * | 2021-10-11 | 2022-01-14 | 安徽京鸿密封件技术有限公司 | Oil-resistant low-pressure-change durable silicone rubber material and preparation method thereof |
| CN113930078B (en) * | 2021-10-11 | 2022-10-04 | 安徽京鸿密封件技术有限公司 | Oil-resistant low-pressure-change durable silicone rubber material and preparation method thereof |
| CN116769264A (en) * | 2023-08-24 | 2023-09-19 | 江苏中煜橡塑科技有限公司 | Fluororubber material for sealing cold-resistant power battery and preparation method and application thereof |
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Application publication date: 20171124 |