CN106348593A - Low-firing glaze for porcelain dinnerware - Google Patents

Low-firing glaze for porcelain dinnerware Download PDF

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Publication number
CN106348593A
CN106348593A CN201610921029.2A CN201610921029A CN106348593A CN 106348593 A CN106348593 A CN 106348593A CN 201610921029 A CN201610921029 A CN 201610921029A CN 106348593 A CN106348593 A CN 106348593A
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CN
China
Prior art keywords
parts
glaze
fine powder
low grade
grade fever
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610921029.2A
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Chinese (zh)
Inventor
许纯荣
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Anhui Blue And White Fang Ci Industry Limited-Liability Co
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Anhui Blue And White Fang Ci Industry Limited-Liability Co
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Application filed by Anhui Blue And White Fang Ci Industry Limited-Liability Co filed Critical Anhui Blue And White Fang Ci Industry Limited-Liability Co
Priority to CN201610921029.2A priority Critical patent/CN106348593A/en
Publication of CN106348593A publication Critical patent/CN106348593A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

The invention relates to the technical field of glaze and particularly relates to low-firing glaze for porcelain dinnerware. The low-firing glaze is prepared from the following components in parts by weight: 20-26 parts of nepheline syenite, 8-16 parts of Suzhou soil, 4-6 parts of zirconium silicate, 4-6 parts of sepiolite, 2-4 parts of potato starch ether, 2-4 parts of asbestos whisker, 2-4 parts of titanium dioxide, 2-4 parts of ground calcium carbonate, 1-2 parts of glass beads, 1-2 parts of asbolane, 4-6 parts of low-firing aids and 3-8 parts of modified zirconite. The glaze provided by the invention is nontoxic and has high adhesive force; when the glaze is fired on the surface of the porcelain dinnerware, the firing temperature is 60-100 DEG C lower than that of low-temperature glaze, and thus the damage to a porcelain body caused by high-temperature firing is avoided; and after drying and molding, the glaze is not volatilized at high temperature and has certain impact resistance.

Description

A kind of porcelain dinner-ware low grade fever's glaze
Technical field
The present invention relates to glaze technical field is and in particular to a kind of porcelain dinner-ware low grade fever's glaze.
Background technology
The ceramic industry of China is of long standing and well established, with a long history.Pottery, the raw material used by porcelain are mostly natural inorganic Nonmetallic mineral, these raw materials pass through processing and refining, cooperation, shaping, high-temperature physics chemical reaction, are just formed a kind of and original group Become the distinct new material of material, be pottery.China make pottery porcelain development have passed through three phases: the original pottery of pottery Device porcelain.
Porcelain dinner-ware needs using glaze come to surface treatment, good glaze affects very big on tableware using effect.At present Much glaze inferior makes tableware unsightly, and has an effect on tableware service life.
Content of the invention
The technical problem to be solved is to provide a kind of porcelain dinner-ware low grade fever's glaze, and glaze is nontoxic, adhesion Power is good, and the firing temperature being applied to when porcelain dinner-ware surface is fired is also lower 60-100 DEG C than the firing temperature of low-temperature glaze, keeps away Exempt from the damage to porcelain body for the high-temperature firing, will not volatilize at high temperature after glaze drying and moulding, and there is certain impact resistance Energy.
The technical problem to be solved employs the following technical solutions to realize:
A kind of porcelain dinner-ware low grade fever's glaze, is made up of the component of following weight portion: nepheline syenite 20-26 part, Suzhou Native 8-16 part, Zirconium orthosilicate. 4-6 part, meerschaum 4-6 part, potato starch ether 2-4 part, asbestos whisker 2-4 part, titanium dioxide 2-4 Part, ground calcium carbonate 2-4 part, glass bead 1-2 part, asbolane 1-2 part, low grade fever's auxiliary agent 4-6 part, modified zircon 3-8 part.
Described low grade fever's auxiliary agent is made up of the component of following weight portion: magnesium stearate 4-6 part, pentaerythritol triacrylate 0.5-1 part, capric acid 1-2 part, Magnetitum 4-6 part, lauryl dimethyl amine 0.5-1 part;Its preparation method is, by each raw material mixer mill It is broken into fine powder, then by fine powder 40-60khz ultrasonic Treatment 10 minutes, then fine powder is mixed into fine powder weight portion 30%-40% Clear water be stirred into slurry, then slurry is sent in dehydrator and dries, continue after drying to be milled to fine powder to be low grade fever Auxiliary agent.
Described modification zircon preparation method is: zircon is freezed 10 minutes with -50 DEG C of low temperature nitrogens, then again with 60 DEG C biogas slurry soaks isothermal holding 30 minutes, then deionized water cleans zircon, is then milled to powder.
A kind of porcelain dinner-ware preparation technology of low grade fever's glaze, comprises the following steps:
(1) mixing of each raw material is milled to 50-80 mesh fine powder;
(2) fine powder is wrapped up post-heating to 80 DEG C with tinfoil, be incubated 20 minutes, then fine powder being cooled to room temperature is Obtain glaze.
The invention has the beneficial effects as follows: glaze of the present invention is nontoxic, and adhesion strength is good, is applied to when porcelain dinner-ware surface is fired Firing temperature is also lower 60-100 DEG C than the firing temperature of low-temperature glaze, it is to avoid the damage to porcelain body for the high-temperature firing, and glaze is done Will not volatilize at high temperature after dry molding, and there is certain shock resistance.
Specific embodiment
In order that technological means, creation characteristic, reached purpose and effect that the present invention realizes are easy to understand, tie below Close specific embodiment, the present invention is expanded on further.
Embodiment 1
A kind of porcelain dinner-ware low grade fever's glaze, is made up of the component of following weight portion: 23 parts of nepheline syenite, Suzhou soil 12 Part, 5 parts of Zirconium orthosilicate., 5 parts of meerschaum, 3 parts of potato starch ether, 3 parts of asbestos whisker, 3 parts of titanium dioxide, 3 parts of ground calcium carbonate, 1.5 parts of glass bead, 1.5 parts of asbolane, 5 parts of low grade fever's auxiliary agent, modified 6 parts of zircon.
Described low grade fever's auxiliary agent is made up of the component of following weight portion: 5 parts of magnesium stearate, pentaerythritol triacrylate 0.8 Part, 1.5 parts of capric acid, 5 parts of Magnetitum, 0.8 part of lauryl dimethyl amine;Its preparation method is that the mixing of each raw material is milled to fine powder, Then by fine powder 50khz ultrasonic Treatment 10 minutes, then the clear water that fine powder is mixed into fine powder weight portion 35% is stirred into Slurry, then sends into slurry in dehydrator and dries, and continues to be milled to fine powder as low grade fever's auxiliary agent after drying.
Described modification zircon preparation method is: zircon is freezed 10 minutes with -50 DEG C of low temperature nitrogens, then again with 60 DEG C biogas slurry soaks isothermal holding 30 minutes, then deionized water cleans zircon, is then milled to powder.
A kind of porcelain dinner-ware preparation technology of low grade fever's glaze, comprises the following steps:
(1) mixing of each raw material is milled to 50-80 mesh fine powder;
(2) fine powder is wrapped up post-heating to 80 DEG C with tinfoil, be incubated 20 minutes, then fine powder being cooled to room temperature is Obtain glaze.
Embodiment 2
A kind of porcelain dinner-ware low grade fever's glaze, is made up of the component of following weight portion: 20 parts of nepheline syenite, Suzhou soil 8 Part, 4 parts of Zirconium orthosilicate., 4 parts of meerschaum, 2 parts of potato starch ether, 2 parts of asbestos whisker, 2 parts of titanium dioxide, 2 parts of ground calcium carbonate, 1 part of glass bead, 1 part of asbolane, 4 parts of low grade fever's auxiliary agent, modified 3 parts of zircon.
Described low grade fever's auxiliary agent is made up of the component of following weight portion: 4 parts of magnesium stearate, pentaerythritol triacrylate 0.5 Part, 1 part of capric acid, 4 parts of Magnetitum, 0.5 part of lauryl dimethyl amine;Its preparation method is the mixing of each raw material to be milled to fine powder, so Afterwards by fine powder 40khz ultrasonic Treatment 10 minutes, then the clear water that fine powder is mixed into fine powder weight portion 30% stirs pulping Material, then sends into slurry in dehydrator and dries, and continues to be milled to fine powder as low grade fever's auxiliary agent after drying.
Described modification zircon preparation method is: zircon is freezed 10 minutes with -50 DEG C of low temperature nitrogens, then again with 60 DEG C biogas slurry soaks isothermal holding 30 minutes, then deionized water cleans zircon, is then milled to powder.
A kind of porcelain dinner-ware preparation technology of low grade fever's glaze, comprises the following steps:
(1) mixing of each raw material is milled to 50-80 mesh fine powder;
(2) fine powder is wrapped up post-heating to 80 DEG C with tinfoil, be incubated 20 minutes, then fine powder being cooled to room temperature is Obtain glaze.
Embodiment 3
A kind of porcelain dinner-ware low grade fever's glaze, is made up of the component of following weight portion: 26 parts of nepheline syenite, Suzhou soil 16 Part, 6 parts of Zirconium orthosilicate., 6 parts of meerschaum, 4 parts of potato starch ether, 4 parts of asbestos whisker, 4 parts of titanium dioxide, 4 parts of ground calcium carbonate, 2 parts of glass bead, 2 parts of asbolane, 6 parts of low grade fever's auxiliary agent, modified 8 parts of zircon.
Described low grade fever's auxiliary agent is made up of the component of following weight portion: 6 parts of magnesium stearate, 1 part of pentaerythritol triacrylate, 2 parts of capric acid, 6 parts of Magnetitum, 1 part of lauryl dimethyl amine;Its preparation method is that the mixing of each raw material is milled to fine powder, then will Fine powder 60khz ultrasonic Treatment 10 minutes, then the clear water that fine powder is mixed into fine powder weight portion 40% is stirred into slurry, so Afterwards slurry is sent in dehydrator and dry, continue after drying to be milled to fine powder as low grade fever's auxiliary agent.
Described modification zircon preparation method is: zircon is freezed 10 minutes with -50 DEG C of low temperature nitrogens, then again with 60 DEG C biogas slurry soaks isothermal holding 30 minutes, then deionized water cleans zircon, is then milled to powder.
A kind of porcelain dinner-ware preparation technology of low grade fever's glaze, comprises the following steps:
(1) mixing of each raw material is milled to 50-80 mesh fine powder;
(2) fine powder is wrapped up post-heating to 80 DEG C with tinfoil, be incubated 20 minutes, then fine powder being cooled to room temperature is Obtain glaze.
Ultimate principle and principal character and the advantages of the present invention of the present invention have been shown and described above.The technology of the industry , it should be appreciated that the present invention is not restricted to the described embodiments, the simply explanation described in above-described embodiment and description is originally for personnel The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these changes Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and its Equivalent thereof.

Claims (4)

1. a kind of porcelain dinner-ware with low grade fever's glaze it is characterised in that being made up of the component of following weight portion: nepheline syenite 20- 26 parts, Suzhou soil 8-16 part, Zirconium orthosilicate. 4-6 part, meerschaum 4-6 part, potato starch ether 2-4 part, asbestos whisker 2-4 part, two Titanium oxide 2-4 part, ground calcium carbonate 2-4 part, glass bead 1-2 part, asbolane 1-2 part, low grade fever's auxiliary agent 4-6 part, modified zircon 3-8 part.
2. a kind of porcelain dinner-ware according to claim 1 with low grade fever's glaze it is characterised in that described low grade fever's auxiliary agent is by following The component of weight portion is constituted: magnesium stearate 4-6 part, pentaerythritol triacrylate 0.5-1 part, capric acid 1-2 part, Magnetitum 4-6 part, Lauryl dimethyl amine 0.5-1 part;Its preparation method is the mixing of each raw material to be milled to fine powder, then by fine powder 40- 60khz ultrasonic Treatment 10 minutes, then the clear water that fine powder is mixed into fine powder weight portion 30%-40% is stirred into slurry, so Afterwards slurry is sent in dehydrator and dry, continue after drying to be milled to fine powder as low grade fever's auxiliary agent.
3. a kind of porcelain dinner-ware according to claim 1 with low grade fever's glaze it is characterised in that described modification zircon preparation Method is: zircon freezed 10 minutes with -50 DEG C of low temperature nitrogens, then soaks isothermal holding 30 minutes with 60 DEG C of biogas slurries again, Deionized water cleans zircon again, is then milled to powder.
4. make any one of claim 1-3 described in a kind of porcelain dinner-ware with the preparation technology of low grade fever's glaze it is characterised in that Comprise the following steps:
(1) mixing of each raw material is milled to 50-80 mesh fine powder;
(2) fine powder is wrapped up post-heating to 80 DEG C with tinfoil, be incubated 20 minutes, then fine powder be cooled to room temperature and obtain final product glaze Material.
CN201610921029.2A 2016-10-21 2016-10-21 Low-firing glaze for porcelain dinnerware Pending CN106348593A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201610921029.2A CN106348593A (en) 2016-10-21 2016-10-21 Low-firing glaze for porcelain dinnerware

Publications (1)

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CN106348593A true CN106348593A (en) 2017-01-25

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108675761A (en) * 2018-07-04 2018-10-19 福建省德化县荣华陶瓷有限公司 A kind of preparation method that the enviroment protective ceramic of thermally equivalent stews

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1765835A (en) * 2005-08-26 2006-05-03 林伟河 Enamel prepared from waste ceramic and its preparation method
KR100635689B1 (en) * 2004-06-24 2006-10-17 요업기술원 Composition of transparent glaze for plate
CN102603365A (en) * 2012-04-13 2012-07-25 江苏省宜兴彩陶工艺厂 Green glaze for ceramic wine bottle and preparation method thereof
CN104011151A (en) * 2012-04-24 2014-08-27 埃斯马尔格拉斯股份有限公司 Digital enamel ink
CN104072205A (en) * 2014-07-11 2014-10-01 江苏拜富科技有限公司 Full polish ceramic product and preparation method thereof
CN105060939A (en) * 2015-09-09 2015-11-18 梅州市林海陶瓷有限公司 Formula of antibacterial ceramic glaze

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100635689B1 (en) * 2004-06-24 2006-10-17 요업기술원 Composition of transparent glaze for plate
CN1765835A (en) * 2005-08-26 2006-05-03 林伟河 Enamel prepared from waste ceramic and its preparation method
CN102603365A (en) * 2012-04-13 2012-07-25 江苏省宜兴彩陶工艺厂 Green glaze for ceramic wine bottle and preparation method thereof
CN104011151A (en) * 2012-04-24 2014-08-27 埃斯马尔格拉斯股份有限公司 Digital enamel ink
CN104072205A (en) * 2014-07-11 2014-10-01 江苏拜富科技有限公司 Full polish ceramic product and preparation method thereof
CN105060939A (en) * 2015-09-09 2015-11-18 梅州市林海陶瓷有限公司 Formula of antibacterial ceramic glaze

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108675761A (en) * 2018-07-04 2018-10-19 福建省德化县荣华陶瓷有限公司 A kind of preparation method that the enviroment protective ceramic of thermally equivalent stews

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Application publication date: 20170125

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