CN105648754B - Mosquito repellent antibacterial socks and preparation method thereof - Google Patents
Mosquito repellent antibacterial socks and preparation method thereof Download PDFInfo
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- CN105648754B CN105648754B CN201610120346.4A CN201610120346A CN105648754B CN 105648754 B CN105648754 B CN 105648754B CN 201610120346 A CN201610120346 A CN 201610120346A CN 105648754 B CN105648754 B CN 105648754B
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- repellent antibacterial
- antibacterial
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 60
- 239000000077 insect repellent Substances 0.000 title claims abstract description 60
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 13
- 230000008569 process Effects 0.000 claims abstract description 9
- 229920000742 Cotton Polymers 0.000 claims abstract description 8
- 239000004952 Polyamide Substances 0.000 claims abstract description 8
- 229920002647 polyamide Polymers 0.000 claims abstract description 8
- 238000009941 weaving Methods 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 35
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 17
- 230000000740 bleeding effect Effects 0.000 claims description 11
- 239000003431 cross linking reagent Substances 0.000 claims description 11
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- 229960001950 benzethonium chloride Drugs 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 241001529749 Lavandula Species 0.000 claims description 4
- 235000002997 Lavandula Nutrition 0.000 claims description 4
- 239000000443 aerosol Substances 0.000 claims description 3
- 238000007796 conventional method Methods 0.000 claims description 3
- 230000018044 dehydration Effects 0.000 claims description 3
- 238000006297 dehydration reaction Methods 0.000 claims description 3
- DHOCGIHFPKXZJB-UHFFFAOYSA-N [Cl+].N[H] Chemical compound [Cl+].N[H] DHOCGIHFPKXZJB-UHFFFAOYSA-N 0.000 claims description 2
- 230000000845 anti-microbial effect Effects 0.000 claims description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
- -1 tridecyl sodium sulfonates Chemical class 0.000 claims description 2
- 241000744766 Cymbopogon winterianus Species 0.000 claims 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 2
- 241000894006 Bacteria Species 0.000 claims 1
- 230000008595 infiltration Effects 0.000 claims 1
- 238000001764 infiltration Methods 0.000 claims 1
- 239000001384 succinic acid Substances 0.000 claims 1
- 238000007493 shaping process Methods 0.000 abstract description 2
- 230000000087 stabilizing effect Effects 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 11
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 7
- VPFNWSAQNWQCNX-UHFFFAOYSA-N CCCCCCCCCCCCC[Na] Chemical compound CCCCCCCCCCCCC[Na] VPFNWSAQNWQCNX-UHFFFAOYSA-N 0.000 description 6
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric Acid Chemical compound [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- OTTXIFWBPRRYOG-UHFFFAOYSA-N 2-hydroxyadipic acid Chemical class OC(=O)C(O)CCCC(O)=O OTTXIFWBPRRYOG-UHFFFAOYSA-N 0.000 description 5
- 244000032014 Java citronella Species 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 244000178870 Lavandula angustifolia Species 0.000 description 4
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- 239000001102 lavandula vera Substances 0.000 description 4
- 235000018219 lavender Nutrition 0.000 description 4
- 241000255925 Diptera Species 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 3
- 239000000463 material Substances 0.000 description 3
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- 206010049244 Ankyloglossia congenital Diseases 0.000 description 2
- 206010015946 Eye irritation Diseases 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 241000283973 Oryctolagus cuniculus Species 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 210000003423 ankle Anatomy 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 231100000013 eye irritation Toxicity 0.000 description 2
- 210000002683 foot Anatomy 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 230000001846 repelling effect Effects 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 240000004784 Cymbopogon citratus Species 0.000 description 1
- 235000017897 Cymbopogon citratus Nutrition 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
- 240000000047 Gossypium barbadense Species 0.000 description 1
- 235000009429 Gossypium barbadense Nutrition 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000255964 Pieridae Species 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 210000001015 abdomen Anatomy 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- 238000010171 animal model Methods 0.000 description 1
- 229960003872 benzethonium Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 210000001255 hallux Anatomy 0.000 description 1
- 210000003128 head Anatomy 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000009377 nuclear transmutation Methods 0.000 description 1
- 238000003305 oral gavage Methods 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000012113 quantitative test Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B11/00—Hosiery; Panti-hose
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B17/00—Selection of special materials for underwear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/005—Compositions containing perfumes; Compositions containing deodorants
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/34—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass antimicrobial or antibacterial
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2500/00—Materials for shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2500/20—Woven
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
- D06M2101/36—Aromatic polyamides
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of mosquito repellent antibacterial socks and preparation method thereof.The mosquito repellent antibacterial socks are formed by the raw material weaving of following weight parts：60 80wt% cotton fibers and 20 40wt% polyamide fibres.The mosquito repellent antibacterial socks of the present invention, process stabilizing is good from raw material, and by checking on for each procedure, steady quality, in appearance, Density is uniform, abundant, pure color for performance, and forming of shaping, is the ideal chose of healthy life staying idle at home.
Description
Technical field
The present invention relates to a kind of socks, and in particular to a kind of mosquito repellent antibacterial socks and preparation method thereof.
Background technology
" socks " one word is seen earliest《China notes at all times》, say：" three generations and week Zhu Jiao Wa, ankle is lain in band "." three generations "
Refer to China's summer on the books earliest, business, all periods, away from the present existing 3000 or four thousand years history." Jiao Wa " should be made of animal skin
Original socks, so writing " Wa ".Later, with the appearance of textile, socks are developed into cloth, fiber crops, silk by beast cloth again
Make , " Wa " " socks " are also correspondingly changed to, " socks " of the today described in us are finally reduced to step by step.The transmutation process of " socks " word,
The development process of Chinese civilization history is contained in fact.
The shape of ancient times socks can about divide the manual socks of three-chip type to have legging, frenulum socks, panty hose, point toe socks, light
Six kinds of socks and bottomless sock etc. of head.Wherein have the stocking leg of legging different in size, some length to belly, have only between ankle.Frenulum socks
In order that difficult for drop-off when wearing.It is to separate big toe with other four toe to divide toe socks, shape such as bifurcation shape.Bare headed socks and bottomless sock are used
The women bound feet in ancient times, is commonly called as half socks.
Now, the species of socks is a lot, by the length point of the stocking leg, has stocking, Knee-sockses and short legging and ship socks (stealthy
Socks)；By stocking blank species point, there are registered permanent residence socks, rib cuff socks and elastic top hosiery；By using object point, there are men's socks, female's socks and Children's Socks.Circular knit hosiery
By stocking blank, the stocking leg and the portion of tissue of stocking foot 3.The specification of socks, is represented with socks size, and socks number are the realities with the stocking sole
Border length dimension is standard, so just can choose the socks fitted after knowing the pin length of oneself.Due to former used in socks
Material is different, and it is also different in socks series.
With the continuous improvement that people are pursued healthy living, the performances of socks is not limited solely to it is warming, attractive in appearance etc.,
Also it is aided with various health cares and the safeguard functions such as more massages, antibacterial, anti-mite, moisture absorbing and sweat releasing, antistatic, uvioresistant.
The invention provides a kind of mosquito repellent antibacterial socks, multi-functional demand of the people to socks is met.
The content of the invention
For deficiencies of the prior art, one of the technical problems to be solved by the invention are to provide a kind of mosquito repellent
Antibacterial socks.
The two of the technical problems to be solved by the invention are to provide the preparation method of above-mentioned mosquito repellent antibacterial socks.
The technical problem of the present invention, is achieved by following technical proposals：
A kind of mosquito repellent antibacterial socks, are formed by the raw material weaving of following weight parts：60-80wt% cotton fibers and 20-40wt%
Polyamide fibre.
Preferably, the mosquito repellent antibacterial socks are obtained by mosquito repellent antibacterial treatment process again.
Preferably, the mosquito repellent antibacterial treatment process is to impregnate the mosquito repellent antibacterial socks in mosquito repellent antibacterial finishing agent,
Described mosquito repellent antibacterial finishing agent is made up of the raw material of following weight parts：0.1-0.3 portions of Lavenders, 0.1-0.3 portions of lemongrass
Essential oil, 0.05-0.5 part benzethonium chloride, 0.1-0.5 parts of bleeding agents, 5-15 parts of 1- propyl alcohol, 0.1-0.5 parts of crosslinking agents, 95-105 parts
Water.
Preferably, described bleeding agent is by 40-60wt% aerosol OTs and 40-60wt% tridecyl sulphurs
Sour sodium is mixed.
Preferably, described crosslinking agent is by 40-60wt%2,3- dyhydrobutanedioic acids and 40-60wt%2- hydroxyl adipic acids
Mix.
Present invention also offers the preparation method of above-mentioned mosquito repellent antibacterial socks, comprise the following steps：
(1) cotton fiber and polyamide fibre weaved using conventional method, be processed into socks；
(2) above-mentioned socks are subjected to mosquito repellent antimicrobial treatment.
Preferably, the step (2) is that under the conditions of 65-85 DEG C, socks are impregnated into 20- in mosquito repellent antibacterial finishing agent
30min, after dehydration, dries 5-10min under the conditions of 70-90 DEG C.
Described mosquito repellent antibacterial finishing agent is made up of the raw material of following weight parts：0.1-0.3 parts of Lavenders, 0.1-
0.3 part of oil of Cymbopogon winterianus, 0.05-0.5 parts of benzethonium chlorides, 0.1-0.5 parts of bleeding agents, 5-15 parts of 1- propyl alcohol, 0.1-0.5 parts of crosslinkings
Agent, 95-105 parts of water.
Specifically, in the present invention：
Lavender, No. CAS：8000-28-0.
Oil of Cymbopogon winterianus, No. CAS：73049-78-2.
Benzethonium chloride, No. CAS：121-54-0.
Aerosol OT, No. CAS：577-11-7.
Tridecyl sodium sulfonate, No. CAS：5802-89-1.
2,3- dyhydrobutanedioic acids, No. CAS：526-83-0.
2- hydroxyl adipic acids, No. CAS：18294-85-4.
1- propyl alcohol, No. CAS：71-23-8.
The mosquito repellent antibacterial socks of the present invention, process stabilizing is good from raw material, passes through checking on for each procedure, steady quality, table
Now in appearance, Density is uniform, abundant, pure color, and forming of shaping, is the ideal chose of healthy life staying idle at home.
Embodiment
With reference to embodiment, the present invention is described further, as described below, is only the preferable implementation to the present invention
Example, not does the limitation of other forms, any those skilled in the art are possibly also with the disclosure above to the present invention
Technology contents be changed to the equivalent embodiment changed on an equal basis.It is every without departing from the present invention program content, according to the present invention
Technical spirit any simple modification that following examples are made or equivalent variations, all fall within protection scope of the present invention.
Embodiment 1
Mosquito repellent antibacterial socks raw material (percentage by weight)：70wt% cotton fibers (cotton fiber is long-staple cotton, and its length is 40mm,
Fineness is 7200nm) and 30wt% polyamide fibres (polyamide fibre 6-DTY, 40D that are produced using Jiangsu Ping Meisha industry Co., Ltd).
Mosquito repellent antibacterial finishing agent raw material (parts by weight)：0.2 part of Lavender, 0.2 part of oil of Cymbopogon winterianus, 0.02 part of benzyl rope chlorine
Ammonium, 0.3 part of bleeding agent, 10 parts of 1- propyl alcohol, 0.3 part of crosslinking agent, 100 parts of deionized waters.
Described bleeding agent is mixed by 50wt% aerosol OTs and the stirring of 50wt% tridecyls sodium sulfonate
Uniformly obtain.
Described crosslinking agent is uniformly mixed by 50wt%2,3- dyhydrobutanedioic acids and 50wt%2- hydroxyl adipic acids
Obtain.
Present invention also offers the preparation method of above-mentioned mosquito repellent antibacterial socks, comprise the following steps：
(1) use braider, according to a conventional method by cotton fiber and polyamide fibre weave into socks blank cloth (grammes per square metre is 160 grams/it is flat
Square rice), according to the technique and requirement for making socks, after socks blank cloth is cut, it is processed into socks；
(2) Lavender, oil of Cymbopogon winterianus, benzethonium chloride, bleeding agent, 1- propyl alcohol, crosslinking agent are added in deionized water
It is uniformly mixed, obtains mosquito repellent antibacterial finishing agent；Socks are placed in the mosquito repellent antibacterial finishing agent that temperature is 75 DEG C and impregnated
The mass ratio of 25min, wherein socks and mosquito repellent antibacterial finishing agent is 1:10 (i.e. 1kg socks 10kg mosquito repellents antibacterial finishing agent leachings
Stain), after dehydration, 8min is dried under the conditions of 80 DEG C；Obtain mosquito repellent antibacterial socks.
Embodiment 2
It is substantially the same manner as Example 1, differ only in：Described bleeding agent is only aerosol OT.
To the mosquito repellent antibacterial socks of embodiment 2.
Embodiment 3
It is substantially the same manner as Example 1, differ only in：Described bleeding agent is only tridecyl sodium sulfonate.Obtain reality
Apply the mosquito repellent antibacterial socks of example 3.
Embodiment 4
It is substantially the same manner as Example 1, differ only in：Described crosslinking agent is only 2,3 dihydroxybutanedioic acid.Obtain
The mosquito repellent antibacterial socks of embodiment 4.
Embodiment 5
It is substantially the same manner as Example 1, differ only in：Described crosslinking agent is only 2- hydroxyl adipic acids.Implemented
The mosquito repellent antibacterial socks of example 5.
Test case 1
Antibacterial test is carried out to embodiment 1-5 mosquito repellent antibacterial socks,
Using standard GB/T/T20944.3-2008《The evaluation third portion of antibacterial textile performance：Succusion》Carry out
Antibiotic property quantitative test, using color fastness to washing testing machine washing methods, the bacteriostasis rate of mosquito repellent antibacterial socks after test is washed 30 times,
Test result is shown in Table 1.
Table 1：Bacteriostasis rate test table after washing 30 times
Comparing embodiment 1-3, embodiment 1 (aerosol OT, tridecyl sodium sulfonate compounding) antibacterial effect,
It is substantially better than embodiment 2-3 (single raw material in aerosol OT, tridecyl sodium sulfonate)；Comparing embodiment 1 with
Embodiment 4-5, embodiment 1 (2,3- dyhydrobutanedioic acids, 2- hydroxyls adipic acid compounding) antibacterial effect, hence it is evident that better than embodiment 4-
5 (single raw materials in 2,3 dihydroxybutanedioic acid, 2- hydroxyl adipic acids).
Test case 2
Mosquito repellent test is carried out to embodiment 1-5 mosquito repellent antibacterial socks,
Experiment is at dusk 18:00-20:00 is carried out, on the three-ply board that small white mouse is fixed on to one piece of 10cm × 15cm, mouse body
Surface covers a silk stocking, and is fixed with elastic in surrounding, and then putting it into feeding has in the mosquito cage of 1000 mosquitoes, timing 3
Minute, observe and record mosquito stopping on sample cloth cover during this period and fall number of times, in triplicate, embodiment is used with comparative example
Color is identical.Test data is shown in Table 2.
Table 2：Synthesis tests table
Comparing embodiment 1-3, embodiment 1 (aerosol OT, tridecyl sodium sulfonate compounding) repelling effect,
It is substantially better than embodiment 2-3 (single raw material in aerosol OT, tridecyl sodium sulfonate)；Comparing embodiment 1 with
Embodiment 4-5, embodiment 1 (2,3- dyhydrobutanedioic acids, 2- hydroxyls adipic acid compounding) repelling effect, hence it is evident that better than embodiment 4-
5 (single raw materials in 2,3 dihydroxybutanedioic acid, 2- hydroxyl adipic acids).
Test case 3
Mosquito repellent antibacterial finishing agent (the mosquito repellent antibacterial finishing agent raw material (parts by weight) of embodiment 1：：0.2 part of Lavender, 0.2
Part oil of Cymbopogon winterianus, 0.02 part of benzethonium chloride, 0.3 part of bleeding agent, 10 parts of 1- propyl alcohol, 0.3 part of crosslinking agent, 100 parts of deionized waters) poison
Property experiment：
(1) the oral acute toxicity of mosquito repellent antibacterial finishing agent；Mosquito repellent antibacterial finishing agent is taken to 40 empty stomach 16h Kunming kind mark
The disposable oral gavage of quasi- small white mouse, mosquito repellent antibiotic finish agent dose is up to 1000mg/kg.Animal and poisoning table are observed daily
Existing, seven days terminate experiment, and each group experimental animal is in whole experiment process, without any poisoning manifestations, and diet and motion are normal,
None animal dead.
(2) to skin irritation：The big ear tag quasi-experiment of 10 Japan is cut respectively with the backbone diamond wool of rabbit, will be impregnated
The gauze of mosquito repellent antibacterial finishing agent is crossed, is applied on the skin exposed on right side.Application site skin is observed after 24 hours, is not gone out
The existing irritation such as erythema and oedema, according to skin irritatin strength grading standard, the mosquito repellent antibacterial finishing agent belongs to stingless to skin
Swash material.
(3) to eye irritation：By mosquito repellent antibacterial finishing agent, right eye of the big ear tag quasi-experiment of Japan with rabbit is directly instilled,
Left eye is compared, passive closure 5 seconds, then clean with normal saline flushing, is observed after 24 hours, eyes are without exception, according to
Eye irritation strength grading standard, the mosquito repellent antibacterial finishing agent belongs to non-stimulated material to eyes.
Claims (5)
1. a kind of mosquito repellent antibacterial socks, it is characterised in that formed by the raw material weaving of following weight parts：60-80wt% cotton fibers and
20-40wt% polyamide fibres；
The mosquito repellent antibacterial socks are obtained by mosquito repellent antibacterial treatment process again；
The mosquito repellent antibacterial treatment process is impregnates the mosquito repellent antibacterial socks in mosquito repellent antibacterial finishing agent, and described mosquito repellent resists
Bacterium finishing agent is made up of the raw material of following weight parts：0.1-0.3 parts of Lavenders, 0.1-0.3 parts of oil of Cymbopogon winterianus, 0.05-0.5
Part benzethonium chloride, 0.1-0.5 parts of bleeding agents, 5-15 parts of 1- propyl alcohol, 0.1-0.5 parts of crosslinking agents, 95-105 parts of water；Described infiltration
Agent is mixed by 40-60wt% aerosol OTs and 40-60wt% tridecyl sodium sulfonates.
2. mosquito repellent antibacterial socks as claimed in claim 1, it is characterised in that described crosslinking agent is by 40-60wt%2,3- dihydroxies
Base succinic acid and 40-60wt%2- hydroxyl adipic acids are mixed.
3. the preparation method of mosquito repellent antibacterial socks according to claim 1 or 2, it is characterised in that comprise the following steps：
(1) cotton fiber and polyamide fibre weaved using conventional method, be processed into socks；
(2) above-mentioned socks are subjected to mosquito repellent antimicrobial treatment.
4. the preparation method of mosquito repellent antibacterial socks according to claim 3, it is characterised in that the step (2) is in 65-85
Under the conditions of DEG C, socks are impregnated into 20-30min in mosquito repellent antibacterial finishing agent, after dehydration, 5- is dried under the conditions of 70-90 DEG C
10min。
5. the preparation method of mosquito repellent antibacterial socks according to claim 4, it is characterised in that described mosquito repellent antibacterial finishing agent
It is made up of the raw material of following weight parts：0.1-0.3 parts of Lavenders, 0.1-0.3 parts of oil of Cymbopogon winterianus, 0.05-0.5 parts of benzyl rope chlorine
Ammonium, 0.1-0.5 part bleeding agent, 5-15 parts of 1- propyl alcohol, 0.1-0.5 parts of crosslinking agents, 95-105 parts of water.
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| CN201610120346.4A CN105648754B (en) | 2016-03-03 | 2016-03-03 | Mosquito repellent antibacterial socks and preparation method thereof |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105982369B (en) * | 2016-06-12 | 2017-07-21 | 浙江梦娜袜业股份有限公司 | A kind of preparation method of the mosquito-proof quilted stockings of plants essential oil |
| CN109235034A (en) * | 2016-07-13 | 2019-01-18 | 金福珍 | Material treatment agent |
| CN106519656A (en) * | 2016-11-21 | 2017-03-22 | 郑州源冉生物技术有限公司 | Composite for socks |
| CN108936835A (en) * | 2017-05-20 | 2018-12-07 | 宜兴市艺蝶针织有限公司 | A kind of antibacterial deodorant socks and its preparation process |
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Effective date of registration: 20190509 Address after: 321000 Block D of Xiaoshun Town North Functional Zone, Jindong District, Jinhua City, Zhejiang Province (in Zhejiang Lanshibutterfly Knitting Garment Co., Ltd.) Patentee after: ZHEJIANG KAINIWEI KNITTING GARMENT Co.,Ltd. Address before: 311825 Yuanxiang Government of Kengxi Village, Paitou Town, Zhuji City, Shaoxing City, Zhejiang Province Patentee before: Xu Mengkui |
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Denomination of invention: Mosquito repellent and antibacterial socks and their preparation method Granted publication date: 20171107 Pledgee: China Postal Savings Bank Co.,Ltd. Jinhua Branch Pledgor: ZHEJIANG KAINIWEI KNITTING GARMENT Co.,Ltd. Registration number: Y2024980005657 |