CN105696319B - Anti-mite socks of absorbing sweat and preparation method thereof - Google Patents
Anti-mite socks of absorbing sweat and preparation method thereof Download PDFInfo
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- CN105696319B CN105696319B CN201610119647.5A CN201610119647A CN105696319B CN 105696319 B CN105696319 B CN 105696319B CN 201610119647 A CN201610119647 A CN 201610119647A CN 105696319 B CN105696319 B CN 105696319B
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- 210000004243 sweat Anatomy 0.000 title claims abstract description 61
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 229920000742 Cotton Polymers 0.000 claims abstract description 8
- 239000004952 Polyamide Substances 0.000 claims abstract description 8
- 229920002647 polyamide Polymers 0.000 claims abstract description 8
- 238000009941 weaving Methods 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 23
- 159000000000 sodium salts Chemical class 0.000 claims description 16
- 239000002738 chelating agent Substances 0.000 claims description 12
- 239000003431 cross linking reagent Substances 0.000 claims description 11
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 9
- 229920002401 polyacrylamide Polymers 0.000 claims description 9
- DTDSAWVUFPGDMX-UHFFFAOYSA-N spirodiclofen Chemical compound CCC(C)(C)C(=O)OC1=C(C=2C(=CC(Cl)=CC=2)Cl)C(=O)OC11CCCCC1 DTDSAWVUFPGDMX-UHFFFAOYSA-N 0.000 claims description 9
- 244000178870 Lavandula angustifolia Species 0.000 claims description 8
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- 239000001102 lavandula vera Substances 0.000 claims description 8
- 235000018219 lavender Nutrition 0.000 claims description 8
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 claims description 7
- 150000007513 acids Chemical class 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 238000007796 conventional method Methods 0.000 claims description 3
- 230000018044 dehydration Effects 0.000 claims description 3
- 238000006297 dehydration reaction Methods 0.000 claims description 3
- -1 polypropylene Polymers 0.000 claims description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 8
- 230000008569 process Effects 0.000 abstract description 5
- 238000007493 shaping process Methods 0.000 abstract description 2
- 230000000087 stabilizing effect Effects 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 8
- 229940120146 EDTMP Drugs 0.000 description 6
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric Acid Chemical compound [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 6
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 6
- ZQHYXNSQOIDNTL-UHFFFAOYSA-N 3-hydroxyglutaric acid Chemical class OC(=O)CC(O)CC(O)=O ZQHYXNSQOIDNTL-UHFFFAOYSA-N 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 238000013329 compounding Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000003578 releasing effect Effects 0.000 description 3
- 210000003371 toe Anatomy 0.000 description 3
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 2
- 206010049244 Ankyloglossia congenital Diseases 0.000 description 2
- 206010015946 Eye irritation Diseases 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 241000283973 Oryctolagus cuniculus Species 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- 210000003423 ankle Anatomy 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 231100000013 eye irritation Toxicity 0.000 description 2
- 210000002683 foot Anatomy 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 206010015150 Erythema Diseases 0.000 description 1
- 240000000047 Gossypium barbadense Species 0.000 description 1
- 235000009429 Gossypium barbadense Nutrition 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 210000001015 abdomen Anatomy 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000010171 animal model Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 210000001255 hallux Anatomy 0.000 description 1
- 210000003128 head Anatomy 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000009377 nuclear transmutation Methods 0.000 description 1
- 238000003305 oral gavage Methods 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B11/00—Hosiery; Panti-hose
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B17/00—Selection of special materials for underwear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/005—Compositions containing perfumes; Compositions containing deodorants
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/44—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing nitrogen and phosphorus
- D06M13/447—Phosphonates or phosphinates containing nitrogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/34—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass antimicrobial or antibacterial
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2500/00—Materials for shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2500/20—Woven
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Socks And Pantyhose (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses anti-mite socks of a kind of absorbing sweat and preparation method thereof.The anti-mite socks of absorbing sweat are formed by the raw material weaving of following weight parts：60 80wt% cotton fibers and 20 40wt% polyamide fibres.The anti-mite socks of absorbing sweat of the present invention, process stabilizing is good from raw material, and by checking on for each procedure, steady quality, in appearance, Density is uniform, abundant, pure color for performance, forming of shaping, and is the ideal chose of healthy life staying idle at home.
Description
Technical field
The present invention relates to a kind of socks, and in particular to a kind of anti-mite socks of absorbing sweat and preparation method thereof.
Background technology
" socks " one word is seen earliest《China notes at all times》, say：" three generations and all Zhu Jiao Wa, ankle is lain in band "." three generations "
Refer to China's summer on the books earliest, business, all periods, away from the present existing 3000 or four thousand years history." Jiao Wa " should be made of animal skin
Original socks, so writing " Wa ".Later, as the appearance of textile, socks are developed into cloth, fiber crops, silk by beast cloth again
Make , " Wa " " socks " are also correspondingly changed to, " socks " of the today described in us are finally reduced to step by step.The transmutation process of " socks " word,
The development process of Chinese civilization history is contained in fact.
The shape of ancient times socks can about divide three-chip type craft socks to have legging, frenulum socks, panty hose, dividing toe socks, light
Six kinds of socks and bottomless sock etc. of head.Wherein there is the stocking leg of legging different in size, some length to belly, some is only between ankle.Frenulum socks
It is in order that difficult for drop-off when wearing.It is to separate big toe and other four toe to divide toe socks, shaped like bifurcation shape.Bare headed socks and bottomless sock use
In the women of ancient times foot-binding, half socks are commonly called as.
Now, the species of socks is a lot, by the length point of the stocking leg, has stocking, Knee-sockses and short legging and ship socks (stealthy
Socks)；By stocking blank species point, there are registered permanent residence socks, rib cuff socks and elastic top hosiery；By using object point, there are men's socks, female's socks and Children's Socks.Circular knit hosiery
By stocking blank, the stocking leg and the portion of tissue of stocking foot 3.The specification of socks, represented with socks size, and socks number are the realities with the stocking sole
Border length dimension is standard, so can choose the socks to fit after knowing the pin length of oneself.Due to former used in socks
Material is different, and it is also different in socks series.
With the continuous improvement that people are pursued healthy living, the performances of socks is not limited solely to it is warming, attractive in appearance etc.,
Also it is aided with various health cares and the safeguard functions such as more massage, antibacterial, anti-mite, moisture absorbing and sweat releasing, antistatic, uvioresistants.
The invention provides a kind of anti-mite socks of absorbing sweat, meet multi-functional demand of the people to socks.
The content of the invention
For deficiencies of the prior art, one of the technical problems to be solved by the invention are to provide a kind of absorbing sweat
Anti-mite socks.
The two of the technical problems to be solved by the invention are to provide the preparation method of the anti-mite socks of above-mentioned absorbing sweat.
The technical problem of the present invention, is achieved by following technical proposals：
A kind of anti-mite socks of absorbing sweat, formed by the raw material weaving of following weight parts：60-80wt% cotton fibers and 20-40wt%
Polyamide fibre.
The anti-mite socks of absorbing sweat obtain by the anti-mite processing step of absorbing sweat again.
The anti-mite processing step of absorbing sweat is impregnates the anti-mite socks of the absorbing sweat in absorbing sweat anti-mite finishing agent, described suction
Sweat anti-mite finishing agent is made up of the raw material of following weight parts：0.1-0.5 parts Lavender, 0.005-0.05 parts Envidor,
0.1-0.5 parts polyacrylamide, 0.1-0.5 parts crosslinking agent, 5-15 part 2- propyl alcohol, 0.1-0.5 parts chelating agent, 95-105 part water.
Preferably, described crosslinking agent is by 40-60wt%2,3- dyhydrobutanedioic acids and 40-60wt%3- hydroxyl glutaric acids
Mix.
Preferably, described chelating agent is by 40-60wt% ethylene diamine tetra methylene phosphonic acids five sodium-salt and 40-60wt% amino three
Methylenephosphonic acid five sodium-salt mixes.
Present invention also offers the preparation method of the anti-mite socks of above-mentioned absorbing sweat, comprise the following steps：
(1) cotton fiber and polyamide fibre weaved using conventional method, be processed into socks；
(2) above-mentioned socks are subjected to the anti-mite processing of absorbing sweat.
Preferably, the step (2) is under the conditions of 65-85 DEG C, and socks are impregnated into 20- in absorbing sweat anti-mite finishing agent
30min, after dehydration, 5-10min is dried under the conditions of 70-90 DEG C.
Described absorbing sweat anti-mite finishing agent is made up of the raw material of following weight parts：0.1-0.5 parts Lavender, 0.005-
0.05 part of Envidor, 0.1-0.5 parts polyacrylamide, 0.1-0.5 parts crosslinking agent, 5-15 part 2- propyl alcohol, 0.1-0.5 parts chelating
Agent, 95-105 part water.
Specifically, in the present invention：
Lavender, No. CAS：8000-28-0.
Envidor, No. CAS：148477-71-8.
Polyacrylamide, No. CAS：9003-05-8.
2,3- dyhydrobutanedioic acids, No. CAS：526-83-0.
3- hydroxyl glutaric acids, No. CAS：638-18-6.
Ethylene diamine tetra methylene phosphonic acid five sodium-salt, No. CAS：7651-99-2.
ATMP five sodium-salt, No. CAS：2235-43-0.
2- propyl alcohol, No. CAS：67-63-0.
The anti-mite socks of absorbing sweat of the present invention, process stabilizing is good from raw material, passes through checking on for each procedure, steady quality, table
Now in appearance, Density is uniform, abundant, pure color, forming of shaping, and is the ideal chose of healthy life staying idle at home.
Embodiment
With reference to embodiment, the present invention is described further, as described below, is only the preferable implementation to the present invention
Example, is not limited the present invention, any person skilled in the art is possibly also with the disclosure above
Technology contents be changed to the equivalent embodiment changed on an equal basis.It is every of the invention without departing from the present invention program content, foundation
Technical spirit any simple modification that following examples are made or equivalent variations, all fall within protection scope of the present invention.
Polyacrylamide, No. CAS：9003-05-8.The molecule provided using Liaocheng of Shandong Province Hong Xin Chemical Co., Ltd.s
Measure as 500-800 ten thousand non-ionic polyacrylamide.
Embodiment 1
The anti-mite socks raw material (percentage by weight) of absorbing sweat：70wt% cotton fibers (cotton fiber is long-staple cotton, and its length is 40mm,
Fineness is 7200nm) and 30wt% polyamide fibres (using the polyamide fibre 6-DTY, 40D of the production of Jiangsu Ping Meisha industry Co., Ltd).
Absorbing sweat anti-mite finishing agent raw material (parts by weight)：0.3 part of Lavender, 0.01 part of Envidor, 0.3 part of polyacrylamide
Amine, 0.3 part of crosslinking agent, 10 parts of 2- propyl alcohol, 0.3 part of chelating agent, 100 parts of deionized waters.
Described crosslinking agent is uniformly mixed by 50wt%2,3- dyhydrobutanedioic acids and 50wt%3- hydroxyl glutaric acids
Obtain.
Described chelating agent is by 50wt% ethylene diamine tetra methylene phosphonic acids five sodium-salt and the sodium of 50wt% ATMPs five
Salt is uniformly mixed to obtain.
Present invention also offers the preparation method of the anti-mite socks of above-mentioned absorbing sweat, comprise the following steps：
(1) use braider, according to a conventional method by cotton fiber and polyamide fibre weaving into socks blank cloth (grammes per square metre is 160 grams/it is flat
Square rice), according to the technique and requirement for making socks, after socks blank cloth is cut, it is processed into socks；
(2) Lavender, Envidor, polyacrylamide, crosslinking agent, 2- propyl alcohol, chelating agent are added in deionized water
It is uniformly mixed, obtains absorbing sweat anti-mite finishing agent；Socks are placed in the absorbing sweat anti-mite finishing agent that temperature is 75 DEG C and impregnated
The mass ratio of 25min, wherein socks and absorbing sweat anti-mite finishing agent is 1:10 (i.e. 1kg socks 10kg absorbing sweats anti-mite finishing agent leachings
Stain), after dehydration, 8min is dried under the conditions of 80 DEG C；Obtain the anti-mite socks of absorbing sweat.
Embodiment 2
It is substantially the same manner as Example 1, differ only in：Described crosslinking agent is only 2,3 dihydroxybutanedioic acid.Obtain
The anti-mite socks of absorbing sweat of embodiment 2.
Embodiment 3
It is substantially the same manner as Example 1, differ only in：Described crosslinking agent is only 3- hydroxyl glutaric acids.Implemented
The anti-mite socks of absorbing sweat of example 3.
Embodiment 4
It is substantially the same manner as Example 1, differ only in：Described chelating agent is only the sodium of ethylene diamine tetra methylene phosphonic acid five
Salt.Obtain the anti-mite socks of absorbing sweat of embodiment 4.
Embodiment 5
It is substantially the same manner as Example 1, differ only in：Described chelating agent is only ATMP five sodium-salt.
Obtain the anti-mite socks of absorbing sweat of embodiment 5.
Test case 1
Anti-mite test is carried out to the embodiment 1-5 anti-mite socks of absorbing sweat, used《The anti-mite bedding of FZ/T62012-2009》
Standard, tested.Test data is shown in Table 1.
Table 1：Anti-mite performance test table
Comparing embodiment 1-3, embodiment 1 (2,3- dyhydrobutanedioic acids, 3- hydroxyls glutaric acid compounding) anti-mite effect, hence it is evident that
Better than embodiment 2-3 (single raw material in 2,3 dihydroxybutanedioic acid, 3- hydroxyl glutaric acids)；Comparing embodiment 1 and embodiment 4-
5, embodiment 1 (ethylene diamine tetra methylene phosphonic acid five sodium-salt, ATMP five sodium-salt compounding) anti-mite effect, hence it is evident that better than reality
Apply a 4-5 (single raw material in ethylene diamine tetra methylene phosphonic acid five sodium-salt, ATMP five sodium-salt).
Test case 2
Wetness guiding perspiration discharging test, reference standard ISO11092 are carried out to the embodiment 1-5 anti-mite socks of absorbing sweat：1993, use
SDL Sweat Exhaust ＆ Moisture Conductivities instrument tests thermal resistance, the dampness of each embodiment and comparative example.Test data is shown in Table 1.
Table 1：Wetness guiding perspiration discharging performance tests table
| Thermal resistance (10-3km2W-1) | Dampness (Pam2W-1) | |
| Embodiment 1 | 9.793 | 4.571 |
| Embodiment 2 | 10.984 | 5.697 |
| Embodiment 3 | 10.978 | 5.706 |
| Embodiment 4 | 11.091 | 5.799 |
| Embodiment 5 | 11.079 | 5.812 |
Comparing embodiment 1-3, embodiment 1 (2,3- dyhydrobutanedioic acids, 3- hydroxyls glutaric acid compounding) moisture absorbing and sweat releasing effect,
It is substantially better than embodiment 2-3 (single raw material in 2,3 dihydroxybutanedioic acid, 3- hydroxyl glutaric acids)；Comparing embodiment 1 is with implementing
Example 4-5, embodiment 1 (ethylene diamine tetra methylene phosphonic acid five sodium-salt, ATMP five sodium-salt compounding) moisture absorbing and sweat releasing effect are bright
It is aobvious to be better than embodiment 4-5 (single raw material in ethylene diamine tetra methylene phosphonic acid five sodium-salt, ATMP five sodium-salt).
Test case 3
Absorbing sweat anti-mite finishing agent (the absorbing sweat anti-mite finishing agent raw material (parts by weight) of embodiment 1：0.3 part of Lavender, 0.01
Part Envidor, 0.3 part of polyacrylamide, 0.3 part of crosslinking agent, 10 parts of 2- propyl alcohol, 0.3 part of chelating agent, 100 parts of deionized waters) poison
Property experiment：
(1) the oral acute toxicity of absorbing sweat anti-mite finishing agent；Take Kunming kind mark of the absorbing sweat anti-mite finishing agent to 40 empty stomach 16h
Disposably oral gavage, absorbing sweat anti-mite agent dose are up to 1000mg/kg to quasi- small white mouse.Observation animal and poisoning table daily
Existing, seven days terminate experiment, and each group experimental animal is in whole experiment process, and without any poisoning manifestations, diet and motion are normal,
None animal dead.
(2) to skin irritation：The big ear tag quasi-experiment of 10 Japan is cut respectively with the backbone diamond wool of rabbit, will be impregnated
The gauze of absorbing sweat anti-mite finishing agent is crossed, is applied on the skin of right side exposure.Application site skin is observed after 24 hours, is not gone out
The existing irritation such as erythema and oedema, according to skin irritatin strength grading standard, the absorbing sweat anti-mite finishing agent belongs to stingless to skin
Swash material.
(3) to eye irritation：By absorbing sweat anti-mite finishing agent, right eye of the big ear tag quasi-experiment of Japan with rabbit is directly instilled,
Left eye compares, passive closure 5 seconds, then clean with normal saline flushing, is observed after 24 hours, and eyes are without exception, according to
Eye irritation strength grading standard, the absorbing sweat anti-mite finishing agent belong to non-stimulated material to eyes.
Claims (5)
1. a kind of anti-mite socks of absorbing sweat, it is characterised in that formed by the raw material weaving of following weight parts：60-80wt% cotton fibers and
20-40wt% polyamide fibres；
The anti-mite socks of absorbing sweat obtain by the anti-mite processing step of absorbing sweat again；
The anti-mite processing step of absorbing sweat for the anti-mite socks of the absorbing sweat are impregnated in absorbing sweat anti-mite finishing agent, prevent by described absorbing sweat
Mite finishing agent is made up of the raw material of following weight parts：0.1-0.5 parts Lavender, 0.005-0.05 parts Envidor, 0.1-0.5
Part polyacrylamide, 0.1-0.5 parts crosslinking agent, 5-15 part 2- propyl alcohol, 0.1-0.5 parts chelating agent, 95-105 part water；Described friendship
Connection agent is mixed by 40-60wt%2,3- dyhydrobutanedioic acids and 40-60wt%3- hydroxyl glutaric acids.
2. the anti-mite socks of absorbing sweat as claimed in claim 1, it is characterised in that described chelating agent is by 40-60wt% ethylenediamine tetraacetics
Methylenephosphonic acid five sodium-salt and 40-60wt% ATMP five sodium-salts mix.
3. the preparation method of the anti-mite socks of absorbing sweat according to claim 1 or 2, it is characterised in that comprise the following steps：
(1) cotton fiber and polyamide fibre weaved using conventional method, be processed into socks；
(2) above-mentioned socks are subjected to the anti-mite processing of absorbing sweat.
4. the preparation method of the anti-mite socks of absorbing sweat according to claim 3, it is characterised in that the step (2) is in 65-85
Under the conditions of DEG C, socks are impregnated into 20-30min in absorbing sweat anti-mite finishing agent, after dehydration, 5- is dried under the conditions of 70-90 DEG C
10min。
5. the preparation method of the anti-mite socks of absorbing sweat according to claim 4, it is characterised in that described absorbing sweat anti-mite finishing agent
It is made up of the raw material of following weight parts：0.1-0.5 parts Lavender, 0.005-0.05 parts Envidor, 0.1-0.5 part polypropylene
Acid amides, 0.1-0.5 parts crosslinking agent, 5-15 part 2- propyl alcohol, 0.1-0.5 parts chelating agent, 95-105 part water.
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| CN201610119647.5A CN105696319B (en) | 2016-03-03 | 2016-03-03 | Anti-mite socks of absorbing sweat and preparation method thereof |
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| CN201610119647.5A CN105696319B (en) | 2016-03-03 | 2016-03-03 | Anti-mite socks of absorbing sweat and preparation method thereof |
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| CN105696319B true CN105696319B (en) | 2018-02-09 |
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| CN104594056A (en) * | 2013-10-31 | 2015-05-06 | 青岛鑫益发工贸有限公司 | Environmentally-friendly anti-mite fabric production method |
| CN105063876A (en) * | 2015-08-21 | 2015-11-18 | 沈汇明 | Production technology for deodorization elastic net socks |
| CN105231503A (en) * | 2015-11-20 | 2016-01-13 | 上海喜眠服饰有限公司 | Sweat removing pajama fabric and manufacturing method thereof |
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Patent Citations (6)
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|---|---|---|---|---|
| CN102277744A (en) * | 2011-06-10 | 2011-12-14 | 东华大学 | Antibiotic and anti-asthma finishing liquid, preparation method thereof and application thereof on fabrics |
| CN103668548A (en) * | 2012-09-21 | 2014-03-26 | 江苏蓝品纤维科技发展有限公司 | Lukens fiber and functional fiber prepared therefrom |
| CN104594056A (en) * | 2013-10-31 | 2015-05-06 | 青岛鑫益发工贸有限公司 | Environmentally-friendly anti-mite fabric production method |
| CN104499273A (en) * | 2014-11-17 | 2015-04-08 | 浙江梦娜袜业股份有限公司 | Mosquito-repelling and mite-resisting finishing agent for silk stockings and silk stocking production technology |
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| CN105231503A (en) * | 2015-11-20 | 2016-01-13 | 上海喜眠服饰有限公司 | Sweat removing pajama fabric and manufacturing method thereof |
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| CN105696319A (en) | 2016-06-22 |
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Effective date of registration: 20200616 Address after: 223600 Building 2, intelligent Knitting Industrial Park, Shuyang County, Suqian City, Jiangsu Province Patentee after: Jiangsu Dali intelligent textile technology Co.,Ltd. Address before: 311825 Zhejiang city of Shaoxing province Zhuji Paitou Zhen Keng Xi Cun township government Patentee before: Xu Mengkui |