CN105661665B - Absorbing sweat mosquito repellent socks and preparation method thereof - Google Patents
Absorbing sweat mosquito repellent socks and preparation method thereof Download PDFInfo
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- CN105661665B CN105661665B CN201610119309.1A CN201610119309A CN105661665B CN 105661665 B CN105661665 B CN 105661665B CN 201610119309 A CN201610119309 A CN 201610119309A CN 105661665 B CN105661665 B CN 105661665B
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- absorbing sweat
- mosquito repellent
- socks
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- 210000004243 sweat Anatomy 0.000 title claims abstract description 61
- 239000000077 insect repellent Substances 0.000 title claims abstract description 58
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 12
- 229920000742 Cotton Polymers 0.000 claims abstract description 8
- 239000004952 Polyamide Substances 0.000 claims abstract description 8
- 229920002647 polyamide Polymers 0.000 claims abstract description 8
- 238000009941 weaving Methods 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 34
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- 230000000740 bleeding effect Effects 0.000 claims description 12
- 239000003431 cross linking reagent Substances 0.000 claims description 12
- 244000178870 Lavandula angustifolia Species 0.000 claims description 8
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 8
- 239000001102 lavandula vera Substances 0.000 claims description 8
- 235000018219 lavender Nutrition 0.000 claims description 8
- 229920002401 polyacrylamide Polymers 0.000 claims description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 6
- 150000007513 acids Chemical class 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- -1 tridecyl sodium sulfonates Chemical class 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 241000255925 Diptera Species 0.000 claims description 4
- 238000007796 conventional method Methods 0.000 claims description 3
- 230000018044 dehydration Effects 0.000 claims description 3
- 238000006297 dehydration reaction Methods 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 241000744766 Cymbopogon winterianus Species 0.000 claims 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 5
- 238000007493 shaping process Methods 0.000 abstract description 2
- 230000000087 stabilizing effect Effects 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 9
- VPFNWSAQNWQCNX-UHFFFAOYSA-N CCCCCCCCCCCCC[Na] Chemical compound CCCCCCCCCCCCC[Na] VPFNWSAQNWQCNX-UHFFFAOYSA-N 0.000 description 6
- 244000032014 Java citronella Species 0.000 description 6
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric Acid Chemical compound [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 6
- OTTXIFWBPRRYOG-UHFFFAOYSA-N 2-hydroxyadipic acid Chemical class OC(=O)C(O)CCCC(O)=O OTTXIFWBPRRYOG-UHFFFAOYSA-N 0.000 description 5
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000003578 releasing effect Effects 0.000 description 3
- 210000003371 toe Anatomy 0.000 description 3
- 206010049244 Ankyloglossia congenital Diseases 0.000 description 2
- 206010015946 Eye irritation Diseases 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical class OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- 241000283973 Oryctolagus cuniculus Species 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 210000003423 ankle Anatomy 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 231100000013 eye irritation Toxicity 0.000 description 2
- 210000002683 foot Anatomy 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 230000001846 repelling effect Effects 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 206010015150 Erythema Diseases 0.000 description 1
- 240000000047 Gossypium barbadense Species 0.000 description 1
- 235000009429 Gossypium barbadense Nutrition 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 210000001015 abdomen Anatomy 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- 238000010171 animal model Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical class CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 210000001255 hallux Anatomy 0.000 description 1
- 210000003128 head Anatomy 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000009377 nuclear transmutation Methods 0.000 description 1
- 238000003305 oral gavage Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B11/00—Hosiery; Panti-hose
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B17/00—Selection of special materials for underwear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of absorbing sweat mosquito repellent socks and preparation method thereof.The absorbing sweat mosquito repellent socks are formed by the raw material weaving of following weight parts：60 80wt% cotton fibers and 20 40wt% polyamide fibres.Absorbing sweat mosquito repellent socks of the invention, process stabilizing is good from raw material, and by checking on for each procedure, steady quality, in appearance, Density is uniform, abundant, pure color for performance, and forming of shaping, is the ideal chose of healthy life staying idle at home.
Description
Technical field
The present invention relates to a kind of socks, and in particular to a kind of absorbing sweat mosquito repellent socks and preparation method thereof.
Background technology
" socks " one word sees earliest《China notes at all times》, say：" three generations and week Zhu Jiao Wa, ankle is lain in band "." three generations "
It refer to China's summer on the books earliest, business, all periods, away from the present existing 3000 or four thousand years history." Jiao Wa " should be made of animal skin
Original socks, so writing " Wa ".Later, with the appearance of textile, socks are developed into cloth, fiber crops, silk by beast cloth again
Make , " Wa " " socks " are also correspondingly changed to, " socks " of the today described in us are finally reduced to step by step.The transmutation process of " socks " word,
The development process of Chinese civilization history is contained in fact.
The shape of ancient times socks can about divide three-chip type craft socks to have legging, frenulum socks, panty hose, point toe socks, light
Six kinds of socks and bottomless sock etc. of head.Wherein have the stocking leg of legging different in size, some length to belly, have only between ankle.Frenulum socks
In order that difficult for drop-off when wearing.Toe socks are divided to be that big toe is separated with other four toe, shape such as bifurcation shape.Bare headed socks and bottomless sock are multiplex
In the women of ancient times foot-binding, half socks are commonly called as.
Now, the species of socks is a lot, by the length point of the stocking leg, has stocking, Knee-sockses and short legging and ship socks (stealthy
Socks)；By stocking blank species point, there are registered permanent residence socks, rib cuff socks and elastic top hosiery；By using object point, there are men's socks, female's socks and Children's Socks.Circular knit hosiery
By stocking blank, the stocking leg and the portion of tissue of stocking foot 3.The specification of socks, is represented with socks size, and socks number are with the reality of the stocking sole
Border length dimension is standard, so knowing that the pin of oneself just can choose the socks for fitting after long.By the original that socks are used
Material is different, and it is also different in socks series.
With the continuous improvement that people are pursued healthy living, the performance of socks is not limited solely to it is warming, attractive in appearance etc.,
Also it is aided with the various health cares such as more massages, antibacterial, anti-mite, moisture absorbing and sweat releasing, antistatic, uvioresistant and safeguard function.
The invention provides a kind of absorbing sweat mosquito repellent socks, multi-functional demand of the people to socks is met.
The content of the invention
For deficiencies of the prior art, one of the technical problems to be solved by the invention are to provide a kind of absorbing sweat
Mosquito repellent socks.
The two of the technical problems to be solved by the invention are to provide the preparation method of above-mentioned absorbing sweat mosquito repellent socks.
Technical problem of the invention, is achieved by following technical proposals：
A kind of absorbing sweat mosquito repellent socks, are formed by the raw material weaving of following weight parts：60-80wt% cotton fibers and 20-40wt%
Polyamide fibre.
The absorbing sweat mosquito repellent socks are obtained by absorbing sweat mosquito repellent process step again.
The absorbing sweat mosquito repellent process step is that the absorbing sweat mosquito repellent socks are impregnated in absorbing sweat mosquito repellent finishing agent, described suction
Sweat mosquito repellent finishing agent is made up of the raw material of following weight parts：0.1-0.3 parts of Lavender, 0.1-0.3 parts of oil of Cymbopogon winterianus, 0.1-
0.5 part of polyacrylamide, 0.1-0.5 parts of crosslinking agent, 5-15 parts of ethanol, 0.1-0.5 parts of bleeding agent, 95-105 parts of water.
Preferably, described crosslinking agent is by 40-60wt%2,3- dyhydrobutanedioic acids and 40-60wt%2- hydroxyl adipic acids
Mix.
Preferably, described bleeding agent is by 40-60wt% dodecyl sodium sulfates and 40-60wt% tridecyl sodium sulfonates
Mix.
Present invention also offers the preparation method of above-mentioned absorbing sweat mosquito repellent socks, comprise the following steps：
(1) cotton fiber and polyamide fibre weaved using conventional method, be processed into socks；
(2) above-mentioned socks are carried out into absorbing sweat mosquito repellent treatment.
Preferably, the step (2) is under the conditions of 65-85 DEG C, socks to be impregnated into 20- in absorbing sweat mosquito repellent finishing agent
30min, after dehydration, dries 5-10min under the conditions of 70-90 DEG C.
Described absorbing sweat mosquito repellent finishing agent is made up of the raw material of following weight parts：0.1-0.3 parts of Lavender, 0.1-
0.3 part of oil of Cymbopogon winterianus, 0.1-0.5 parts of polyacrylamide, 0.1-0.5 parts of crosslinking agent, 5-15 parts of ethanol, 0.1-0.5 parts of bleeding agent,
95-105 parts of water.
Specifically, in the present invention：
Lavender, No. CAS：8000-28-0.
Oil of Cymbopogon winterianus, No. CAS：73049-78-2.
Polyacrylamide, No. CAS：9003-05-8.
2,3- dyhydrobutanedioic acids, No. CAS：526-83-0.
2- hydroxyl adipic acids, No. CAS：18294-85-4.
Dodecyl sodium sulfate, No. CAS：2386-53-0.
Tridecyl sodium sulfonate, No. CAS：5802-89-1.
Ethanol, No. CAS：64-17-5.
Absorbing sweat mosquito repellent socks of the invention, process stabilizing is good from raw material, by checking on for each procedure, steady quality, table
Now in appearance, Density is uniform, abundant, pure color, and forming of shaping, is the ideal chose of healthy life staying idle at home.
Specific embodiment
With reference to embodiment, the present invention is described further, as described below, is only to preferable implementation of the invention
Example, not does the limitation of other forms to the present invention, and any those skilled in the art are possibly also with the disclosure above
Technology contents be changed to the Equivalent embodiments of equal change.It is every without departing from the present invention program content, according to the present invention
Technical spirit any simple modification that following examples are made or equivalent variations, all fall within protection scope of the present invention.
Polyacrylamide, No. CAS：9003-05-8.The molecule provided using Liaocheng of Shandong Province Hong Xin Chemical Co., Ltd.s
It is the non-ionic polyacrylamide of 500-800 ten thousand to measure.
Embodiment 1
Absorbing sweat mosquito repellent socks raw material (percentage by weight)：70wt% cotton fibers (cotton fiber is long-staple cotton, and its length is 40mm,
Fineness is 7200nm) and 30wt% polyamide fibres (using the polyamide fibre 6-DTY, 40D of the production of Jiangsu Ping Meisha industry Co., Ltd).
Absorbing sweat mosquito repellent finishing agent raw material (weight portion)：0.2 part of Lavender, 0.2 part of oil of Cymbopogon winterianus, 0.3 part of polypropylene
Acid amides, 0.3 part of crosslinking agent, 10 parts of ethanol, 0.3 part of bleeding agent, 100 parts of deionized waters.
Described crosslinking agent is uniformly mixed by 50wt%2,3- dyhydrobutanedioic acids and 50wt%2- hydroxyl adipic acids
Obtain.
Described bleeding agent is uniformly mixed by 50wt% dodecyl sodium sulfates and 50wt% tridecyl sodium sulfonates
Obtain.
Present invention also offers the preparation method of above-mentioned absorbing sweat mosquito repellent socks, comprise the following steps：
(1) use braider, according to a conventional method by cotton fiber and polyamide fibre weave into socks blank cloth (grammes per square metre is 160 grams/it is flat
Square rice), according to the technique and requirement that make socks, after socks blank cloth is cut, it is processed into socks；
(2) by Lavender, oil of Cymbopogon winterianus, polyacrylamide, crosslinking agent, ethanol, bleeding agent addition deionized water
It is uniformly mixed, obtains absorbing sweat mosquito repellent finishing agent；Socks are placed in the absorbing sweat mosquito repellent finishing agent that temperature is 75 DEG C and are impregnated
25min, wherein socks are 1 with the mass ratio of absorbing sweat mosquito repellent finishing agent:10 (i.e. 1kg socks 10kg absorbing sweat mosquito repellents finishing agent leachings
Stain), after dehydration, 8min is dried under the conditions of 80 DEG C；Obtain absorbing sweat mosquito repellent socks.
Embodiment 2
It is substantially the same manner as Example 1, differ only in：Described crosslinking agent is only 2,3 dihydroxybutanedioic acid.Obtain
The absorbing sweat mosquito repellent socks of embodiment 2.
Embodiment 3
It is substantially the same manner as Example 1, differ only in：Described crosslinking agent is only 2- hydroxyl adipic acids.Implemented
The absorbing sweat mosquito repellent socks of example 3.
Embodiment 4
It is substantially the same manner as Example 1, differ only in：Described bleeding agent is only dodecyl sodium sulfate.Obtain reality
Apply the absorbing sweat mosquito repellent socks of example 4.
Embodiment 5
It is substantially the same manner as Example 1, differ only in：Described bleeding agent is only tridecyl sodium sulfonate.Obtain reality
Apply the absorbing sweat mosquito repellent socks of example 5.
Test case 1
Absorbing sweat mosquito repellent socks to embodiment 1-5 carry out mosquito repellent test.
Experiment is at dusk 18:00-20:00 is carried out, and small white mouse is fixed on one block of three-ply board of 10cm × 15cm, mouse body
Surface covers a silk stocking, and is fixed in surrounding with elastic, and then putting it into feeding has in 1000 mosquito cages of mosquito, timing 3
Minute, observe and record mosquito during this period and stop the number of times that falls on sample cloth cover, in triplicate, embodiment is used with comparative example
Color is identical.Test data is shown in Table 1.
Table 1：Synthesis test table
Comparing embodiment 1-3, embodiment 1 (2,3- dyhydrobutanedioic acids, 2- hydroxyls adipic acid compounding) repelling effect, hence it is evident that
Better than embodiment 2-3 (single raw material in 2,3 dihydroxybutanedioic acid, 2- hydroxyl adipic acids)；Comparing embodiment 1 and embodiment 4-
5, embodiment 1 (dodecyl sodium sulfate, tridecyl sodium sulfonate compounding) repelling effect, hence it is evident that better than embodiment 4-5 (dodecanes
Single raw material in base sodium sulfonate, tridecyl sodium sulfonate).
Test case 2
Absorbing sweat mosquito repellent socks to embodiment 1-5 carry out wetness guiding perspiration discharging test, reference standard ISO11092：1993, use
SDL Sweat Exhaust ＆ Moisture Conductivities instrument tests thermal resistance, the dampness of each embodiment and comparative example.Test data is shown in Table 1.
Table 1：Wetness guiding perspiration discharging performance tests table
| Embodiment 1 | 9.8023 | 4.568 |
| Embodiment 2 | 10.991 | 5.710 |
| Embodiment 3 | 10.982 | 5.708 |
| Embodiment 4 | 11.079 | 5.806 |
| Embodiment 5 | 11.092 | 5.792 |
Comparing embodiment 1-3, embodiment 1 (2,3- dyhydrobutanedioic acids, 2- hydroxyls adipic acid compounding) moisture absorbing and sweat releasing effect,
It is substantially better than embodiment 2-3 (single raw material in 2,3 dihydroxybutanedioic acid, 2- hydroxyl adipic acids)；Comparing embodiment 1 and implementation
Example 4-5, embodiment 1 (dodecyl sodium sulfate, tridecyl sodium sulfonate compounding) moisture absorbing and sweat releasing effect, hence it is evident that better than embodiment 4-
5 (single raw materials in dodecyl sodium sulfate, tridecyl sodium sulfonate).
Test case 3
Absorbing sweat mosquito repellent finishing agent (absorbing sweat mosquito repellent finishing agent raw material (weight portion) of embodiment 1：0.2 part of Lavender, 0.2
Part oil of Cymbopogon winterianus, 0.3 part of polyacrylamide, 0.3 part of crosslinking agent, 3 parts of ethanol, 0.3 part of bleeding agent, 100 parts of deionized waters) toxicity
Experiment：
(1) the oral acute toxicity of absorbing sweat mosquito repellent finishing agent；Absorbing sweat mosquito repellent finishing agent is taken to 40 Kunming kind marks of empty stomach 16h
The disposable oral gavage of quasi- small white mouse, absorbing sweat mosquito repellent arranges agent dose and is up to 1000mg/kg.Animal and poisoning table are observed daily
Existing, seven days terminate experiment, and in whole experiment process, without any poisoning manifestations, diet and motion are normal for each group experimental animal,
None animal dead.
(2) to skin irritation：10 big ear tag quasi-experiments of Japan are cut respectively with the backbone diamond wool of rabbit, will be impregnated
The gauze of absorbing sweat mosquito repellent finishing agent is crossed, is applied on the exposed skin in right side.Application site skin is observed after 24 hours, is not gone out
The irritations such as existing erythema and oedema, according to skin irritatin strength grading standard, the absorbing sweat mosquito repellent finishing agent belongs to stingless to skin
Swash material.
(3) to eye irritation：By absorbing sweat mosquito repellent finishing agent, right eye of the big ear tag quasi-experiment of Japan with rabbit is directly instilled,
Left eye is compared, passive closure 5 seconds, then clean with normal saline flushing, is observed after 24 hours, and eyes are without exception, according to
Eye irritation strength grading standard, the absorbing sweat mosquito repellent finishing agent belongs to non-stimulated material to eyes.
Claims (5)
1. a kind of absorbing sweat mosquito repellent socks, it is characterised in that formed by the raw material weaving of following weight parts：60-80wt% cotton fibers and
20-40wt% polyamide fibres；
The absorbing sweat mosquito repellent socks are obtained by absorbing sweat mosquito repellent process step again；
The absorbing sweat mosquito repellent process step is that the absorbing sweat mosquito repellent socks are impregnated in absorbing sweat mosquito repellent finishing agent, and described absorbing sweat drives
Mosquito finishing agent is made up of the raw material of following weight parts：0.1-0.3 parts of Lavender, 0.1-0.3 parts of oil of Cymbopogon winterianus, 0.1-0.5
Part polyacrylamide, 0.1-0.5 parts of crosslinking agent, 5-15 parts of ethanol, 0.1-0.5 parts of bleeding agent, 95-105 parts of water；
Described crosslinking agent is mixed by 40-60wt%2,3- dyhydrobutanedioic acids and 40-60wt%2- hydroxyl adipic acids.
2. absorbing sweat mosquito repellent socks as claimed in claim 1, it is characterised in that described bleeding agent is by 40-60wt% dodecyls
Sodium sulfonate and 40-60wt% tridecyl sodium sulfonates are mixed.
3. the preparation method of absorbing sweat mosquito repellent socks according to claim 1 and 2, it is characterised in that comprise the following steps：
(1) cotton fiber and polyamide fibre weaved using conventional method, be processed into socks；
(2) above-mentioned socks are carried out into absorbing sweat mosquito repellent treatment.
4. the preparation method of absorbing sweat mosquito repellent socks according to claim 3, it is characterised in that the step (2) is in 65-85
Under the conditions of DEG C, socks are impregnated into 20-30min in absorbing sweat mosquito repellent finishing agent, after dehydration, 5- is dried under the conditions of 70-90 DEG C
10min。
5. the preparation method of absorbing sweat mosquito repellent socks according to claim 4, it is characterised in that described absorbing sweat mosquito repellent finishing agent
It is made up of the raw material of following weight parts：0.1-0.3 parts of Lavender, 0.1-0.3 parts of oil of Cymbopogon winterianus, 0.1-0.5 parts of polypropylene
Acid amides, 0.1-0.5 part crosslinking agent, 5-15 parts of ethanol, 0.1-0.5 parts of bleeding agent, 95-105 parts of water.
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| CN201610119309.1A CN105661665B (en) | 2016-03-03 | 2016-03-03 | Absorbing sweat mosquito repellent socks and preparation method thereof |
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| CN201610119309.1A CN105661665B (en) | 2016-03-03 | 2016-03-03 | Absorbing sweat mosquito repellent socks and preparation method thereof |
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| CN105661665B true CN105661665B (en) | 2017-06-06 |
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| KR101099994B1 (en) * | 2008-09-16 | 2011-12-28 | 양원동 | stocking |
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| CN103262839A (en) * | 2013-05-31 | 2013-08-28 | 广州立白企业集团有限公司 | Mosquito repelling gel composition with natural plant essential oil |
| CN104382242A (en) * | 2014-12-10 | 2015-03-04 | 江南大学 | Anti-flea knitted stocking |
| CN104499273A (en) * | 2014-11-17 | 2015-04-08 | 浙江梦娜袜业股份有限公司 | Mosquito-repelling and mite-resisting finishing agent for silk stockings and silk stocking production technology |
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|---|---|---|---|---|
| CN1102767A (en) * | 1994-09-10 | 1995-05-24 | 王星 | Method for making mosquito-repelling socks |
| KR101099994B1 (en) * | 2008-09-16 | 2011-12-28 | 양원동 | stocking |
| CN101994192A (en) * | 2010-11-01 | 2011-03-30 | 台华特种纺织（嘉兴）有限公司 | Moisture-absorbing quick-drying type jacquard fabric as well as hydrophilic quick-drying finishing agent and post processing method thereof |
| CN102587127A (en) * | 2011-12-29 | 2012-07-18 | 安徽中天印染股份有限公司 | Method for finishing mosquito-protective clothing |
| CN103262839A (en) * | 2013-05-31 | 2013-08-28 | 广州立白企业集团有限公司 | Mosquito repelling gel composition with natural plant essential oil |
| CN104499273A (en) * | 2014-11-17 | 2015-04-08 | 浙江梦娜袜业股份有限公司 | Mosquito-repelling and mite-resisting finishing agent for silk stockings and silk stocking production technology |
| CN104382242A (en) * | 2014-12-10 | 2015-03-04 | 江南大学 | Anti-flea knitted stocking |
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| CN105661665A (en) | 2016-06-15 |
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Effective date of registration: 20190704 Address after: 236500 Industrial Park, Fuyang City, Anhui Patentee after: JIESHOU SHUANGXIN TEXTILE CO., LTD. Address before: 311825 Yuanxiang Government of Kengxi Village, Paitou Town, Zhuji City, Shaoxing City, Zhejiang Province Patentee before: Xu Mengkui |
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