CN105648754A - Mosquito-repellent antibacterial socks and preparation method thereof - Google Patents
Mosquito-repellent antibacterial socks and preparation method thereof Download PDFInfo
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- CN105648754A CN105648754A CN201610120346.4A CN201610120346A CN105648754A CN 105648754 A CN105648754 A CN 105648754A CN 201610120346 A CN201610120346 A CN 201610120346A CN 105648754 A CN105648754 A CN 105648754A
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- Prior art keywords
- anophelifuge
- socks
- antibacterial
- agent
- antibacterial socks
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 63
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000000077 insect repellent Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 claims abstract description 11
- 229920000742 Cotton Polymers 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 34
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 25
- 239000002994 raw material Substances 0.000 claims description 15
- 239000003431 cross linking reagent Substances 0.000 claims description 12
- 230000000149 penetrating effect Effects 0.000 claims description 12
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims description 10
- VPFNWSAQNWQCNX-UHFFFAOYSA-N CCCCCCCCCCCCC[Na] Chemical compound CCCCCCCCCCCCC[Na] VPFNWSAQNWQCNX-UHFFFAOYSA-N 0.000 claims description 9
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 claims description 9
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 9
- 241000744766 Cymbopogon winterianus Species 0.000 claims description 8
- 229960001950 benzethonium chloride Drugs 0.000 claims description 8
- 229920006052 Chinlon® Polymers 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 3
- 235000011037 adipic acid Nutrition 0.000 claims description 3
- 239000001361 adipic acid Substances 0.000 claims description 3
- 238000007796 conventional method Methods 0.000 claims description 3
- 230000018044 dehydration Effects 0.000 claims description 3
- 238000006297 dehydration reaction Methods 0.000 claims description 3
- WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 3
- 230000000845 anti-microbial effect Effects 0.000 claims description 2
- 239000004744 fabric Substances 0.000 abstract description 6
- 239000000463 material Substances 0.000 abstract description 3
- 239000000835 fiber Substances 0.000 abstract description 2
- 238000007493 shaping process Methods 0.000 abstract description 2
- 239000004952 Polyamide Substances 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 238000009941 weaving Methods 0.000 abstract 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric Acid Chemical compound [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- OTTXIFWBPRRYOG-UHFFFAOYSA-N 2-hydroxyadipic acid Chemical compound OC(=O)C(O)CCCC(O)=O OTTXIFWBPRRYOG-UHFFFAOYSA-N 0.000 description 7
- 241001465754 Metazoa Species 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 241000255925 Diptera Species 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 210000002683 foot Anatomy 0.000 description 3
- 210000003371 toe Anatomy 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 206010049244 Ankyloglossia congenital Diseases 0.000 description 2
- 206010015946 Eye irritation Diseases 0.000 description 2
- 241000699670 Mus sp. Species 0.000 description 2
- 241000283973 Oryctolagus cuniculus Species 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- 210000003423 ankle Anatomy 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 231100000013 eye irritation Toxicity 0.000 description 2
- 210000003128 head Anatomy 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 230000001846 repelling effect Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 206010015150 Erythema Diseases 0.000 description 1
- 240000000047 Gossypium barbadense Species 0.000 description 1
- 235000009429 Gossypium barbadense Nutrition 0.000 description 1
- 241000699666 Mus <mouse, genus> Species 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 230000003187 abdominal effect Effects 0.000 description 1
- 230000007059 acute toxicity Effects 0.000 description 1
- 231100000403 acute toxicity Toxicity 0.000 description 1
- 238000010171 animal model Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000003304 gavage Methods 0.000 description 1
- 210000001255 hallux Anatomy 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000009377 nuclear transmutation Methods 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 238000012113 quantitative test Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B11/00—Hosiery; Panti-hose
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B17/00—Selection of special materials for underwear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/005—Compositions containing perfumes; Compositions containing deodorants
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/34—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass antimicrobial or antibacterial
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2500/00—Materials for shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2500/20—Woven
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
- D06M2101/36—Aromatic polyamides
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a pair of mosquito-repellent antibacterial socks and a preparation method thereof. The mosquito-repellent antibacterial socks are made by weaving of, by weight, 60-80wt% of cotton fibers and 20-40wt% of polyamide fibers. The mosquito-repellent antibacterial socks made of excellent selected materials are stable technically and stable in quality due to strict requirements on each procedure, and visually, fabric density uniformity, thickness, high color purity and favorable shaping and forming are realized. Therefore, the mosquito-repellent antibacterial socks are ideal for healthy household life.
Description
Technical field
The present invention relates to a kind of socks, be specifically related to a kind of anophelifuge antibacterial socks and preparation method thereof.
Background technology
" socks " word sees " China notes at all times " the earliest, says: " three generations and week work angle, lie in ankle with band ". " three generations " refers to China's summer on the books the earliest, business, period in week, from the present existing 3000 or four thousand years history. " angle " should be the original socks made of animal skin, so writing " ". Later, along with the appearance of textile, socks again by beast cloth develop into cloth, fiber crops, silk make, " " also correspondingly changes into " socks ", be finally reduced to step by step today we described " socks ". The transmutation process of " socks " word, has contained the development process of Chinese civilization history in fact.
Ancient times, the shape system of socks about can divide three-chip type craft socks for having legging, frenulum socks, panty hose, point toe socks, shaven head socks and bottomless sock etc. six kinds. The stocking leg wherein having legging is different in size, some length to abdominal part, have only between ankle. Frenulum socks are in order that difficult drop-off when wearing. Dividing toe socks is separated with other four toes by big toe, and shape is bifurcation shape such as. Shaven head socks and bottomless sock are used for the women of foot-binding in ancient times, are commonly called as half socks.
Now, the kind of socks is a lot, divides by the length of the stocking leg, has stocking, Knee-socks and short legging and ship socks (invisible socks); Divide by stocking blank kind, have registered permanent residence socks, rib cuff socks and elastic top hosiery; By using object to divide, there are men's socks, female's socks and Children's Socks. Circular knit hosiery is by stocking blank, the stocking leg and stocking foot 3 portion of tissue. The specification of socks, represents with socks size, and socks number is to be of a size of standard with the physical length of the stocking sole, so just can choose, after knowing the foot length of oneself, the socks fitted. The raw material used due to socks is different, and it is also different in socks series.
Along with people are to improving constantly that healthy living is pursued, the performance of socks are not limited solely to warming, attractive in appearance etc., are also aided with various health cares and the safeguard functions such as more massage, demodicid mite antibacterial, anti-, moisture absorbing and sweat releasing, antistatic, uvioresistant.
The invention provides a kind of anophelifuge antibacterial socks, meet the people's multi-functional demand to socks.
Summary of the invention
For prior art above shortcomings, one of the technical problem to be solved is to provide a kind of anophelifuge antibacterial socks.
The preparation method that the two of the technical problem to be solved are to provide above-mentioned anophelifuge antibacterial socks.
The technical problem of the present invention, is achieved by following technical proposals:
A kind of anophelifuge antibacterial socks, is weaved by the raw material of following weight parts and forms: 60-80wt% cotton fiber and 20-40wt% chinlon.
Preferably, described anophelifuge antibacterial socks obtains then through anophelifuge antibacterial treatment process.
Preferably, described anophelifuge antibacterial treatment process is impregnated in anophelifuge antibacterial finishing agent by described anophelifuge antibacterial socks, and described anophelifuge antibacterial finishing agent is made up of the raw material of following weight parts: 0.1-0.3 part Herba Lysimachiae foenum-graeci quintessence oil, 0.1-0.3 part oil of Cymbopogon winterianus, 0.05-0.5 part benzethonium chloride, 0.1-0.5 part penetrating agent, 5-15 part 1-propanol, 0.1-0.5 part cross-linking agent, 95-105 part water.
Preferably, described penetrating agent is mixed by 40-60wt% aerosol OT and 40-60wt% tridecyl sodium sulfonate.
Preferably, described cross-linking agent is mixed by 40-60wt%2,3-dyhydrobutanedioic acid and 40-60wt%2-hydroxyl adipic acid.
The preparation method that present invention also offers above-mentioned anophelifuge antibacterial socks, comprises the following steps:
(1) conventional method is adopted cotton fiber and chinlon to be weaved, be processed into socks;
(2) above-mentioned socks are carried out anophelifuge antimicrobial treatment.
Preferably, described step (2) is under 65-85 DEG C of condition, and socks impregnate 20-30min in anophelifuge antibacterial finishing agent, after dehydration, dries 5-10min under 70-90 DEG C of condition.
Described anophelifuge antibacterial finishing agent is made up of the raw material of following weight parts: 0.1-0.3 part Herba Lysimachiae foenum-graeci quintessence oil, 0.1-0.3 part oil of Cymbopogon winterianus, 0.05-0.5 part benzethonium chloride, 0.1-0.5 part penetrating agent, 5-15 part 1-propanol, 0.1-0.5 part cross-linking agent, 95-105 part water.
Concrete, in the present invention:
Herba Lysimachiae foenum-graeci quintessence oil, No. CAS: 8000-28-0.
Oil of Cymbopogon winterianus, No. CAS: 73049-78-2.
Benzethonium chloride, No. CAS: 121-54-0.
Aerosol OT, No. CAS: 577-11-7.
Tridecyl sodium sulfonate, No. CAS: 5802-89-1.
2,3 dihydroxybutanedioic acid, No. CAS: 526-83-0.
2-hydroxyl adipic acid, No. CAS: 18294-85-4.
1-propanol, No. CAS: 71-23-8.
The anophelifuge antibacterial socks of the present invention, process stabilizing, to select raw material good, by checking on of each procedure, steady quality, show in appearance, Density is uniform, abundant, pure color, forming of shaping, and is the ideal chose of healthy life staying idle at home.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further, the following stated, it is only to presently preferred embodiments of the present invention, the present invention not does the restriction of other forms, and any those skilled in the art are changed to the equal Equivalent embodiments changed possibly also with the technology contents of the disclosure above. Every without departing from the present invention program content, any simple modification following example done according to the technical spirit of the present invention or equivalent variations, all fall within protection scope of the present invention.
Embodiment 1
Anophelifuge antibacterial socks raw material (percentage by weight): (cotton fiber is long-staple cotton to 70wt% cotton fiber, its length is 40mm, fineness is 7200nm) and 30wt% chinlon (adopting chinlon 6-DTY, 40D that Jiangsu Ping Meisha industry company limited produces).
Anophelifuge antibacterial finishing agent raw material (weight portion): 0.2 part of Herba Lysimachiae foenum-graeci quintessence oil, 0.2 part of oil of Cymbopogon winterianus, 0.02 part of benzethonium chloride, 0.3 part of penetrating agent, 10 parts of 1-propanol, 0.3 part of cross-linking agent, 100 parts of deionized waters.
Described penetrating agent is uniformly mixed is obtained by 50wt% aerosol OT and 50wt% tridecyl sodium sulfonate.
Described cross-linking agent is uniformly mixed is obtained by 50wt%2,3-dyhydrobutanedioic acid and 50wt%2-hydroxyl adipic acid.
The preparation method that present invention also offers above-mentioned anophelifuge antibacterial socks, comprises the following steps:
(1) adopt braider, according to a conventional method cotton fiber and chinlon are woven into socks blank cloth (grammes per square metre is 160 grams/m), according to the technique and the requirement that make socks, after socks blank cloth cutting, be processed into socks;
(2) Herba Lysimachiae foenum-graeci quintessence oil, oil of Cymbopogon winterianus, benzethonium chloride, penetrating agent, 1-propanol, cross-linking agent are added deionized water for stirring mix homogeneously, obtain anophelifuge antibacterial finishing agent; Socks are placed in the anophelifuge antibacterial finishing agent that temperature is 75 DEG C and impregnate 25min, wherein socks are 1:10 (i.e. 1kg socks 10kg anophelifuge antibacterial finishing agent dipping) with the mass ratio of anophelifuge antibacterial finishing agent, after dehydration, under 80 DEG C of conditions, dry 8min; Obtain anophelifuge antibacterial socks.
Embodiment 2
Substantially the same manner as Example 1, differ only in: described penetrating agent is only aerosol OT. Obtain the anophelifuge antibacterial socks of embodiment 2.
Embodiment 3
Substantially the same manner as Example 1, differ only in: described penetrating agent is only tridecyl sodium sulfonate. Obtain the anophelifuge antibacterial socks of embodiment 3.
Embodiment 4
Substantially the same manner as Example 1, differ only in: described cross-linking agent is only 2,3 dihydroxybutanedioic acid. Obtain the anophelifuge antibacterial socks of embodiment 4.
Embodiment 5
Substantially the same manner as Example 1, differ only in: described cross-linking agent is only 2-hydroxyl adipic acid. Obtain the anophelifuge antibacterial socks of embodiment 5.
Test case 1
The anophelifuge antibacterial socks of embodiment 1-5 is carried out antibacterial test,
Standard GB/T/T20944.3-2008 " the evaluation third portion of antibacterial textile performance: succusion " is adopted to carry out antibiotic property quantitative test, adopt color fastness to washing testing machine washing methods, the bacteriostasis rate of anophelifuge antibacterial socks after 30 times is washed in test, and test result is in Table 1.
Table 1: bacteriostasis rate test chart after washing 30 times
Comparing embodiment 1-3, embodiment 1 (aerosol OT, tridecyl sodium sulfonate are composite) antibacterial effect, hence it is evident that be better than embodiment 2-3 (in aerosol OT, tridecyl sodium sulfonate single raw material); Comparing embodiment 1 and embodiment 4-5, embodiment 1 (2,3 dihydroxybutanedioic acid, 2-hydroxyl adipic acid are composite) antibacterial effect, hence it is evident that be better than embodiment 4-5 (in 2,3 dihydroxybutanedioic acid, 2-hydroxyl adipic acid single raw material).
Test case 2
The anophelifuge antibacterial socks of embodiment 1-5 is carried out anophelifuge test,
Test 18:00-20:00 between the lights to carry out, white mice is fixed on the three-ply board of one piece of 10cm �� 15cm, Mus surface covers silk stocking, and fix in surrounding with elastic, then put it in the mosquito cage raising 1000 mosquitoes, timing 3 minutes, observe and record mosquito during this period and stop, on sample cloth cover, the number of times that falls, in triplicate, embodiment uses color identical with comparative example. Test data are in Table 2.
Table 2: synthesis test chart
Comparing embodiment 1-3, embodiment 1 (aerosol OT, tridecyl sodium sulfonate are composite) repelling effect, hence it is evident that be better than embodiment 2-3 (in aerosol OT, tridecyl sodium sulfonate single raw material); Comparing embodiment 1 and embodiment 4-5, embodiment 1 (2,3 dihydroxybutanedioic acid, 2-hydroxyl adipic acid are composite) repelling effect, hence it is evident that be better than embodiment 4-5 (in 2,3 dihydroxybutanedioic acid, 2-hydroxyl adipic acid single raw material).
Test case 3
Embodiment 1 anophelifuge antibacterial finishing agent (anophelifuge antibacterial finishing agent raw material (weight portion):: 0.2 part of Herba Lysimachiae foenum-graeci quintessence oil, 0.2 part of oil of Cymbopogon winterianus, 0.02 part of benzethonium chloride, 0.3 part of penetrating agent, 10 parts of 1-propanol, 0.3 part of cross-linking agent, 100 parts of deionized waters) toxicity test:
(1) anophelifuge antibacterial finishing agent per os acute toxicity; Taking the anophelifuge antibacterial finishing agent Kunming disposable per os gavage of kind standard white mice to 40 empty stomach 16h, anophelifuge antibiotic finish agent dose is up to 1000mg/kg.Observing animal and poisoning manifestations every day, within seven days, terminate experiment, each group laboratory animal is in whole experimentation, all normal without any poisoning manifestations, diet and motion, none animal dead.
(2) to skin irritation: 10 Japan's big ear tag quasi experiment spinal column diamond wools of rabbit are cut respectively, the gauze of anophelifuge antibacterial finishing agent will be impregnated, apply ointment or plaster on the skin that right side exposes. Observing application site skin after 24 hours, the irritation such as erythema and edema all do not occur, according to skin irritation strength grading standard, skin is belonged to non-stimulated material by this anophelifuge antibacterial finishing agent.
(3) to eye irritation: by anophelifuge antibacterial finishing agent, directly instill the big ear tag quasi experiment right eye of rabbit of Japan, left eye compares, passive Guan Bi 5 seconds, then clean with normal saline flushing, to observe after 24 hours, eyes are all without exception, according to eye irritation strength grading standard, eyes are belonged to non-stimulated material by this anophelifuge antibacterial finishing agent.
Claims (6)
1. an anophelifuge antibacterial socks, it is characterised in that weaved by the raw material of following weight parts and form: 60-80wt% cotton fiber and 20-40wt% chinlon.
Described anophelifuge antibacterial socks obtains then through anophelifuge antibacterial treatment process.
Described anophelifuge antibacterial treatment process is impregnated in anophelifuge antibacterial finishing agent by described anophelifuge antibacterial socks, and described anophelifuge antibacterial finishing agent is made up of the raw material of following weight parts: 0.1-0.3 part Herba Lysimachiae foenum-graeci quintessence oil, 0.1-0.3 part oil of Cymbopogon winterianus, 0.05-0.5 part benzethonium chloride, 0.1-0.5 part penetrating agent, 5-15 part 1-propanol, 0.1-0.5 part cross-linking agent, 95-105 part water.
2. anophelifuge antibacterial socks as claimed in claim 1, it is characterised in that described penetrating agent is mixed by 40-60wt% aerosol OT and 40-60wt% tridecyl sodium sulfonate.
3. anophelifuge antibacterial socks as claimed in claim 1 or 2, it is characterised in that described cross-linking agent is mixed by 40-60wt%2,3-dyhydrobutanedioic acid and 40-60wt%2-hydroxyl adipic acid.
4. the preparation method of the anophelifuge antibacterial socks according to any one of claim 1-3, it is characterised in that comprise the following steps:
(1) conventional method is adopted cotton fiber and chinlon to be weaved, be processed into socks;
(2) above-mentioned socks are carried out anophelifuge antimicrobial treatment.
5. the preparation method of anophelifuge antibacterial socks according to claim 4, it is characterized in that, described step (2) is under 65-85 DEG C of condition, and socks impregnate 20-30min in anophelifuge antibacterial finishing agent, after dehydration, under 70-90 DEG C of condition, dry 5-10min.
6. the preparation method of anophelifuge antibacterial socks according to claim 5, it is characterized in that, described anophelifuge antibacterial finishing agent is made up of the raw material of following weight parts: 0.1-0.3 part Herba Lysimachiae foenum-graeci quintessence oil, 0.1-0.3 part oil of Cymbopogon winterianus, 0.05-0.5 part benzethonium chloride, 0.1-0.5 part penetrating agent, 5-15 part 1-propanol, 0.1-0.5 part cross-linking agent, 95-105 part water.
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| CN106519656A (en) * | 2016-11-21 | 2017-03-22 | 郑州源冉生物技术有限公司 | Composite for socks |
| CN108936835A (en) * | 2017-05-20 | 2018-12-07 | 宜兴市艺蝶针织有限公司 | A kind of antibacterial deodorant socks and its preparation process |
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| CN105648754B (en) | 2017-11-07 |
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Effective date of registration: 20190509 Address after: 321000 Block D of Xiaoshun Town North Functional Zone, Jindong District, Jinhua City, Zhejiang Province (in Zhejiang Lanshibutterfly Knitting Garment Co., Ltd.) Patentee after: ZHEJIANG KAINIWEI KNITTING GARMENT Co.,Ltd. Address before: 311825 Yuanxiang Government of Kengxi Village, Paitou Town, Zhuji City, Shaoxing City, Zhejiang Province Patentee before: Xu Mengkui |
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Denomination of invention: Mosquito repellent and antibacterial socks and their preparation method Granted publication date: 20171107 Pledgee: China Postal Savings Bank Co.,Ltd. Jinhua Branch Pledgor: ZHEJIANG KAINIWEI KNITTING GARMENT Co.,Ltd. Registration number: Y2024980005657 |
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