CN105565784A - 陶瓷研磨体及其制备方法 - Google Patents

陶瓷研磨体及其制备方法 Download PDF

Info

Publication number
CN105565784A
CN105565784A CN201510988241.6A CN201510988241A CN105565784A CN 105565784 A CN105565784 A CN 105565784A CN 201510988241 A CN201510988241 A CN 201510988241A CN 105565784 A CN105565784 A CN 105565784A
Authority
CN
China
Prior art keywords
grinding body
clay
ceramic grinding
parts
graphite powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510988241.6A
Other languages
English (en)
Inventor
牟元全
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chongqing Luoman New Material Technology Co Ltd
Original Assignee
Chongqing Luoman New Material Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chongqing Luoman New Material Technology Co Ltd filed Critical Chongqing Luoman New Material Technology Co Ltd
Priority to CN201510988241.6A priority Critical patent/CN105565784A/zh
Publication of CN105565784A publication Critical patent/CN105565784A/zh
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3839Refractory metal carbides
    • C04B2235/3843Titanium carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3852Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
    • C04B2235/3886Refractory metal nitrides, e.g. vanadium nitride, tungsten nitride
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/42Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
    • C04B2235/422Carbon
    • C04B2235/425Graphite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54Particle size related information
    • C04B2235/5418Particle size related information expressed by the size of the particles or aggregates thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567Treatment time

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

本发明公开了一种陶瓷研磨体,由重量份数的以下原材料制成:铝矾土60-90份,粘土5-20份,石墨粉3-15份。按照如下方法制备:将所述铝矾土、粘土和石墨粉混合,球磨至粒径≥300目,然后加水练泥,喷雾造粒后烘干,成型,再在1200-1500℃下烧结16-32h得到产品。本发明制得的陶瓷研磨体弹性模量大,耐磨性好、抗冲击性好,化学稳定性好,研磨效率高,适合在干磨工艺中使用。且本发明用于陶瓷原材料、水泥、火电、冶金和矿山中,对这些原材料的污染少,制造成本低。

Description

陶瓷研磨体及其制备方法
技术领域
本发明涉及一种适合于干法球磨工艺的陶瓷研磨体,本发明还涉及该研磨体的制备方法。
背景技术
陶瓷、水泥、火电、冶金、矿山等行业在生产之前需要用球磨机磨粉,目前,在干磨工艺中,大都采用钢球和钢锻作为研磨体,能耗高,耐磨性差,且在使用过程中,铁质物质容易进入原材料中,对产品品质造成影响。
在湿磨工艺中已有采用陶瓷研磨体来代替钢球和钢锻来研磨陶瓷类原料,现有的陶瓷研磨体其抗冲击性能差,用于干磨工艺容易碎裂,不能满足使用要求。因此,开发一种抗冲击性能好的,能适合干磨工艺中的陶瓷研磨体成为我们急需要解决的问题。
发明内容
本发明的目的就在于提供一种耐磨性好、抗冲击性能好的陶瓷研磨体,主要用于干磨工艺中,本发明还涉及该种陶瓷研磨体的制备方法。
为达到上述目的,本发明是这样实现的:一种陶瓷研磨体,其特征在于:由重量份数的以下原材料制成:
铝矾土60-90份,粘土5-20份,石墨粉3-15份。
在上述方案中:所述粘土中Al2O3的含量≥22%。
本发明的第二目的是这样实现的:一种权利要求1或2所述陶瓷研磨体的制备方法,其特征在于:按照如下方法制备:
将所述铝矾土、粘土和石墨粉混合,球磨至粒径≥300目,然后加水练泥,喷雾造粒后烘干,成型,再在1200-1500℃下烧结16-32h得到产品。
在上述方案中:烘干的温度为200-300℃。
采用上述方案,铝矾土的主要成分为Al2O3和Fe2O3,粘土的主要成分为SiO2、Al2O3、TiO2和Fe2O3,粘土和铝矾土与石墨粉混合烧结,烧结时,在产品中生成碳化硅和碳化钛,碳化硅热膨胀系数小,耐磨性好,弹性模量大,硬度高,抗弯强度大,有助于增加研磨体的硬度、致密性和抗裂性。碳化钛有利于增加研磨体的韧性,改变陶瓷研磨体的晶形结构,本发明得到的陶瓷研磨体维氏硬度大于1800,抗弯曲强度大于320Mpa,断裂韧性大于5.0Mpa,用于干磨工艺中不易碎裂。
本发明的有益效果是:本发明制得的陶瓷研磨体弹性模量大,耐磨性好、抗冲击性好,韧性好、化学稳定性好,研磨效率高,适合在干磨工艺中使用。且本发明用于陶瓷原材料、水泥、火电、冶金和矿山中,对这些原材料的污染少,制造成本低。
具体实施方式
下面结合具体实施例对本发明做进一步的描述。
实施例1:
陶瓷研磨体的制备方法,按照如下方法制备:
按照重量份,准备铝矾土60份,粘土5份,石墨粉3份,铝矾土要求Fe2O3的含量为15%-20%,Al2O3的含量≥55%,粒径≥200目。
粘土中Al2O3的含量≥22%,粒径≥100目。
石墨粉的粒径≥120目。
将铝矾土、粘土和石墨粉混合,采用湿式磨粉机混合磨粉,至混合粒径≥300目。
将上述混合料加水,用小磨机练泥,然后喷雾造粒。在200-300℃下烘干,成型后再在1200-1500℃下进行烧结得到产品,烧结时间16-32h。
实施例2:
陶瓷研磨体的制备方法,按照如下方法制备:
按照重量份数,准备铝矾土90份,粘土20份,石墨粉15份,铝矾土要求Fe2O3的含量为15%-20%,Al2O3的含量≥55%,粒径≥200目。
粘土中Al2O3的含量≥22%,粒径≥100目。
石墨粉的粒径≥120目。
将铝矾土、粘土和石墨粉混合,采用湿式磨粉机混合磨粉,至混合粒径≥300目。
将上述混合料加水练泥,喷雾造粒,经200-300℃干燥后加入成型机,干压成圆球形或圆锻型,再在1200-1500℃下进行烧结得到产品,烧结时间16-32h。
实施例3:
陶瓷研磨体的制备方法,按照如下方法制备:
准备铝矾土80份,粘土15份,石墨粉9份,铝矾土要求Fe2O3的含量为15%-20%,Al2O3的含量≥55%,粒径≥200目。
粘土中Al2O3的含量≥22%,粒径≥100目。
石墨粉的粒径≥120目。
将铝矾土、粘土和石墨粉混合,采用湿式磨粉机混合磨粉,至混合粒径≥300目。
将上述混合料加水练泥,喷雾造粒,经200-300℃干燥后加入成型机,干压成圆球形或圆锻型,再在1200-1500℃下进行烧结得到产品,烧结时间16-32h。
本发明不局限于上述具体实施例,应当理解,本领域的普通技术人员无需创造性劳动就可以根据本发明的构思做出诸多修改和变化。总之,凡本技术领域中技术人员依本发明的构思在现有技术的基础上通过逻辑分析、推理或者有限的实验可以得到的技术方案,皆应在由权利要求书所确定的保护范围内。

Claims (4)

1.一种陶瓷研磨体,其特征在于:由重量份数的以下原材料制成:
铝矾土60-90份,粘土5-20份,石墨粉3-15份。
2.根据权利要求1所述陶瓷研磨体,其特征在于:所述粘土中Al2O3的含量≥22%。
3.一种权利要求1或2所述陶瓷研磨体的制备方法,其特征在于:按照如下方法制备:
将所述铝矾土、粘土和石墨粉混合,球磨至粒径≥300目,然后加水练泥,喷雾造粒后烘干,成型,再在1200-1500℃下烧结16-32h得到产品。
4.根据权利要求3所述陶瓷研磨体的制备方法,其特征在于:烘干的温度为200-300℃。
CN201510988241.6A 2015-12-24 2015-12-24 陶瓷研磨体及其制备方法 Pending CN105565784A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510988241.6A CN105565784A (zh) 2015-12-24 2015-12-24 陶瓷研磨体及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510988241.6A CN105565784A (zh) 2015-12-24 2015-12-24 陶瓷研磨体及其制备方法

Publications (1)

Publication Number Publication Date
CN105565784A true CN105565784A (zh) 2016-05-11

Family

ID=55876500

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510988241.6A Pending CN105565784A (zh) 2015-12-24 2015-12-24 陶瓷研磨体及其制备方法

Country Status (1)

Country Link
CN (1) CN105565784A (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106587669A (zh) * 2016-12-12 2017-04-26 廊坊天盛环保建材科技有限公司 一种低密度粉磨体在矿渣粉磨中的应用
CN106747362A (zh) * 2017-03-06 2017-05-31 广州浩方节能科技有限公司 一种陶瓷研磨体及其制备方法
CN107915468A (zh) * 2017-12-07 2018-04-17 鲁忠华 一种高硬度的陶瓷材料及其制备方法
CN114634351A (zh) * 2022-03-28 2022-06-17 醴陵华鑫电瓷科技股份有限公司 利用非煅烧瓷废泥制备电瓷生产用陶瓷磨球的方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1187479A (zh) * 1997-09-04 1998-07-15 赵德胜 以高铝矾土为主原料制作刚玉陶瓷制品的方法及其制品
CN101913905A (zh) * 2010-08-31 2010-12-15 麦乔智 一种多孔性陶瓷组成物及其制备方法与应用
CN102391835A (zh) * 2011-09-30 2012-03-28 河南金源新材料科技股份有限公司 一种中铝研磨球及制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1187479A (zh) * 1997-09-04 1998-07-15 赵德胜 以高铝矾土为主原料制作刚玉陶瓷制品的方法及其制品
CN101913905A (zh) * 2010-08-31 2010-12-15 麦乔智 一种多孔性陶瓷组成物及其制备方法与应用
CN102391835A (zh) * 2011-09-30 2012-03-28 河南金源新材料科技股份有限公司 一种中铝研磨球及制备方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
周川生 等: "《连铸"三大件"生产与使用 整体塞棒、长水口、浸入式水口》", 31 January 2015 *
王俊波 等: ""石墨-陶瓷电阻的冲击电压试验研究"", 《电瓷避雷器》 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106587669A (zh) * 2016-12-12 2017-04-26 廊坊天盛环保建材科技有限公司 一种低密度粉磨体在矿渣粉磨中的应用
CN106587669B (zh) * 2016-12-12 2018-12-21 廊坊天盛环保建材科技有限公司 一种低密度粉磨体在矿渣粉磨中的应用
CN106747362A (zh) * 2017-03-06 2017-05-31 广州浩方节能科技有限公司 一种陶瓷研磨体及其制备方法
CN107915468A (zh) * 2017-12-07 2018-04-17 鲁忠华 一种高硬度的陶瓷材料及其制备方法
CN114634351A (zh) * 2022-03-28 2022-06-17 醴陵华鑫电瓷科技股份有限公司 利用非煅烧瓷废泥制备电瓷生产用陶瓷磨球的方法

Similar Documents

Publication Publication Date Title
CN101838530B (zh) 低密度高强陶粒支撑剂及其制备方法
CN105565784A (zh) 陶瓷研磨体及其制备方法
WO2015131761A1 (zh) 一种辉石瓷及其制备方法
CN101734934A (zh) 高强度钢纤维浇注料
CN103725281B (zh) 一种低成本石油压裂支撑剂的制备方法
CN106673626B (zh) 用于生产自增韧氧化铝耐磨陶瓷的低成本氧化铝粉体材料
CN103819211A (zh) 循环流化床锅炉用轻型耐磨耐火可塑料及其制备方法
CN105541362B (zh) 一种环保砖
CN104387072A (zh) 一种高性能碳化硼陶瓷喷嘴及其制作方法
CN104944980A (zh) 耐磨耐腐蚀砖的制备方法
CN101786867A (zh) 一种硅酸锆球珠的制备方法
CN102942375A (zh) 莫来石晶须前驱体定量原位制备刚玉-莫来石(晶须)质耐火材料的方法
CN108610073A (zh) 一种耐火抗裂复合砖及其制备方法
CN105859258A (zh) 一种水泥球磨机用陶瓷研磨球及其制备方法
CN101555148B (zh) 一种高强度耐酸耐温砖及其制备方法
CN104829255A (zh) 一种含有碳增强纤维的陶瓷碳化硅砂轮
CN101712560B (zh) 一种高强度浇注料
CN103588487A (zh) 一种低膨胀型陶瓷辊棒及其制备方法
CN104961445A (zh) 一种坩埚用复合陶瓷材料及其制备方法
CN106336227A (zh) 一种矿产废弃物耐火材料及其制备工艺
CN105481380A (zh) 一种低成本新型钢纤维耐火浇注料
CN104671789A (zh) 一种防护构件用碳化硅陶瓷基复合材料及其制备方法
CN107971938A (zh) 一种制造低温烧结超硬陶瓷砂轮的结合剂
CN104788031A (zh) 一种铝酸盐水泥及其制备方法
CN104876609A (zh) 抗热震耐火砖

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20160511