CN1055491C - 贱金属氧化物一氧化碳助燃剂及其制备方法和用途 - Google Patents
贱金属氧化物一氧化碳助燃剂及其制备方法和用途 Download PDFInfo
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- CN1055491C CN1055491C CN93120042A CN93120042A CN1055491C CN 1055491 C CN1055491 C CN 1055491C CN 93120042 A CN93120042 A CN 93120042A CN 93120042 A CN93120042 A CN 93120042A CN 1055491 C CN1055491 C CN 1055491C
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- Prior art keywords
- base metal
- carbon monoxide
- metal oxide
- carrier
- supporting agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000010953 base metal Substances 0.000 title claims abstract description 29
- 229910044991 metal oxide Inorganic materials 0.000 title claims abstract description 25
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- -1 metal oxide carbon monoxide Chemical class 0.000 title claims description 20
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 8
- 230000004913 activation Effects 0.000 claims abstract description 6
- 229910052751 metal Inorganic materials 0.000 claims abstract description 6
- 239000007864 aqueous solution Substances 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 16
- 238000012216 screening Methods 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000004005 microsphere Substances 0.000 claims description 13
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 10
- 239000000395 magnesium oxide Substances 0.000 claims description 10
- 229940095064 tartrate Drugs 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 9
- 238000007493 shaping process Methods 0.000 claims description 8
- 229910052596 spinel Inorganic materials 0.000 claims description 8
- 239000011029 spinel Substances 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 8
- 238000009826 distribution Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- GANNOFFDYMSBSZ-UHFFFAOYSA-N [AlH3].[Mg] Chemical compound [AlH3].[Mg] GANNOFFDYMSBSZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000001994 activation Methods 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052878 cordierite Inorganic materials 0.000 claims description 5
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000007598 dipping method Methods 0.000 claims description 5
- 206010013786 Dry skin Diseases 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052737 gold Inorganic materials 0.000 claims description 4
- 239000010931 gold Substances 0.000 claims description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 4
- 229910021645 metal ion Inorganic materials 0.000 claims description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 4
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- 238000007747 plating Methods 0.000 claims description 3
- 229910052723 transition metal Inorganic materials 0.000 claims description 3
- 150000003624 transition metals Chemical group 0.000 claims description 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims 8
- 229910001051 Magnalium Inorganic materials 0.000 claims 1
- 238000005470 impregnation Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 19
- 238000002485 combustion reaction Methods 0.000 abstract description 13
- 239000004480 active ingredient Substances 0.000 abstract description 11
- 238000004519 manufacturing process Methods 0.000 abstract description 10
- 239000002671 adjuvant Substances 0.000 abstract description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 229910052742 iron Inorganic materials 0.000 abstract description 2
- 238000007654 immersion Methods 0.000 abstract 2
- 150000001261 hydroxy acids Chemical class 0.000 abstract 1
- 238000005303 weighing Methods 0.000 description 16
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 13
- 239000012530 fluid Substances 0.000 description 8
- 235000012245 magnesium oxide Nutrition 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 7
- 239000003208 petroleum Substances 0.000 description 7
- 238000007670 refining Methods 0.000 description 7
- 239000011324 bead Substances 0.000 description 6
- BYFGZMCJNACEKR-UHFFFAOYSA-N Al2O Inorganic materials [Al]O[Al] BYFGZMCJNACEKR-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 238000004523 catalytic cracking Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229910052697 platinum Inorganic materials 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000010970 precious metal Substances 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 3
- 238000004231 fluid catalytic cracking Methods 0.000 description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 101000809257 Homo sapiens Ubiquitin carboxyl-terminal hydrolase 4 Proteins 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 102100038463 Ubiquitin carboxyl-terminal hydrolase 4 Human genes 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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Abstract
Description
Claims (12)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN93120042A CN1055491C (zh) | 1993-12-17 | 1993-12-17 | 贱金属氧化物一氧化碳助燃剂及其制备方法和用途 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN93120042A CN1055491C (zh) | 1993-12-17 | 1993-12-17 | 贱金属氧化物一氧化碳助燃剂及其制备方法和用途 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1091460A CN1091460A (zh) | 1994-08-31 |
CN1055491C true CN1055491C (zh) | 2000-08-16 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN93120042A Expired - Lifetime CN1055491C (zh) | 1993-12-17 | 1993-12-17 | 贱金属氧化物一氧化碳助燃剂及其制备方法和用途 |
Country Status (1)
Country | Link |
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CN (1) | CN1055491C (zh) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1089362C (zh) * | 1999-12-24 | 2002-08-21 | 中国石油化工集团公司 | 一种一氧化碳助燃剂及其制备方法 |
CN100363099C (zh) * | 2005-09-16 | 2008-01-23 | 山西大学 | 一氧化碳低温氧化催化剂及其制备方法 |
CN102463120A (zh) * | 2010-11-05 | 2012-05-23 | 中国石油化工股份有限公司 | 一种含镍和锰的催化剂及其制备方法和应用 |
CN103464164B (zh) * | 2013-08-27 | 2015-11-18 | 中国华能集团清洁能源技术研究院有限公司 | 酒石酸络合法制备甲烷化催化剂的方法 |
CN103623835B (zh) * | 2013-11-08 | 2016-05-04 | 北京龙宝科技发展有限公司 | 一种尾气催化净化吸收材料、制备工艺及净化方法 |
CN107335429A (zh) * | 2017-06-29 | 2017-11-10 | 连云港师范高等专科学校 | 一种室内甲醛催化氧化净化剂的制造方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6051544A (ja) * | 1983-08-31 | 1985-03-23 | Mitsubishi Heavy Ind Ltd | 酸化触媒 |
CN1074630A (zh) * | 1992-01-24 | 1993-07-28 | 北京大学 | 复合氧化物燃烧催化剂及其制法和应用 |
-
1993
- 1993-12-17 CN CN93120042A patent/CN1055491C/zh not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6051544A (ja) * | 1983-08-31 | 1985-03-23 | Mitsubishi Heavy Ind Ltd | 酸化触媒 |
CN1074630A (zh) * | 1992-01-24 | 1993-07-28 | 北京大学 | 复合氧化物燃烧催化剂及其制法和应用 |
Non-Patent Citations (1)
Title |
---|
JOURNAL OF CATALYSIS33 1974.1.1 YUNG-FANG YU YAO THE OXIDATION OF HYDROCARBONS AND CO OVER METAL OXIDES * |
Also Published As
Publication number | Publication date |
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CN1091460A (zh) | 1994-08-31 |
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C10 | Entry into substantive examination | ||
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C06 | Publication | ||
PB01 | Publication | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C53 | Correction of patent for invention or patent application | ||
COR | Change of bibliographic data |
Free format text: CORRECT: PATENTEE; FROM: LIN KE TO: SANJU ENVIRONMENT PROTECTION NEW MATERIAL CO., LTD., BEIJING |
|
CP03 | Change of name, title or address |
Address after: 100089 Beijing Haidian District Sanhuan Sanhuan company Zhang Jieshou Patentee after: Sanju New Environment Protection Materials Co., Ltd., Beijing Address before: Beijing City 100029 Anwai Xiaoguan Street No. 24 Sinopec Engineering Company Engineering Department Zhang Yuzhuan Patentee before: Lin Ke |
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C56 | Change in the name or address of the patentee |
Owner name: BEIJING SANJU ENVIRONMENTAL PROTECTION AND NEW MAT Free format text: FORMER NAME OR ADDRESS: SANJU ENVIRONMENT PROTECTION NEW MATERIAL CO., LTD., BEIJING |
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CP03 | Change of name, title or address |
Address after: Beijing Haidian District people's Congress Road 33, the big line foundation building 9 floor Patentee after: Beijing Sj Environmental Protection New Material Co., Ltd. Address before: Beijing Haidian District people's Congress Road 33, the big line foundation building 17 floor Patentee before: Sanju New Environment Protection Materials Co., Ltd., Beijing |
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C17 | Cessation of patent right | ||
CX01 | Expiry of patent term |
Expiration termination date: 20131217 Granted publication date: 20000816 |