CN105544247A - 一种用于数码印花的印花粘合剂及其制备方法 - Google Patents

一种用于数码印花的印花粘合剂及其制备方法 Download PDF

Info

Publication number
CN105544247A
CN105544247A CN201610049138.XA CN201610049138A CN105544247A CN 105544247 A CN105544247 A CN 105544247A CN 201610049138 A CN201610049138 A CN 201610049138A CN 105544247 A CN105544247 A CN 105544247A
Authority
CN
China
Prior art keywords
parts
printing
printing adhesive
adhesive
add
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610049138.XA
Other languages
English (en)
Other versions
CN105544247B (zh
Inventor
周继东
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GAOMI FUMEITE PRINTING CO., LTD.
Original Assignee
Suzhou Insilk Digital Textile Science and Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Insilk Digital Textile Science and Technology Co Ltd filed Critical Suzhou Insilk Digital Textile Science and Technology Co Ltd
Priority to CN201610049138.XA priority Critical patent/CN105544247B/zh
Publication of CN105544247A publication Critical patent/CN105544247A/zh
Application granted granted Critical
Publication of CN105544247B publication Critical patent/CN105544247B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
    • D06P1/5285—Polyurethanes; Polyurea; Polyguanides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3228—Polyamines acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/348—Hydroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6603—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6607—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C08G18/6611—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6603—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6614—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3225 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6618—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3225 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6625—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/34
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
    • C08G18/722—Combination of two or more aliphatic and/or cycloaliphatic polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/758—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Textile Engineering (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Coloring (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Ink Jet (AREA)

Abstract

本发明公开了一种用于数码印花的印花粘合剂，以重量份数计，包含以下组分：内酯二醇低聚物20-30份，聚酯型多元醇20-30份，聚醚型多元醇15-20份，二环己基甲烷二异氰酸酯30-50份，六次甲基二异氰酸酯20-40份，二羟甲基丙酸20-30份，甘油10-15份，乙二胺12-18份，二月桂基二丁基锡5-9份，流平剂2-5份，分散剂5-9份，尿素10-15份，水30-50份。本发明还提供该印花粘合剂的制备方法。本发明绿色环保，并且其在使用过程中无需高温加热，对织物的损害小，不会影响染料的鲜艳度即饱和度。同时在常温下该粘合剂可以保持良好的稳定性，不会造成喷头的堵塞，不会给机器带来不良影响。

Description

一种用于数码印花的印花粘合剂及其制备方法
技术领域：
本发明属于纺织材料技术领域，具体涉及一种用于数码印花的印花粘合剂及其制备方法。
背景技术：
数码印花在操作过程中无需制版，仅通过数字化手段将印花图案输入计算机后，控制数码喷墨印花机，直接将印花墨水喷印到织物上，即可印制出所需要的图案。数码印花的生产过程比传统的印花过程流程大大缩短，操作简单，生产时间缩短，打样成本大大降低。此外数码印花打破了传统印花生产中套色以及花回长度的限制，可以实现更加复杂的图案印花。同时数码印花过程是高精度的喷印过程，不会造成墨水的浪费，也不会对环境带来污染。
在数码印花工艺中，相关研究主要是集中在工艺、印花机以及墨水等方面。数码印花的墨水是最为重要的环节，其中印花粘合剂是影响墨水质量的关键成分。目前用于数码印花的印花粘合剂质量良莠不齐，一般都存在手感僵硬，冷脆热粘以及耐水性差等问题。同时一般此类粘合剂均需要经过高温烘焙，这样会使织物受到伤害，同时会对染料的色彩饱和度、鲜艳度产生不良影响。另外，一些印花粘合剂含有甲醛等物质，会释放出对身体有害的物质，影响人们的身体健康。
中国专利CN201210411389.X公开了一种数码印花粘合剂、制备方法及其应用，该类数码印花粘合剂包括按重量百分比的下列组成：低温自交联数值40％-50％；表面活性剂5％-10％，分散剂5％-15％；多元醇10％-20％，去离子水余量。此数码印花粘合剂不含APEO、甲醛及难降解化合物，环保无污染，具有良好的稳定性和分散性。但是该数码印花剂在使用过程中仍需要100-120℃的烘干，仍然会对一些不耐高温的织物造成伤害。
发明内容：
本发明的目的是提供一种用于数码印花的印花粘合剂，该类粘合剂不含甲醛等对身体有害的污染性物质，绿色环保。并且其在使用过程中无需高温加热，对织物的损害小，不会影响染料的鲜艳度即饱和度。同时在常温下该粘合剂可以保持良好的稳定性，不会造成喷头的堵塞，不会给机器带来不良影响。
本发明的另一目的是提供该印花粘合剂的制备方法。
为实现上述目的，本发明采取的技术方案如下：
一种用于数码印花的印花粘合剂，以重量份数计，包含以下组分：
内酯二醇低聚物20-30份，聚酯型多元醇20-30份，聚醚型多元醇15-20份，二环己基甲烷二异氰酸酯30-50份，六次甲基二异氰酸酯20-40份，二羟甲基丙酸20-30份，甘油10-15份，乙二胺12-18份，二月桂基二丁基锡5-9份，流平剂2-5份，分散剂5-9份，尿素10-15份，水30-50份。
所述聚酯型多元醇为丁二酸，丙二酸或马来酸中的任意一种与丙二醇、三羟甲基丙烷或丁二醇中的任意一种发生酯化反应形成的聚酯型多元醇。
所述聚醚型多元醇为环氧乙烷，环氧丙烷或环氧丁烷中的任意一种与甘油或丁三醇中的任意一种反应值得的聚醚型多元醇。
所述流平剂为羟甲基纤维素，十二烷基二甲基甜菜碱或十四烷基二甲基甜菜碱中的一种或多种混合物。
所述分散剂为液体石蜡，硬脂酸锌中的一种或两种混合物。
一种用于数码印花的印花粘合剂的制备方法，包括以下步骤：
将内酯二醇低聚物，聚酯型多元醇，聚醚型多元醇，二环己基甲烷二异氰酸酯，六次甲基二异氰酸酯和二羟甲基丙酸混合，加入反应釜中，加热，控制温度在60-75℃之间，以70-90转/min的速度搅拌，持续反应7-9h后，加入甘油和乙二胺，搅拌1h后，加入水，以1000-1500转/min的速度高速搅拌30min后停止，降低温度至50-60℃，再加入二月桂基二丁基锡，流平剂，分散剂，尿素，搅拌均匀后，既得该印花粘合剂。
本发明具有以下有益效果：
该粘合剂不含甲醛等对身体有害的物质，并且对环境不会造成污染，安全环保。该印花粘合剂粘合效果好，在80-90℃条件下烘干即可定型，对织物不会造成伤害，适用于多种面料。同时其在常温下十分稳定，不会堵塞喷头，不会带来不必要的经济损失。使用后的织物，仍然可以保持较高的柔软性，不会影响织物手感。总而言之，该用于数码印花的印花粘合剂性能优良，安全环保，不会对织物带来不良影响，具有较高的工业生产价值。
具体实施方式：
为了更好的理解本发明，下面通过实施例对本发明进一步说明，实施例只用于解释本发明，不会对本发明构成任何的限定。
实施例1
一种用于数码印花的印花粘合剂的制备方法，包括以下步骤：
将20份内酯二醇低聚物，25份聚酯型多元醇，15份聚醚型多元醇，30份二环己基甲烷二异氰酸酯，35份六次甲基二异氰酸酯和30份二羟甲基丙酸混合，加入反应釜中，加热，控制温度在60-75℃之间，以70-90转/min的速度搅拌，持续反应7-9h后，加入10份甘油和12份乙二胺，搅拌1h后，加入30份水，以1000-1500转/min的速度高速搅拌30min后停止，降低温度至50-60℃，再加入9份二月桂基二丁基锡，2份流平剂，5份分散剂，15份尿素，搅拌均匀后，既得该印花粘合剂。
使用该印花粘合剂，干摩擦牢度4级，湿摩擦牢度4级。
实施例2
一种用于数码印花的印花粘合剂的制备方法，包括以下步骤：
将25份内酯二醇低聚物，30份聚酯型多元醇，15份聚醚型多元醇，35份二环己基甲烷二异氰酸酯，40份六次甲基二异氰酸酯和20份二羟甲基丙酸混合，加入反应釜中，加热，控制温度在60-75℃之间，以70-90转/min的速度搅拌，持续反应7-9h后，加入11份甘油和14份乙二胺，搅拌1h后，加入40份水，以1000-1500转/min的速度高速搅拌30min后停止，降低温度至50-60℃，再加入8份二月桂基二丁基锡，3份流平剂，6份分散剂，14份尿素，搅拌均匀后，既得该印花粘合剂。
使用该印花粘合剂，干摩擦牢度4级，湿摩擦牢度4级。
实施例3
一种用于数码印花的印花粘合剂的制备方法，包括以下步骤：
将30份内酯二醇低聚物，20份聚酯型多元醇，15份聚醚型多元醇，40份二环己基甲烷二异氰酸酯，30份六次甲基二异氰酸酯和25份二羟甲基丙酸混合，加入反应釜中，加热，控制温度在60-75℃之间，以70-90转/min的速度搅拌，持续反应7-9h后，加入12份甘油和15份乙二胺，搅拌1h后，加入50份水，以1000-1500转/min的速度高速搅拌30min后停止，降低温度至50-60℃，再加入7份二月桂基二丁基锡，5份流平剂，7份分散剂，13份尿素，搅拌均匀后，既得该印花粘合剂。
使用该印花粘合剂，干摩擦牢度4级，湿摩擦牢度4级。
实施例4
一种用于数码印花的印花粘合剂的制备方法，包括以下步骤：
将25份内酯二醇低聚物，25份聚酯型多元醇，20份聚醚型多元醇，45份二环己基甲烷二异氰酸酯，35份六次甲基二异氰酸酯和30份二羟甲基丙酸混合，加入反应釜中，加热，控制温度在60-75℃之间，以70-90转/min的速度搅拌，持续反应7-9h后，加入13份甘油和16份乙二胺，搅拌1h后，加入35份水，以1000-1500转/min的速度高速搅拌30min后停止，降低温度至50-60℃，再加入6份二月桂基二丁基锡，4份流平剂，8份分散剂，12份尿素，搅拌均匀后，既得该印花粘合剂。
使用该印花粘合剂，干摩擦牢度4级，湿摩擦牢度4级。
实施例5
一种用于数码印花的印花粘合剂的制备方法，包括以下步骤：
将20份内酯二醇低聚物，30份聚酯型多元醇，20份聚醚型多元醇，50份二环己基甲烷二异氰酸酯，25份六次甲基二异氰酸酯和25份二羟甲基丙酸混合，加入反应釜中，加热，控制温度在60-75℃之间，以70-90转/min的速度搅拌，持续反应7-9h后，加入14份甘油和17份乙二胺，搅拌1h后，加入45份水，以1000-1500转/min的速度高速搅拌30min后停止，降低温度至50-60℃，再加入5份二月桂基二丁基锡，3份流平剂，9份分散剂，11份尿素，搅拌均匀后，既得该印花粘合剂。
使用该印花粘合剂，干摩擦牢度4级，湿摩擦牢度4级。
实施例6
一种用于数码印花的印花粘合剂的制备方法，包括以下步骤：
将30份内酯二醇低聚物，25份聚酯型多元醇，20份聚醚型多元醇，50份二环己基甲烷二异氰酸酯，30份六次甲基二异氰酸酯和20份二羟甲基丙酸混合，加入反应釜中，加热，控制温度在60-75℃之间，以70-90转/min的速度搅拌，持续反应7-9h后，加入15份甘油和18份乙二胺，搅拌1h后，加入30份水，以1000-1500转/min的速度高速搅拌30min后停止，降低温度至50-60℃，再加入6份二月桂基二丁基锡，5份流平剂，8份分散剂，10份尿素，搅拌均匀后，既得该印花粘合剂。
使用该印花粘合剂，干摩擦牢度4级，湿摩擦牢度4级。

Claims (6)

1.一种用于数码印花的印花粘合剂，其特征在于，以重量份数计，包含以下组分：
内酯二醇低聚物20-30份，聚酯型多元醇20-30份，聚醚型多元醇15-20份，二环己基甲烷二异氰酸酯30-50份，六次甲基二异氰酸酯20-40份，二羟甲基丙酸20-30份，甘油10-15份，乙二胺12-18份，二月桂基二丁基锡5-9份，流平剂2-5份，分散剂5-9份，尿素10-15份，水30-50份。
2.根据权利要求1所述的用于数码印花的印花粘合剂，其特征在于：所述聚酯型多元醇为丁二酸，丙二酸或马来酸中的任意一种与丙二醇、三羟甲基丙烷或丁二醇中的任意一种发生酯化反应形成的聚酯型多元醇。
3.根据权利要求1所述的用于数码印花的印花粘合剂，其特征在于：所述聚醚型多元醇为环氧乙烷，环氧丙烷或环氧丁烷中的任意一种与甘油或丁三醇中的任意一种反应值得的聚醚型多元醇。
4.根据权利要求1所述的用于数码印花的印花粘合剂，其特征在于：所述流平剂为羟甲基纤维素，十二烷基二甲基甜菜碱或十四烷基二甲基甜菜碱中的一种或多种混合物。
5.根据权利要求1所述的用于数码印花的印花粘合剂，其特征在于：所述分散剂为液体石蜡，硬脂酸锌中的一种或两种混合物。
6.一种用于数码印花的印花粘合剂的制备方法，其特征在于，包括以下步骤：
将内酯二醇低聚物，聚酯型多元醇，聚醚型多元醇，二环己基甲烷二异氰酸酯，六次甲基二异氰酸酯和二羟甲基丙酸混合，加入反应釜中，加热，控制温度在60-75℃之间，以70-90转/min的速度搅拌，持续反应7-9h后，加入甘油和乙二胺，搅拌1h后，加入水，以1000-1500转/min的速度高速搅拌30min后停止，降低温度至50-60℃，再加入二月桂基二丁基锡，流平剂，分散剂，尿素，搅拌均匀后，既得该印花粘合剂。
CN201610049138.XA 2016-01-25 2016-01-25 一种用于数码印花的印花粘合剂及其制备方法 Active CN105544247B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610049138.XA CN105544247B (zh) 2016-01-25 2016-01-25 一种用于数码印花的印花粘合剂及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610049138.XA CN105544247B (zh) 2016-01-25 2016-01-25 一种用于数码印花的印花粘合剂及其制备方法

Publications (2)

Publication Number Publication Date
CN105544247A true CN105544247A (zh) 2016-05-04
CN105544247B CN105544247B (zh) 2018-10-12

Family

ID=55823785

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610049138.XA Active CN105544247B (zh) 2016-01-25 2016-01-25 一种用于数码印花的印花粘合剂及其制备方法

Country Status (1)

Country Link
CN (1) CN105544247B (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105821681A (zh) * 2016-05-12 2016-08-03 东莞市联洲知识产权运营管理有限公司 一种低成本环保织物粘合剂的制备方法
CN108864401A (zh) * 2018-06-28 2018-11-23 浙江新迪在龙涂料科技有限公司 一种聚氨酯丙烯酸酯低聚物及其制备方法和一种水性涂料
CN109517192A (zh) * 2017-11-16 2019-03-26 广东安之伴实业有限公司 一种水性弹性聚酯乳液的制备方法
CN109535363A (zh) * 2017-11-16 2019-03-29 广东安之伴实业有限公司 一种水性弹性聚酯乳液的制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020135648A1 (en) * 1998-05-06 2002-09-26 Sawgrass Systems, Inc. Digital transfer printing process
CN1740259A (zh) * 2005-09-21 2006-03-01 北京高盟化工有限公司 一种低温涂布的单组分无溶剂聚氨酯粘合剂及其制备方法
CN101121869A (zh) * 2007-09-21 2008-02-13 北京市化学工业研究院 一种鞋用水性聚氨酯粘合剂制备方法
CN102516920A (zh) * 2011-12-12 2012-06-27 东莞市山力高分子材料科研有限公司 水性聚氨酯胶粘剂及其制备方法
CN102899927A (zh) * 2012-10-24 2013-01-30 绍兴中纺院江南分院有限公司 一种数码印花粘合剂、制备方法及其应用
CN102936480A (zh) * 2012-11-08 2013-02-20 无锡市万力粘合材料有限公司 面料用水性聚氨酯胶粘剂及其制备方法
CN103526587A (zh) * 2013-10-23 2014-01-22 合肥聚合辐化技术有限公司 一种数码印花粘合剂及其制备方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020135648A1 (en) * 1998-05-06 2002-09-26 Sawgrass Systems, Inc. Digital transfer printing process
CN1740259A (zh) * 2005-09-21 2006-03-01 北京高盟化工有限公司 一种低温涂布的单组分无溶剂聚氨酯粘合剂及其制备方法
CN101121869A (zh) * 2007-09-21 2008-02-13 北京市化学工业研究院 一种鞋用水性聚氨酯粘合剂制备方法
CN102516920A (zh) * 2011-12-12 2012-06-27 东莞市山力高分子材料科研有限公司 水性聚氨酯胶粘剂及其制备方法
CN102899927A (zh) * 2012-10-24 2013-01-30 绍兴中纺院江南分院有限公司 一种数码印花粘合剂、制备方法及其应用
CN102936480A (zh) * 2012-11-08 2013-02-20 无锡市万力粘合材料有限公司 面料用水性聚氨酯胶粘剂及其制备方法
CN103526587A (zh) * 2013-10-23 2014-01-22 合肥聚合辐化技术有限公司 一种数码印花粘合剂及其制备方法

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105821681A (zh) * 2016-05-12 2016-08-03 东莞市联洲知识产权运营管理有限公司 一种低成本环保织物粘合剂的制备方法
CN105821681B (zh) * 2016-05-12 2018-02-27 陈芬芬 一种低成本环保织物粘合剂的制备方法
CN109517192A (zh) * 2017-11-16 2019-03-26 广东安之伴实业有限公司 一种水性弹性聚酯乳液的制备方法
CN109535363A (zh) * 2017-11-16 2019-03-29 广东安之伴实业有限公司 一种水性弹性聚酯乳液的制备方法
CN108864401A (zh) * 2018-06-28 2018-11-23 浙江新迪在龙涂料科技有限公司 一种聚氨酯丙烯酸酯低聚物及其制备方法和一种水性涂料

Also Published As

Publication number Publication date
CN105544247B (zh) 2018-10-12

Similar Documents

Publication Publication Date Title
CN105544247A (zh) 一种用于数码印花的印花粘合剂及其制备方法
CN102108641B (zh) 一种数码印花活性染料喷墨墨水
CN101531848B (zh) 环保型数码喷墨直接印花纺织墨水及其制备方法
CN103952922B (zh) 一种植物染料数码印花墨水及其制备方法
CN105369652B (zh) 一种墨水及其制备方法
CN104213443B (zh) 一种热发泡式或热气泡式打印机的活性染料墨水数码印花工艺
CN106519177A (zh) 一种压纹无溶剂聚氨酯合成革的制造方法
CN107385963A (zh) 用于颜料型喷墨印花墨水的粘合剂、包含其的墨水、制备方法和用途
JP2017137468A (ja) 水性染料高分子インクジェット印刷用インク組成物
CN103965430A (zh) 一种自修复聚氨酯、纺织品印花涂料及其制备方法
US20190106587A1 (en) Method of inkjet printing
CN101112808A (zh) 一种水洗标识带及其制备方法
CN102409553B (zh) 一种基于原位聚合法制备不含溶剂的汽车内饰革方法
CN106012595A (zh) 一种涤纶织物的数码印花工艺
CN102493236A (zh) 一种天然纤维数码打印转移印花载体
CN106758326A (zh) 尼龙织物及其印花生产工艺和尼龙专用热转印墨水的应用
CN104514157A (zh) 一种基于纤维素纳米球为分散剂的真丝绸印花用纳米墨水的制备方法
CN108587321A (zh) 一种数码喷墨印花白色和彩色涂料墨水及其制备方法
CN109334292A (zh) 用于纺织品个性化印刷的水性喷墨转印方法
CN101113567A (zh) 颜料墨水数字喷墨印花用织物的低温等离子体处理工艺
CN103938470A (zh) 一种羊毛衫数码印花固色剂
CN106758422A (zh) 印花尼龙织物及其生产工艺和热转印墨水的应用
CN114059362A (zh) 一种热敏凝胶化的直喷型纺织墨水及其应用
CN113293631A (zh) 一种毛衫数码印花工艺
CN103865319B (zh) 用于工业喷头的热升华墨水及其打印方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20180830

Address after: 318050 24 new towns in the former seven villages in Xinqiao Town, Luqiao District, Taizhou, Zhejiang, China, 3

Applicant after: Wu Yulu

Address before: 215000 2 Taishan Road, high tech Zone, Suzhou, Jiangsu (Room 101 and 201, zone A, test center, Poji science and Technology Pioneer Park)

Applicant before: SUZHOU INSILK DIGITAL TEXTILE SCIENCE & TECHNOLOGY CO., LTD.

GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20190417

Address after: 261500 Dongshou 188 Shengquan Street, Gaomi High-tech Zone, Weifang City, Shandong Province

Patentee after: GAOMI FUMEITE PRINTING CO., LTD.

Address before: 318050 24 new towns in the former seven villages in Xinqiao Town, Luqiao District, Taizhou, Zhejiang, China, 3

Patentee before: Wu Yulu