CN105541454A - Efficient fertilizer contributing to reduction of accumulation of chromium heavy metal pollutant in vegetable and preparation method of fertilizer - Google Patents
Efficient fertilizer contributing to reduction of accumulation of chromium heavy metal pollutant in vegetable and preparation method of fertilizer Download PDFInfo
- Publication number
- CN105541454A CN105541454A CN201510905350.7A CN201510905350A CN105541454A CN 105541454 A CN105541454 A CN 105541454A CN 201510905350 A CN201510905350 A CN 201510905350A CN 105541454 A CN105541454 A CN 105541454A
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- Prior art keywords
- heavy metal
- powder
- chromium
- fertilizer
- enzyme
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses an efficient fertilizer contributing to reduction of accumulation of a chromium heavy metal pollutant in a vegetable. The fertilizer comprises the following components, by weight part: betaine, activated nanometer attapulgite, rice bran, powder or fermented substances of stem-type vegetables with strong fiber, cationic chitosan, germinated brown rice, microzyme, melatonin, an anion-modified macro-molecule chitosan heavy metal adsorbent, and a proper amount of mineralized micromolecule activated water. Melatonin and betaine treated with mineralized micromolecule activated water match activated nanometer attapulgite to prepare factors for self-cleaning of a chromium heavy metal. The factors easily enter the inside of cells, quickly participate into living movement of plants, promote plant bodies to absorb and utilize heavy-metal-chromium-type substance, and further promote living movement of the bodies, thereby reducing pollution. The fertilizer matching a nutrient solution treated through mineralized micromolecule activated water, and main materials can effectively convert heavy metals left in the vegetable, thereby having a function of self-cleaning of heavy metals.
Description
Technical field
The present invention relates to vegetable fertilizer technical field, particularly relate to and a kind ofly contribute to reducing the chromium heavy metal contaminants concentrated fertilizer and preparation method thereof at vegetables cylinder accumulation.
Background technology
Industrial activity and using of mud cause soil, in water, air, heavy metal sharply increases, add life-time service chemical fertilizer and chemical pesticide, agricultural eco_environmental quality worsens and agricultural and animal products pollution becomes increasingly conspicuous, human life is caused to be subject to great threat, specific in vegetables also often because there is the phenomenon of heavy metals exceeding standard in heavy metal pollution of soil, normally adopt natural larger molecular organics humic acids and its esters and heavy metal ion chela synthetic macromolecule inner complex or be adsorbed on soil particle surperficial and block biomass cells and absorb heavy metal in soil.But can not reach and definitely stop, moreover, a small amount of chromium heavy metal ion or time different shape exist the growth tool of heavy metal chelate to vegetable plant have certain effect, how to realize the maximum using of Heavy Metals In Vegetables, reduce its negative effect, have great importance.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides a kind of and contributes to reducing the chromium heavy metal contaminants concentrated fertilizer and preparation method thereof at vegetables cylinder accumulation.
The present invention is achieved by the following technical solutions:
A kind of contributing to, reduces the concentrated fertilizer of chromium heavy metal contaminants at vegetables cylinder accumulation, comprise following parts by weight of component: trimethyl-glycine 1.5-1.6, activation nano-attapulgite 1.2-1.3, rice bran 20-21, propylene glycol alginate 0.9-1, proteinase-10 .7-0.8, super oxidation qi enzyme 0.8-0.9, poly-carbon enzyme 0.65-0.75, photosynthetic enzyme 0.75-0.85, fermented bean dregs 20-21, hybrid giant napier powder 18-19, eggplant stem powder 21-22, the powder of the stem class vegetables and fruits of strong fiber or fermented product 19-20, ammonium octamolybdate 0.3-0.4, polyether glycol 1.2-1.3, D-Glucosamine Hydrochloride 1-1.1, sugar alcohol calcium 1.2-1.3, positively charged ion chitin 4-4.1, dish dregs of rice 19.5-20, sprout brown rice 20-21, whey powder 3.7-3.8, yeast 1.3-1.4, fulvic acid potassium 0.9-1, aminoacids complex 0.95-1, melatonin 2.1-2.2, negatively charged ion changes the macromole chitosan heavy metal absorbent 2.6-2.8 of surname, appropriate mineralising activation of small molecule water, appropriate deionized water, appropriate water.
Described a kind of contributing to, reduces chromium heavy metal contaminants in the concentrated fertilizer preparation method of vegetables cylinder accumulation, comprises the following steps:
(1) by melatonin, trimethyl-glycine and gross weight 7-8 mineralising activation of small molecule water mixing doubly, put into processor for ultrasonic wave, adopt the ultrasonication 1.1-1.2h of 130W, add activation nano-attapulgite afterwards, adopt high pressure homogenizer homogenization treatment 0.5-0.6h, employing spray drying technology is dry that the self-cleaning chromium heavy metal factor is for subsequent use;
(2) by proteolytic enzyme, super oxidation qi enzyme, poly-carbon enzyme, photosynthetic enzyme, yeast, whey powder and gross weight 2.5-2.6 deionized water mixing and stirring doubly, adding positively charged ion chitin, adopt clarifixator low speed 95r/min homogeneous 30-31min, it is for subsequent use that cryodrying obtains mushroom composite powder;
(3) by ammonium octamolybdate, polyether glycol, D-Glucosamine Hydrochloride, sugar alcohol calcium, fulvic acid potassium, aminoacids complex and gross weight 10-12 mineralising activation of small molecule water mixing and stirring doubly, nutritive medium is obtained for subsequent use;
(4) by rice bran, fermented bean dregs, hybrid giant napier powder, eggplant stem powder, the powder of the stem class vegetables and fruits of strong fiber or fermented product, the dish dregs of rice, sprout brown rice co-grinding, cross 20 orders, by crushed material, after mushroom composite powder and gross weight 2.1-2.3 water mixing and stirring doubly, compost maturity 24-30d, wind airing 4-5d opened by rake, evenly be sprinkled into nutritive medium afterwards, admix the chromium heavy metal factor again, negatively charged ion changes the macromole chitosan heavy metal absorbent of surname, 4 times of water diluting solns of propylene glycol alginate, stir, and adjust the 24.3-24.4% that moisture content is gross weight, high-temperature spiral Squeezinggranulator is adopted to manufacture the particle of diameter 2.6-3mm afterwards, obtain.
Advantage of the present invention is:
The present invention adopts melatonin, trimethyl-glycine through mineralising activation of small molecule water, join activation nano-attapulgite and prepare the self-cleaning chromium heavy metal factor, these factors easily enter cell interior, the vital movement of involved in plant more efficiently, promote absorbing of body heavy metal chromium form material, further promotion body vital movement, reduces it and pollutes; Coordinate the nutritive medium that mineralising activation of small molecule water treatment ammonium octamolybdate, polyether glycol, D-Glucosamine Hydrochloride, sugar alcohol calcium, fulvic acid potassium, aminoacids complex are formed simultaneously, and fertilizer prepared by the major ingredient that yeast composite powder and the comminuted powder prepared by the powder of the stem class vegetables and fruits of rice bran, fermented bean dregs, hybrid giant napier powder, eggplant stem powder, strong fiber or fermented product, the dish dregs of rice, sprout brown rice are formed through compost, effectively can realize the trans-utilization of residual heavy metal in vegetables body, play the effect of itself clean heavy metal; Prepared fertilizer has nutritious, quickening vegetable growth metabolic activity, promotes vegetables Efficient Cultivation, reduces the feature of heavy metal contamination.The activated yeast composite powder that the yeast composite powder adopted is positively charged ion chitin, proteolytic enzyme, super oxidation qi enzyme, poly-carbon enzyme, photosynthetic enzyme, yeast, whey powder are formed jointly, ensure that yeast has good living space and nutrition in composting process, there is fermentation capacity strong, the feature that can effectively build up fertility.
Embodiment
A kind of contributing to, reduces the concentrated fertilizer of chromium heavy metal contaminants at vegetables cylinder accumulation, comprise following parts by weight of component: trimethyl-glycine 1.5, activation nano-attapulgite 1.2, rice bran 20, propylene glycol alginate 0.9, proteinase-10 .7, super oxidation qi enzyme 0.8, poly-carbon enzyme 0.65, photosynthetic enzyme 0.75, fermented bean dregs 20, hybrid giant napier powder 18, eggplant stem powder 21, the powder of the stem class vegetables and fruits of strong fiber or fermented product 19, ammonium octamolybdate 0.3, polyether glycol 1.2, D-Glucosamine Hydrochloride 1, sugar alcohol calcium 1.2, positively charged ion chitin 4, the dish dregs of rice 19.5, sprout brown rice 20, whey powder 3.7, yeast 1.3, fulvic acid potassium 0.9, aminoacids complex 0.95, melatonin 2.1, negatively charged ion changes the macromole chitosan heavy metal absorbent 2.6 of surname, appropriate mineralising activation of small molecule water, appropriate deionized water, appropriate water.
Described a kind of contributing to, reduces chromium heavy metal contaminants in the concentrated fertilizer preparation method of vegetables cylinder accumulation, comprises the following steps:
(1) the mineralising activation of small molecule water of melatonin, trimethyl-glycine and gross weight 7 times is mixed, put into processor for ultrasonic wave, adopt the ultrasonication 1.1h of 130W, add activation nano-attapulgite afterwards, adopt high pressure homogenizer homogenization treatment 0.5h, employing spray drying technology is dry that the self-cleaning chromium heavy metal factor is for subsequent use;
(2) by the deionized water mixing and stirring of proteolytic enzyme, super oxidation qi enzyme, poly-carbon enzyme, photosynthetic enzyme, yeast, whey powder and gross weight 2.5 times, adding positively charged ion chitin, adopt clarifixator low speed 95r/min homogeneous 30min, it is for subsequent use that cryodrying obtains mushroom composite powder;
(3) by the mineralising activation of small molecule water mixing and stirring of ammonium octamolybdate, polyether glycol, D-Glucosamine Hydrochloride, sugar alcohol calcium, fulvic acid potassium, aminoacids complex and gross weight 10 times, nutritive medium is obtained for subsequent use;
(4) by rice bran, fermented bean dregs, hybrid giant napier powder, eggplant stem powder, the powder of the stem class vegetables and fruits of strong fiber or fermented product, the dish dregs of rice, sprout brown rice co-grinding, cross 20 orders, by crushed material, after the water mixing and stirring of mushroom composite powder and gross weight 2.1 times, compost maturity 24d, wind airing 4d opened by rake, evenly be sprinkled into nutritive medium afterwards, admix the chromium heavy metal factor again, negatively charged ion changes the macromole chitosan heavy metal absorbent of surname, 4 times of water diluting solns of propylene glycol alginate, stir, and adjust that moisture content is gross weight 24.3%, high-temperature spiral Squeezinggranulator is adopted to manufacture the particle of diameter 2.6mm afterwards, obtain.
Two pieces of Chromium in Soil heavy metal content are adopted to be 0.2Kg/100Kg, area 3*3m
2soil cultivate pachyrhizus, fertilizer 30Kg of the present invention is evenly added as experimental group in first piece, second piece adopts space management as a control group, other condition of experimental group and control group is consistent, treat that fruit maturation is plucked, get experimental group fruit 100Kg and control group fruit 100Kg respectively as material to be detected, material to be detected is analyzed respectively by LIBS, the content that can obtain heavy metal chromium in experimental group 100Kg fruit is 0.0013mg, and the content of heavy metal chromium is 0.0068mg in control group 100Kg fruit, as can be seen here, more than in control group, heavy metal chromium is 5 times of experimental group, fertilizer of the present invention can be obtained and can reduce the accumulation of heavy metal chromium pollution thing in vegetables pachyrhizus body to a certain extent.
Claims (2)
1. contribute to reducing chromium heavy metal contaminants at a concentrated fertilizer for vegetables cylinder accumulation, it is characterized in that, comprise following parts by weight of component: trimethyl-glycine 1.5-1.6, activation nano-attapulgite 1.2-1.3, rice bran 20-21, propylene glycol alginate 0.9-1, proteinase-10 .7-0.8, super oxidation qi enzyme 0.8-0.9, poly-carbon enzyme 0.65-0.75, photosynthetic enzyme 0.75-0.85, fermented bean dregs 20-21, hybrid giant napier powder 18-19, eggplant stem powder 21-22, the powder of the stem class vegetables and fruits of strong fiber or fermented product 19-20, ammonium octamolybdate 0.3-0.4, polyether glycol 1.2-1.3, D-Glucosamine Hydrochloride 1-1.1, sugar alcohol calcium 1.2-1.3, positively charged ion chitin 4-4.1, dish dregs of rice 19.5-20, sprout brown rice 20-21, whey powder 3.7-3.8, yeast 1.3-1.4, fulvic acid potassium 0.9-1, aminoacids complex 0.95-1, melatonin 2.1-2.2, negatively charged ion changes the macromole chitosan heavy metal absorbent 2.6-2.8 of surname, appropriate mineralising activation of small molecule water, appropriate deionized water, appropriate water.
2. a kind of contributing to, reduces chromium heavy metal contaminants in the concentrated fertilizer preparation method of vegetables cylinder accumulation as claimed in claim 1, it is characterized in that, comprises the following steps:
(1) by melatonin, trimethyl-glycine and gross weight 7-8 mineralising activation of small molecule water mixing doubly, put into processor for ultrasonic wave, adopt the ultrasonication 1.1-1.2h of 130W, add activation nano-attapulgite afterwards, adopt high pressure homogenizer homogenization treatment 0.5-0.6h, employing spray drying technology is dry that the self-cleaning chromium heavy metal factor is for subsequent use;
(2) by proteolytic enzyme, super oxidation qi enzyme, poly-carbon enzyme, photosynthetic enzyme, yeast, whey powder and gross weight 2.5-2.6 deionized water mixing and stirring doubly, adding positively charged ion chitin, adopt clarifixator low speed 95r/min homogeneous 30-31min, it is for subsequent use that cryodrying obtains mushroom composite powder;
(3) by ammonium octamolybdate, polyether glycol, D-Glucosamine Hydrochloride, sugar alcohol calcium, fulvic acid potassium, aminoacids complex and gross weight 10-12 mineralising activation of small molecule water mixing and stirring doubly, nutritive medium is obtained for subsequent use;
(4) by rice bran, fermented bean dregs, hybrid giant napier powder, eggplant stem powder, the powder of the stem class vegetables and fruits of strong fiber or fermented product, the dish dregs of rice, sprout brown rice co-grinding, cross 20 orders, by crushed material, after mushroom composite powder and gross weight 2.1-2.3 water mixing and stirring doubly, compost maturity 24-30d, wind airing 4-5d opened by rake, evenly be sprinkled into nutritive medium afterwards, admix the chromium heavy metal factor again, negatively charged ion changes the macromole chitosan heavy metal absorbent of surname, 4 times of water diluting solns of propylene glycol alginate, stir, and adjust the 24.3-24.4% that moisture content is gross weight, high-temperature spiral Squeezinggranulator is adopted to manufacture the particle of diameter 2.6-3mm afterwards, obtain.
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| CN201510905350.7A CN105541454A (en) | 2015-12-10 | 2015-12-10 | Efficient fertilizer contributing to reduction of accumulation of chromium heavy metal pollutant in vegetable and preparation method of fertilizer |
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| CN201510905350.7A CN105541454A (en) | 2015-12-10 | 2015-12-10 | Efficient fertilizer contributing to reduction of accumulation of chromium heavy metal pollutant in vegetable and preparation method of fertilizer |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108513877A (en) * | 2018-03-05 | 2018-09-11 | 中国计量大学 | Application of the glycine betaine in reducing Cadmium in Rice accumulation |
| CN108651208A (en) * | 2018-04-09 | 2018-10-16 | 河南中烟工业有限责任公司 | A kind of method of chromium content in reduction tobacco leaf |
| CN111302858A (en) * | 2020-03-09 | 2020-06-19 | 沃博特生物科技有限公司 | Chelation method of medium trace elements in optical carbon ribozyme |
| CN111454103A (en) * | 2020-03-09 | 2020-07-28 | 沃博特生物科技有限公司 | Quick-acting light carbon nuclear enzyme compound fertilizer and preparation method thereof |
| CN111990412A (en) * | 2020-07-21 | 2020-11-27 | 广东拉多美化肥有限公司 | Humic acid composite plant high-temperature-resistant protective agent and preparation method thereof |
| CN112919967A (en) * | 2021-03-02 | 2021-06-08 | 青海高原地沣肥业有限公司 | Method for preparing organic fertilizer from municipal sludge |
| CN115466147A (en) * | 2022-09-05 | 2022-12-13 | 沈阳美华农业科技有限公司 | Efficient fertilizer produced by micro-nano attapulgite and micro-nano carbon sol |
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| CN104230590A (en) * | 2014-08-22 | 2014-12-24 | 合肥四方磷复肥有限责任公司 | Soil-activator-added organic fertilizer and preparation method thereof |
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Patent Citations (5)
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| CN101177360A (en) * | 2007-11-23 | 2008-05-14 | 何章杰 | Method for manufacturing amino acid active fertilizer |
| CN103739411A (en) * | 2014-01-17 | 2014-04-23 | 合肥市东方美捷分子材料技术有限公司 | Preparation method of functional organic fertilizer for soil restoration |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108513877A (en) * | 2018-03-05 | 2018-09-11 | 中国计量大学 | Application of the glycine betaine in reducing Cadmium in Rice accumulation |
| CN108651208A (en) * | 2018-04-09 | 2018-10-16 | 河南中烟工业有限责任公司 | A kind of method of chromium content in reduction tobacco leaf |
| CN108651208B (en) * | 2018-04-09 | 2020-06-23 | 河南中烟工业有限责任公司 | Method for reducing chromium content in tobacco leaves |
| CN111302858A (en) * | 2020-03-09 | 2020-06-19 | 沃博特生物科技有限公司 | Chelation method of medium trace elements in optical carbon ribozyme |
| CN111454103A (en) * | 2020-03-09 | 2020-07-28 | 沃博特生物科技有限公司 | Quick-acting light carbon nuclear enzyme compound fertilizer and preparation method thereof |
| CN111990412A (en) * | 2020-07-21 | 2020-11-27 | 广东拉多美化肥有限公司 | Humic acid composite plant high-temperature-resistant protective agent and preparation method thereof |
| CN111990412B (en) * | 2020-07-21 | 2021-09-03 | 广东拉多美化肥有限公司 | Humic acid composite plant high-temperature-resistant protective agent and preparation method thereof |
| CN112919967A (en) * | 2021-03-02 | 2021-06-08 | 青海高原地沣肥业有限公司 | Method for preparing organic fertilizer from municipal sludge |
| CN112919967B (en) * | 2021-03-02 | 2023-06-13 | 青海高原地沣肥业有限公司 | Method for preparing organic fertilizer from municipal sludge |
| CN115466147A (en) * | 2022-09-05 | 2022-12-13 | 沈阳美华农业科技有限公司 | Efficient fertilizer produced by micro-nano attapulgite and micro-nano carbon sol |
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Application publication date: 20160504 |