CN105462597A - Breathable water retention biological bacterial fertilizer and production method thereof - Google Patents

Breathable water retention biological bacterial fertilizer and production method thereof Download PDF

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Publication number
CN105462597A
CN105462597A CN201410422404.XA CN201410422404A CN105462597A CN 105462597 A CN105462597 A CN 105462597A CN 201410422404 A CN201410422404 A CN 201410422404A CN 105462597 A CN105462597 A CN 105462597A
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parts
water
bacterial manure
mixture
initiator
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CN201410422404.XA
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Inventor
刘泽华
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Qingdao Xin Runtu Nursery Stock Specialty Co-Operative Organization
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Qingdao Xin Runtu Nursery Stock Specialty Co-Operative Organization
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Publication of CN105462597A publication Critical patent/CN105462597A/en
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Abstract

The invention discloses a breathable water retention biological bacterial fertilizer, which comprises the following raw materials by weight: 100 parts of acrylic acid, 15-20 parts of chlorantraniliprole, 6-8 parts of an aqueous emulsion of 2, 5-diketopiperazine derivative, 0.06-0.08 part of an initiator, 0.06-0.08 part of a crosslinking agent, 10-15 part of microbial fermented bacterial liquid, 15-18 parts of attapulgite clay, 6-8 parts of peat, 3-5 parts of bamboo charcoal powder, 0.6-0.8 part of sodium alginate, 0.6-0.8 part of guar gum, 8-12 parts of polyvinyl alcohol, and 4-6 parts of borax. The produced product has both water retention properties and sustained release performance, the pesticide efficacy can be released continuously and stably so as to reach the purposes of economical, safe and effective control of harmful organisms. Active microbial bacteria are added to decompose and transform some substances unabsorbable by crops in soil into nutrients so as to increase production, at the same time, the soil properties are improved, and the crop quality and yield are enhanced.

Description

A kind of ventilative water-maintaining bio-bacterial manure and production method thereof
Technical field
The invention belongs to agricultural chemicals and manufacture technology field thereof, be specifically related to a kind of ventilative water-maintaining bio-bacterial manure.
Background technology
In agriculture production, harmful organism be one of important factor causing grain drop in production, and spraying pesticide be prevention and elimination of disease and pests, improve grain yield, guarantee agricultural high yield effective way.Water-holding agent is a kind of new formulation that can keep soil moisture, improvement soil, and in an especially nearly period, the impact that global arid is brought, demonstrates the importance of water-holding agent development and application more.Existing water-holding agent also exists that Water-saving effect is undesirable, the life-span is short, easy degraded, the shortcoming that stable and salt resistance is poor.There is the shortcomings such as effective constituent release rate is fast, drug effect efficiency time is short, dosage is large in traditional conventional type pesticide preparation, utilization ratio generally only has 20% ~ 30%.In order to maintain certain drug effect, just must spray higher than effective dose of medicine amount, or increase spraying times.Both easily produce poisoning like this, increase pesticide residue, harm humans health, contaminate environment, time-consuming again, very uneconomical.
Therefore, how to produce a kind of ventilative water-maintaining bio-bacterial manure, make the release that agricultural chemicals is continual and steady, the water conservation time is long, to reach most economical, safe, effectively to control the object of harmful organism, by adding living microorganism bacterium, the nonabsorbable material decomposition of some crop in soil is changed into nutritive substance, reach volume increase, have important practical significance.
Summary of the invention
For Problems existing in prior art, the object of the present invention is to provide a kind of ventilative water-maintaining bio-bacterial manure, not only there is water-retentivity but also there is slow-releasing, make the release that pesticide efficacy is continual and steady, reaching most economical, safe, effectively control the object of harmful organism, by adding living microorganism bacterium, the nonabsorbable material decomposition of some crop in soil being changed into nutritive substance, reach volume increase, improve soil function simultaneously, improve crop quality and output.
The technical scheme that the present invention takes is:
A kind of ventilative water-maintaining bio-bacterial manure, it is characterized in that, the weight fraction of raw material is composed as follows:
Water miscible liquid 6-8 part of 100 parts, vinylformic acid, Rynaxypyr 15-20 part, 2,5-Diketopiperazine derivatives, initiator 0.06-0.08 part, linking agent 0.06-0.08 part, fermentable bacterium liquid 10-15 part, attapulgite clay 15-18 part, peat composed of rotten mosses 6-8 part, bamboo charcoal powder 3-5 part, sodium alginate 0.6-0.8 part, guar gum 0.6-0.8 part, polyvinyl alcohol 8-12 part, borax 4-6 part.
Further, described initiator is the mixture that azo two NSC 18620 hydrochloric acid sodium and azo two isobutyl tetrahydroglyoxaline hydrochloric acid sodium form according to weight ratio 2:3.
Further, described linking agent is triallyl ammonio methacrylate and N, N '-methylene-bisacrylamide according to weight ratio be 3:4 composition mixture.
Further, described fermentable bacterium liquid is the genus bacillus of 30-100 hundred million/ml and the bacterium liquid of subtilis mixed preparing by living bacteria count.
A production method for ventilative water-maintaining bio-bacterial manure, is characterized in that, specifically comprise the steps:
(1) internal layer insecticide processed: get the mixing of Rynaxypyr, the water miscible liquid of 2,5-Diketopiperazine derivatives and linking agent according to said ratio, stir, add initiator, be warming up to 65-70 ° of C, slowly add attapulgite clay, dry 25-30min, ground 180 mesh sieves;
(2) water-holding agent processed: vinylformic acid concentration is the potassium hydroxide neutralization of 20%, and make part acrylic acid be converted into potassium acrylate, degree of neutralization is 50-75%, then adds fermentable bacterium liquid successively, mixes;
(3) coated middle level water-retaining film: above-mentioned obtained internal layer insecticide is inserted in granulating disc, spray water-holding agent in tablets press, the peat composed of rotten mosses in 200 mesh sieve holes and the powder mix of bamboo charcoal powder were sprayed in interval, Hot-blast Heating, obtained work in-process;
(4) outer release membranes is sprayed: open air blast feeder, get the mixture of sodium alginate and guar gum on the work in-process rolled, occur slightly being adhered to particle surface, spray the quality hundred number borax soln of specific concentration 5% and the mixture of polyvinyl alcohol again, temperature maintains 50-55 ° of C, Hot-blast Heating is dried, cooling packing.
Beneficial effect of the present invention is:
1, bio-bacterial manure of the present invention forms by three layers; be respectively release membranes, water-retaining film and insecticide from outside to inside; the mixed solvent that release membranes is made up of borax soln and polyvinyl alcohol; the release of farm chemical ingredients can be delayed; improve the utilization ratio of agricultural chemicals; under the protection of internal layer insecticide composition of layer outside, drug effect can be extended.
2, the peat composed of rotten mosses and bamboo charcoal powder act as the function of pharmaceutical carrier, not only have water-retentivity but also have slow-releasing, can absorb water fast and save, and when plant needs, slow releasing again, makes soil keep moistening for a long time, repeatedly can absorb water, discharge water, in addition, this carrier is that fermentable bacterium liquid provides favourable living environment, improves microbic activity, in growing process, the breeding of mushroom in soil can be improved, increase soil fertility.
3, bio-bacterial manure of the present invention can make soil water retention capacity increase after using, water absorbent rate is 250-600g/g, enhance the drought-resistant ability of crop, increase the water retention of soil, keep soil from packing together, this product has good environmental degradability, can improve soil function, improve crop quality and output.
Embodiment
Embodiment 1
A production method for ventilative water-maintaining bio-bacterial manure, is characterized in that, specifically comprise the steps:
(1) internal layer insecticide processed: get Rynaxypyr 15 parts, 2 according to said ratio, the water miscible liquid 6 parts of 5-Diketopiperazine derivative and by triallyl ammonio methacrylate and N, N '-methylene-bisacrylamide is the linking agent 0.06 part mixing of 3:4 composition according to weight ratio, stir, add the initiator 0.06 part be made up of according to weight ratio 2:3 azo two NSC 18620 hydrochloric acid sodium and azo two isobutyl tetrahydroglyoxaline hydrochloric acid sodium, be warming up to 65 ° of C, slowly add attapulgite clay 15 parts, dry 30min, ground 180 mesh sieves;
(2) water-holding agent processed: 100 parts, vinylformic acid is the potassium hydroxide neutralization of 20% by concentration, part acrylic acid is made to be converted into potassium acrylate, degree of neutralization is 50-75%, then adding by living bacteria count is successively the genus bacillus of 30-100 hundred million/ml and the fermentable bacterium liquid 10 parts of subtilis mixed preparing, mixes;
(3) coated middle level water-retaining film: above-mentioned obtained internal layer insecticide is inserted in granulating disc, spray water-holding agent in tablets press, the peat composed of rotten mosses 6 parts in 200 mesh sieve holes, the powder mix of bamboo charcoal powder 3 parts were sprayed in interval, Hot-blast Heating, obtained work in-process;
(4) outer release membranes is sprayed: open air blast feeder, get the mixture of sodium alginate 0.6 part and guar gum 0.6 part on the work in-process rolled, occur slightly being adhered to particle surface, spray the quality hundred number polyvinyl alcohol 8 parts of specific concentration 5% and the mixture of borax 4 parts again, temperature maintains 50 ° of C, Hot-blast Heating is dried, cooling packing.
Embodiment 2
A production method for ventilative water-maintaining bio-bacterial manure, is characterized in that, specifically comprise the steps:
(1) internal layer insecticide processed: get Rynaxypyr 18 parts, 2 according to said ratio, the water miscible liquid 7 parts of 5-Diketopiperazine derivative and by triallyl ammonio methacrylate and N, N '-methylene-bisacrylamide is the linking agent 0.07 part mixing of 3:4 composition according to weight ratio, stir, add the initiator 0.07 part be made up of according to weight ratio 2:3 azo two NSC 18620 hydrochloric acid sodium and azo two isobutyl tetrahydroglyoxaline hydrochloric acid sodium, be warming up to 68 ° of C, slowly add attapulgite clay 16 parts, dry 28min, ground 180 mesh sieves;
(2) water-holding agent processed: 100 parts, vinylformic acid is the potassium hydroxide neutralization of 20% by concentration, part acrylic acid is made to be converted into potassium acrylate, degree of neutralization is 65%, then adding by living bacteria count is successively the genus bacillus of 30-100 hundred million/ml and the fermentable bacterium liquid 12 parts of subtilis mixed preparing, mixes;
(3) coated middle level water-retaining film: above-mentioned obtained internal layer insecticide is inserted in granulating disc, spray water-holding agent in tablets press, the peat composed of rotten mosses 7 parts in 200 mesh sieve holes, the powder mix of bamboo charcoal powder 4 parts were sprayed in interval, Hot-blast Heating, obtained work in-process;
(4) outer release membranes is sprayed: open air blast feeder, get the mixture of sodium alginate 0.7 part and guar gum 0.7 part on the work in-process rolled, occur slightly being adhered to particle surface, spray the quality hundred number polyvinyl alcohol 10 parts of specific concentration 5% and the mixture of borax 5 parts again, temperature maintains 53 ° of C, Hot-blast Heating is dried, cooling packing.
Embodiment 3.
A production method for ventilative water-maintaining bio-bacterial manure, is characterized in that, specifically comprise the steps:
(1) internal layer insecticide processed: get Rynaxypyr 20 parts, 2 according to said ratio, the water miscible liquid 8 parts of 5-Diketopiperazine derivative and by triallyl ammonio methacrylate and N, N '-methylene-bisacrylamide is the linking agent 0.08 part mixing of 3:4 composition according to weight ratio, stir, add the initiator 0.08 part be made up of according to weight ratio 2:3 azo two NSC 18620 hydrochloric acid sodium and azo two isobutyl tetrahydroglyoxaline hydrochloric acid sodium, be warming up to 65-70 ° of C, slowly add attapulgite clay 18 parts, dry 25min, ground 180 mesh sieves;
(2) water-holding agent processed: 100 parts, vinylformic acid is the potassium hydroxide neutralization of 20% by concentration, part acrylic acid is made to be converted into potassium acrylate, degree of neutralization is 50-75%, then adding by living bacteria count is successively the genus bacillus of 30-100 hundred million/ml and the fermentable bacterium liquid 15 parts of subtilis mixed preparing, mixes;
(3) coated middle level water-retaining film: above-mentioned obtained internal layer insecticide is inserted in granulating disc, spray water-holding agent in tablets press, the peat composed of rotten mosses 8 parts in 200 mesh sieve holes, the powder mix of bamboo charcoal powder 5 parts were sprayed in interval, Hot-blast Heating, obtained work in-process;
(4) outer release membranes is sprayed: open air blast feeder, get the mixture of sodium alginate 0.8 part and guar gum 0.8 part on the work in-process rolled, occur slightly being adhered to particle surface, spray the quality hundred number polyvinyl alcohol 12 parts of specific concentration 5% and the mixture of borax 6 parts again, temperature maintains 55 ° of C, Hot-blast Heating is dried, cooling packing.
Adopt the water-maintaining bio-bacterial manure that described in embodiment 2 prepared by method to carry out water conservation test, obtain the water evaporation rate under different time, the results are shown in Table 1.
Table 1
Time/sky 1 2 4 6 8 10 15 20 25 30
Release rate/% 3.2 8.0 15.4 25.0 38.5 51.0 74.2 86.0 94.1 99.8

Claims (5)

1. a ventilative water-maintaining bio-bacterial manure, is characterized in that, the weight fraction of raw material is composed as follows:
Water miscible liquid 6-8 part of 100 parts, vinylformic acid, Rynaxypyr 15-20 part, 2,5-Diketopiperazine derivatives, initiator 0.06-0.08 part, linking agent 0.06-0.08 part, fermentable bacterium liquid 10-15 part, attapulgite clay 15-18 part, peat composed of rotten mosses 6-8 part, bamboo charcoal powder 3-5 part, sodium alginate 0.6-0.8 part, guar gum 0.6-0.8 part, polyvinyl alcohol 8-12 part, borax 4-6 part.
2. a kind of ventilative water-maintaining bio-bacterial manure according to claim 1, it is characterized in that, described initiator is the mixture that azo two NSC 18620 hydrochloric acid sodium and azo two isobutyl tetrahydroglyoxaline hydrochloric acid sodium form according to weight ratio 2:3.
3. a kind of ventilative water-maintaining bio-bacterial manure according to claim 1, it is characterized in that, described linking agent is triallyl ammonio methacrylate and N, N '-methylene-bisacrylamide is the mixture of 3:4 composition according to weight ratio.
4. a kind of ventilative water-maintaining bio-bacterial manure according to claim 1, is characterized in that, described fermentable bacterium liquid is the genus bacillus of 30-100 hundred million/ml and the bacterium liquid of subtilis mixed preparing by living bacteria count.
5. a production method for ventilative water-maintaining bio-bacterial manure, is characterized in that, specifically comprise the steps:
(1) internal layer insecticide processed: get the mixing of Rynaxypyr, the water miscible liquid of 2,5-Diketopiperazine derivatives and linking agent according to said ratio, stir, add initiator, be warming up to 65-70 ° of C, slowly add attapulgite clay, dry 25-30min, ground 180 mesh sieves;
(2) water-holding agent processed: vinylformic acid concentration is the potassium hydroxide neutralization of 20%, and make part acrylic acid be converted into potassium acrylate, degree of neutralization is 50-75%, then adds fermentable bacterium liquid successively, mixes;
(3) coated middle level water-retaining film: above-mentioned obtained internal layer insecticide is inserted in granulating disc, spray water-holding agent in tablets press, the peat composed of rotten mosses in 200 mesh sieve holes and the powder mix of bamboo charcoal powder were sprayed in interval, Hot-blast Heating, obtained work in-process;
(4) outer release membranes is sprayed: open air blast feeder, get the mixture of sodium alginate and guar gum on the work in-process rolled, occur slightly being adhered to particle surface, spray the quality hundred number borax soln of specific concentration 5% and the mixture of polyvinyl alcohol again, temperature maintains 50-55 ° of C, Hot-blast Heating is dried, cooling packing.
CN201410422404.XA 2014-08-26 2014-08-26 Breathable water retention biological bacterial fertilizer and production method thereof Pending CN105462597A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106676049A (en) * 2017-03-03 2017-05-17 广西壮族自治区农业科学院生物技术研究所 Bacillus amyloliquefaciens strain and application thereof
CN110432266A (en) * 2019-08-28 2019-11-12 山东辉瀚生物科技有限公司 A kind of high-efficiency sustained-release pesticide and its production technology
CN111057553A (en) * 2018-10-17 2020-04-24 武汉市秀谷科技有限公司 Cadmium and arsenic composite pollution passivator for farmland, preparation method and use method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1587211A (en) * 2004-09-20 2005-03-02 中国农业科学院土壤肥料研究所 Process for producing water preserving type film coated urea fertilizer
CN101125782A (en) * 2007-09-07 2008-02-20 扬州苏扬农业发展有限公司 Rice seed dressing medicament fertilizer ground substance and its seed dressing medicament fertilizer formulation and preparation method
CN101463247A (en) * 2007-12-21 2009-06-24 中国科学院沈阳应用生态研究所 Composite type soil water retention agent and preparation
CN102391057A (en) * 2011-08-03 2012-03-28 广州普邦园林股份有限公司 Inorganic-organic slow-acting fertilizer suitable for landscaping nursery stocks and preparation method and application thereof
CN102584477A (en) * 2012-03-27 2012-07-18 贾洪涛 Slowly-releasing water conservation biological organic and inorganic compound fertilizer particles and production method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1587211A (en) * 2004-09-20 2005-03-02 中国农业科学院土壤肥料研究所 Process for producing water preserving type film coated urea fertilizer
CN101125782A (en) * 2007-09-07 2008-02-20 扬州苏扬农业发展有限公司 Rice seed dressing medicament fertilizer ground substance and its seed dressing medicament fertilizer formulation and preparation method
CN101463247A (en) * 2007-12-21 2009-06-24 中国科学院沈阳应用生态研究所 Composite type soil water retention agent and preparation
CN102391057A (en) * 2011-08-03 2012-03-28 广州普邦园林股份有限公司 Inorganic-organic slow-acting fertilizer suitable for landscaping nursery stocks and preparation method and application thereof
CN102584477A (en) * 2012-03-27 2012-07-18 贾洪涛 Slowly-releasing water conservation biological organic and inorganic compound fertilizer particles and production method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106676049A (en) * 2017-03-03 2017-05-17 广西壮族自治区农业科学院生物技术研究所 Bacillus amyloliquefaciens strain and application thereof
CN106676049B (en) * 2017-03-03 2020-07-14 广西壮族自治区农业科学院生物技术研究所 Bacillus amyloliquefaciens and application thereof
CN111057553A (en) * 2018-10-17 2020-04-24 武汉市秀谷科技有限公司 Cadmium and arsenic composite pollution passivator for farmland, preparation method and use method thereof
CN110432266A (en) * 2019-08-28 2019-11-12 山东辉瀚生物科技有限公司 A kind of high-efficiency sustained-release pesticide and its production technology

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