CN1054613C - 橡胶改性的苯乙烯类树脂组合物 - Google Patents
橡胶改性的苯乙烯类树脂组合物 Download PDFInfo
- Publication number
- CN1054613C CN1054613C CN93105230A CN93105230A CN1054613C CN 1054613 C CN1054613 C CN 1054613C CN 93105230 A CN93105230 A CN 93105230A CN 93105230 A CN93105230 A CN 93105230A CN 1054613 C CN1054613 C CN 1054613C
- Authority
- CN
- China
- Prior art keywords
- styrene
- weight
- rubber
- particle
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 246
- 239000005060 rubber Substances 0.000 title claims abstract description 157
- 229920001890 Novodur Polymers 0.000 title abstract 3
- 239000011342 resin composition Substances 0.000 title abstract 3
- 239000002245 particle Substances 0.000 claims abstract description 353
- 229920000642 polymer Polymers 0.000 claims abstract description 127
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 41
- 230000001186 cumulative effect Effects 0.000 claims abstract description 20
- 229920001519 homopolymer Polymers 0.000 claims abstract description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 371
- 239000000805 composite resin Substances 0.000 claims description 85
- 238000006243 chemical reaction Methods 0.000 claims description 71
- 239000002775 capsule Substances 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 22
- 238000012935 Averaging Methods 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 19
- 238000006116 polymerization reaction Methods 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 9
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 3
- 230000005484 gravity Effects 0.000 claims description 3
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims 1
- 238000010298 pulverizing process Methods 0.000 claims 1
- 239000005062 Polybutadiene Substances 0.000 abstract description 6
- 229920002857 polybutadiene Polymers 0.000 abstract description 6
- 239000000178 monomer Substances 0.000 abstract description 4
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 72
- 230000000052 comparative effect Effects 0.000 description 59
- 239000011347 resin Substances 0.000 description 56
- 229920005989 resin Polymers 0.000 description 32
- 239000000243 solution Substances 0.000 description 29
- 235000013339 cereals Nutrition 0.000 description 24
- 230000035939 shock Effects 0.000 description 21
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 18
- 238000011156 evaluation Methods 0.000 description 15
- 238000000635 electron micrograph Methods 0.000 description 12
- 230000001105 regulatory effect Effects 0.000 description 8
- 230000003247 decreasing effect Effects 0.000 description 7
- 238000002156 mixing Methods 0.000 description 6
- 238000012986 modification Methods 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 230000000704 physical effect Effects 0.000 description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
- 229920002554 vinyl polymer Polymers 0.000 description 5
- 238000012662 bulk polymerization Methods 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 238000004898 kneading Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 150000005194 ethylbenzenes Chemical class 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 150000003440 styrenes Chemical class 0.000 description 3
- FUGYGGDSWSUORM-UHFFFAOYSA-N 4-hydroxystyrene Chemical compound OC1=CC=C(C=C)C=C1 FUGYGGDSWSUORM-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- GVOBUBSHVYUNJC-UHFFFAOYSA-N 1,2-dichlorobenzene ethene Chemical compound C=C.ClC1=C(C=CC=C1)Cl GVOBUBSHVYUNJC-UHFFFAOYSA-N 0.000 description 1
- HLOUDBQOEJSUPI-UHFFFAOYSA-N 1-ethenyl-2,3-dimethylbenzene Chemical compound CC1=CC=CC(C=C)=C1C HLOUDBQOEJSUPI-UHFFFAOYSA-N 0.000 description 1
- LUECERFWADIZPD-UHFFFAOYSA-N 1-tert-butyl-2-ethenylbenzene Chemical compound CC(C)(C)C1=CC=CC=C1C=C LUECERFWADIZPD-UHFFFAOYSA-N 0.000 description 1
- NJOLLDDWCSUSCA-UHFFFAOYSA-N C=C.BrC=1C(=C(C=CC1)Br)Br Chemical compound C=C.BrC=1C(=C(C=CC1)Br)Br NJOLLDDWCSUSCA-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- SQHOHKQMTHROSF-UHFFFAOYSA-N but-1-en-2-ylbenzene Chemical compound CCC(=C)C1=CC=CC=C1 SQHOHKQMTHROSF-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- SFBTTWXNCQVIEC-UHFFFAOYSA-N o-Vinylanisole Chemical compound COC1=CC=CC=C1C=C SFBTTWXNCQVIEC-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920000555 poly(dimethylsilanediyl) polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- XNYYNDAEXFUXBD-UHFFFAOYSA-N tert-butylbenzene ethene Chemical compound C=C.C(C)(C)(C)C1=CC=CC=C1 XNYYNDAEXFUXBD-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/902—Core-shell
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP65051/92 | 1992-03-23 | ||
| JP65051/1992 | 1992-03-23 | ||
| JP6505192 | 1992-03-23 | ||
| JP79712/92 | 1992-04-01 | ||
| JP79712/1992 | 1992-04-01 | ||
| JP7971292 | 1992-04-01 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1082564A CN1082564A (zh) | 1994-02-23 |
| CN1054613C true CN1054613C (zh) | 2000-07-19 |
Family
ID=26406194
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN93105230A Expired - Fee Related CN1054613C (zh) | 1992-03-23 | 1993-03-23 | 橡胶改性的苯乙烯类树脂组合物 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5473014A (enExample) |
| EP (1) | EP0562804B1 (enExample) |
| KR (1) | KR960006159B1 (enExample) |
| CN (1) | CN1054613C (enExample) |
| DE (1) | DE69306628T2 (enExample) |
| TW (1) | TW289039B (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5428106A (en) * | 1993-09-02 | 1995-06-27 | The Dow Chemical Company | Rubber modified polystyrene |
| US6011117A (en) * | 1997-02-11 | 2000-01-04 | Basf Corporation | High gloss, high impact polystyrene composition |
| US7875678B2 (en) * | 2005-04-15 | 2011-01-25 | Chevron Phillips Cheimcal Company, LP | Process for making high impact strength polystyrene and related compositions |
| EP3057067B1 (en) * | 2015-02-16 | 2017-08-23 | Thomson Licensing | Device and method for estimating a glossy part of radiation |
| KR102651969B1 (ko) * | 2017-07-19 | 2024-03-26 | 니폰 제온 가부시키가이샤 | 폼 러버의 제조 방법 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0390508A1 (en) * | 1989-03-31 | 1990-10-03 | Idemitsu Petrochemical Company Limited | Styrene-based resin composition |
| EP0429986A2 (en) * | 1989-11-20 | 1991-06-05 | Idemitsu Petrochemical Co. Ltd. | Process for production of styrene-based resin composition |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5221095A (en) * | 1975-07-21 | 1977-02-17 | Asahi Chem Ind Co Ltd | Preparation of high-impact styrene polymer with outstanding appearance |
| DE3035570A1 (de) * | 1980-09-20 | 1982-05-06 | Basf Ag, 6700 Ludwigshafen | Schlagfeste thermoplastische formmasse |
| JPS5796006A (en) * | 1980-12-05 | 1982-06-15 | Mitsui Toatsu Chem Inc | Production of rubber-modified styrene resin |
| NL8202281A (nl) * | 1982-06-04 | 1984-01-02 | Dow Chemical Nederland | Met rubber versterkte polymeren van aromatische monovinylideenverbindingen en werkwijze voor de bereiding daarvan. |
| JPS5984912A (ja) * | 1982-11-04 | 1984-05-16 | Mitsui Toatsu Chem Inc | ゴム変性耐衝撃性樹脂の連続的製造方法 |
| NL8304029A (nl) * | 1983-11-23 | 1985-06-17 | Dow Chemical Nederland | Met rubber versterkte polymeren van monovinylideen-aromatische verbindingen met een zeer goede verhouding tussen glans en sterkteeigenschappen en een werkwijze voor hun bereiding. |
| DE3510877A1 (de) * | 1985-03-26 | 1986-10-02 | Basf Ag, 6700 Ludwigshafen | Schlagfeste und transluzente formmasse |
| JPS6348317A (ja) * | 1986-08-18 | 1988-03-01 | Asahi Chem Ind Co Ltd | 耐衝撃性ポリスチレン系樹脂およびその製造方法 |
| JPH01261444A (ja) * | 1988-04-11 | 1989-10-18 | Asahi Chem Ind Co Ltd | 光沢と耐衝撃性に優れたポリスチレン樹脂組成物 |
| JPS63112646A (ja) * | 1986-10-29 | 1988-05-17 | Asahi Chem Ind Co Ltd | 高光沢耐衝撃性ポリスチレン樹脂組成物 |
| JPH0676464B2 (ja) * | 1987-03-28 | 1994-09-28 | 出光石油化学株式会社 | スチレン系樹脂の製造方法 |
| JPS6474209A (en) * | 1987-09-17 | 1989-03-20 | Nippon Elastomer Kk | Impact-resistant styrenic resin and manufacture thereof |
| US4839418A (en) * | 1988-01-05 | 1989-06-13 | Basf Aktiengesellschaft | Thermoplastic molding materials and their preparation |
| US5210132A (en) * | 1988-12-28 | 1993-05-11 | Mitsui Toatsu Chemicals, Inc. | Continuous process for preparing rubber modified high impact resin |
| US5180780A (en) * | 1989-01-12 | 1993-01-19 | Idemitsu Petrochemical Company Limited | Rubber-modified styrene-based copolymer |
-
1993
- 1993-03-18 US US08/034,411 patent/US5473014A/en not_active Expired - Fee Related
- 1993-03-22 DE DE69306628T patent/DE69306628T2/de not_active Expired - Fee Related
- 1993-03-22 EP EP93302174A patent/EP0562804B1/en not_active Expired - Lifetime
- 1993-03-22 KR KR1019930004404A patent/KR960006159B1/ko not_active Expired - Fee Related
- 1993-03-23 CN CN93105230A patent/CN1054613C/zh not_active Expired - Fee Related
- 1993-04-20 TW TW082103021A patent/TW289039B/zh active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0390508A1 (en) * | 1989-03-31 | 1990-10-03 | Idemitsu Petrochemical Company Limited | Styrene-based resin composition |
| EP0429986A2 (en) * | 1989-11-20 | 1991-06-05 | Idemitsu Petrochemical Co. Ltd. | Process for production of styrene-based resin composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1082564A (zh) | 1994-02-23 |
| KR960006159B1 (ko) | 1996-05-09 |
| EP0562804A1 (en) | 1993-09-29 |
| TW289039B (enExample) | 1996-10-21 |
| DE69306628T2 (de) | 1997-07-10 |
| DE69306628D1 (de) | 1997-01-30 |
| US5473014A (en) | 1995-12-05 |
| KR930019753A (ko) | 1993-10-18 |
| EP0562804B1 (en) | 1996-12-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Applicant after: Mitsui Chemical Industry Co., Ltd. Applicant before: Mitsui Toatsu Chem. Inc. |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: MITSUI TOATSU CHEMICALS, LTD. TO: MITSUI CHEMICALS, INC. |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |