CN1054591C - Magic stone ceramic tile made by the process of infiltration - Google Patents
Magic stone ceramic tile made by the process of infiltration Download PDFInfo
- Publication number
- CN1054591C CN1054591C CN96116361A CN96116361A CN1054591C CN 1054591 C CN1054591 C CN 1054591C CN 96116361 A CN96116361 A CN 96116361A CN 96116361 A CN96116361 A CN 96116361A CN 1054591 C CN1054591 C CN 1054591C
- Authority
- CN
- China
- Prior art keywords
- ceramic tile
- percolating solution
- stone ceramic
- making method
- coloured
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5007—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with salts or salty compositions, e.g. for salt glazing
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Finishing Walls (AREA)
Abstract
The present invention provides a method for preparing magic stone ceramic tile with natural cloud and mist without using wire-mesh screens and other supplementary means, which comprises the following steps: multiple-color osmosis solution is sprayed on the surface of a body; then, the sprayed body is baked at the temperature of baking a temp lower than 200 DEG C until water content is less than 1%; the baked body is sintered into a tile with the osmosis thickness of at least 1mm at the temperature of 1000 to 1350 DEG C; the tile is polished after being cooled so that a mirror stone ceramic tile can be prepared. The grinding depth is less than 1mm.
Description
The present invention relates to colorful ceramic wall and floor bricks and production method thereof, be specifically related to the cloud and mist magic type stone ceramic tile that osmosis process is made.
The applicant is in Chinese patent application CN90106500.5, a kind of ceramic and method for making thereof of high permeability coloring have been disclosed, system imposes on billet surface by colored drawing or silk screen printing with high permeability coloring solution, through burning till, polishing, makes the pervious course thickness above ceramic of 1mm at least.When making, it need adopt silk screen or other supplementary means to obtain pattern effect, so production efficiency is lower, the pattern of goods is more stiff, and is not smooth.
In order to overcome above-mentioned shortcoming, the purpose of this invention is to provide does not a kind ofly need to utilize any silk screen or other supplementary means to carry out design producing, and the goods pattern has the natural characteristic and the manufacture craft like the stone ceramic tile of the hazy and illusionary type of cloud and mist of randomness to a certain degree.
Above-mentioned purpose of the present invention realizes in the following manner: a kind of making method of cloud and mist magic type stone ceramic tile, the billet surface that is included in ceramic once sprays the percolating solution of multiple coloring element compound, after the drying, between 1000 °-1350 ℃, burn till, described coloring element comprises the solution of the compound of Co, Cr, Fe, Mn, Ce, Cd, Au, Nd, Ni, Pr, V and/or Zr, add or do not add comprise be selected from the glycerine auxiliary agent in the presence of, bedye in the billet surface of ceramic.The compound of described coloring element is selected from water dissolved or dissolved comprises described coloring element in other organic solvent nitrate, vitriol, muriate, carbonate, or other organic compound.
It is characterized in that described polychrome percolating solution adopts a plurality of shower nozzles once to directly spray in green compact or biscuit surface.
Its feature is that also the decorative pattern of described ceramic and/or the pervious course thickness of color are at least 1mm.
Advantage of the present invention is tangible: the cloud and mist magic type stone ceramic tile that the present invention makes has the polychrome pool pattern of the hazy and illusionary shape of cloud and mist of nature, the surface shows bright mirrored effect after polishing, overcome the wall floor tile color and luster of other method making and the shortcoming of dull image.The ceramic tile that the present invention makes has good quality, and intensity is higher than natural granite, and Mohs' hardness reaches 8, and wear resistance is good, and water-intake rate is low, and freeze proof, corrosion resistant has very strong sight and practicality.Owing to adopt the once polychrome percolating solution of spraying, be penetrated into base substrate inside and be integral with blank sintering, the kind of color and luster and the degree of depth can be regulated within the specific limits, utilize the polychrome percolating solution once to spray, save silk screen printing and supplementary means, improved production efficiency.Owing to the blending that interpenetrates of solution, like the artistic characteristics of hazy and illusionary shape, this is to adopt the unapproachable boundary of any other technology again for phase mapping of a set onto another brightness, formationization cloud and mist.
The present invention is described in further detail below with reference to embodiment.
Described in an embodiment dye penetrating solution is to contain the metal-salt of transition element and an amount of auxiliary agent composition, and the pH value of penetrating fluid is controlled in the 5-8 scope.After the metal-salt of transition element infiltrates adobe, produce various color and lusters after high temperature burns till, they are selected from the salt of one or more metallic elements that comprise Co, Cr, Fe, Mn, Ce, Cd, Au, Nd, Ni, Pr, V and/or Zr.
The effect of auxiliary agent is the surface tension that reduces penetrating fluid, improves the wettability on adobe surface, and add-on what can utilize, and regulates infiltration and depth of color within the specific limits.
Implement among the present invention, can adopt the equipment that a plurality of nozzles are housed, utilize shower nozzle once one or more penetrating fluid sprays to be watered on the adobe surface in process of production, adobe spray water the back less than 200 ℃ dry to moisture content less than 1% scope, burn till at 1000 °-1350 ℃ again, after the cooling, polish, make the minute surface stone ceramic tile.Embodiment:
1. base substrate can be used in below 200 ℃ or at 600 ℃ of left and right sides unglazed green compact.
2. will be selected from above-mentioned transition element metal-salt and an amount of glycerine auxiliary agent is mixed with the percolating solution that is dissolvable in water water, the concentration of percolating solution can be regulated arbitrarily until saturation concentration, and the pH value of penetrating fluid is controlled at the 5-8 scope.
3. above-mentioned coloring solution is sprayed or atomizing by selected arbitrarily pouring glaze device, once spray one or more coloured percolating solutions on billet surface, in dry below 200 ℃ to moisture content less than 1%, burn till the pervious course thickness ceramic tile of 1mm at least at 1000 °-1350 ℃ again, ceramic tile can further polish, grinding depth is made brick with smooth surface less than 1mm.
Claims (4)
1. the making method of a cloud and mist magic type stone ceramic tile, its feature is included in below 200 ℃ or on 600 ℃ of left and right sides unglazed base substrates and once sprays multiple coloured percolating solution on billet surface, then dry below 200 ℃ to moisture content less than 1%, burn till the pervious course thickness ceramic tile of 1mm at least at 1000 ℃～1350 ℃ again, cooling, polishing promptly make product; Described coloured percolating solution is selected from one or more metallic salts that comprise Co, Cr, Fe, Mn, Ce, Cd, Au, Nd, Ni, Pr, V and/or Zr, described metallic salt is selected from water dissolved or dissolved comprises described metallic element in other organic solvent nitrate, vitriol, muriate, carbonate, or other organic compound.
2. making method as claimed in claim 1 is characterized in that described polychrome percolating solution adopts a plurality of shower nozzles once to spray in billet surface.
3. method as claimed in claim 1 or 2 is characterized in that described pervious course thickness is at least 1mm.
4. making method as claimed in claim 1 is characterized in that described coloured percolating solution also can add glycerine auxiliary agent and water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96116361A CN1054591C (en) | 1996-05-17 | 1996-05-17 | Magic stone ceramic tile made by the process of infiltration |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96116361A CN1054591C (en) | 1996-05-17 | 1996-05-17 | Magic stone ceramic tile made by the process of infiltration |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1165796A CN1165796A (en) | 1997-11-26 |
| CN1054591C true CN1054591C (en) | 2000-07-19 |
Family
ID=5123473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96116361A Expired - Fee Related CN1054591C (en) | 1996-05-17 | 1996-05-17 | Magic stone ceramic tile made by the process of infiltration |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1054591C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102795892B (en) * | 2012-09-10 | 2014-07-02 | 杭州诺贝尔陶瓷有限公司 | Soluble salt ceramic tile and production method thereof |
| CN104829266B (en) * | 2015-04-17 | 2017-06-13 | 无锡工艺职业技术学院 | A kind of non-manufacture method for smoking salt glaze ceramics |
| CN108975892B (en) * | 2018-08-27 | 2021-01-22 | 佛山石湾鹰牌陶瓷有限公司 | Method for preparing ink-jet flower-penetrating jade polished brick and ink-jet flower-penetrating jade polished brick |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1062891A (en) * | 1990-12-29 | 1992-07-22 | 泰山陶瓷有限公司 | The ceramic of high permeability coloring and method for making thereof |
-
1996
- 1996-05-17 CN CN96116361A patent/CN1054591C/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1062891A (en) * | 1990-12-29 | 1992-07-22 | 泰山陶瓷有限公司 | The ceramic of high permeability coloring and method for making thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1165796A (en) | 1997-11-26 |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |